Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2017.01.003
Abdelmajid Regti , My Rachid Laamari , Salah-Eddine Stiriba , Mohammadine El Haddad
The use of Persea americana has been studied as an alternative source of activated carbon for the removal of dyes from wastewater. Chemical activation using phosphoric acid was employed for the preparation of the activated carbon (C-PAN). The BET surface area and the total pore volumes were found to be 1593 m2/g and 1.053 cm3/g, respectively. This study investigates the effect of some parameters like, dye concentration, adsorbent dose, contact time and pH for the best comprehension of the adsorption manner. Adsorption kinetic follows pseudo-second order kinetic model. Langmuir and Freundlich isotherms models were used to analyze the adsorption equilibrium data and the best fits to the experimental data were provided by Langmuir model. Maximum adsorption capacity is equal to 400 mg/g of Basic Yellow 28 onto the activated carbon derived from Persea americana. Thermodynamic parameters, such as standard Gibbs free energy (ΔG0), standard enthalpy (ΔH0) and standard entropy (ΔS0) has been calculated. The adsorption process was found to be spontaneous and exothermic process.
This study shows that the activated carbon provided from Persea americana can be an alternative to the commercially available adsorbents for dyes removal from liquid solutions.
{"title":"Potential use of activated carbon derived from Persea species under alkaline conditions for removing cationic dye from wastewaters","authors":"Abdelmajid Regti , My Rachid Laamari , Salah-Eddine Stiriba , Mohammadine El Haddad","doi":"10.1016/j.jaubas.2017.01.003","DOIUrl":"10.1016/j.jaubas.2017.01.003","url":null,"abstract":"<div><p>The use of <em>Persea americana</em> has been studied as an alternative source of activated carbon for the removal of dyes from wastewater. Chemical activation using phosphoric acid was employed for the preparation of the activated carbon (C-PAN). The BET surface area and the total pore volumes were found to be 1593<!--> <!-->m<sup>2</sup>/g and 1.053<!--> <!-->cm<sup>3</sup>/g, respectively. This study investigates the effect of some parameters like, dye concentration, adsorbent dose, contact time and pH for the best comprehension of the adsorption manner. Adsorption kinetic follows pseudo-second order kinetic model. Langmuir and Freundlich isotherms models were used to analyze the adsorption equilibrium data and the best fits to the experimental data were provided by Langmuir model. Maximum adsorption capacity is equal to 400<!--> <!-->mg/g of Basic Yellow 28 onto the activated carbon derived from <em>Persea americana</em>. Thermodynamic parameters, such as standard Gibbs free energy (Δ<em>G</em><sup>0</sup>), standard enthalpy (Δ<em>H</em><sup>0</sup>) and standard entropy (Δ<em>S</em><sup>0</sup>) has been calculated. The adsorption process was found to be spontaneous and exothermic process.</p><p>This study shows that the activated carbon provided from <em>Persea americana</em> can be an alternative to the commercially available adsorbents for dyes removal from liquid solutions.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 10-18"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2017.01.003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74887763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2016.11.001
Mahmood Hilal , Sawsan Hilal
Herbal medicines are widely accepted as a primary source of healthcare due to their natural origin. However, this widespread popularity is counterbalanced with the lack of relevant research. The need to account for this deficiency motivated the present study which aims at (1) assessing physicians’ knowledge and attitude toward herbal medicines, (2) determining to what extent herbal medicines are utilized by physicians in the Kingdom of Bahrain, and (3) highlighting the main factors that may facilitate or hinder the utilization of herbal medicines. A cross-sectional study was conducted to cover 96 physicians conveniently sampled from different departments among one public and two private hospitals. The main tool that was used to gather the required data was a self-administered questionnaire that has been specifically developed by the researchers to address the study objectives. The collected data were processed by the statistical package for social sciences SPSS (version 18). The study found that 64.6% of the participated physicians have generally basic knowledge on herbal medicines, and half of them acquired their knowledge from experience. Moreover, the results showed a tendency by physicians to use herbal medicines personally more frequently than prescribing them to the patients. Interestingly, the majority (91.7%) of the participants showed a desire to enhance their knowledge with regard to herbal medicines. They ascertained that the rational use of herbal medicines is hindered by poor quality control (65.6%) and limited information on their adverse events (62.5%). The physicians claimed that the availability of sufficient knowledge (68.8%) beside the low cost (66.7%) are major facilitating factors toward utilizing herbal medicines.
