{"title":"Liquid Phase Oxidation of Glycerol over Gold-based Catalysts in Flow and Batch Reactor","authors":"Naoki MIMURA","doi":"10.1627/jpi.66.195","DOIUrl":"https://doi.org/10.1627/jpi.66.195","url":null,"abstract":"金を主成分とする触媒を用い，酸素を酸化剤として用いるグリセロールの酸化反応の研究を行った。本研究において，グリセロールを原料にして得られる生成物はカルボン酸類であり，高付加価値 · 高機能な分子として期待される。反応は，バッチ式反応器とフロー式反応器の両者を用いて行った。特に，フロー式反応器に適した触媒の開発に重点を置き，高活性と長寿命を両立する触媒を見出した。反応機構については，Au/Al2O3触媒に着目し，添加アルカリの効果を明らかにするとともに，触媒上で酸素が活性化する機構を提案した。また，高分解能電子顕微鏡を用いることで，触媒の活性を担っているナノサイズの金，および金と複合化した他の貴金属の状態を明らかにし，反応に与える影響について考察した。","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"84 1-9","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135161557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Katsuhiko Takeuchi, Keisuke Takahashi, Yusuke Ishizaka, Hiroki Koizumi, Haruki Nagae, Kazuhiro Matsumoto, N. Fukaya, J. Kuwabara, T. Kanbara, Jun-Chul Choi
{"title":"亜鉛錯体触媒によるテトラメチルオルトシリケートを用いたCO2からの有機カルバメート合成におけるフェナントロリン配位子上の置換基効果","authors":"Katsuhiko Takeuchi, Keisuke Takahashi, Yusuke Ishizaka, Hiroki Koizumi, Haruki Nagae, Kazuhiro Matsumoto, N. Fukaya, J. Kuwabara, T. Kanbara, Jun-Chul Choi","doi":"10.1627/jpi.66.185","DOIUrl":"https://doi.org/10.1627/jpi.66.185","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"1 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91145393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Satoru Murata, Taichi Nakai, M. Hatakeyama, S. Sunada
{"title":"ベンゾチオフェンおよびジベンゾチオフェン誘導体の酸化における構造と反応性の相関","authors":"Satoru Murata, Taichi Nakai, M. Hatakeyama, S. Sunada","doi":"10.1627/jpi.66.142","DOIUrl":"https://doi.org/10.1627/jpi.66.142","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"21 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82001815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ken Motokura, Kyosuke Gomi, K. Maeda, Shunichi Sakai, S. Hasegawa, Wang Chun, Yuichi Manaka
{"title":"Silica-supported Cu Complex Catalysis for Chan–Evans–Lam Coupling Reaction between Aniline and Phenylboronic Acid","authors":"Ken Motokura, Kyosuke Gomi, K. Maeda, Shunichi Sakai, S. Hasegawa, Wang Chun, Yuichi Manaka","doi":"10.1627/jpi.66.171","DOIUrl":"https://doi.org/10.1627/jpi.66.171","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"58 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86227314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junya Ohyama, A. Hirayama, H. Yoshida, M. Machida, Kazuo Kato, S. Nishimura, Keisuke Takahashi
{"title":"Relationship between Redox Rate and Catalytic Activity of Cu Zeolite in the Partial Oxidation of Methane","authors":"Junya Ohyama, A. Hirayama, H. Yoshida, M. Machida, Kazuo Kato, S. Nishimura, Keisuke Takahashi","doi":"10.1627/jpi.66.180","DOIUrl":"https://doi.org/10.1627/jpi.66.180","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"9 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81949511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Uchida, Jun Akimoto, Hiroyuki Nakamura, Takao Nozaki
{"title":"Creation of a Safety Information Platform Applying AI Analysis Technology: Prototyping Analysis Methods","authors":"M. Uchida, Jun Akimoto, Hiroyuki Nakamura, Takao Nozaki","doi":"10.1627/jpi.66.189","DOIUrl":"https://doi.org/10.1627/jpi.66.189","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"35 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77994053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Co修飾によるアセチレン部分水素化用In2O3触媒の安定性向上","authors":"Jiamin Ma, Ken-ichi Shimizu, S. Furukawa","doi":"10.1627/jpi.66.149","DOIUrl":"https://doi.org/10.1627/jpi.66.149","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"18 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73953107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Riku Takamura, Tatsuki Tomono, Miru Yoshida-Hirahara, H. Ogihara, H. Kurokawa
{"title":"Dehydrogenative Conversion of Methane to C2 Hydrocarbons and Aromatics over Pt/Al2O3 Catalysts","authors":"Riku Takamura, Tatsuki Tomono, Miru Yoshida-Hirahara, H. Ogihara, H. Kurokawa","doi":"10.1627/jpi.66.162","DOIUrl":"https://doi.org/10.1627/jpi.66.162","url":null,"abstract":"","PeriodicalId":17362,"journal":{"name":"Journal of The Japan Petroleum Institute","volume":"13 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82375987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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