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Correction: Cu(i) diimine complexes as immobilised antibacterial photosensitisers operating in water under visible light. 更正:作为固定化抗菌光敏剂的 Cu(i) 二亚胺配合物在可见光下可在水中工作。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-11 DOI: 10.1039/d4ma90119c
Martin V Appleby, Peter G Walker, Dylan Pritchard, Sandra van Meurs, Carly M Booth, Craig Robertson, Michael D Ward, David J Kelly, Julia A Weinstein

[This corrects the article DOI: 10.1039/D0MA00642D.].

[此处更正了文章 DOI:10.1039/D0MA00642D]。
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引用次数: 0
Selective placement of functionalised DNA origami via thermal scanning probe lithography patterning. 通过热扫描探针光刻技术图案化选择性放置功能化 DNA 折纸。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1039/d4ma00828f
Tingting Zheng, Caoimhe O'Neill, John F Marshall, Thomas Iskratsch, Matteo Palma

Here we present a nanopatterning strategy utilising thermal scanning probe lithography (t-SPL) for the precise organisation of DNA origami into nanoarrays. The aim of this approach is to demonstrate control in the fabrication of nanoarray platforms exhibiting single-molecule accuracy. Combining the inherent programmability of DNA origami structures with t-SPL nanopatterning, we demonstrated the controlled immobilisation on surfaces of functionalised DNA origami - as proof of concept we employed gold nanoparticles (AuNPs) and quantum dots (QDs) - at predefined positions and in nanoarray configurations. This method holds great potential for the construction of hetero-functionalised biomolecular nanoarrays with single-molecule control, with applications in bionanotechnology and (nano)materials science.

在这里,我们介绍一种利用热扫描探针光刻技术(t-SPL)将 DNA 折纸精确组织成纳米阵列的纳米图案化策略。这种方法的目的是展示对纳米阵列平台制造的控制,展现单分子精度。结合 DNA 折纸结构固有的可编程性和 t-SPL 纳米图案化技术,我们展示了在预定位置和纳米阵列配置上可控地固定功能化 DNA 折纸(作为概念验证,我们采用了金纳米粒子(AuNPs)和量子点(QDs))。这种方法在构建单分子控制的异功能化生物分子纳米阵列方面具有巨大潜力,可应用于仿生技术和(纳米)材料科学。
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引用次数: 0
Synthesis and magneto-dielectric properties of Ti-doped Ni0.5Zn0.5TixFe2−xO4 ferrite via a conventional sol–gel process 通过传统溶胶-凝胶工艺合成掺 Ti- 的 Ni0.5Zn0.5TixFe2-xO4 铁氧体及其磁介质特性
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1039/D4MA00529E
M. Farzana Alam, M. Atikur Rahman, Md. Sarowar Hossain, M. N. I. Khan, R. Rashid, M. Saiful Islam, William Ghann, M. K. Alam and Jamal Uddin

Ni–Zn-based ferrites (NZFO) need to possess the ideal ratio of dielectric and magnetic characteristics for uses involving electromagnetic fields. Consequently, the NZFO system has been modified by Ti4+ substitution at Fe3+ producing Ni0.5Zn0.5TixFe2−xO4 (x = 0.00, 0.02, 0.04, 0.06, 0.08 and 0.10) and a conventional sol–gel process was followed for the synthesis. The structure of the synthesized samples was evaluated from the X-ray diffraction (XRD) patterns. Fourier transform infrared (FTIR) measurement provided information on chemical interaction with thermodynamic conditions. In addition, the grain sizes were obtained from scanning electron microscopy (SEM). Furthermore, the studied samples exhibit a notable light absorption in the visible spectrum with band gaps between 3.8 and 4.8 eV. The magneto-dielectric properties were analyzed by field (H) dependent magnetization (M), frequency-dependent permeability (μ), and permittivity (ε) measurements. Ti4+ substitution in NZFO led to a decrease in magnetic saturation (Ms) and μ while the values of creased and improved the mismatching impedance (Z/η0 = (μ′/ε′)1/2). The lowest value of Ms (14 emu g−1) is achieved for the sample with x = 0.1 for which μ is also the lowest. Finally, a stable value of Z/η0 (∼4.0) has been obtained for the x = 0.10 sample over a wide range of frequencies (1–10 MHz), making it suitable as a miniaturizing device material in this frequency range.

