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Relationship between Thermal Conductivity and Compressive Strength of Insulation Concrete: A Review 保温混凝土导热系数与抗压强度关系的研究进展
Pub Date : 2023-08-04 DOI: 10.6000/1929-5995.2023.12.08
Chao Wu, Shaoqing Liu, Jianping Guo, Hongqiang Ma, Li He
Developing insulation concrete with high strength is essential for the construction of energy saving buildings. This is important to achieve carbon neutrality in the modern building industry. This paper reviews the existing studies in the literature on insulation concrete. This paper aims to reveal the correlation between the thermal conductivity and strength of concrete and identify the most effective method to make insulation concrete with lower thermal conductivity but higher strength. The review is carried out from two perspectives, including the effects of different foaming methods and various lightweight aggregates. As for the foaming methods, the chemical and mechanical foaming methods are discussed. As for the lightweight aggregates, cenospheres, porous aggregates, aerogels, and phase change materials are assessed. It is clearly observed that the thermal conductivity and compressive strength of concrete can be fitted by a linear function. As for the foaming methods, chemical foaming using hydrogen peroxide is the most effective to produce concrete with relatively lower thermal conductivity and higher compressive strength. For concrete with lightweight aggregates, cenospheres are the best option. Finally, recommendations are made to develop concrete with lower thermal conductivity and higher strength.
开发高强度保温混凝土是建设节能建筑的必要条件。这对于实现现代建筑行业的碳中和非常重要。本文对已有的保温混凝土研究文献进行了综述。本文旨在揭示混凝土的导热系数与强度之间的关系,找出制造低导热系数高强度保温混凝土的最有效方法。从不同发泡方式和各种轻骨料的影响两方面进行了综述。在发泡方法方面,分别讨论了化学发泡法和机械发泡法。对于轻质骨料,评估了微球、多孔骨料、气凝胶和相变材料。可以清楚地观察到,混凝土的导热系数和抗压强度可以用线性函数拟合。在发泡方法方面,双氧水化学发泡是最有效的,可以生产出导热系数较低、抗压强度较高的混凝土。对于轻质集料的混凝土,微球是最好的选择。最后,对开发导热系数低、强度高的混凝土提出了建议。
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引用次数: 0
Development and Characterization of Supercooled Polyethylene Naphthalate 过冷聚萘二甲酸乙二醇酯的研制与表征
Pub Date : 2023-07-26 DOI: 10.6000/1929-5995.2023.12.07
Jian Wang, Hang Li, P. Dai, Jinnan Chen
The utilization of undercooled or supercooled polymers presents a promising approach for the creation of single-polymer composites (SPCs), applicable not only to compaction processing but also to extrusion, injection molding, and 3D printing techniques. This study focuses on the development and characterization of supercooled polyethylene naphthalate (PEN) through differential scanning calorimetry (DSC) and rheological measurements. By employing predetermined conditions, a supercooling degree of 50 ˚C for PEN was achieved. The impact of maximum heating temperature, cooling rate, and shear rate on the supercooling degree was examined, revealing that higher supercooling degrees of PEN can be attained by increasing these factors. Additionally, the flow behavior of supercooled polymer melts at various temperatures was analyzed. The supercooling state of PEN exhibited remarkable stability for a minimum duration of half an hour at temperatures exceeding 250 ˚C.
利用过冷或过冷聚合物为制造单聚合物复合材料(spc)提供了一种很有前途的方法,不仅适用于压实加工,还适用于挤出、注射成型和3D打印技术。本研究主要通过差示扫描量热法(DSC)和流变学测量来开发和表征过冷聚萘二甲酸乙二醇酯(PEN)。采用预先设定的条件,使PEN的过冷度达到50℃。研究了最高加热温度、冷却速率和剪切速率对过冷度的影响,结果表明,增加这些因素可以获得更高的过冷度。此外,还分析了过冷聚合物熔体在不同温度下的流动行为。在超过250˚C的温度下,PEN的过冷状态在至少半小时内表现出显著的稳定性。
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引用次数: 0
Topological Shape Optimization Design of the Whole Bead of 265/35R18 Steel-Belted Radial Tire 265/35R18钢带子午线轮胎全胎头拓扑形状优化设计
Pub Date : 2023-07-19 DOI: 10.6000/1929-5995.2023.12.06
Yong Li, Shuang Zhang, Tao Wang, K. Zhang, Long Chen, S. Han
The tire bead, as the most important load-bearing component at the bead area, is closely related to the durability of the tire, but its structure is developing slowly. For this reason, the topological whole bead design was proposed, although it performs well, many defects existed due to the design based on traditional experience. Therefore, this paper studies the topology shape optimization algorithm, delves into the main criterion based on von Mises and the interlaminar shear stress, and provides guidance for the structurally optimal design of the 265/35R18 radial tire whole bead. The finite element simulation results show that the von Mises of the inner end of the chafer and the end of the carcass cord are reduced by 14.48% and 24.12%, respectively. The interlaminar shear stress decreased by 28.96% and 49.51%, respectively. The von Mises of chafer and carcass cord decreased by 13.17% to 40.36% and 7.71% to 20.51%, respectively. The optimization design is of great significance to further improve the safety performance of tires.