{"title":"Knowledge, attitude, and utilization of herbal medicines by physicians in the Kingdom of Bahrain: A cross-sectional study","authors":"Mahmood Hilal , Sawsan Hilal","doi":"10.1016/j.jaubas.2016.11.001","DOIUrl":"10.1016/j.jaubas.2016.11.001","url":null,"abstract":"<div><p>Herbal medicines are widely accepted as a primary source of healthcare due to their natural origin. However, this widespread popularity is counterbalanced with the lack of relevant research. The need to account for this deficiency motivated the present study which aims at (1) assessing physicians’ knowledge and attitude toward herbal medicines, (2) determining to what extent herbal medicines are utilized by physicians in the Kingdom of Bahrain, and (3) highlighting the main factors that may facilitate or hinder the utilization of herbal medicines. A cross-sectional study was conducted to cover 96 physicians conveniently sampled from different departments among one public and two private hospitals. The main tool that was used to gather the required data was a self-administered questionnaire that has been specifically developed by the researchers to address the study objectives. The collected data were processed by the statistical package for social sciences SPSS (version 18). The study found that 64.6% of the participated physicians have generally basic knowledge on herbal medicines, and half of them acquired their knowledge from experience. Moreover, the results showed a tendency by physicians to use herbal medicines personally more frequently than prescribing them to the patients. Interestingly, the majority (91.7%) of the participants showed a desire to enhance their knowledge with regard to herbal medicines. They ascertained that the rational use of herbal medicines is hindered by poor quality control (65.6%) and limited information on their adverse events (62.5%). The physicians claimed that the availability of sufficient knowledge (68.8%) beside the low cost (66.7%) are major facilitating factors toward utilizing herbal medicines.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 325-333"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2016.11.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72785306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2016.10.001
Suaad S. Alwakeel
To isolate fungal communities from coastal areas of the Red Sea in Saudi Arabia and identify and classify them by molecular techniques. Samples were collected from the seaside of the Red Sea in Jeddah, Saudi Arabia during March 2012 and stored in sterile screw cap bottles for further analysis. Phenotypic and genotypic characterization of fungal isolates were done using standard techniques. Eight fungal genera including Aspergillus, Penicillium, Thielavia, Fusarium, Emericella, Cladosporium, Scytalidium and Alternaria. Most isolated fungi showed significant growth on petroleum media and were thus considered capable of biodegradation of crude oil based substances. The fungal genera isolated from the Red Sea had 97–100% similarity with the related fungi recorded in the GenBank in which they were deposited. The morphological and molecular structure of these marine fungal isolates closely resembles their terrestrial counterparts in the GenBank. The capabilities of these fungal species to utilize petroleum as a source of carbon speaks to future applications in which marine fungi may be utilized in the breakdown of petroleum-based waste in an ecologically efficient manner.
{"title":"Molecular identification of fungi isolated from coastal regions of Red Sea, Jeddah, Saudi Arabia","authors":"Suaad S. Alwakeel","doi":"10.1016/j.jaubas.2016.10.001","DOIUrl":"10.1016/j.jaubas.2016.10.001","url":null,"abstract":"<div><p>To isolate fungal communities from coastal areas of the Red Sea in Saudi Arabia and identify and classify them by molecular techniques. Samples were collected from the seaside of the Red Sea in Jeddah, Saudi Arabia during March 2012 and stored in sterile screw cap bottles for further analysis. Phenotypic and genotypic characterization of fungal isolates were done using standard techniques. Eight fungal genera including <em>Aspergillus</em>, <em>Penicillium</em>, <em>Thielavia</em>, <em>Fusarium</em>, <em>Emericella</em>, <em>Cladosporium</em>, <em>Scytalidium</em> and <em>Alternaria.</em> Most isolated fungi showed significant growth on petroleum media and were thus considered capable of biodegradation of crude oil based substances. The fungal genera isolated from the Red Sea had 97–100% similarity with the related fungi recorded in the GenBank in which they were deposited. The morphological and molecular structure of these marine fungal isolates closely resembles their terrestrial counterparts in the GenBank. The capabilities of these fungal species to utilize petroleum as a source of carbon speaks to future applications in which marine fungi may be utilized in the breakdown of petroleum-based waste in an ecologically efficient manner.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 115-119"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2016.10.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86331454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2017.06.001
Mourad S. Semary , Hany N. Hassan , Ahmed G. Radwan
This paper presents a semi-analytical method for solving fractional differential equations with strong terms like (exp, sin, cos,…). An auxiliary parameter is introduced into the well-known Picard’s method and so called controlled Picard’s method. The proposed approach is based on a combination of controlled Picard’s method with Simpson rule. This approach can cover a wider range of integer and fractional orders differential equations due to the extra auxiliary parameter which enhances the convergence and is suitable for higher order differential equations. The proposed approach can be effectively applied to Bratu’s problem in fractional order domain to predict and calculate all branches of problem solutions simultaneously. Also, it is tested on other fractional differential equations like nonlinear fractional order Sine-Gordon equation. The results demonstrate reliability, simplicity and efficiency of the approach developed.
