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Properties of Zinc Phosphate Coatings on Carbon Steel Using a Thermostatic Cell and a Mobile System 用恒温槽和移动体系制备碳钢表面磷酸锌涂层的性能
Pub Date : 2019-03-12 DOI: 10.31031/ACSR.2019.01.000507
Reyes Astivia Mje, Torres Jv, Barrera Gm, Díaz Cb
Phosphate coatings can prevent or minimize the environmental corrosion of metals and they are often used as the base for subsequent coatings or painting processes. In this work a mobile device was used to perform carbon steel phosphating, which will work against corrosion. The methodology used involved mechanical cleaning of the substrate as well as a chemical cleaning to eliminate possible contaminants on the metal surface. Following that, the superficial phosphating was performed to find the ideal conditions that gave the best results. Finally, the results from SEM and XRD analysis showed the morphology and surface composition of the coatings obtained from both studied methods. The results from the applied dipped cell method compared with the mobile system indicated the reliability of the methods.
磷酸盐涂层可以防止或尽量减少金属的环境腐蚀,它们经常被用作后续涂层或油漆工艺的基础。在这项工作中,使用了一个移动装置来进行碳钢磷化,这将防止腐蚀。所使用的方法包括对基材进行机械清洗以及化学清洗,以消除金属表面可能存在的污染物。然后,进行表面磷化,以寻找最佳磷化效果的理想条件。最后,通过扫描电镜(SEM)和x射线衍射(XRD)分析了两种方法制备的涂层的形貌和表面组成。应用浸槽法与移动系统的对比结果表明了方法的可靠性。
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引用次数: 0
Potential Health Benefits in Controlling Type 2 Diabetes of Resistant Starches in Taro (Colocasia Esculenta) Flour Stored During 5 Months 芋粉中抗性淀粉储存5个月对控制2型糖尿病的潜在健康益处
Pub Date : 2019-02-28 DOI: 10.31031/acsr.2019.01.000506
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引用次数: 0
The Centrality of Chemistry 化学的中心地位
Pub Date : 2019-02-15 DOI: 10.31031/ACSR.2019.01.000505
T. George, Guoping Zhang, R. Letfullin
We applaud Crimson Publishers for launching the new online journal called Annals of Chemical Science Research. It can be argued that chemistry represents the most commonly shared branch of science and engineering among the various disciplines, including physics, biology, materials, spectroscopy and lasers/ optics – hence its descriptor of centrality. To fully understand and appreciate any field of science (pure and applied), being grounded in the fundamentals of chemistry is essential. This is of course why varying levels of chemistry courses are required by students majoring in any area of science and many areas of engineering.
我们为Crimson出版社推出名为《化学科学研究年鉴》的新在线期刊而喝彩。可以说,在包括物理学、生物学、材料学、光谱学和激光/光学在内的各种学科中,化学代表了科学和工程中最常见的分支——因此,它具有中心地位。要充分理解和欣赏任何科学领域(纯科学和应用科学),以化学基础为基础是必不可少的。当然,这就是为什么主修任何科学领域和许多工程领域的学生都需要不同程度的化学课程。
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引用次数: 0
About the Moving Force of Chemical Reactions 关于化学反应的动力
Pub Date : 2019-02-05 DOI: 10.31031/ACSR.2019.01.000504
B. T. Utelbayev, E. Suleimenov, A. Utelbayeva
Chemistry is well known-the science of substances that studies the processes of their transformation accompanied by changes in the composition and structure [1-3]. As a result of a chemical reaction, chemical work is performed with the redistribution of chemical bonds, accompanied by the release or absorption of heat, light, and other manifestations. And here the question arises about the nature of the moving force of the work, what is, the reasons for the occurrence of a chemical reaction. At the same time, the number of nucleons, electrons participating in chemical transformations remains unchanged, however, new “chemical individuals” are formed [4-11] and the internal energy of the reacting systems changes. In [2], the authors of the theory of elementary interactions, the course of chemical reactions, conclude that molecules break down into active particles that interact with the molecule in three stages: association, electronic isomerization and dissociation. At their suggestion, the presence of the electron isomerization stage explains why and how the chemical bond-breaking reactions proceed at room temperature. And temperature, catalyst and other factors, with all their physical differences, play the same rolethe initiator. In our opinion, in the case under consideration, the association of reacting molecules is a modification of the theory of the transition state and most importantly, the moving force of electron isomerization is not indicated. It can react only when an active particle appears, for which radicals, ions and solvent molecules are taken, i.e., it also requires activation energy.