胎头作为胎头区域最重要的承重部件,与轮胎的耐久性密切相关,但其结构发展缓慢。为此,提出了拓扑全头设计,虽然性能良好,但由于传统经验设计存在许多缺陷。因此,本文对拓扑形状优化算法进行了研究,研究了基于von Mises和层间剪切应力的主要判据,为265/35R18子午线轮胎全胎头结构优化设计提供了指导。有限元模拟结果表明,鸡笼内端和胴体索端von Mises分别降低了14.48%和24.12%。层间剪切应力分别降低了28.96%和49.51%。鸡皮和胴体索的von Mises分别降低了13.17% ~ 40.36%和7.71% ~ 20.51%。优化设计对进一步提高轮胎的安全性能具有重要意义。
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引用次数: 0
Hemicellulose-g-PAAc/TiO2 Nanocomposite Hydrogel for Dye Removal 半纤维素-g- paac /TiO2纳米复合水凝胶染料脱除
Pub Date : 2023-07-05 DOI: 10.6000/1929-5995.2023.12.05
Yudan Li, Xiao-feng Sun, Jiayi Chen, Le Sun
Dyes pollution on urban environment is of great concern because of the human health hazards associated with this kind of contaminants, and the use of low-cost photocatalytic composite material is an efficient treatment method to minimize the environmental impact. A novel hemicellulose-g-PAAc/TiO2 composite hydrogel was prepared as a promising alternative material for dye removal. Wheat straw hemicellulose and TiO2 nanoparticles were first modified and then incorporated into hydrogel via covalent bonds. Effects of gel dosage, pH, initial concentration and contact time on the adsorption amount of methylene blue were systematically studied using the prepared hydrogel. The equilibrium adsorption data was fitted well to the Freundlich isotherm model, and Langmuir isotherm analysis indicated that the adsorption capacity of the hemicellulose-g-PAAc/TiO2 composite hydrogel was 389.1 mg/g, and adsorption kinetic study showed that the adsorption process can be described by the pseudo second-order kinetic model. The prepared composite hydrogel exhibited high photodegradation ability for methylene blue under alkaline conditions, and all results indicated that the hemicellulose-g-PAAc/TiO2 composite hydrogel had excellent photocatalytic degradability for dyes, which can be used in practical process.
染料污染对城市环境的危害是人们非常关注的问题,而使用低成本的光催化复合材料是一种有效的处理方法,可以最大限度地减少对环境的影响。制备了一种新型半纤维素-g- paac /TiO2复合水凝胶,作为一种很有前途的染料去除材料。首先对麦草半纤维素和TiO2纳米颗粒进行修饰,然后通过共价键将其掺入水凝胶中。用制备的水凝胶系统地研究了凝胶用量、pH、初始浓度和接触时间对亚甲基蓝吸附量的影响。平衡吸附数据符合Freundlich等温线模型,Langmuir等温线分析表明,半纤维素-g- paac /TiO2复合水凝胶的吸附量为389.1 mg/g,吸附动力学研究表明,吸附过程可以用拟二级动力学模型描述。制备的复合水凝胶在碱性条件下对亚甲基蓝具有良好的光降解能力,表明半纤维素-g- paac /TiO2复合水凝胶对染料具有良好的光催化降解能力,可用于实际工艺。
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引用次数: 0
Conjoint Effect of Boron Nitride and Surface-Enhanced Flake Graphite in Thermal Conductivity of Thermally Conductive Grease 氮化硼和表面增强片状石墨对导热润滑脂导热性能的共同影响
Pub Date : 2023-06-08 DOI: 10.6000/1929-5995.2023.12.04
Xiaojun Xiong, Yifan Li
The next generation of high-power electronic devices is expected to exhibit improved heat dissipation capabilities despite their smaller size. Current studies have investigated the utilization of hybrid fillers, our study introduces a novel approach by combining boron nitride (BN) and surface-enhanced flake graphite (G), both of which possess a platelet-like structure, to develop a thermally conductive grease. The grease shows an exceptionally high thermal conductivity of 2.21 W/mK and an extremely low electrical conductivity of 7.3×10-6 S/m. The viscosity of the grease is measured at 149 Pa·s. By incorporating hybrid fillers with a significantly high aspect ratio into EPON 828, a notable reduction of interfacial thermal resistance is observed, which is attributed to the formation of an effective pathway for phonon transfer facilitated by the unique characteristics of the hybrid fillers. Various theoretical models are employed to corroborate the experimental data, which facilitates substantiating the fundamental principles underlying the enhanced thermal conductivity of the prepared thermal grease.
