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Lehmann effect in nematic and cholesteric liquid crystals: a review 向列型和胆甾醇型液晶中的莱曼效应
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-07-03 DOI: 10.1080/21680396.2019.1671244
P. Oswald, A. Dequidt, G. Poy
ABSTRACT The Lehmann effect is the continuous rotation of cholesteric droplets subjected to a temperature gradient. Discovered by Otto Lehmann in 1900, this effect was re-observed recently by several authors not only in cholesterics but also in nematics when the director field is twisted inside the droplets. In most experiments, the droplets coexist with their isotropic liquid, but the Lehmann effect can also be observed when the droplets are dispersed in an isotropic liquid in which the LC is partly miscible. After a brief history on the Lehmann effect and its first explanation by Leslie in 1968, we will review the main experimental results obtained on this subject from 2008. In particular, the role of the temperature gradient, of the size of the droplets, of the textures and their orientation with respect to the temperature gradient, of the confinement effects, of the impurities and of the concentration of chiral molecules will be described. A special emphasis will also be placed on the research of hydrodynamic effects to answer the fundamental question of whether it is just the texture or the droplet itself that rotates. We will then review the different models proposed in the literature to explain the Lehmann effect. Among them are two thermomechanical models directly based on the Leslie explanation (named TM1 and TM2 models), a thermomechanical model of rotating texture ‘surfing’ on a heat wave (TM3 model), a model of melting-growth (MG model) that only applies when the droplets coexist with their own isotropic liquid, and a pure hydrodynamic model (H model) based on the existence of Marangoni flows – currently, only evidenced in emulsified cholesterics. The strengths and weaknesses of each model will be discussed in relation with the experimental results.
摘要莱曼效应是胆甾醇型液滴在温度梯度作用下的连续旋转。Otto Lehmann于1900年发现了这种效应,最近几位作者不仅在胆甾醇中,而且在指向矢场在液滴内部扭曲时的向列相中都重新观察到了这种效应。在大多数实验中,液滴与其各向同性液体共存,但当液滴分散在LC部分混溶的各向同性液体中时,也可以观察到莱曼效应。在简要介绍了莱曼效应的历史以及Leslie在1968年对其的首次解释之后,我们将回顾2008年以来在该主题上获得的主要实验结果。特别地,将描述温度梯度、液滴的大小、纹理及其相对于温度梯度的取向、限制效应、杂质和手性分子浓度的作用。还将特别强调流体动力学效应的研究,以回答旋转的是纹理还是液滴本身这一基本问题。然后,我们将回顾文献中提出的不同模型来解释莱曼效应。其中有两个直接基于Leslie解释的热机械模型(命名为TM1和TM2模型),一个是在热浪上旋转纹理“冲浪”的热力学模型(TM3模型),另一个是仅适用于液滴与其自身各向同性液体共存时的熔融生长模型(MG模型),以及基于Marangoni流存在的纯流体动力学模型(H模型)——目前仅在乳化胆固醇中得到证明。每个模型的优点和缺点将结合实验结果进行讨论。
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引用次数: 17
Recent advancements in the mesogens comprising of 1,3,5-triazine core moiety 1,3,5-三氮嘧啶核片段的介原研究进展
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-07-03 DOI: 10.1080/21680396.2019.1666753
Deepak Devadiga, T. N. Ahipa
ABSTRACT Research works on new discoid molecules, comprehending an aromatic/heteroaromatic rigid core with flexible peripheral chains, have been gathered with the multiplying attentiveness due to their prime importance as prototype systems for the charge and energy transport investigation and owing to the prospect of their organo-electronic applications. This critical review article delineates the recent headway in the fundamental design ideas and the available synthetic approaches to obtain the most often encountered triazine-based discotic liquid crystals. The major focal point of the review is to explore the exhilarating research on 1,3,5-triazine-based mesogens that has been reported in the last 5 years. Moreover, the current review not only highlights the variety of structural modifications that are undertaken by the various researchers across the globe in the field of 1,3,5-triazine-based discoid molecules, but also facilitates the fascinating and beneficial altering of properties, both for the rudimentary intentions of demonstrating structure–property relationships and for materials focused in the direction of commercially triumphant liquid crystal display and other applications. GRAPHICAL ABSTRACT