众所周知,化学是一门研究物质在组成和结构变化的同时转化过程的科学[1-3]。作为化学反应的结果,化学功是通过化学键的重新分配来完成的,同时伴随着热、光和其他表现的释放或吸收。这里的问题是,功的移动力的性质,化学反应发生的原因是什么。同时,参与化学转化的核子、电子数量保持不变,但形成了新的“化学个体”[4-11],反应体系的内能发生了变化。在[2]中,化学反应过程的基本相互作用理论的作者得出结论,分子分解成活性粒子,并通过三个阶段与分子相互作用:缔合、电子异构化和解离。根据他们的建议,电子异构化阶段的存在解释了为什么以及如何在室温下进行化学断键反应。而温度、催化剂等因素,虽各有物理差异,却起着同样的引发剂作用。我们认为,在考虑的情况下,反应分子的结合是对过渡态理论的修正,最重要的是,电子异构化的移动力没有显示出来。只有当活性粒子出现时,它才能发生反应,这些活性粒子带走了自由基、离子和溶剂分子,也就是需要活化能。
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引用次数: 0
Characterization of Rubber Seed Shell and Kernel (Hevea brasiliensis) as Raw Materials for Co-liquefaction with Low Rank Coal 橡胶树壳和仁与低阶煤共液化原料的表征
Pub Date : 2019-01-22 DOI: 10.31031/ACSR.2019.01.000503
M. Ishak, S. Hassan, Ali H. Jawad, K. Ismail
sam-Abstract The present study focuses on characterization of two biomass samples namely rubber seed shell (RSS) and rubber seed kernel (RSK), as potential raw materials for co-liquefaction with Mukah Balingian low rank Malaysian coal. The physical and chemical characteristics of the biomass samples such as proximate and ultimate analyses, number of extractives, holocellulose and hemicelluloses content, calorific value, bio-oil yield and pyrolysis behavior were determined. Apparently, RSK was found to be more suitable as co-liquefaction material with Mukah Balingian coal due to its high carbon (64.5wt%), high volatile matter (92.4wt%) content, and high percent yield of bio-oil (33.1wt%). Further, the pyrolysis thermogram indicated that RSK contained higher lignified material than RSS. Moreover, RSK exhibits higher calorific value with comparison to RSS and coal.
摘要本研究重点研究了橡胶籽壳(RSS)和橡胶籽仁(RSK)两种生物质样品的特性,作为与Mukah Balingian低阶马来西亚煤共液化的潜在原料。测定了生物质样品的理化特性,包括近似值和终值分析、萃取物数量、全纤维素和半纤维素含量、热值、生物油收率和热解行为。RSK具有高碳(64.5wt%)、高挥发物(92.4wt%)和高生物油收率(33.1wt%)的特点,更适合作为木卡巴林根煤的共液化原料。此外,热解热像图显示RSK比RSS含有更多的木质化物质。此外,与RSS和煤相比,RSK具有更高的热值。
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引用次数: 2
Nano-chemistry: The Toolbox for Nanoparticle Based Diagnosis and Theraphy 纳米化学:基于纳米粒子的诊断和治疗工具箱
Pub Date : 2018-09-06 DOI: 10.31031/ACSR.2018.01.000502
D. Karaman
The direction for synthetic chemistry that focuses on the approaches to building new materials form the fundamental building units of atoms and molecules is regarded as nanochemistry. In the framework of nanomedicine, new freedoms can be proposed with the help of nano-chemistry approaches in order to create nano-pharmaceuticals for theraphy and nanoimaging probes for diagnostic. Nanoparticles with different functionalities can be created by tuning their size, shape, surfaces, interfaces, and constituents with the aid of nano-chemistry approaches. Nano-chemistry has provided the opportunity to weaken the boundaries between the disciplines and connect them globally. As already depicted by Niemeyer in the beginning of this century “chemistry is the central science for the development of applied disciplines such as materials research and biotechnology” [1]. In today’s research, nano-chemistry has contributed for diminishing the defined boundaries of biology, chemistry, physics, material, medicine, pharmacy for the benefit of nanomedicine research mainly by providing nanoparticles for medicine. By this way, innovative nanoparticle designs can address the challenges and shortcomings faced by traditional medicine. In this context, nanochemistry approaches help to form a nanoparticle-based diagnosis and theraphy.