镍锌基铁氧体(NZFO)需要具备理想的介电特性和磁特性比例,才能用于涉及电磁场的用途。因此,对 NZFO 体系进行了改良,用 Ti4+ 取代 Fe3+,生成了 Ni0.5Zn0.5TixFe2-xO4(x = 0.00、0.02、0.04、0.06、0.08 和 0.10),并采用传统的溶胶-凝胶工艺进行合成。通过 X 射线衍射(XRD)图对合成样品的结构进行了评估。傅立叶变换红外(FTIR)测量提供了化学作用与热力学条件的信息。此外,还通过扫描电子显微镜(SEM)获得了晶粒尺寸。此外,所研究的样品在可见光谱中有明显的光吸收现象,带隙在 3.8 至 4.8 eV 之间。通过磁场(H)相关磁化率(M)、频率相关磁导率(μ)和介电常数(ε)的测量,分析了样品的磁介电特性。在 NZFO 中取代 Ti4+ 会导致磁饱和度(Ms)和 μ 下降,而磁饱和度(Ms)和 μ 的值上升,并改善了错配阻抗(Z/η0 = (μ′/ε′)1/2)。在 x = 0.1 的样品中,Ms 值最低(14 emu g-1),μ 值也最低。最后,x = 0.10 的样品在很宽的频率范围(1-10 MHz)内都能获得稳定的 Z/η0 值(∼4.0),因此适合作为该频率范围内的微型器件材料。
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引用次数: 0
Biocompatible and low-cost iodine-doped carbon dots as a bifunctional fluorescent and radiocontrast agent for X-ray CT imaging† 生物相容性和低成本碘掺杂碳点作为双功能荧光和放射对比剂用于 X 射线 CT 成像†。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-29 DOI: 10.1039/D4MA00823E
Timur Sh. Atabaev, Dinara Askar, Zarina Baranchiyeva, Balnur A. Zhainsabayeva, Timur Elebessov, Moon Sung Kang, Bakyt Duisenbayeva, Ellina A. Mun, Tri Thanh Pham and Dong-Wook Han

Carbon dot-based radiocontrast agents have recently sparked the interest of researchers owing to their better contrasting capabilities, simple synthesis protocols, high colloidal stability, and good biocompatibility. In this study, we propose for the first time the synthesis of iodine-doped carbon dots (I-CDs) using low-cost reagents such as citric acid (C6H8O7), urea (CH4N2O) and potassium iodide (KI). The as-prepared I-CDs demonstrated excellent colloidal stability (with a zeta potential value of −64.7 mV), excitation-dependent fluorescent properties (with a maximum quantum yield of ∼8.9%), and a mean iodine concentration of ∼4.67 wt%. Notably, the as-prepared I-CDs displayed greater X-ray attenuation efficiency (42.87 HU mL mg−1) as compared to the commercially employed iopromide radiocontrast agent (30.98 HU mL mg−1). Furthermore, ATPase activity, cytotoxicity analysis with HeLa, NHDF, HEK293, and A549 cell lines, and live-cell imaging experiments of the Drosophila neuroblasts in intact brain lobes suggested high biocompatibility and nontoxicity of the prepared I-CDs. Overall, biocompatible and low-cost I-CDs show great promise as bifunctional radiocontrast and fluorescent agents for biomedical applications.

