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Solvothermal synthesis of Li<sub>3</sub>BO<sub>3</sub>-coated graphite powder as an anode material for all-solid-state lithium batteries 作为全固态锂电池负极材料的Li&lt;sub&gt;3&lt;/sub&gt;BO&lt;sub&gt;3&lt;/sub&gt
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-11-01 DOI: 10.2109/jcersj2.23123
Hirosuke Sonomura, Tomoatsu Ozaki, Yasunori Hasegawa, Yoshiaki Sakurai, Masanobu Chiku
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引用次数: 0
Investigation into the effect on the property of Na<sub>2</sub>WO<sub>4</sub> ceramic prepared by the further modified solid-state reaction method 对Na&lt;sub&gt;2& gt; /sub&gt;WO&lt;sub&gt;4&lt;/sub&gt;进一步改进固相反应法制备的陶瓷
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-11-01 DOI: 10.2109/jcersj2.23122
Jiefeng Wang, Xiaofeng Yuan, Jun Li, Qiushi Wang, Wentao Xiong, Taiang Song
After a long time of exploration, the solid-state reaction method is further modified. In the granulation process, 10 % isopropanol is added into ethanol to increase the viscosity. More than that, the green body of the ceramic is placed into the isostatic press and pressed at 200 MPa for 3 min again after being kept in the muffle furnace at 120 °C for 1 h. The modified solid-state reaction method further improves the sintering property of the Na2WO4 ceramic, which increases the dielectric property of the ceramic sample greatly. Besides, the granulation problem, the bubble problem and the problem in demoulding process are solved. The substitution of ethanol and isopropanol for polyvinyl ethanol (PVA) completely avoids the residue of PVA in the ceramic sample and increases the fluidity of the ceramic particles in the granulation process. As a result, the Na2WO4 ceramic can be sintered well at 560 °C with a relative permittivity of 5.82, Q × f value of 131300 GHz and a temperature coefficient of resonant frequency (TCF) value of −56.2 ppm/°C in this work. The modified solid-state reaction method is a good substitute for the conventional solid-state method.
经过长时间的探索,对固相反应法进行了进一步的改进。在造粒过程中,在乙醇中加入10%的异丙醇以增加粘度。在此基础上,将陶瓷坯体放入等静压机中,在120℃的马弗炉中保持1 h后,再次在200 MPa的压力下压制3 min。改进的固相反应法进一步提高了Na2WO4陶瓷的烧结性能,大大提高了陶瓷样品的介电性能。同时解决了脱模过程中的造粒问题、气泡问题和脱模问题。用乙醇和异丙醇替代聚乙烯醇(PVA),完全避免了PVA在陶瓷样品中的残留,增加了陶瓷颗粒在造粒过程中的流动性。结果表明,该陶瓷在560℃下烧结良好,相对介电常数为5.82,Q × f值为131300 GHz,谐振频率温度系数(TCF)值为- 56.2 ppm/℃。改进的固相反应法可以很好地替代传统固相反应法。
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引用次数: 0
Call for a Guest Editor for a Special Issue 邀请特刊的客座编辑
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-11-01 DOI: 10.2109/jcersj2.131.a11-1
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引用次数: 0
Sulfur-rich composite cathodes using carbon replica frameworks for all-solid-state lithium–sulfur batteries 全固态锂硫电池用碳复制框架的富硫复合阴极
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23018
Kota Suzuki, Jinan Cui, Jiang Peilu, Hanseul Kim, Yumi Yamaguchi, Satoshi Hori, Masaaki Hirayama, Ryoji Kanno
In this study, high-sulfur-containing carbon replica (sulfur-rich S-CR) composites were prepared using a melt-diffusion method. Melt diffusion under vacuum enabled the introduction of four times the weight ratio of sulfur into the mesopores of a carbon replica (CR). The obtained sulfur-rich S-CR exhibited an initial discharge capacity of 700 mAh gsulfur−1, indicating the low utilization of sulfur in the composite. The classification of the particle sizes of the solid electrolyte and CR contributed to the improvement in electrochemical performance. An initial discharge capacity of over 1,200 mAh g−1 was confirmed for the S-CR composite using the smaller solid electrolyte and CR prepared via a dry classification process. An analysis of the effect of the additives indicated that the rational design of electronic and ionic conduction pathways is required for higher cycle performance when using sulfur-rich S-CRs.