本文给出了一类具有(exp, sin, cos,…)强项的分数阶微分方程的半解析解。在众所周知的皮卡德法中引入了一个辅助参数,也就是所谓的受控皮卡德法。提出了一种将受控皮卡德方法与辛普森规则相结合的方法。由于增加了辅助参数,该方法可以适用于更大范围的整数阶和分数阶微分方程,提高了收敛性,适用于高阶微分方程。该方法可以有效地应用于分数阶域Bratu问题,同时预测和计算问题解的所有分支。并对非线性分数阶正弦-戈登方程等分数阶微分方程进行了验证。结果证明了该方法的可靠性、简单性和高效性。
{"title":"Single and dual solutions of fractional order differential equations based on controlled Picard’s method with Simpson rule","authors":"Mourad S. Semary , Hany N. Hassan , Ahmed G. Radwan","doi":"10.1016/j.jaubas.2017.06.001","DOIUrl":"10.1016/j.jaubas.2017.06.001","url":null,"abstract":"<div><p>This paper presents a semi-analytical method for solving fractional differential equations with strong terms like (exp, sin, cos,…). An auxiliary parameter is introduced into the well-known Picard’s method and so called controlled Picard’s method. The proposed approach is based on a combination of controlled Picard’s method with Simpson rule. This approach can cover a wider range of integer and fractional orders differential equations due to the extra auxiliary parameter which enhances the convergence and is suitable for higher order differential equations. The proposed approach can be effectively applied to Bratu’s problem in fractional order domain to predict and calculate all branches of problem solutions simultaneously. Also, it is tested on other fractional differential equations like nonlinear fractional order Sine-Gordon equation. The results demonstrate reliability, simplicity and efficiency of the approach developed.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 247-253"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2017.06.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79130284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2016.09.003
Elsayed M.E. Zayed , Abdul-Ghani Al-Nowehy
Using the well-known solitary wave ansatz method, we obtain new exact bright and dark soliton solutions for two nonlinear Schrödinger equations, namely, the perturbed nonlinear Schrödinger equation with the Kerr law nonlinearity and a higher order nonlinear Schrödinger equation which describe the propagation of ultra short pulses in nonlinear optical fibers. The parameters of the soliton envelope (amplitude, width, velocity) are obtained as a function of the dependent model coefficients. Comparing the new solutions for these two equations with the well-known results are given.
{"title":"The solitary wave ansatz method for finding the exact bright and dark soliton solutions of two nonlinear Schrödinger equations","authors":"Elsayed M.E. Zayed , Abdul-Ghani Al-Nowehy","doi":"10.1016/j.jaubas.2016.09.003","DOIUrl":"10.1016/j.jaubas.2016.09.003","url":null,"abstract":"<div><p>Using the well-known solitary wave ansatz method, we obtain new exact bright and dark soliton solutions for two nonlinear Schrödinger equations, namely, the perturbed nonlinear Schrödinger equation with the Kerr law nonlinearity and a higher order nonlinear Schrödinger equation which describe the propagation of ultra short pulses in nonlinear optical fibers. The parameters of the soliton envelope (amplitude, width, velocity) are obtained as a function of the dependent model coefficients. Comparing the new solutions for these two equations with the well-known results are given.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 184-190"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2016.09.003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85643203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2016.09.004
Syed Tauseef Mohyud-Din, Waseem Sikander, Umar Khan, Naveed Ahmed
This paper focuses on the study of boundary value problems using well-known He’s variational iteration method which is coupled with an auxiliary parameter. Three examples are given to show the efficiency and importance of the proposed algorithm. The reliability and accuracy has been proved by comparing our results with the solution obtained by standard variational iteration method.