以碳点为基础的放射对比剂因其较好的对比能力、简单的合成方案、较高的胶体稳定性和良好的生物相容性,最近引发了研究人员的兴趣。在本研究中,我们首次提出使用柠檬酸(C6H8O7)、尿素(CH4N2O)和碘化钾(KI)等低成本试剂合成碘掺杂碳点(I-CDs)。所制备的 I-CD 具有优异的胶体稳定性(zeta 电位值为 -64.7 mV)、激发相关荧光特性(最大量子产率为 8.9%)和平均碘浓度为 4.67 wt%。值得注意的是,与市场上使用的碘普罗米德放射性对比剂(30.98 HU mL mg-1)相比,制备的 I-CD 具有更高的 X 射线衰减效率(42.87 HU mL mg-1)。此外,ATPase 活性、HeLa、NHDF、HEK293 和 A549 细胞系的细胞毒性分析以及果蝇神经细胞在完整脑叶中的活细胞成像实验表明,制备的 I-CD 具有很高的生物相容性和无毒性。总之,生物相容性好且成本低廉的 I-CDs 作为双功能放射对比剂和荧光剂在生物医学应用中大有可为。
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引用次数: 0
Improved performance of a SWCNT/ZnO nanostructure-integrated silicon thin-film solar cell: role of annealing temperature 提高集成了 SWCNT/ZnO 纳米结构的硅薄膜太阳能电池的性能:退火温度的作用
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-29 DOI: 10.1039/D4MA00726C
Nandang Mufti, Olga Dilivia Ardilla, Erma Surya Yuliana, Retno Fitri Wulandari, Ahmad Taufiq, Henry Setiyanto, Muhammad Aziz, Ali Aqeel Salim, Risa Suryana and Wilman Septina

Efficiency improvement of heterogeneous silicon thin-film solar cells (SiTFSCs) remains challenging. Thus, single-walled carbon nanotube (SWCNT) and zinc oxide nanostructures (ZnO NCs) were integrated into Si thin films using the spray-spin coating approach to realize such solar cells. The effect of various annealing temperatures (100–175 °C) on the solar cells’ efficiency, structure, morphology, and absorbance was assessed. X-ray diffraction analysis confirmed the existence of highly crystalline wurtzite and hexagonal structures corresponding to ZnO and graphite with maximum nanocrystallite sizes of 51.92 nm. Scanning electron microscopy images of the samples showed uniform surface morphology without any aggregation. In addition, with the increase of the annealing temperature from 100 to 175 °C, the efficiency, porosity, optical absorbance bands, and band gap energy of the films were increased from 17.0–18.6%, 70–74.8%, 246–326 nm, and 2.0–2.5 eV, respectively. It was asserted that by controlling the annealing temperature, the overall performance of the proposed SWCNT/ZnO NC-integrated SiTFSC can be enhanced, contributing to the further advancement of high-performance Si-based photovoltaics.

提高异质硅薄膜太阳能电池(SiTFSCs)的效率仍然具有挑战性。因此,为了实现这种太阳能电池,研究人员采用喷旋镀膜方法将单壁碳纳米管(SWCNT)和氧化锌纳米结构(ZnO NCs)集成到硅薄膜中。评估了不同退火温度(100-175 °C)对太阳能电池的效率、结构、形态和吸光度的影响。X 射线衍射分析证实,存在与氧化锌和石墨相对应的高结晶菱面体和六方体结构,最大纳米晶粒尺寸为 51.92 nm。样品的扫描电子显微镜图像显示出均匀的表面形态,没有任何聚集现象。此外,随着退火温度从 100 ℃ 升高到 175 ℃,薄膜的效率、孔隙率、光学吸光度带和带隙能分别从 17.0%-18.6%、70%-74.8%、246-326 nm 和 2.0-2.5 eV 增加。研究认为,通过控制退火温度,可以提高所提出的 SWCNT/ZnO NC 集成 SiTFSC 的整体性能,为进一步推动高性能硅基光伏技术的发展做出贡献。
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引用次数: 0
Exploring the chemistry and composition of black soldier fly eumelanin, a material for a circular economy† 探索循环经济材料--黑色兵蝇乌黑色素的化学成分和组成†。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1039/D4MA00825A
A. B. Mostert, S. Mattiello, S. Li, G. Perna, M. Lasalvia, P. F. Ambrico, J. V. Paulin, J. V. M. Lima, C. F. O. Graeff, J. W. Phua, M. Matta, A. J. Surman, R. Gunnella and M. Ambrico

