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Synthesis and coating properties of (La0.5Eu0.25Y0.25)2Zr2O7 ceramic powder (La0.5Eu0.25Y0.25)2Zr2O7陶瓷粉末的合成与涂层性能
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-24 DOI: 10.1177/02670836241247751
Chao Yan, Xiufang Cui, Yongzhi Jing, Zhuo Chen, Rui Wang, Guo Jin, Jinna Liu
The (La0.5Eu0.25Y0.25)2Zr2O7 (LEYZ) ceramic powder for spraying was prepared and synthesised by combining spray granulation and solid phase reaction phase, and a double ceramic layer structure with (La0.5Eu0.25Y0.25)2Zr2O7 ceramic surface coating and YSZ intermediate coating was prepared by atmospheric plasma spraying. Experimental characterisation revealed that the moulding state of spray granulated powders was significantly influenced by the solid content. When the solid content is small, the viscosity of the slurry is insufficient, and the prepared powder has poor formability and small overall particle size. When the solid content is large, the slurry is too viscous, which easily leads to unfavourable conditions such as sticky walls. The best formability of the pelletised powder was obtained with a solid content of 55 wt-% and a binder content of 2.0 wt-%. Compared with La2Zr2O7 (LZ) ceramics, the fracture toughness of the rare-earth co-doped modified LEYZ ceramic coating was increased by 8.4% and the bond strength was increased by 49.9%, showing good toughness and crack resistance. Moreover, LEYZ coating has significantly better resistance to solid phase particle erosion than LZ coating, with 46.3% and 45.4% reduction in erosion rate at 45° and 90°, respectively.
采用喷雾造粒和固相反应相结合的方法制备合成了(La0.5Eu0.25Y0.25)2Zr2O7(LEYZ)喷涂用陶瓷粉末,并通过大气等离子体喷涂制备了(La0.5Eu0.25Y0.25)2Zr2O7 陶瓷表面涂层和 YSZ 中间涂层的双陶瓷层结构。实验表征表明,喷雾造粒粉末的成型状态受固体含量的影响很大。固体含量少时,浆料的粘度不够,制备的粉末成型性差,整体粒度小。固体含量大时,浆液粘度过高,容易导致粘壁等不利情况。固体含量为 55 wt-%、粘合剂含量为 2.0 wt-%时,颗粒粉末的成型性最好。与 La2Zr2O7(LZ)陶瓷相比,稀土共掺改性 LEYZ 陶瓷涂层的断裂韧性提高了 8.4%,粘结强度提高了 49.9%,显示出良好的韧性和抗裂性。此外,LEYZ 涂层的抗固相颗粒侵蚀能力明显优于 LZ 涂层,在 45° 和 90° 时侵蚀率分别降低了 46.3% 和 45.4%。
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引用次数: 0
Effect of surface roughness and eutectic segregation on anodising of Al-Si-Cu alloys 表面粗糙度和共晶偏析对铝硅铜合金阳极氧化的影响
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-22 DOI: 10.1177/02670836241245205
G. Scampone, G. Timelli
To study the influence of the surface roughness and eutectic silicon segregation on the anodising of diecast Al-Si-Cu alloys, an AlSi11Cu2(Fe) alloy was high-pressure diecast and hard anodised. The microstructure and surface topography of milled and grit-blasted regions were investigated to analyse their effect on the growth of the anodic layer. The surface mechanical properties of the anodised surfaces were also studied. The results showed how high surface roughness and silicon segregation present in the grit-blasted surface hindered the thickening of the oxide layer. After anodising, the milled surface exhibited better mechanical properties than the grit-blasted one. The wear resistance was enhanced by a thicker anodic layer, while the scratch resistance was positively affected by a lower surface roughness.