{"title":"Optimal variational iteration method for nonlinear problems","authors":"Syed Tauseef Mohyud-Din, Waseem Sikander, Umar Khan, Naveed Ahmed","doi":"10.1016/j.jaubas.2016.09.004","DOIUrl":"10.1016/j.jaubas.2016.09.004","url":null,"abstract":"<div><p>This paper focuses on the study of boundary value problems using well-known He’s variational iteration method which is coupled with an auxiliary parameter. Three examples are given to show the efficiency and importance of the proposed algorithm. The reliability and accuracy has been proved by comparing our results with the solution obtained by standard variational iteration method.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 191-197"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2016.09.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81608324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2016.07.004
Abdulrahman K. Al-Asmari , Nasreddien M.A. Osman , Rajamohamed Abbasmanthiri , Sarah A. Al-Asmari
Ascorbic acid (AsAc) was tested to evaluate its ability to reverse the oxidative stress induced by envenoming. Test groups of rats were envenomed with sub-lethal doses (4.0 mg/kg s.c.) of Bitis arietans venom (BaV) whilst, single doses (500 mg/kg, orally) of AsAc were pre-administered in half of them. Blood samples were collected within three periods and levels of lipid peroxidation (LPO) and total-SH increased significantly, whilst, the ‘Venom + AsAc’ groups were significantly less than both, the respective ‘Venom’ groups and controls, at different periods. The antioxidant, superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPx) enzyme level changes were trivial at the three periods, whilst, there were no changes in the ‘Venom + AsAc’ groups, compared with controls, except SOD which, became significant after 24 h. SCr and BUN levels were significantly higher than the controls within the three periods with variable degrees, whilst, the ‘Venom + AsAc’ group level changes were insignificant compared with controls and their respective ‘Venom’ groups at all periods. Blood urea Nitrogen (BUN), became significantly lower after 24 h. After 6 and 24 h AST levels were significantly higher than controls, whilst, ALT was not. Level changes of both AST and ALT ‘Venom + AsAc’ groups were insignificant, compared with controls at all periods. It is concluded that oxidative stress due to envenoming by BaV induced variable levels of significant changes in levels of nephrotoxic, hepatotoxic markers and antioxidant enzyme parameters. Administration of AsAc relatively adjusted these changes with different degrees, at variable periods of time that demands further deeper research in beneficiary mechanisms of antioxidants.
{"title":"The effect of ascorbic acid on Bitis arietans venom induced toxicity in rats","authors":"Abdulrahman K. Al-Asmari , Nasreddien M.A. Osman , Rajamohamed Abbasmanthiri , Sarah A. Al-Asmari","doi":"10.1016/j.jaubas.2016.07.004","DOIUrl":"10.1016/j.jaubas.2016.07.004","url":null,"abstract":"<div><p>Ascorbic acid (AsAc) was tested to evaluate its ability to reverse the oxidative stress induced by envenoming. Test groups of rats were envenomed with sub-lethal doses (4.0<!--> <!-->mg/kg<!--> <!-->s.c.) of <em>Bitis arietans</em> venom (BaV) whilst, single doses (500<!--> <!-->mg/kg, orally) of AsAc were pre-administered in half of them. Blood samples were collected within three periods and levels of lipid peroxidation (LPO) and total-SH increased significantly, whilst, the ‘Venom<!--> <!-->+<!--> <!-->AsAc’ groups were significantly less than both, the respective ‘Venom’ groups and controls, at different periods. The antioxidant, superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPx) enzyme level changes were trivial at the three periods, whilst, there were no changes in the ‘Venom<!--> <!-->+<!--> <!-->AsAc’ groups, compared with controls, except SOD which, became significant after 24<!--> <!-->h. SCr and BUN levels were significantly higher than the controls within the three periods with variable degrees, whilst, the ‘Venom<!--> <!-->+<!--> <!-->AsAc’ group level changes were insignificant compared with controls and their respective ‘Venom’ groups at all periods. Blood urea Nitrogen (BUN), became significantly lower after 24<!--> <!-->h. After 6 and 24<!--> <!-->h AST levels were significantly higher than controls, whilst, ALT was not. Level changes of both AST and ALT ‘Venom<!