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New Developments in the Application of Phthalocyanines in Textile Printing 酞菁在纺织印花中的应用新进展
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1953.TB02810.X
F. Gund
A completely new method of using phthalocyanines in textile printing was introduced by the discovery of the Phthalogens, from which the phthalocyanine pigment may be produced in the fibre. Special methods of application were developed, which are characterised by the use of 10–20% of special solvent mixtures, the Levasols, in the aqueous printing pastes containing the intermediate product and the metal, the latter in the form of a soluble salt or as a complex compound. The printing method is adapted to the usual processes and apparatus used in textile printing. Particular attention must be paid to the drying of the prints and pads. Condensation to the dye is best carried out by steaming. The printing process with Phthalogen Brilliant Blue IF3G, the intermediate product, which with a popper salt or the copper complex compound Phthalogen K gives very bright blues of high fastness to light, weather, and boiling, and with nickel salts greenish blues of equally high fastness properties, is described in detail, and the solubility and the stability of the intermediate product are discussed. The possibility of printing alongside dyes of other groups is considered. Success has recently been achieved in developing a process for the production of white and coloured resists under Phthalogen Brilliant Blue IF3G, the resisting agent being an organic base (Phthalotrop B). The production of a green phthalocyanine pigment on the fibre has been made possible by the manufacture of the intermediate product Phthalogen Brilliant Green IFFB. The printing process is similar to that used for the production of the blue dye. The lower solubility of the intermediate product requires the use of another solvent, Levasol F, and the dispersing agent, Emulsifier W. Owing to its extraordinary brightness and outstanding fastness properties, the dye containing copper is of greater importance, the copper being applied as Phthalogen K. The method of printing is discussed, as well as the possibility of application alongside other dye groups in direct printing.
酞菁素的发现为纺织印花中酞菁素的使用提供了一种全新的方法,酞菁素可用于纤维中的酞菁色素的生产。开发了特殊的应用方法,其特点是在含有中间产品和金属的水性印刷糊中使用10-20%的特殊溶剂混合物,Levasols,后者以可溶性盐的形式或作为复杂的化合物。该印花方法适用于纺织品印花中常用的工艺和设备。必须特别注意印品和衬垫的干燥。对染料的凝结最好用蒸煮的方法进行。详细介绍了中间产物酞菁菁IF3G的印刷工艺,酞菁菁与罂粟盐或铜络合物酞菁菁K可产生耐光、耐气候、耐煮沸的极亮蓝色,与镍盐可产生同样高牢度的绿蓝色。并讨论了中间产物的溶解度和稳定性。考虑了与其他基团染料一起印刷的可能性。最近,在酞菁IF3G下成功开发了一种生产白色和彩色抗染剂的工艺,抗染剂是一种有机碱(酞菁B)。通过生产中间产品酞菁IFFB,在纤维上生产绿色酞菁色素成为可能。印刷过程类似于用于生产蓝色染料的过程。由于中间产物的溶解度较低,需要使用另一种溶剂Levasol F和分散剂乳化剂w。由于其非凡的亮度和出色的牢度性能,含铜的染料更为重要,铜被用作酞菁K.讨论了印刷方法,以及与其他染料基团一起应用于直接印刷的可能性。
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引用次数: 2
Synthesis and Electronic Spectra of Some Monoazo Disperse Dyes Derived from N‐Methylindoline N -甲基喹啉单偶氮分散染料的合成及电子光谱研究
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1982.TB03615.X
G. Hallas, S. F. Ho
Several monoazo dyes suitable for transfer printing have been prepared from N-methylindoline and compared with the corresponding derivatives of N-methyl -12,3,4-tetrahy-droquinoline (kairoline). The presence of a five-membered terminal ring system leads to diminished π-interaction and results in modest hypsochromic and hypochromic shifts of the visible absorption band, relative to the analogous kairo-line derivatives, together with some deterioration in light-fastness properties on synthetic-polymer fibres.
以n -甲基喹啉为原料制备了几种适合转移印花的单偶氮染料,并与相应的n -甲基-12,3,4-四氢喹啉衍生物进行了比较。五元端环体系的存在导致π相互作用减弱,并导致可见光吸收带相对于类似的凯罗线衍生物出现适度的异色和异色偏移,同时合成聚合物纤维的耐光性也有所下降。
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引用次数: 0
The Properties of Cotton Wax in Relation to the Scouring Process 棉蜡性能与精练过程的关系
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1924.TB01277.X
R. Fargher
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引用次数: 0
Dermatitis Alleged to be Due to the Wearing of Textiles 指称因穿着纺织品而引致皮炎
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1938.TB01987.X
C. M. Whittaker
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引用次数: 0
A Volumetric Process for the Estimation of Azo Dyes, Nitro Compounds 偶氮染料、硝基化合物测定的体积法
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1903.TB00244.X
W. H. Pennington
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引用次数: 2
NOTE ON THE APPLICATION OF ALIZARIN IN LEATHER DYEING 茜素在皮革染色中的应用
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1891.TB02850.X
H. Koechlin, E. Knecht
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引用次数: 0
The Development of a Generalised Equation to Determine Affinity. Part 1‐Theoretical Derivation and Application to Dyeing Cellulose with Anionic Dyes 确定亲和力的广义方程的发展。第1部分-阴离子染料在纤维素染色中的理论推导和应用
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1986.TB01041.X
H. H. Sumner
The more recent developments in the theoretical treatment of the dyeing of cellulosic materials with anionic dyes are described, and the usefulness of the derived equation in interpreting the effects of electrolytes and pH is illustrated.
描述了用阴离子染料染色纤维素材料的理论处理的最新进展,并说明了推导方程在解释电解质和pH值的影响方面的有用性。
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引用次数: 11
NOTE ON THE CARBONISING OF WOOL IN PRESENCE OF SILK 注意羊毛在丝绸存在时的碳化
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1891.TB02849.X
F. Knecht
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引用次数: 0
THE INFLUENCE OF THE POSITION OF THE SULPHO GROUP ON THE SHADE AND FASTNESS OF THE TRIPHENYLMETHANE DYESTUFFS. 巯基位置对三苯基甲烷染料色度和牢度的影响。
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1896.TB00108.X
T. Sandmeyer
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引用次数: 1
The Measurement of the Colour of Textile Fabrics 纺织织物颜色的测定
Pub Date : 2008-10-22 DOI: 10.1111/J.1478-4408.1930.TB01619.X
J. M. Preston
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引用次数: 0
期刊
Journal of The Society of Dyers and Colourists
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