下一代高功率电子器件虽然体积更小,但散热能力有望得到改善。目前已有研究对杂化填料的利用进行了研究,本研究介绍了一种将氮化硼(BN)和表面增强片状石墨(G)结合的新方法,这两种材料都具有片状结构,以制备导热润滑脂。该润滑脂具有极高的导热系数为2.21 W/mK,极低的导电性为7.3×10-6 S/m。润滑脂的粘度为149 Pa·s。在EPON 828中加入高纵横比的杂化填料,可以显著降低EPON 828的界面热阻,这是由于杂化填料的独特特性为声子传递提供了有效的途径。采用多种理论模型对实验数据进行验证,有助于证实制备的导热脂导热性增强的基本原理。
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引用次数: 0
Design Concepts for Peel-Dominant Adhesive Joints in Aeronautic Applications 航空应用中以剥离为主导的粘合接头的设计概念
Pub Date : 2023-04-20 DOI: 10.6000/1929-5995.2023.12.03
J. Lopes, R. Campilho, M. A. Bellali, M. Baghdadi
The adhesive bonding technique is employed from the aeronautical/aerospace industry to current house products. To comply with the requirements of distinct applications, different joint configurations are available to the designer. While single-lap joints (SLJ) are the most common in application and research, double-lap joints, scarf joints and T-joints find specific applications. T-joints are seldom studied in the literature, but these are used, for instance, in aircraft to bond the stiffener beams to the skin, or in the cars between the B-pillar and the rocker. Due to the high stress concentrations, T-joints often fail under average stresses much lower than the adhesive strengths, giving rise to the necessity for proper design and strength improvement methodologies. This work initially aims to validate the cohesive zone modelling (CZM) technique with experiments, and then use it to numerically evaluate and optimize the performance of T-joints subjected to peel loads. CZM is nowadays regarded as the most powerful strength prediction tool for adhesive joints, and can be a valuable tool to improve T-joints. Different features are addressed for a complete analysis: adhesive type, geometrical parameters, dual-adhesive technique for strength improvement, and composite joints. The evaluated geometrical parameters are the base adherend thickness (a), T-part thickness (t), overlap or bonding length (l) and curvature radius (r). As a result of this work, the model was successfully validated, and clear design guidelines were provided to define the ideal geometric and material (adhesive) conditions for best performance.
粘接技术从航空/航天工业应用到目前的家用产品。为了满足不同应用的要求,设计人员可以选择不同的关节配置。在应用和研究中,单搭接(SLJ)最为常见,而双搭接、围巾接头和t型接头也有其特殊的应用。t型接头在文献中很少被研究,但它们被用于,例如,在飞机上,将加强梁连接到皮肤上,或者在汽车的b柱和摇杆之间。由于高应力集中,t型接头在平均应力远低于粘接强度的情况下往往会失效,因此需要适当的设计和强度改进方法。本工作首先旨在通过实验验证黏结区建模(CZM)技术,然后使用它来数值评估和优化t形节点在剥离荷载下的性能。CZM被认为是目前最强大的粘接强度预测工具,可以作为改进t型接头的有价值的工具。针对不同的特征进行了完整的分析:粘合剂类型,几何参数,用于提高强度的双粘合剂技术和复合接头。评估的几何参数是基础粘附厚度(a), t部分厚度(t),重叠或粘合长度(l)和曲率半径(r)。由于这项工作,该模型被成功验证,并提供了明确的设计指南,以定义最佳性能的理想几何和材料(粘合剂)条件。
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引用次数: 0
Numerical and Experimental Analyses of Hybrid Composites Made from Amazonian Natural Fibers 亚马逊天然纤维混杂复合材料的数值与实验分析
Pub Date : 2023-04-01 DOI: 10.6000/1929-5995.2023.12.02
G. G. del Pino, A. Bezazi, H. Boumediri, J. L. Valín Rivera, A. C. Kieling, Sofia Dehaini Garcia, José Costa de Macêdo Neto, Marcos Dantas dos Santos, T. Panzera, Aristides Rivera Torres, César Alberto Chagoyen Méndez, F. V. Valenzuela Díaz