为了研究表面粗糙度和共晶硅偏析对压铸铝硅铜合金阳极氧化的影响,对一种 AlSi11Cu2(Fe)合金进行了高压压铸和硬质阳极氧化。研究了铣削和喷砂区域的微观结构和表面形貌,以分析它们对阳极氧化层生长的影响。此外,还研究了阳极氧化表面的表面机械性能。结果表明,喷砂表面的高表面粗糙度和硅偏析阻碍了氧化层的增厚。阳极氧化后,研磨表面的机械性能优于喷砂表面。较厚的阳极氧化层增强了耐磨性,而较低的表面粗糙度则对耐刮擦性产生了积极影响。
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引用次数: 0
Enhancement of strength–ductility combination and corrosion resistance behaviour in (FeCoNiCr)92Ti3.5Al4.5 high-entropy alloy 增强(FeCoNiCr)92Ti3.5Al4.5 高熵合金的强度-电导率组合和耐腐蚀性能
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-18 DOI: 10.1177/02670836241247721
Yun Zou, Rongtao Shen, Yang Lian, Yang Li
The effects of thermo-mechanical treatment on the mechanical properties and corrosion resistance behaviour of the (FeCoNiCr)92Ti3.5Al4.5 (at.-%) high-entropy alloy (HEA) were studied. Compared with the untreated specimen, the yield and ultimate tensile strength increased by 227.5% and 129.4% after thermo-mechanical treatment, with ductility remaining almost constant. The results indicated that the grain size refined from 233.44 to 2.31 μm, and the dislocation density considerably increased from 2.69 × 1012 to 1.23 × 1014. Notably, after thermo-mechanical treatment, the formation of precipitates can narrow the passivation zone, thus increasing the tendency of pitting corrosion. The corrosion current decreased and the radius of the impedance curve increased, indicating the corrosion resistance behaviour improved, which was attributed to the grain refinement.
研究了热机械处理对 (FeCoNiCr)92Ti3.5Al4.5 (at.-%) 高熵合金 (HEA) 的机械性能和耐腐蚀性能的影响。与未处理的试样相比,热机械处理后的屈服强度和极限抗拉强度分别提高了 227.5% 和 129.4%,而延展性几乎保持不变。结果表明,晶粒尺寸从 233.44 微米细化到 2.31 微米,位错密度从 2.69 × 1012 显著增加到 1.23 × 1014。值得注意的是,经过热机械处理后,析出物的形成会缩小钝化区,从而增加点蚀倾向。腐蚀电流减小,阻抗曲线半径增大,表明耐腐蚀性能得到改善,这归因于晶粒细化。
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引用次数: 0
Texture evolution and stress formation behaviour during tensile deformation using crystalplasticity finite element method 使用晶体塑性有限元法分析拉伸变形过程中的纹理演变和应力形成行为
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-18 DOI: 10.1177/02670836241246663
Yang Qu, Qi Zhao, Dongwei Ma
In this work, a three-dimensional crystal plasticity (CP) model was constructed to study the texture evolution behaviour and stress distribution of AA2024 alloy under uniaxial tensile conditions. After parameter calibration, the accuracy of simulated stress–strain curve reached 98.82%, and with good convergence. It was found that the {111} plane dots of Brass in (111) pole figure predominantly prolong at an angle of approximately 35.8° with respect to the RD, while those of Copper, S, Goss and Cube scatter towards almost all directions by the way in a circular augmentation. Moreover, it was revealed that Brass orientation is more conducive to alleviating stress during deformation process, while Copper is the least effective. The situations for Cube and Goss orientations are similar.
本文构建了三维晶体塑性(CP)模型,以研究 AA2024 合金在单轴拉伸条件下的纹理演变行为和应力分布。经过参数校准,模拟应力应变曲线的准确率达到 98.82%,且收敛性良好。研究发现,黄铜的{111}平面点在(111)极图中主要以与 RD 约 35.8° 的角度延伸,而铜、S、Goss 和立方体的{111}平面点则以环形增强的方式向几乎所有方向散布。此外,研究还表明,黄铜取向更有利于在变形过程中减轻应力,而铜取向的效果最差。立方体和戈斯取向的情况类似。
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引用次数: 0
Tribological behaviour of Fe-based amorphous coating at elevated temperatures 铁基非晶涂层在高温下的摩擦学特性
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-17 DOI: 10.1177/02670836241247739
Yongkang Zhang, Haimin Zhai, Yu Bian, Wensheng Li, S. Cui, Zhornik Viktor, Uladzimir Seniuts
Fe-based amorphous coatings (AMCs) were deposited using detonation spraying technology to investigate its performance in high-temperature wear conditions. The results indicate that the detonation-sprayed Fe-based AMC possesses a dense structure, low porosity, high amorphous phase content. At 300 °C, the coating has a maximum wear rate of 6.53 × 10−6 mm3 N−1 m−1, which is almost three times that at room temperature. The main wear mechanisms are oxidative wear, accompanied by fatigue stripping wear and adhesive wear. At 500 °C, the wear scar surface demonstrates increased toughness, resisting plastic deformation due to high-temperature softening. Additionally, partial crystallisation occurs, leading to an overall increase in the hardness of coating. Combined, these factors reduce the wear rate of the coating.