由于其作为电荷和能量输运研究的原型系统的重要性以及其有机电子应用的前景,新型盘状分子的研究工作受到了越来越多的关注。这篇重要的综述文章描述了最近在基本设计思想和可用的合成方法获得最常见的三嗪基盘状液晶的进展。本综述的主要重点是对近5年来报道的1,3,5-三嗪类中效原的令人振奋的研究进行探讨。此外,当前的综述不仅强调了全球不同研究人员在1,3,5-三嗪基盘状分子领域所进行的各种结构修饰,而且还促进了令人着迷和有益的性质改变,无论是为了展示结构-性质关系的基本意图,还是为了聚焦于商业上成功的液晶显示和其他应用方向的材料。图形抽象
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引用次数: 14
The role of hydrogen bonds in the mesomorphic behaviour of supramolecular assemblies organized in dendritic architectures 氢键在树枝状结构超分子组装体介晶行为中的作用
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-01-02 DOI: 10.1080/21680396.2019.1621226
M. Arkas, I. Kitsou, A. Gkouma, M. Papageorgiou
ABSTRACT Dendritic polymers are artificial compounds with a unique, repeatedly branched structure inspired by the respective patterns, encountered in trees. They are recognized as the fourth major macromolecular architectural class next to linear, cross linked and branched polymers. Regarding the formation of liquid crystalline phases, they follow the same rules as all the other categories. Suitable chemical functionalization induces segregation. Secondary interactions, in the form of hydrogen bonds in particular, also play a crucial role in mesophase formation by regulating polarity fluctuations and other properties such as rigidity. As a consequence, there are some cases where liquid crystallinity is attributed exclusively to the presence of hydrogen bonding networks, whereas in many more examples mesophase formation is induced mainly due to these interactions. A survey of intra and intermolecular bond influence on the liquid crystalline character of dendritic polymers is presented. The review also covers some examples of supramolecular assemblies exhibiting architecture or incorporating elements reminiscent of trees which cannot be classified as dendritic polymers where segregation resulting by hydrogen bonding is governed by the same principles. In parallel, a description of the various mesophases observed in correlation to different hydrogen bonding patterns is included, and some general conclusions and rules are suggested.
摘要树枝状聚合物是一种人造化合物,具有独特的重复支化结构,其灵感来源于树木中遇到的各种图案。它们被认为是继线性、交联和支链聚合物之后的第四大分子结构类别。关于液晶相的形成,它们遵循与所有其他类别相同的规则。适当的化学官能化可诱导偏析。二次相互作用,特别是氢键形式的相互作用,通过调节极性波动和其他性质(如刚性),在中间相的形成中也起着至关重要的作用。因此,在一些情况下,液晶性完全归因于氢键网络的存在,而在更多的例子中,中间相的形成主要是由于这些相互作用而诱导的。综述了分子内键和分子间键对树枝状聚合物液晶特性的影响。这篇综述还涵盖了一些超分子组装体的例子,这些超分子组装体表现出结构或结合了让人想起树的元素,而树不能被归类为树枝状聚合物,其中由氢键引起的偏析由相同的原理控制。同时,还描述了观察到的与不同氢键模式相关的各种中间相,并提出了一些一般结论和规则。
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引用次数: 8
Tailoring surface patterns to direct the assembly of liquid crystalline materials 定制表面图案以指导液晶材料的组装
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-01-02 DOI: 10.1080/21680396.2019.1598295
Yu Xia, Apiradee Honglawan, Shu Yang
ABSTRACT Molecular ordering and the defect structures of a material play essential roles in its function and performance. Controlling molecular alignment and topological defects has been a cornerstone in the field of liquid crystalline (LC) materials. Here, we present an overview of different methods to tailor surface chemistry and surface topography in order to direct the assemblies of LCs, leading to complex morphologies of topological defects. We detail various top-down patterning techniques in specific LC systems, including small molecule nematic and smectic LCs, and LC polymers (LCPs), and their roles in discoveries of new phenomena, new materials, and new applications. We close the review with a prospective on the potential impact of the LC patterning efforts to fundamental understanding, advancement of new materials and new phenomena, and potential technological applications.