The application of lignocellulosic fibers as reinforcements in composite materials has found increasing use in recent years, due to the attractive characteristics of natural fibers such as their low cost, high specific modulus, biodegradability, abundance and with many technical qualities. Natural fiber hybrid composites are very frequently used in automotive aerospace and other industries. In this work, numerical and experimental analysis is carried out to compare curauá, jute and sisal fibers in epoxy composites for use in industry. The most appropriate hybridization effect by establishing the amounts of each fiber on the mechanical properties was considered. Finite Element Models were designed and validated through mechanical tests. The number of Finite Element models and specimens performed was determined through the design of experiments using the Taguchi Method and then the results were statistically validated. Higher strength was obtained in composites made with curauá fiber, followed by jute and sisal fibers. Such behavior was achieved by FEM and experimental tests, revealing an increase in tensile strength by increasing the amount of fibers up to 35% in total. Higher strength was achieved when the composite was made with curauá (20 wt.%), jute (10 wt.%) and sisal (5 wt.%) fibers. The results show a good agreement between the FEM and the experimental tests. Furthermore, the results of the present study were compared with those obtained previously mentioned in the open literature.
近年来,由于天然纤维具有低成本、高比模量、可生物降解性、丰富度和许多技术特性等吸引人的特点,木质纤维素纤维作为增强材料在复合材料中的应用越来越广泛。天然纤维混杂复合材料广泛应用于汽车、航空航天等行业。本文对工业环氧复合材料中curauau、黄麻和剑麻纤维的性能进行了数值和实验分析比较。通过确定每种纤维的用量,考虑了最适宜的杂化效应对力学性能的影响。设计了有限元模型,并通过力学试验进行了验证。采用田口法进行试验设计,确定有限元模型和试样的数量,并对结果进行统计验证。黄麻纤维的复合材料强度最高,其次是黄麻和剑麻纤维。这种行为是通过有限元和实验测试来实现的,表明通过增加纤维总量达到35%,拉伸强度增加。当复合材料由curaut (20wt .%),黄麻(10wt .%)和剑麻(5wt .%)纤维制成时,强度更高。结果表明,有限元计算结果与试验结果吻合较好。此外,本研究的结果与先前在公开文献中获得的结果进行了比较。
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引用次数: 1
Dynamic Elastic Modulus Variability in Anisotropic and Isotropic Materials: Comparison by Acoustic Emission 各向异性和各向同性材料的动态弹性模量变化:声发射的比较
Pub Date : 2023-03-09 DOI: 10.6000/1929-5995.2023.12.01
Henrique Pina Cardim, Larissa Q. Minillo, Fernando Nakao, A. Ortenzi
This study compared the variation of the dynamic elastic modulus (E) of three types of composite pipes made by the filament winding process and a steel alloy specimen, according to signal source changes. The specimens were produced with three different winding angles, i.e., ±50°, ±52.5°, and ±55°. The moduli were obtained through a known signal source and the angular variation, according to two sensors positioned over the specimen's surface. In a previous article, the variation in the velocity of acoustic emission (AE) signals, performed in the same type of pipes, was discussed based on the standards for glass fiber-reinforced epoxy (GFRE) filament wound specimens. This work took these preliminary findings to compare with the results found for steel alloy pipes (SAE 1020). This data was used with appropriate equations to determine the dynamic elastic moduli of each material. It was found that, even for small angular differences, the modulus changes position concerning the lamination angle. Thus, the lower the quality control, the lower the final product with composite materials. As expected, for isotropic materials such as steel alloys, the modulus remains constant along the angles, while for anisotropic ones, it is dependent on the principal directions of stress and strain, or on the other hand, dependent on the correlation between the angular wave velocity of the AE signals.