采用爆轰喷涂技术沉积了铁基非晶涂层(AMC),以研究其在高温磨损条件下的性能。结果表明,雷管喷涂的铁基非晶涂层具有致密的结构、低孔隙率和高非晶相含量。300 °C 时,涂层的最大磨损率为 6.53 × 10-6 mm3 N-1 m-1,几乎是室温下磨损率的三倍。主要磨损机理是氧化磨损,同时伴有疲劳剥离磨损和粘着磨损。在 500 °C时,磨损痕表面的韧性增加,可抵抗高温软化引起的塑性变形。此外,部分结晶也会发生,从而导致涂层硬度的整体提高。这些因素结合在一起,降低了涂层的磨损率。
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引用次数: 0
Effect of C-Mn-Cu on microstructure and properties of wire arc additive manufacturing of high-manganese steels C-Mn-Cu 对高锰钢线弧增材制造微观结构和性能的影响
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-17 DOI: 10.1177/02670836241242566
Jingjing Peng, Tianli Zhang, Lianyong Xu, Geng Chen, Donghai Hu, Zhiming Zhu, Jianguo Ma, Kou Sindo
High-manganese steels, due to their unique combination of strength and elongation, have been widely used in aerospace, petrochemical and rail transportation. However, a prevalent challenge in advancing the utilization of high-manganese steel is the need for corresponding welding consumables. The deformation mechanism of high-manganese steel encompasses three primary mechanisms: martensitic phase transformation, twinning and dislocation movement. The stacking fault energy (SFE) is a critical factor in determining the dominant deformation mechanism in high-manganese austenitic steels. Furthermore, the magnitude of the SFE is principally influenced by the alloying elements present and the temperature at which deformation occurs. Alloying elements can significantly influence the microstructure and mechanical properties of wire arc additive manufacturing (WAAM) of high-manganese steels. The metal powder-cored wire of high-manganese steel with full austenitic microstructure was designed in this paper. The effects of C, Mn and Cu on the microstructure, solute segregation and properties of WAAM of high-manganese steels were systematically investigated by optical microscopy, electron microscopy and mechanical testing. The influence of SFE on the microstructure characteristics and work hardening behaviour were also studied. The results showed that as an increase of the C content, the tensile strength and elongation of deposited metals were improved. The corresponding low-temperature impact toughness increased at first and then decreased. The highest value of impact toughness was 68.5 J with 0.79%C. As the Mn increased, the strength decreased, the elongation increased and the low-temperature impact toughness value displayed an initial increase followed by a subsequent decrease. With the increase of Cu, the yield strength and elongation improved significantly. The tensile strength exhibited a marginal initial increase followed by a decrease, whereas the change was not substantial. In contrast, the low-temperature impact toughness value showed a substantial increase followed by a decrease. The developed M3 wire containing 1.10%C-21%Mn-0.3%Cu possessed the optimum performance (yield strength of 551 MPa, tensile strength of 909 MPa, elongation at break of 30.2%, impact toughness value of 57.5J), with the good mechanical stability and low solidification cracking sensitivity.