Eumelanin is a black-brown biopigment that provides photoprotection and pigmentation in mammals, insects, and invertebrates. It can be obtained by oxidative polymerisation of 5,6-dihydroxyindole (DHI) and its 2-carboxylic acid (DHICA). Due to its unique physical and chemical properties and its biocompatibility, eumelanin is a promising biomaterial for applications in energy storage, biomedicine, and sensing. However, poor solubility in water and lack of sustainable and low-cost sources of eumelanin have so far limited the full exploitation of this biomaterial. Insect farming is rapidly emerging as an alternative source of eumelanin. Unlike other types of eumelanin, BSF eumelanin, which is extracted from the exoskeleton of the black soldier fly (BSF, Hermetia illucens), is water-dispersible; however, its fundamental chemical properties are not completely understood. Here, we report the characterisation of BSF eumelanin using various spectroscopy techniques. Contrary to what is known about other insect eumelanins, which are believed to contain exclusively DHI, our results indicate that BSF eumelanin may contain both DHI and DHICA moieties. We discuss the potential reasons for this discrepancy.

乌黑色素是一种黑褐色生物色素,可为哺乳动物、昆虫和无脊椎动物提供光保护和色素沉着。它可以通过 5,6-二羟基吲哚(DHI)及其 2-羧酸(DHICA)的氧化聚合而获得。由于其独特的物理和化学特性以及生物相容性,乌梅素是一种很有前途的生物材料,可应用于能量储存、生物医学和传感领域。然而,由于在水中的溶解性较差以及缺乏可持续和低成本的乌黑色素来源,迄今为止这种生物材料的充分利用受到了限制。昆虫养殖正在迅速崛起,成为一种可替代的乌黑色素来源。与其他类型的乌黑色素不同,从黑兵蝇(BSF,Hermetia illucens)外骨骼中提取的 BSF 乌黑色素可在水中分散,但其基本化学特性尚未完全明了。在此,我们报告了利用各种光谱技术对 BSF eumelanin 的特性进行的分析。其他昆虫的乌黑色素被认为只含有 DHI,与此相反,我们的研究结果表明 BSF 乌黑色素可能同时含有 DHI 和 DHICA 两个分子。我们将讨论造成这种差异的潜在原因。
{"title":"Exploring the chemistry and composition of black soldier fly eumelanin, a material for a circular economy†","authors":"A. B. Mostert, S. Mattiello, S. Li, G. Perna, M. Lasalvia, P. F. Ambrico, J. V. Paulin, J. V. M. Lima, C. F. O. Graeff, J. W. Phua, M. Matta, A. J. Surman, R. Gunnella and M. Ambrico","doi":"10.1039/D4MA00825A","DOIUrl":"https://doi.org/10.1039/D4MA00825A","url":null,"abstract":"<p >Eumelanin is a black-brown biopigment that provides photoprotection and pigmentation in mammals, insects, and invertebrates. It can be obtained by oxidative polymerisation of 5,6-dihydroxyindole (DHI) and its 2-carboxylic acid (DHICA). Due to its unique physical and chemical properties and its biocompatibility, eumelanin is a promising biomaterial for applications in energy storage, biomedicine, and sensing. However, poor solubility in water and lack of sustainable and low-cost sources of eumelanin have so far limited the full exploitation of this biomaterial. Insect farming is rapidly emerging as an alternative source of eumelanin. Unlike other types of eumelanin, BSF eumelanin, which is extracted from the exoskeleton of the black soldier fly (BSF, <em>Hermetia illucens</em>), is water-dispersible; however, its fundamental chemical properties are not completely understood. Here, we report the characterisation of BSF eumelanin using various spectroscopy techniques. Contrary to what is known about other insect eumelanins, which are believed to contain exclusively DHI, our results indicate that BSF eumelanin may contain both DHI and DHICA moieties. We discuss the potential reasons for this discrepancy.</p>","PeriodicalId":18242,"journal":{"name":"Materials Advances","volume":" 22","pages":" 8986-8999"},"PeriodicalIF":5.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ma/d4ma00825a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142598763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light-induced spiking response in proteinoid–actin–kombucha system 蛋白-肌动蛋白-昆布系统中的光诱导尖峰响应
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-28 DOI: 10.1039/D4MA00791C
Panagiotis Mougkogiannis, Anna Nikolaidou and Andrew Adamatzky