本研究比较了长丝缠绕工艺制备的三种复合管材和钢合金试样在信号源变化情况下的动态弹性模量(E)变化。样品采用±50°、±52.5°和±55°三种不同的缠绕角度制作。模量是通过已知的信号源和角度变化获得的,根据放置在试样表面的两个传感器。在之前的一篇文章中,基于玻璃纤维增强环氧树脂(GFRE)长丝缠绕试样的标准,讨论了在同一类型管道中进行声发射(AE)信号的速度变化。这项工作将这些初步发现与钢制合金管(SAE 1020)的结果进行了比较。该数据与适当的方程一起用于确定每种材料的动态弹性模量。结果表明,即使角差很小,模量也随层合角的变化而变化。因此,质量控制越低,最终产品的复合材料利用率就越低。正如预期的那样,对于各向同性材料(如钢合金),模量沿角度保持恒定,而对于各向异性材料,它取决于应力和应变的主方向,或者另一方面取决于声发射信号的角波速度之间的相关性。
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引用次数: 1
Annealing Temperature Effect on Structural and Luminescence Spectroscopy of Y2SiO5:Ce3+ Nanomaterial Synthesized by Sol–Gel Method 退火温度对溶胶-凝胶法制备Y2SiO5:Ce3+纳米材料结构和发光光谱的影响
Pub Date : 2022-12-31 DOI: 10.6000/1929-5995.2022.11.08
M. Hamroun, A. Guenanou, L. Guerbous, R. Chebout, K. Bacharı
Ce3+ - doped Y2SiO5 nanophosphors were successfully produced by Sol-Gel process. To study the influence of the temperature on the structure and the luminescence of Y2SiO5:Ce3+, we annealed the xerogels at the temperatures 800, 900, 950, 1000, 1050 and 1250 °C. The X-ray diffraction technique (XRD), field emission scanning electron microscopy (FEG-SEM), Fourier transform infrared spectroscopy (FTIR) and steady photoluminescence were used to characterize the samples. The crystallite size keeps the same value in the temperature range 950-1050 °C. The room temperature steady photoluminescence emission and excitation of Ce3+ in X1-Y2SiO5:Ce3+ nanomaterial with increasing temperature were measured and investigated. At the crystallization temperature of 1250 °C, we have a new structure X2- Y2SiO5:Ce3+ with grain sizes larger than the X1-Y2SiO5:Ce3+ and also intense violet-blue emission.
采用溶胶-凝胶法制备了Ce3+掺杂的Y2SiO5纳米荧光粉。为了研究温度对Y2SiO5:Ce3+的结构和发光的影响,我们在800、900、950、1000、1050和1250℃的温度下对干凝胶进行了退火。利用x射线衍射技术(XRD)、场发射扫描电镜(fg - sem)、傅里叶变换红外光谱(FTIR)和稳态光致发光技术对样品进行了表征。晶粒尺寸在950 ~ 1050℃范围内保持不变。研究了Ce3+在X1-Y2SiO5:Ce3+纳米材料中随温度升高的室温稳态光致发光发射和激发。在1250℃的结晶温度下,我们得到了一种新的结构X2- Y2SiO5:Ce3+,晶粒尺寸比X1-Y2SiO5:Ce3+大,并且发出强烈的紫蓝色辐射。
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引用次数: 0
A Simplified Analytical Solution for the Computation of Machine Path in Filament Winding of Cylindrical Angle-Ply and Double-Double Structures 圆柱角-铺层及双-双结构绕丝机径计算的简化解析解
Pub Date : 2022-12-16 DOI: 10.6000/1929-5995.2022.11.07
A. Andrianov, A.P.F. Militão
This paper presents a simplified computation approach for the machine path (or winding trajectory) of grid structures and tubes with a circular cross-section and angle-ply or double-double layup. The solution for the machine path is given through controllable degrees of freedom of a low-cost two-axis filament winding machine (FWM): mandrel rotation and translation of the delivery eye along the axis of the mandrel. The efficiency of the analytical solution for the machine path of the FWM was ascertained by automated laying the cotton thread over the geodesic and non-geodesic groove imprinted on the surface of a cylindrical polylactide mandrel. These results validated the possibility of manufacturing cylindrical composite structures with an angle-ply layup or double-double stacking sequence, without the need for expensive software, making the winding technology accessible to society and promoting university extension.
本文提出了一种简化计算圆形截面、角铺层或双铺层的网格结构和管的机械轨迹(或缠绕轨迹)的方法。通过一种低成本的两轴绕丝机(FWM)的可控自由度:芯轴旋转和输送眼沿芯轴的平移,给出了机床轨迹的求解方法。通过在圆柱型聚乳酸芯棒表面的测地线槽和非测地线槽上自动敷设棉线,确定了FWM机床轨迹解析解的有效性。这些结果验证了制造具有角度层叠或双层叠顺序的圆柱形复合材料结构的可能性,而不需要昂贵的软件,使缠绕技术能够进入社会并促进大学的推广。
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引用次数: 0
期刊
Journal of Research Updates in Polymer Science
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