高锰钢因其强度和伸长率的独特组合,已被广泛应用于航空航天、石油化工和轨道交通领域。然而,推进高锰钢应用的一个普遍挑战是需要相应的焊接材料。高锰钢的变形机制主要包括三种:马氏体相变、孪晶和位错运动。堆积断层能(SFE)是决定高锰奥氏体钢主要变形机制的关键因素。此外,SFE 的大小主要受存在的合金元素和发生变形时的温度影响。合金元素会极大地影响高锰钢线弧快速成型(WAAM)的微观结构和机械性能。本文设计了具有全奥氏体显微结构的高锰钢金属粉末包芯线。通过光学显微镜、电子显微镜和力学测试系统地研究了C、Mn和Cu对高锰钢WAAM的微观结构、溶质偏析和性能的影响。此外,还研究了 SFE 对微观结构特征和加工硬化行为的影响。结果表明,随着 C 含量的增加,沉积金属的抗拉强度和伸长率都有所提高。相应的低温冲击韧性先上升后下降。0.79%C 时,冲击韧性的最高值为 68.5 J。随着锰含量的增加,强度降低,伸长率增加,低温冲击韧性值呈现先增加后降低的趋势。随着铜含量的增加,屈服强度和伸长率显著提高。拉伸强度最初略有上升,随后有所下降,但变化不大。与此相反,低温冲击韧性值先大幅上升后下降。所开发的含 1.10%C-21%Mn-0.3%Cu 的 M3 线材具有最佳性能(屈服强度为 551 兆帕、抗拉强度为 909 兆帕、断裂伸长率为 30.2%、冲击韧性值为 57.5J),并且具有良好的机械稳定性和较低的凝固开裂敏感性。
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引用次数: 0
Microstructure and property evolution during tempering of a medium carbon bainitic steel 中碳贝氏体钢回火过程中的微观结构和性能演变
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-16 DOI: 10.1177/02670836241240370
Sumanta Mandal, Pampa Ghosh, Ajeet Singh Rajput, Sonu Yadav, Arunansu Haldar
Tempering a medium carbon carbide-free bainite steel led to two distinct microstructures and properties below and above the bainitic start (Bs) temperature. Austenite decomposition during tempering, depended on carbon content, tempering temperatures and time, determining retained austenite (RA) stability. Up to 400 °C, most RA remained intact, but a significant reduction occurred above the Bs temperature. Film austenite primarily turned into carbides within the bainitic–ferrite matrix and form lines of carbide particles, while blocky austenite decomposed into troostite at 500 °C and sorbite at 600 °C. During tempering, on the other hand, bainitic ferrite lost tetragonality losing its carbon and resulting in the growth of bainitic–ferrite plates through grain boundary migration and misorientation annihilation. Above Bs, drastic microstructural changes caused significant alterations in tensile properties.
对中碳无碳化物贝氏体钢进行回火,在贝氏体开始(Bs)温度以下和以上会产生两种截然不同的微观结构和性能。回火过程中奥氏体的分解取决于碳含量、回火温度和时间,决定了残余奥氏体(RA)的稳定性。回火温度最高可达400 °C,大部分奥氏体保持完好,但超过Bs温度后奥氏体明显减少。膜状奥氏体主要在贝氏体-铁素体基体中转变成碳化物,并形成碳化物颗粒线,而块状奥氏体在500 ℃时分解成托氏体,在600 ℃时分解成索氏体。另一方面,在回火过程中,贝氏体铁素体失去了四方性,失去了碳,并通过晶界迁移和错位湮灭导致贝氏体-铁素体板的生长。当温度超过 Bs 时,微观结构的急剧变化会导致拉伸性能的显著改变。
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引用次数: 0
Influence of second phase precipitates on the microstructure and mechanical properties of WE43-0.5Ca alloy during hot deformation process 热变形过程中第二相析出物对 WE43-0.5Ca 合金微观结构和机械性能的影响
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-15 DOI: 10.1177/02670836241245817
Mengyuan Xia, Hui-wen Zhu, B. Yu, Li Zheng, Shunning Lv, Lei Li, Tao Huang
The WE43-0.5Ca alloy was processed by the combination of extrusion, ageing treatment and rolling in the present study. The results showed that the strength of the alloy is better at an extrusion temperature of 470 °C. The alloy was then subjected to ageing treatment. The alloy aged for 14 h had the highest strength. However, there was still a high amount of the second phase enriched at the shear bands. The as-extruded state alloy was rolled. The strength of the alloy in the rolled state was significantly increased. Broken into fine second-phase particles during rolling, these second-phase particles are diffusely distributed in the matrix, resulting in second-phase strengthening that enhances the strength of the alloy.