本研究采用熔融扩散法制备了高含硫碳副本(富硫S-CR)复合材料。熔体在真空下的扩散使硫的重量比增加了四倍,从而进入了碳复制品(CR)的介孔。得到的富硫S-CR的初始放电容量为700 mAh g硫- 1,表明复合材料中硫的利用率较低。固体电解质和CR的粒径分级有助于电化学性能的提高。使用更小的固体电解质和通过干燥分类工艺制备的CR, S-CR复合材料的初始放电容量超过1200 mAh g - 1。对添加剂的影响分析表明,在使用富硫s - cr时,合理设计电子和离子传导途径是提高循环性能的必要条件。
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引用次数: 0
Prediction for crystal growth rates in borides under supercooled temperature conditions 过冷温度条件下硼化物晶体生长速率的预测
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23111
Munemichi Kawaguchi, Masayoshi Uno
Two-types of phase-field (PF) calculations were developed to predict the crystallization of borides. The first calculation used an empirical PF mobility [Lexp = A(kBTΔT/6π2λ3η)B], which was determined from experimental crystal growth rates (vexp). The calculation results for various binary borides such as Li2O–2B2O3, Na2O–2B2O3, Na2O–4B2O3, K2O–4B2O3, BaO–2B2O3, and PbO–2B2O3, agreed well with the experimental vexp below their melting points. Furthermore, the A and B values of the Lexp for the borides depended on diffusivity and cation molar mass, including that it is important for cation transfers during crystallization. The second calculation solved the PF equation using versatile PF mobility (L′ ∼ rD/κ2), in which an interfacial process (r) was included. The calculation results agreed well with the first calculation results and the experimental vexp, except for Li2O–2B2O3. In Li2O–2B2O3, the interfacial process strongly affected the crystal growth rates because of the strong nonlinear phenomenon. For diffusive ceramics such as Li2O–2B2O3, we should use the empirical Lexp. However, the versatile PF equation, which includes the interfacial process (L′) can predict the vexp of many borides.
提出了两种相场(PF)计算方法来预测硼化物的结晶。第一次计算采用经验的PF迁移率[Lexp = A(kBTΔT/6π2λ3η)B],由实验晶体生长速率(vexp)确定。对Li2O-2B2O3、Na2O-2B2O3、Na2O-4B2O3、K2O-4B2O3、BaO-2B2O3和PbO-2B2O3等多种二元硼化物熔点以下的计算结果与实验结果吻合较好。此外,硼化物的Lexp的A和B值取决于扩散率和阳离子摩尔质量,包括结晶过程中阳离子转移的重要因素。第二次计算使用通用PF迁移率(L′~ rD/κ2)求解PF方程,其中包括一个界面过程(r)。除Li2O-2B2O3外,计算结果与第一次计算结果和实验结果吻合较好。在li20 - 2b2o3中,界面过程由于强烈的非线性现象而强烈影响晶体生长速率。对于扩散陶瓷如li20 - 2b2o3,我们应该使用经验Lexp。然而,包含界面过程(L′)的通用PF方程可以预测许多硼化物的杂化。
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引用次数: 0
Spark plasma sintering on the thermoelectric sulfide Ta<sub>2</sub>PdS<sub>6</sub> 火花等离子烧结热电硫化物Ta&lt;sub&gt;2&lt;/sub&gt;PdS&lt;sub&gt;6&lt;/sub&gt;
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23038
Akitoshi Nakano, Koichiro Suekuni, Nanako Hattori, Ichiro Terasaki
We have prepared a dense ceramic sample of a novel thermoelectric sulfide Ta2PdS6 by means of spark plasma sintering technique under a uniaxial pressure. The Rietveld analyses of the X-ray diffraction patterns have clarified occurrence of weak preferred orientation in the sintering process. Resistivity, thermopower, and Hall resistivity measurements on the ceramic sample have indicated that it shows higher carrier density and lower carrier mobility than a single crystal. The inferior carrier mobility in the ceramic sample may partly come from increased point-defect and/or grain-boundary scattering, to which poor power factor is attributed.
