Pub Date : 2023-05-04DOI: 10.1142/s1088424623500992
Luca J. Zocchi, Willow A. Davis, L. Zakharov, Darren W. Johnson
{"title":"Expanding pnictogen-assisted self-assembly of disulfide macrocycles to include heteroarenes","authors":"Luca J. Zocchi, Willow A. Davis, L. Zakharov, Darren W. Johnson","doi":"10.1142/s1088424623500992","DOIUrl":"https://doi.org/10.1142/s1088424623500992","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49430156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-04DOI: 10.1142/s1088424623500980
H. Uno, S. Hata, Kohei Hashimoto, Kota Muramatsu, H. Nakano, Takahiro Takiue, Hiroki Uoyama, Yuma Tanioka, Shigeki Mori, T. Okujima, M. Takase
{"title":"Benzene-crosslinked hexaphyrin: Molecules of benzene in hexaphyrin","authors":"H. Uno, S. Hata, Kohei Hashimoto, Kota Muramatsu, H. Nakano, Takahiro Takiue, Hiroki Uoyama, Yuma Tanioka, Shigeki Mori, T. Okujima, M. Takase","doi":"10.1142/s1088424623500980","DOIUrl":"https://doi.org/10.1142/s1088424623500980","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42436201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-04DOI: 10.1142/s1088424623500955
D. Serrano-Molina, M. González-Sánchez, Alberto de Juan, M. Mayoral, D. González‐Rodríguez
{"title":"Watson-Crick hydrogen-bonded macrocycles self-assembled from Z-shaped dinucleoside monomers","authors":"D. Serrano-Molina, M. González-Sánchez, Alberto de Juan, M. Mayoral, D. González‐Rodríguez","doi":"10.1142/s1088424623500955","DOIUrl":"https://doi.org/10.1142/s1088424623500955","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49602996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-04DOI: 10.1142/s108842462350092x
Vasilis Nikolaou, J. W. Wood, Georgios Charalambidis, A. Coutsolelos, E. Stulz
{"title":"Post-synthetic DNA modification with porphyrins for DNA-templated supramolecular assemblies","authors":"Vasilis Nikolaou, J. W. Wood, Georgios Charalambidis, A. Coutsolelos, E. Stulz","doi":"10.1142/s108842462350092x","DOIUrl":"https://doi.org/10.1142/s108842462350092x","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48962863","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-05-04DOI: 10.1142/s1088424623500967
Bentian Xiao, W. R. Osterloh, Xiao-Meng Lv, Yuanyuan Fang, Daiki Kuzuhara, N. Aratani, H. Yamada, F. Qiu, Songlin Xue, K. Kadish
{"title":"Synthesis, characterization and electrochemistry of mono- and dirhodium(I) meso-diaryl dibenzoporphyrin(2.1.2.1) complexes","authors":"Bentian Xiao, W. R. Osterloh, Xiao-Meng Lv, Yuanyuan Fang, Daiki Kuzuhara, N. Aratani, H. Yamada, F. Qiu, Songlin Xue, K. Kadish","doi":"10.1142/s1088424623500967","DOIUrl":"https://doi.org/10.1142/s1088424623500967","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41953154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Near-infrared light-induced phototherapy including photothermal therapy (PTT) and photodynamic therapy (PDT) has emerged as a new noninvasive method for cancer treatment owing to the nature of high efficiency and spatiotemporal selectivity. In this study, a new boron-dipyrromethene (BODIPY) molecule (BDP-BT) with donor (D)-receptor (A)-donor (D) structure was designed and successfully synthesized by conjugation of benzothiadiazole (BT) with BODIPY structure. The polyethylene glycol chain (PEG) was modified onto the meso site of BODIPY to improve the hydrophilicity and biocompatibility of the compound. The amphiphilic BDP-BT was then self-assembled into nanoparticles (BDP-BT NPs) with red-shifted absorption and enhanced hydrophilicity. BDP-BT NPs can produce effective reactive oxygen species and local hyperthermia triggered by a single laser. The in vitro experiments revealed that BDP-BT NPs had good biocompatibility and remarkable photocytoxicity. The half maximal inhibitory concentration (IC[Formula: see text] of BDP-BT NPs was valued at 22.17 [Formula: see text]g/mL under 635 nm laser irradiation. Furthermore, BDP-BT NPs can efficiently generate reactive oxygen species (ROS) in the tumor cells under light irradiation. Thus, the as-prepared BDP-BT NPs could be used as promising agents for PDT and PTT synergistic cancer therapy.