This study examines the spiking response of a proteinoid–actin–kombucha system when exposed to varying frequency of yellow light pulses. The objective is to understand the frequency-dependent characteristics of this system's response and explore the possibility of using light pulses to regulate and manipulate how it functions. The kombucha samples, which contained proteinoid–actin complexes, were exposed to several stimulation conditions. These settings included no light (blank) and yellow light pulses at frequencies of 2 Hz, 4 Hz, 10 Hz, 20 Hz, and 100 Hz. The spiking response was analyzed in terms of potential (mV) over time (s), and the characteristics of the response, such as amplitude and period, were examined. The findings indicate that the spiking patterns and characteristics fluctuate according on the stimulation frequency, with higher frequencies generally leading to more distinct and numerous spikes compared to lower frequencies and the absence of stimulation. The skewness and kurtosis values of the potential data indicate different levels of asymmetry and tail tendency in the probability distributions, which further supports the fact that the response is based on frequency. The study emphasises the capacity to manipulate and regulate the functions of the proteinoid–actin–kombucha system using light pulses, hence creating opportunities for future usage in several domains, including biosensors and biocomputing.

本研究探讨了蛋白酶-肌动蛋白-昆布系统在不同频率的黄色光脉冲照射下的尖峰响应。目的是了解该系统响应的频率依赖性特征,并探索利用光脉冲调节和操纵其功能的可能性。含有蛋白酶-肌动蛋白复合物的昆布样品暴露在几种刺激条件下。这些条件包括无光(空白)和频率分别为 2 赫兹、4 赫兹、10 赫兹、20 赫兹和 100 赫兹的黄色光脉冲。以电位(mV)随时间(秒)的变化对尖峰响应进行了分析,并研究了响应的特征,如振幅和周期。研究结果表明,尖峰模式和特征随刺激频率而波动,与低频和无刺激相比,频率越高,尖峰越明显,数量越多。电位数据的偏度和峰度值表明概率分布存在不同程度的不对称性和尾部趋势,这进一步证实了反应是基于频率的这一事实。这项研究强调了利用光脉冲操纵和调节蛋白酶-肌动蛋白-昆布系统功能的能力,从而为未来在生物传感器和生物计算等多个领域的应用创造了机会。
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引用次数: 0
Tandem NiO–Ni(OH)2/VS2 nanosheets: a robust photocatalyst for hydrogen evolution† NiO-Ni(OH)2/VS2串联纳米片:氢气进化的强效光催化剂†。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-26 DOI: 10.1039/D4MA00789A
Mona S. NourEldien, Mostafa Y. Nassar, Islam M. Ibrahim and Hisham M. Aly

The utilization of hydrogen as a sustainable alternative to fossil fuels is gaining momentum due to its environmental compatibility and recyclability. In this study, we present a novel approach employing a NiO–Ni(OH)2 hybrid decorated on VS2 nanosheets, synthesized through a facile one-pot hydrothermal method, for enhancing the photocatalytic activity in the hydrogen evolution reaction (HER) from a methanol–water mixture under visible light irradiation. The synthesized samples underwent comprehensive characterization via XRD, FT-IR, SEM, TEM, XPS, BET, optical bandgap determination, and electrochemical analyses including CV, LSV, Tafel slope, and EIS Nyquist plot. Characterization results revealed that the presence of a minor quantity of NiO–Ni(OH)2 effectively restrained the growth of VS2 crystallites, leading to a reduction in average crystallite size with increasing NiO–Ni(OH)2 content. XPS analysis confirmed the presence of NiO–Ni(OH)2 on VS2 and the oxidation states of V4+ and Ni2+ cations. Notably, the photocatalytic experiments demonstrated that NiO–Ni(OH)2 served as an excellent co-catalyst for enhancing H2 production over VS2, with the H2 production rate of 41642.2 μmol g−1 h−1 achieved with a loading of 0.8 mol% of NiO–Ni(OH)2 to VS2, surpassing the pristine VS2 by over fourfold. The enhanced H2 production activity was attributed to the accumulation of NiO–Ni(OH)2 particles on the VS2 surface, facilitating efficient movement of photoexcitons and minimizing photogenerated electron–hole pair recombination, thereby reducing hydrogen production overpotential and enhancing catalytic hydrogen generation. The outstanding performance and durability of the NiO–Ni(OH)2/VS2 photocatalyst suggest its potential as a cost-effective and promising candidate for hydrogen evolution reaction photocatalysis.