纳米化学是合成化学的一个方向,它关注的是如何从原子和分子的基本构建单元中构建新材料。在纳米医学的框架下,借助纳米化学方法可以提出新的自由,以创造用于治疗的纳米药物和用于诊断的纳米成像探针。在纳米化学方法的帮助下,通过调整它们的大小、形状、表面、界面和成分,可以创造出具有不同功能的纳米颗粒。纳米化学提供了削弱学科之间的界限并在全球范围内连接它们的机会。正如尼迈耶在本世纪初所描述的那样,“化学是材料研究和生物技术等应用学科发展的核心科学”[1]。在当今的研究中,纳米化学主要通过为医学提供纳米粒子,为纳米医学研究的利益缩小了生物学、化学、物理学、材料、医学、药学的界限。通过这种方式,创新的纳米颗粒设计可以解决传统医学面临的挑战和缺点。在这种情况下,纳米化学方法有助于形成基于纳米粒子的诊断和治疗。
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引用次数: 1
Liquefaction of Lignocelluloses as a Promising Alternative to Petrochemicals 木质纤维素液化作为石油化工产品的一种有前途的替代品
Pub Date : 2018-08-30 DOI: 10.31031/ACSR.2018.01.000501
L. A. Panamgama
Current world population is heavily dependent on fossil fuels (petrochemicals) for their energy needs and it is difficult to imagine what would happen to the world when this limited resource has come to the end in one day. Fossil resources are limited, environmentally unfriendly and their prices are liable to change unpredictably and rapidly depending on political and economic situations. It has predicted that if we use this scary limited resource at the current rate of consumption, less than a half century it would come to an end. On the other hand, excessive usage of petrochemicals has created a lot of environmental issuers as well, such as polluted environments in most of the highly congested cities in the world and global warming due to greenhouse effect. Further evaluation of much warmer climates in the world is responsible for the rising of sea levels due to melting of snow etc., It can be expected that in the near future tiny island around the globe would be no longer visible and would sink. Therefore, seeking and developing of alternative and new energy resources as well as lowering of the rate of consumption of petrochemicals are equally vital.
目前世界人口严重依赖化石燃料(石化产品)来满足他们的能源需求,很难想象当这种有限的资源在某一天耗尽时,世界将会发生什么。化石资源是有限的,对环境不友好,其价格容易根据政治和经济情况发生不可预测的迅速变化。它预测,如果我们以目前的消费速度使用这种可怕的有限资源,不到半个世纪,它就会结束。另一方面,石化产品的过度使用也造成了许多环境问题,例如世界上大多数高度拥挤的城市的环境污染以及温室效应导致的全球变暖。进一步的评估表明,由于冰雪融化等原因,全球气候变暖是海平面上升的原因。可以预期,在不久的将来,全球的小岛将不再可见并下沉。因此,寻找和开发替代能源和新能源,降低石化产品的消费率同样至关重要。
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引用次数: 0
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