在单轴压力下,采用火花等离子烧结技术制备了新型热电硫化物Ta2PdS6致密陶瓷样品。x射线衍射图的Rietveld分析明确了烧结过程中弱择优取向的发生。陶瓷样品的电阻率、热功率和霍尔电阻率测量表明,它比单晶具有更高的载流子密度和更低的载流子迁移率。陶瓷样品中载流子迁移率较低的部分原因可能是点缺陷和/或晶界散射的增加,这归因于较差的功率因数。
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引用次数: 0
Photoplastic effect in MgO single crystals MgO单晶的光塑性效应
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23060
Yu Ogura, Yuki Tsuchiya, Sena Hoshino, Tatsuya Yokoi, Katsuyuki Matsunaga
The photoplastic effect, phenomena that flow stress and/or hardness change by light illuminations, has been known mainly in II–VI compound semiconductors. In this study, it was revealed for the first time that magnesium oxide (MgO) single crystals exhibit increase in flow stress by light illumination, namely, the positive photoplastic effect. Scanning transmission electron microscope (STEM) observations demonstrated that the plastic deformation of MgO is realized by generation of glide dislocations on the slip system of {110}〈110〉. Therefore, the observed positive photoplastic effect of MgO is likely due to interactions of the glide dislocations and photo-excited carriers. According to the theoretical calculations, individual dislocations in MgO had a specific band structure that differs from the bulk. This also indicates possible interactions between dislocations and carriers. It is expected that light illumination can reduce dislocation mobility in MgO, leading to the increase in flow stress under light illuminations.
光塑性效应,即流动应力和/或硬度随光照变化的现象,主要是在II-VI化合物半导体中发现的。本研究首次揭示了氧化镁(MgO)单晶在光照下表现出流动应力的增加,即正光塑性效应。扫描透射电镜(STEM)观察表明,MgO的塑性变形是通过在{110}< 110 >滑移系上产生滑移位错实现的。因此,观察到的MgO的正光塑性效应可能是由于滑动位错和光激发载流子的相互作用。根据理论计算,MgO中的单个位错具有不同于体的特定能带结构。这也表明位错和载流子之间可能存在相互作用。预计光照可以降低MgO中的位错迁移率,从而导致光照下流动应力的增加。
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引用次数: 0
Time-reduction imaging method for scanning-probe microscopy using a compressed sensing algorithm based on sequential reconstruction method 基于序列重建方法的压缩感知扫描探针显微镜成像时间缩短方法
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23042
Keiichi Ueda, Diao Zhuo, Linfeng Hou, Hayato Yamashita, Masayuki Abe
The surface image measurement time was reduced by data completion using a compressed sensing algorithm in the image-acquisition of scanning probe microscopy. In particular, by reducing the number of acquisition points of the surface-roughness image and reconstructing the image using estimated values, acquiring the surface image at one-eighth of the data-measurement time became possible. The reduced measurement time was shown to reduce the influence of thermal drift during image capture. The real time surface image demonstrated that reconstruction is possible during surface image acquisition.