--> <!-->+<!--> <!-->AsAc’ groups were insignificant, compared with controls at all periods. It is concluded that oxidative stress due to envenoming by BaV induced variable levels of significant changes in levels of nephrotoxic, hepatotoxic markers and antioxidant enzyme parameters. Administration of AsAc relatively adjusted these changes with different degrees, at variable periods of time that demands further deeper research in beneficiary mechanisms of antioxidants.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 89-94"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2016.07.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87903563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2017.01.001
R.A. Belakhmima , N. Errahmany , M. Ebn Touhami , H. Larhzil , R. Touir
A new basic formulation of electroless Cu–P plating using sodium hypophosphite as reducing agent was developed at different concentration of NiSO4. So, the effect of temperature solution, pH and immersion time on deposition rate was also investigated. It is found that the deposition rate increases with nickel sulphate concentration and temperature and decreases with immersion time. The cyclic voltammetry study showed that the electroless deposition was controlled by the anodic processes. In addition, the scanning electron microscopy (SEM) observations and energy dispersive X-ray (EDX) analysis were used to characterize Cu–P deposit. Thus, the micrograph showed that coating presents a nodular aspect and is relatively homogeneous. Finally, the corrosion protection of mild steel by this coating in 1.0 M HCl was studied using electrochemical measurements. It is found that the protection increases with NiSO4 concentration and reaches 92% at 2 g L−1.
以次亚磷酸钠为还原剂,在不同浓度NiSO4的条件下,研制了化学镀Cu-P的新基本配方。因此,研究了温度、溶液、pH和浸泡时间对沉积速率的影响。沉积速率随硫酸镍浓度和温度的升高而升高,随浸液时间的延长而降低。循环伏安法研究表明,化学沉积是由阳极过程控制的。此外,利用扫描电镜(SEM)观察和能量色散x射线(EDX)分析对Cu-P矿床进行了表征。因此,显微照片显示涂层呈现结节状且相对均匀。最后,通过电化学测量研究了该涂层对低碳钢在1.0 M HCl中的防腐效果。结果表明,随着NiSO4浓度的增加,保护作用增强,在2 g L−1时达到92%。
{"title":"Preparation and characterization of electroless Cu–P deposition protection for mild steel corrosion in molar hydrochloric solution","authors":"R.A. Belakhmima , N. Errahmany , M. Ebn Touhami , H. Larhzil , R. Touir","doi":"10.1016/j.jaubas.2017.01.001","DOIUrl":"10.1016/j.jaubas.2017.01.001","url":null,"abstract":"<div><p>A new basic formulation of electroless Cu–P plating using sodium hypophosphite as reducing agent was developed at different concentration of NiSO<sub>4</sub>. So, the effect of temperature solution, pH and immersion time on deposition rate was also investigated. It is found that the deposition rate increases with nickel sulphate concentration and temperature and decreases with immersion time. The cyclic voltammetry study showed that the electroless deposition was controlled by the anodic processes. In addition, the scanning electron microscopy (SEM) observations and energy dispersive X-ray (EDX) analysis were used to characterize Cu–P deposit. Thus, the micrograph showed that coating presents a nodular aspect and is relatively homogeneous. Finally, the corrosion protection of mild steel by this coating in 1.0<!--> <!-->M HCl was studied using electrochemical measurements. It is found that the protection increases with NiSO<sub>4</sub> concentration and reaches 92% at 2<!--> <!-->g<!--> <!-->L<sup>−1</sup>.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 46-53"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2017.01.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89970227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2017.06.004
Md. Tarikul Islam , M. Ali Akbar , Md. Abul Kalam Azad
The purpose of this article is to generate the closed form traveling wave solutions of some nonlinear partial differential equations namely; the KdV equation and the modified KdV equation using the recently established rational (G′/G)-expansion method. By this method, new and further general closed form solutions expressed by three types of functions as for instance hyperbolic, trigonometric and rational function solutions are found. The basic ideas presented in this article and the obtained solutions might be useful to analyze the shallow water waves, ion acoustic waves in plasma, acoustic waves on a crystal lattice and the role of nonlinear dispersion in the formation of structures like liquid drops.