由于氢气具有环境兼容性和可回收性,氢气作为化石燃料的可持续替代品正日益受到重视。在本研究中,我们提出了一种新方法,即在 VS2 纳米片上装饰一种 NiO-Ni(OH)2 杂化物,这种杂化物是通过一种简便的一锅水热法合成的,用于在可见光照射下提高甲醇-水混合物中氢进化反应(HER)的光催化活性。合成样品通过 XRD、FT-IR、SEM、TEM、XPS、BET、光带隙测定和电化学分析(包括 CV、LSV、Tafel 斜坡和 EIS Nyquist 图)进行了全面表征。表征结果表明,少量 NiO-Ni(OH)2 的存在有效抑制了 VS2 结晶的生长,导致平均结晶尺寸随着 NiO-Ni(OH)2 含量的增加而减小。XPS 分析证实了 VS2 上存在 NiO-Ni(OH)2,以及 V4+ 和 Ni2+ 阳离子的氧化态。值得注意的是,光催化实验表明,NiO-Ni(OH)2 是一种极好的辅助催化剂,可提高 VS2 的 H2 产率,在 VS2 上负载 0.8 摩尔% 的 NiO-Ni (OH)2 时,H2 产率达到 41642.2 μmol g-1 h-1,是原始 VS2 的四倍以上。氢气生产活性的提高归功于 NiO-Ni(OH)2 粒子在 VS2 表面的聚集,促进了光激子的有效移动,最大程度地减少了光生电子-空穴对的重组,从而降低了氢气生产的过电位,提高了催化制氢能力。NiO-Ni(OH)2/VS2光催化剂的出色性能和耐久性表明,它有望成为氢进化反应光催化技术中一种具有成本效益且前景广阔的候选材料。
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引用次数: 0
Crystal size-dependent framework flexibility of a prototypical metal organic framework is related to metal content: zeolitic imidazolate framework-7† 原型金属有机框架的晶体尺寸取决于框架柔韧性与金属含量的关系:沸石咪唑啉框架-7†
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-23 DOI: 10.1039/D4MA00804A
Akalanka B. Ekanayake, Al A. Tiba, Leonard R. MacGillivray and Alexei V. Tivanski

Crystal size engineering is an emerging strategy to modulate mechanical and gas adsorption properties of metal–organic frameworks (MOFs). Fundamental principles on how the properties of these materials change with size remain to be understood and explored. Here, supermicron-, micro-, and nano-sized single crystals of a prototypical MOF zeolitic imidazolate framework-7 (ZIF-7) were generated using a solvothermal method. Atomic force microscopy (AFM) imaging revealed that nano- and micro-sized crystals exhibited rounded and prism-like morphologies, respectively. AFM nanoindentation was used to assess the stiffness (Young's modulus) of the rounded and prism-like crystals as a function of crystal size. We demonstrate that the framework flexibility increases (Young's modulus decreases) with crystal size reduction for both morphologies, which can be attributed to a larger number of point defects (missing metal nodes and/or missing linkers) for smaller crystals. Remarkably, scanning electron microscopy (SEM) energy dispersive X-ray spectroscopy measurements on individual prism-like micro-sized crystals of various sizes revealed a decreasing trend in the Zn/C ratio with crystal size reduction. Collectively, the size-dependent SEM and AFM characterization studies suggest that smaller crystals have lower relative metal content via a larger number of missing metal node defects. Our findings highlight how the mechanical properties of MOFs can vary significantly as a function of crystal size likely due to a variable and size-dependent number of missing metal node defects. Such size-dependent behavior especially towards the nanoscale is thus important to consider for the rational design of various functional crystalline materials.