材料的分子有序和缺陷结构对材料的功能和性能起着至关重要的作用。分子取向和拓扑缺陷的控制一直是液晶材料研究领域的基石。在这里,我们概述了不同的方法来调整表面化学和表面形貌,以指导lc的组装,导致拓扑缺陷的复杂形态。我们详细介绍了特定LC系统中的各种自上而下的图图化技术,包括小分子向列型和近晶型LC,以及LC聚合物(lcp),以及它们在发现新现象,新材料和新应用中的作用。最后,我们展望了LC图案化工作对基础理解、新材料和新现象的发展以及潜在的技术应用的潜在影响。
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引用次数: 16
Interaction and self-organization of inclusions in two-dimensional free-standing smectic films 二维独立晶膜中夹杂物的相互作用和自组织
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-01-02 DOI: 10.1080/21680396.2019.1586590
P. Dolganov, P. Cluzeau, V. Dolganov
ABSTRACT In this article we review interactions and collective behavior of inclusions in free-standing smectic films with in-plane orientational ordering. The inclusions interact on large distances and can form various self-organised structures. Topological defects of the director field play a key role in self-organization. Various types of interaction are realized, including dipolar, quadrupolar and interactions of mixed type. We describe different approaches which can be used to modify the interaction of inclusions. Effects of polarity and chirality of the host medium, behavior in external field are discussed. We describe open problems and perspective directions of investigations.
摘要本文综述了具有平面内取向有序的独立晶膜中夹杂物的相互作用和集体行为。包裹体在远距离上相互作用,形成各种自组织结构。指挥域的拓扑缺陷在自组织中起着关键作用。实现了多种类型的相互作用,包括偶极、四极和混合型相互作用。我们描述了可以用来改变包裹体相互作用的不同方法。讨论了宿主介质极性和手性的影响及其在外场中的行为。我们描述了开放的问题和研究的前景方向。
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引用次数: 16
Lipid-based Liquid Crystalline Films and Solutions for the Delivery of Cargo to Cells. 用于向细胞输送货物的脂基液晶薄膜和解决方案。
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2019-01-01 Epub Date: 2019-11-04 DOI: 10.1080/21680396.2019.1666752
Marilyn Porras-Gomez, Cecilia Leal

A major challenge in the delivery of cargo (genes and/or drugs) to cells using nanostructured vehicles is the ability to safely penetrate plasma membranes by escaping the endosome before degradation, later releasing the payload into the cytoplasm or organelle of interest. Lipids are a class of bio-compatible molecules that self-assemble into a variety of liquid crystalline constructs. Most of these materials can be used to encapsulate drugs, proteins, and nucleic acids to deliver them safely into various cell types. Lipid phases offer a plethora of structures capable of forming complexes with biomolecules, most notably nucleic acids. The physichochemical characteristics of the lipid molecular building blocks, one might say the lipid primary structure, dictates how they collectively interact to assemble into various secondary structures. These include bilayers, lamellar stacks of bilayers, two-dimensional (2D) hexagonal arrays of lipid tubes, and even 3D cubic constructs. The liquid crystalline materials can be present in the form of aqueous suspensions, bulk materials or confined to a film configuration depending on the intended application (e.g. bolus vs surface-based delivery). This work compiles recent findings of different lipid-based liquid crystalline constructs both in films and particles for gene and drug delivery applications. We explore how lipid primary and secondary structures endow liquid crystalline materials with the ability to carry biomolecular cargo and interact with cells.

利用纳米结构载体向细胞输送货物(基因和/或药物)的一个主要挑战是,能否在降解前安全地穿透质膜,逃出内质体,随后将有效载荷释放到细胞质或相关细胞器中。脂质是一类生物相容性分子,可自组装成各种液晶结构。这些材料大多可用于封装药物、蛋白质和核酸,将其安全地输送到各种细胞中。脂相具有大量能够与生物大分子(尤其是核酸)形成复合物的结构。脂质分子构件的物理化学特性,也可以说是脂质的一级结构,决定了它们如何共同作用以组合成各种二级结构。这些结构包括双分子层、双分子层的层状堆叠、二维(2D)六边形脂管阵列,甚至三维立方体结构。液晶材料可以以水悬浮液、块状材料或薄膜结构的形式存在,具体取决于预期的应用(如栓剂给药与表面给药)。本研究汇编了最近在基因和药物递送应用中对不同的脂基液晶结构薄膜和颗粒的研究成果。我们探讨了脂质一级和二级结构如何赋予液晶材料携带生物分子货物并与细胞相互作用的能力。
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引用次数: 0
Interpretation of saddle-splay and the Oseen-Frank free energy in liquid crystals 液晶中鞍展开和Oseen-Frank自由能的解释
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2018-07-03 DOI: 10.1080/21680396.2019.1581103
Jonathan V Selinger
ABSTRACT This article re-examines a classic question in liquid-crystal physics: What are the elastic modes of a nematic liquid crystal? The analysis uses a recent mathematical construction, which breaks the director gradient tensor into four distinct types of mathematical objects, representing splay, twist, bend, and a fourth deformation mode. With this construction, the Oseen-Frank free energy can be written as the sum of squares of the four modes, and saddle-splay can be regarded as bulk rather than surface elasticity. This interpretation leads to an alternative way to think about several previous results in liquid-crystal physics, including: (1) free energy balance between cholesteric and blue phases, (2) director deformations in hybrid-aligned nematic cells, (3) spontaneous twist of achiral liquid crystals confined in a torus or cylinder, and (4) curvature of smectic layers.