{"title":"Multiple closed form wave solutions to the KdV and modified KdV equations through the rational (G′/G)-expansion method","authors":"Md. Tarikul Islam , M. Ali Akbar , Md. Abul Kalam Azad","doi":"10.1016/j.jaubas.2017.06.004","DOIUrl":"10.1016/j.jaubas.2017.06.004","url":null,"abstract":"<div><p>The purpose of this article is to generate the closed form traveling wave solutions of some nonlinear partial differential equations namely; the KdV equation and the modified KdV equation using the recently established rational (<em>G</em>′/<em>G</em>)-expansion method. By this method, new and further general closed form solutions expressed by three types of functions as for instance hyperbolic, trigonometric and rational function solutions are found. The basic ideas presented in this article and the obtained solutions might be useful to analyze the shallow water waves, ion acoustic waves in plasma, acoustic waves on a crystal lattice and the role of nonlinear dispersion in the formation of structures like liquid drops.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 160-168"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2017.06.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76624780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1016/j.jaubas.2017.01.004
Maryam Al-Jabri, Salma M.Z. Al-Kindy, Fakhr Eldin O. Suliman, Beena Varghese, Saleh N. Al-Busafi, Haider J. Al-Lawati
A spectrofluorimetric method based on complex formation between Zn2+ ions and 5-(4-flourophenyl)-quinolin-8-ol has been developed for the rapid determination of trace levels of zinc ions. The method is sensitive and selective. The complex formed emit strongly at 535 nm with excitation wavelength at 394 nm. Complexation formation was optimized by studying the effect of pH, molar ratio of the metal to the ligand and the type of buffers. The study indicated that maximum complexation resulted when the pH of the mixture was maintained at 8.0 with 0.2 M carbonate buffer and metal to ligand was at a stoichiometric ratio of 1:2. Under the optimum conditions, the detection limit was 3 ppb. Appropriate validation of the method, yielded acceptable relative standard deviations of less than 2% (n = 5). The method was applied to the trace determination of Zn2+ ions in tap water, mineral water, fresh milk and cream samples successfully.
{"title":"Spectrofluorimetric determination of Zn2+ ions in aqueous medium using 5-(4-flourophenyl)-quinolin-8-ol","authors":"Maryam Al-Jabri, Salma M.Z. Al-Kindy, Fakhr Eldin O. Suliman, Beena Varghese, Saleh N. Al-Busafi, Haider J. Al-Lawati","doi":"10.1016/j.jaubas.2017.01.004","DOIUrl":"10.1016/j.jaubas.2017.01.004","url":null,"abstract":"<div><p>A spectrofluorimetric method based on complex formation between Zn<sup>2+</sup> ions and 5-(4-flourophenyl)-quinolin-8-ol has been developed for the rapid determination of trace levels of zinc ions. The method is sensitive and selective. The complex formed emit strongly at 535<!--> <!-->nm with excitation wavelength at 394<!--> <!-->nm. Complexation formation was optimized by studying the effect of pH, molar ratio of the metal to the ligand and the type of buffers. The study indicated that maximum complexation resulted when the pH of the mixture was maintained at 8.0 with 0.2<!--> <!-->M carbonate buffer and metal to ligand was at a stoichiometric ratio of 1:2. Under the optimum conditions, the detection limit was 3<!--> <!-->ppb. Appropriate validation of the method, yielded acceptable relative standard deviations of less than 2% (<em>n</em> <!-->=<!--> <!-->5). The method was applied to the trace determination of Zn<sup>2+</sup> ions in tap water, mineral water, fresh milk and cream samples successfully.</p></div>","PeriodicalId":17232,"journal":{"name":"Journal of the Association of Arab Universities for Basic and Applied Sciences","volume":"24 ","pages":"Pages 66-73"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jaubas.2017.01.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76837487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}