本研究采用挤压、时效处理和轧制相结合的方法对 WE43-0.5Ca 合金进行了加工。结果表明,挤压温度为 470 ℃ 时,合金的强度较高。然后对合金进行时效处理。时效处理 14 小时的合金强度最高。然而,在剪切带处仍然富集了大量的第二相。对挤压状态的合金进行轧制。轧制状态下的合金强度显著提高。在轧制过程中破碎成细小的第二相颗粒,这些第二相颗粒弥散地分布在基体中,导致第二相强化,从而提高了合金的强度。
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引用次数: 0
Microstructural and electrochemical behaviour of severely surface-deformed 316L steel manufactured by conventional and selective laser melting routes 采用传统和选择性激光熔化工艺制造的严重表面变形 316L 钢的微观结构和电化学特性
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-13 DOI: 10.1177/02670836241245811
Vikesh Kumar, Nilesh K. Kumbhar, Manoj D. Joshi, Yuan-Ron Ma, Indrasen Singh, S. Hosmani
This study thoroughly examines the influence of conventional and selective laser melting (SLM) routes and surface mechanical attrition treatment (SMAT) on the microstructural and electrochemical properties of 316L steel. Compared to wrought specimens, the SLM specimens exhibit significantly smaller grains (∼41 vs. ∼83 µm) and higher dislocation density (∼7.2 × 1013 vs. ∼3.7 × 1012 m−2). Both specimens show nearly doubled surface hardness after SMAT, with the SLM surface displaying a ∼30 nm grain size and minimal α’ phase. The microstructure significantly influences passivation and corrosion behaviour. The SLM specimens exhibit superior electrochemical characteristics to wrought counterparts in SMATed (0.00299 mmpy) and non-SMATed (0.00771 mmpy) conditions. SMAT effectively eliminates surface porosity, enhancing the passivation and corrosion resistance of SLM steel.
本研究深入探讨了传统和选择性激光熔化 (SLM) 工艺以及表面机械损耗处理 (SMAT) 对 316L 钢微观结构和电化学性能的影响。与锻造试样相比,SLM 试样的晶粒明显更小(∼41 对 ∼83 µm),位错密度更高(∼7.2 × 1013 对 ∼3.7 × 1012 m-2)。在 SMAT 之后,两种试样的表面硬度都提高了近一倍,SLM 表面的晶粒大小为 ∼30 nm,α'相最小。微观结构对钝化和腐蚀行为有重大影响。在 SMAT(0.00299 mmpy)和非 SMAT(0.00771 mmpy)条件下,SLM 试样的电化学特性优于锻造试样。SMAT 能有效消除表面孔隙,提高 SLM 钢的钝化和耐腐蚀性。
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引用次数: 0
A survey of the high-cycle fatigue performance of additively manufactured alloy 718 快速成型合金 718 的高循环疲劳性能调查
IF 1.8 4区 材料科学 Q2 Engineering Pub Date : 2024-04-13 DOI: 10.1177/02670836241245214
Matthew Mills, Meurig Thomas
This paper presents a survey of the published high-cycle fatigue (hcf) data for the nickel–iron superalloy alloy 718 fabricated by additive manufacture. Approximately 680 fatigue data points were collected from the published literature and the reported data are presented in the form of stress versus cycles to failure curves for load ratios of R = −1, 0 and 0.1. Following this, curves showing estimated survival probabilities of 0.5, 0.95 and 0.99 are constructed using a statistical analysis based on the Weibull probability density function. Finally, a comparison between the fatigue performance of additively manufactured and wrought alloy 718 under fully reversed loading conditions ( R = −1) is provided.
本文对已发表的通过添加剂制造的镍铁超级合金 718 的高循环疲劳(hcf)数据进行了调查。本文从已发表的文献中收集了约 680 个疲劳数据点,并以 R =-1、0 和 0.1 负载比时的应力与失效循环曲线的形式展示了所报告的数据。随后,利用基于 Weibull 概率密度函数的统计分析,构建了显示 0.5、0.95 和 0.99 估计存活概率的曲线。最后,比较了在完全反向加载条件(R =-1)下添加制造和锻造合金 718 的疲劳性能。
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引用次数: 0
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