晶体尺寸工程是调节金属有机框架(MOFs)机械和气体吸附特性的一种新兴策略。关于这些材料的特性如何随尺寸变化的基本原理仍有待了解和探索。本文采用溶热法生成了超微米、微米和纳米尺寸的原型 MOF 唑基咪唑啉框架-7(ZIF-7)单晶。原子力显微镜(AFM)成像显示,纳米和微米大小的晶体分别呈现出圆形和棱柱形形态。原子力显微镜纳米压痕法评估了圆形和棱柱形晶体的刚度(杨氏模量)与晶体尺寸的函数关系。我们发现,随着晶体尺寸的减小,两种形态的框架柔性都会增加(杨氏模量减小),这可能是由于较小晶体中存在较多的点缺陷(缺失的金属节点和/或缺失的连接体)。值得注意的是,对不同尺寸的单个棱柱状微尺寸晶体进行的扫描电子显微镜(SEM)能量色散 X 射线光谱测量显示,随着晶体尺寸的减小,Zn/C 比率呈下降趋势。总之,与晶体尺寸有关的扫描电镜和原子力显微镜表征研究表明,较小的晶体由于存在较多的缺失金属节点缺陷,其相对金属含量较低。我们的研究结果突显了 MOFs 的机械性能如何随着晶体尺寸的变化而发生显著变化,这可能是由于缺失金属节点缺陷的数量可变且与尺寸有关。因此,在合理设计各种功能晶体材料时,必须考虑这种尺寸依赖行为,尤其是纳米级尺寸依赖行为。
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引用次数: 0
Investigating pressure-driven semiconductor-to-metal transition in lead-free perovskites AlGeX3 (X = F, Cl, and Br): insights from first-principles calculations† 无铅过磷酸盐 AlGeX3(X = F、Cl 和 Br)中压力驱动的半导体到金属转变研究:第一原理计算的启示†。
IF 5.2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-22 DOI: 10.1039/D4MA00611A
Md. Amran Sarker, Md. Mehedi Hasan, Md. Rafiqul Islam, Md. Rabbi Talukder, Md. Rasidul Islam and Ahmed Sharif

In the pursuit of commercializing electronic and optoelectronic devices, researchers have turned their attention to non-toxic inorganic cubic metal halide perovskites. This study focuses on novel lead-free compounds—specifically AlGeX3 (where X = F, Cl, and Br) and examines their structural, electronic, optical, and mechanical properties under the application of hydrostatic pressure through density functional theory (DFT). The mechanical stability of all compounds is rigorously assessed using Born stability criteria and formation energy. The elastic investigations reveal that the materials have anisotropy, ductility, and good Machinenabilty index depending on the halide type and applied pressure. The pressure-dependent electronic band structures are calculated by GGA-PBE functional to demonstrate the intriguing behavior of the compounds. Band structures are also calculated by HSE06 functional without pressure. Further, the substitution of the halide F with Cl/Br leads to an indirect to direct band gap transformation. Additionally, increasing positive hydrostatic pressure results in a tunable band gap with decreasing trends for all the compounds leading them to transit from semiconductor to metallic state. This phenomenon is explained by the partial and total density of states (PDOS and TDOS). The improvement of pressure-dependent optical properties in both visible and UV regions makes them valuable contenders in the quest for efficient solar cells and other electronic and optoelectronic devices.

为了实现电子和光电设备的商业化,研究人员将目光转向了无毒的无机立方金属卤化物包晶。本研究侧重于新型无铅化物,特别是 AlGeX3(其中 X = F、Cl 和 Br),并通过密度泛函理论(DFT)研究了它们在静水压力作用下的结构、电子、光学和机械性能。利用博恩稳定性标准和形成能对所有化合物的机械稳定性进行了严格评估。弹性研究表明,这些材料具有各向异性、延展性和良好的机械指数,具体取决于卤化物类型和施加的压力。利用 GGA-PBE 函数计算了与压力有关的电子能带结构,以展示化合物的奇妙行为。此外,还利用 HSE06 函数计算了无压电子能带结构。此外,用 Cl/Br 替代卤化物 F 会导致带隙从间接转变为直接。此外,增加正静水压会导致所有化合物的带隙呈可调的递减趋势,从而使它们从半导体状态转变为金属状态。这种现象可以用部分态密度和总态密度(PDOS 和 TDOS)来解释。在可见光和紫外光区域,压力相关光学特性的改善使它们成为高效太阳能电池和其他电子及光电设备的重要竞争者。
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