摘要本文重新审视了液晶物理学中的一个经典问题:向列型液晶的弹性模式是什么?该分析使用了最近的数学结构,将指向矢梯度张量分解为四种不同类型的数学对象,分别表示展开、扭曲、弯曲和第四种变形模式。利用这种结构,Oseen-Frank自由能可以写成四种模式的平方和,鞍展开可以被视为体积而不是表面弹性。这种解释为思考液晶物理学中先前的几个结果提供了另一种方式,包括:(1)胆甾醇相和蓝相之间的自由能平衡,(2)混合排列向列相单元中的指向矢变形,(3)限制在环面或圆柱体中的非手性液晶的自发扭曲,以及(4)近晶层的曲率。
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引用次数: 72
Nematicons: reorientational solitons from optics to photonics 向列矩阵:从光学到光子学的重定向孤子
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2018-07-03 DOI: 10.1080/21680396.2019.1588797
G. Assanto
ABSTRACT The most recent advances on phenomena and effects which involve spatial optical solitons stemming from the reorientational optical response of nematic liquid crystals, the so called Nematicons, are reviewed hereby. After the initial assessment and basic understanding, in the past few years, significant progress on nematicon optics has included cavity-less beam bistability and hysteresis, spontaneous symmetry breaking, power-adjusted refraction, curved waveguides. In photonics, a novel approach for the bottom-up realization of permanent optical waveguides has been introduced, as well as a soliton-aided random laser with enhanced directionality and pointing control.
摘要本文综述了由向列相液晶的重定向光学响应引起的空间光孤子现象和效应的最新进展。经过初步评估和基本了解,在过去几年中,向列型光学的重大进展包括无腔光束双稳态和磁滞、自发对称性破坏、功率调节折射、弯曲波导。在光子学中,介绍了一种自下而上实现永久光波导的新方法,以及一种具有增强方向性和指向控制的孤子辅助随机激光器。
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引用次数: 24
Ferroelectric liquid crystal nanocomposites: recent development and future perspective 铁电液晶纳米复合材料的最新发展与展望
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2018-07-03 DOI: 10.1080/21680396.2019.1589400
S. Yadav, Kanchan Yadav, J. Lahiri, Avanish Singh Parmar
ABSTRACT In recent years, dispersion of nanomaterials in liquid crystal media has attracted a great deal of attention for their applications in various fields and basic understanding. In this regard, nanocomposites of ferroelectric liquid crystals hold a great promise for technological advancement in displays, sensors, development of hybrid materials for optical applications and others. With the emphasis on the properties of ferroelectric liquid crystals, this paper presents a summarizing overview with critical comments on the progress made in last one decade in understanding the influence of nanoparticles on the ferroelectric liquid crystals. The dispersion of nanoparticles in liquid crystal (host material) significantly influences its properties, thereby making the dispersed material more promising for potential applications.
摘要近年来,纳米材料在液晶介质中的分散因其在各个领域的应用和基本认识而引起了人们的广泛关注。在这方面,铁电液晶的纳米复合材料在显示器、传感器、光学应用混合材料的开发等方面具有巨大的技术进步前景。本文以铁电液晶的性质为重点,对近十年来在理解纳米颗粒对铁电液晶的影响方面取得的进展进行了综述和评论。纳米颗粒在液晶(主体材料)中的分散显著影响其性能,从而使分散的材料更具潜在应用前景。
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引用次数: 15
Pierre-Gilles de Gennes and physics of liquid crystals Pierre-Gilles de Gennes和液晶物理学
IF 5.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Pub Date : 2018-07-03 DOI: 10.1080/21680396.2018.1474813
A. A. Sonin
ABSTRACT A contribution of the well-known physicist-theoretician, the Nobel prize laureate P.-G. de Gennes to the liquid crystal research is analyzed. A history of creation by de Gennes of the so-called Orsay liquid crystal group is also described and a brief scientist’s biography is given.
著名物理学家、理论家、诺贝尔奖得主p.g.爱因斯坦的贡献。对德热纳对液晶的研究进行了分析。德·热纳对所谓的奥赛液晶群的创造历史也进行了描述,并给出了简要的科学家传记。
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引用次数: 5
期刊
Liquid Crystals Reviews
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