在扫描探针显微镜图像采集中,采用压缩感知算法进行数据补全,缩短了表面图像测量时间。特别是,通过减少表面粗糙度图像的采集点数量并使用估计值重建图像,可以在八分之一的数据测量时间内获取表面图像。缩短的测量时间可以减少图像捕获过程中热漂移的影响。实时表面图像表明,在表面图像采集过程中,重构是可能的。
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引用次数: 0
Strain-rate insensitive photoindentation pop-in behavior in ZnS single crystals at room temperature 室温下ZnS单晶应变速率不敏感的光压痕弹出行为
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23064
Yan Li, Hiroto Oguri, Ayaka Matsubara, Eita Tochigi, Xufei Fang, Yu Ogura, Katsuyuki Matsunaga, Atsutomo Nakamura
The structural and mechanical reliability of inorganic semiconductors for practical applications is determined by the rate at which they can deform and sustain externally applied strain. In this research, nanoindentation experiments under three strain rates and two light conditions were performed on single-crystal ZnS with an 80 nm radius Berkovich tip at a peak load of 60 µN. Significant pop-in events were observed in all indentation tests. The calculated maximum resolved shear stress at the first pop-in approximated the theoretical strength of ZnS, indicating a homogeneous dislocation nucleation process. The cumulative spreads of the maximum shear stress were found to be insensitive to the strain rate, and the distribution at a small strain rate was slightly broader than that of the other two strain rates because of thermal noise. Calculated activation energy ΔG required for the dislocation nucleation indicates that dislocation nucleation in ZnS could occur with external stress and without much assistance of thermal energy, leading to weak dependence of the first pop-in on the strain rate. At three strain rates, light consistently showed little influence on the pop-in behavior and dislocation nucleation process.
无机半导体在实际应用中的结构和机械可靠性取决于其变形和承受外部施加应变的速度。在本研究中,在三种应变速率和两种光照条件下,对具有80 nm半径Berkovich尖端的单晶ZnS进行了纳米压痕实验,峰值负载为60µN。在所有缩进测试中都观察到显著的弹出事件。计算得到的第一次弹出时的最大分解剪应力与ZnS的理论强度接近,表明这是一个均匀的位错成核过程。最大剪切应力的累积分布对应变速率不敏感,由于热噪声的影响,小应变速率下的最大剪切应力累积分布比其他两种应变速率下的最大剪切应力累积分布略宽。计算得出位错形核所需的活化能ΔG表明,ZnS中的位错形核可以在外部应力作用下发生,而不需要太多的热能辅助,导致第一次弹出对应变速率的依赖性较弱。在三种应变速率下,光对弹入行为和位错成核过程的影响均较小。
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引用次数: 0
A guideline for searching for stable grain boundary structure by utilizing crystallographic information: A method based on non-identical termination 利用晶体学信息寻找稳定晶界结构的准则:一种基于非同终止的方法
4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Pub Date : 2023-10-01 DOI: 10.2109/jcersj2.23019
Yuki Hata, Yaoshu Xie, Kiyou Shibata, Teruyasu Mizoguchi
Determining the stable atomic structure of grain boundaries (GBs) is one of the most important tasks for computational materials science to comprehensively understand the structure-property relationship of GBs in real polycrystalline materials. In this paper, we revisit a proposed method (PM) that was thought to be ineffective in determining the stable GB structures based on sampling non-identical terminating crystal planes of the two adjoining crystals forming the GB. In contrast to the previous conclusion, we found that the PM is effective regarding both the reproducibility of stable structures and calculation cost. This method could determine the most stable GB structures and energies of not only elemental materials of face-centered-cubic and body-centered-cubic metals, including Cu and Mo, but also a binary ceramic material, MgO. We show that the PM can greatly reduce the number of necessary candidate structures calculated to determine the stable GB structures compared with other brute-force methods sampling the rigid body translation between the two adjoining crystals. We demonstrated that sampling GB structures made of non-identical termination combinations is a useful and effective method to determine the stable GB structures of various materials.
确定晶界的稳定原子结构是全面了解实际多晶材料中晶界的结构-性能关系的计算材料科学的重要任务之一。在本文中,我们重新审视了一种被认为是无效的方法(PM),该方法基于采样形成GB的两个相邻晶体的不相同的终止晶体平面来确定稳定的GB结构。与之前的结论相比,我们发现PM在稳定结构的再现性和计算成本方面都是有效的。该方法不仅可以测定面心立方和体心立方金属元素材料Cu和Mo以及二元陶瓷材料MgO的最稳定的GB结构和能量。我们的研究表明,与其他暴力方法取样相邻晶体之间的刚体平移相比,PM可以大大减少确定稳定GB结构所需的候选结构的计算数量。我们证明了由不同端接组合组成的GB结构取样是测定各种材料的稳定GB结构的一种有用而有效的方法。
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引用次数: 0
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Journal of the Ceramic Society of Japan
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