{"title":"Organic nanomaterials from self-assembly of BODIPY-benzothiadiazole conjugate for PDT/PTT synergistic therapy","authors":"Qilong Sha, Jingran Deng, Huishuang Zhang, Xiao-Fei Luo, Fengshou Wu","doi":"10.1142/s1088424623500621","DOIUrl":"https://doi.org/10.1142/s1088424623500621","url":null,"abstract":"Near-infrared light-induced phototherapy including photothermal therapy (PTT) and photodynamic therapy (PDT) has emerged as a new noninvasive method for cancer treatment owing to the nature of high efficiency and spatiotemporal selectivity. In this study, a new boron-dipyrromethene (BODIPY) molecule (BDP-BT) with donor (D)-receptor (A)-donor (D) structure was designed and successfully synthesized by conjugation of benzothiadiazole (BT) with BODIPY structure. The polyethylene glycol chain (PEG) was modified onto the meso site of BODIPY to improve the hydrophilicity and biocompatibility of the compound. The amphiphilic BDP-BT was then self-assembled into nanoparticles (BDP-BT NPs) with red-shifted absorption and enhanced hydrophilicity. BDP-BT NPs can produce effective reactive oxygen species and local hyperthermia triggered by a single laser. The in vitro experiments revealed that BDP-BT NPs had good biocompatibility and remarkable photocytoxicity. The half maximal inhibitory concentration (IC[Formula: see text] of BDP-BT NPs was valued at 22.17 [Formula: see text]g/mL under 635 nm laser irradiation. Furthermore, BDP-BT NPs can efficiently generate reactive oxygen species (ROS) in the tumor cells under light irradiation. Thus, the as-prepared BDP-BT NPs could be used as promising agents for PDT and PTT synergistic cancer therapy.","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49206939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-11DOI: 10.1142/s1088424623500682
Prachi Varshney, Amit Kumar, S. Sujesh, Svastik Jaiswal, J. Sankar
First-row transition metal complexes derived from corrole-based ligands are considered efficient catalysts for hydrogen evolution reaction (HER). They are known to enhance the rate of hydrogen production by lowering the energy barrier in the water-splitting process. Here, the synthesis and characterization of a copper corrole complex (CuN2CA) having amine functionality on corrole has been reported. This complex is immobilized onto reduced graphene oxide (CuN2CA-rGO) that exhibited excellent electrocatalytic activity towards hydrogen evolution reaction (HER) with a significantly lower onset potential of -0.57 V vs. NHE efficiency of the corrole complex has significantly been improved when combined with reduced graphene oxide (rGO).
{"title":"Copper corrole immobilized onto reduced graphene oxide: An efficient electrocatalyst for hydrogen evolution reaction","authors":"Prachi Varshney, Amit Kumar, S. Sujesh, Svastik Jaiswal, J. Sankar","doi":"10.1142/s1088424623500682","DOIUrl":"https://doi.org/10.1142/s1088424623500682","url":null,"abstract":"First-row transition metal complexes derived from corrole-based ligands are considered efficient catalysts for hydrogen evolution reaction (HER). They are known to enhance the rate of hydrogen production by lowering the energy barrier in the water-splitting process. Here, the synthesis and characterization of a copper corrole complex (CuN2CA) having amine functionality on corrole has been reported. This complex is immobilized onto reduced graphene oxide (CuN2CA-rGO) that exhibited excellent electrocatalytic activity towards hydrogen evolution reaction (HER) with a significantly lower onset potential of -0.57 V vs. NHE efficiency of the corrole complex has significantly been improved when combined with reduced graphene oxide (rGO).","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44285987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-05DOI: 10.1142/s1088424623500852
Pinky Chauhan, K. C. Behera, M. Ravikanth
{"title":"Synthesis and aggregation-induced emission properties of α-perimidinyl 3-pyrrolyl BODIPY","authors":"Pinky Chauhan, K. C. Behera, M. Ravikanth","doi":"10.1142/s1088424623500852","DOIUrl":"https://doi.org/10.1142/s1088424623500852","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45452559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and properties of 5,10-calixphyrin and its palladium-inserted complex","authors":"Zhengxin Kang, Long Wang, Zhongxin Li, Qinghua Wu, Ying Wei, Huiquan Zuo, Erhong Hao, Lijuan Jiao","doi":"10.1142/s1088424623500839","DOIUrl":"https://doi.org/10.1142/s1088424623500839","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41650548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-05DOI: 10.1142/s1088424623300070
Dilek K Dogutan, D. Nocera
{"title":"Reductive chemistry of pyrrolic macrocycles: A PCET dichotomy between metal and ligand","authors":"Dilek K Dogutan, D. Nocera","doi":"10.1142/s1088424623300070","DOIUrl":"https://doi.org/10.1142/s1088424623300070","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47127418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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