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Current Density Regulating Lithium Metal Directional Deposition for Long Cycle Life Lithium Metal Batteries 长循环寿命锂金属电池的电流密度调节定向沉积
Pub Date : 2020-12-19 DOI: 10.2139/ssrn.3751761
Heng Mao, Wei Yu, Zhuanyun Cai, Guixian Liu, Limin Liu, R. Wen, Yaqiong Su, Kai Xi, Benqiang Li, Xinyu Da, H. Kou, Wei Yan, Shujiang Ding
Uncontrolled dendrite formation in the high energy density of lithium metal batteries (LMBs) may pose serious safety risks. Numerous works have been reported to protect separator. However, these methods still couldn’t inhibit the dendrite upward growth to protect the separator, effectively. Here, we introduce a novel “orientated-growth” strategy that makes the depositional interface transfer to the anode/current collector interface from the anode/separator interface. We placed a layer of cellulose/graphene carbon composite aerogel (CCA) between the current collector and the anode (CCA-Li). This layer works as the charge organizer; it induces a higher current density distribution and makes Li prefer to deposit in the bottom CCA layer of CCA-Li electrode. Both in-situ and ex-situ images of the electrode demonstrate the anode part of the cell has been flipped; with the new deposited particles facing the current collector and smooth surface facing the separator. Electrochemical characterization of the electrode in half and full cells showed outstanding cyclic stability and rate capability, with the CCA-Li/LPF full cell able to maintain 94% of its initial capacity after 1000 cycles. We believe that the innovative strategy would promote the leapfrog development for LMBs.
高能量密度锂金属电池中不受控制的枝晶形成可能会带来严重的安全隐患。保护分离器的工作有很多报道。然而,这些方法仍然不能有效地抑制枝晶向上生长以保护分离器。在这里,我们引入了一种新的“定向生长”策略,使沉积界面从阳极/分离器界面转移到阳极/集流器界面。我们在电流收集器和阳极(CCA- li)之间放置了一层纤维素/石墨烯碳复合气凝胶(CCA)。这一层作为电荷组织者;诱导较高的电流密度分布,使Li更倾向于沉积在CCA-Li电极的底部CCA层。电极的原位和非原位图像均表明电池的阳极部分已被翻转;新沉积的颗粒面向集流器,表面光滑面向分离器。电极在半电池和全电池中的电化学表征显示出出色的循环稳定性和倍率能力,CCA-Li/LPF全电池在1000次循环后仍能保持94%的初始容量。我们相信,创新战略将推动中小企业实现跨越式发展。
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引用次数: 0
Self-Cleaning and Self-Cooling Cellulose-Fiber-Based Hierarchical Composites 自清洁和自冷却纤维素-纤维基分层复合材料
Pub Date : 2020-12-14 DOI: 10.2139/ssrn.3748560
Yanpei Tian, Hong Shao, Xiaojie Liu, Fangqi Chen, Yongsheng Li, Changyu Tang, Y. Zheng
Passive daytime radiative cooling (PDRC) cools an object down by simultaneously reflecting sunlight and thermally radiating heat to the cold outer space through the Earth's atmospheric window. However, for practical applications, current PDRC materials are facing unprecedented challenges such as complicated and expensive fabrication approaches and performance degradation arising from surface contamination. Here, we develop scalable cellulose-fiber-based hierarchical composites with excellent self-cleaning and self-cooling capabilities, through air-spraying ethanolic polytetrafluoroethylene (PTFE) microparticles suspensions embedded within the micropores of the cellulose fiber. The formed superhydrophobic PTFE coating not only protects the cellulose-fiber-based paper from water wetting and dust contamination for real-life applications but also reinforces its solar reflectance by sunlight backscattering. It results in a sub-ambient cooling performance of 5°C and radiative cooling power of 104 W/m2 under direct solar irradiance of 834 W/m2 and 671 W/m2, respectively. The self-cleaning surface of the hierarchical composites extends its lifespan and keep its good cooling performance for outdoor applications. Additionally, dyed cellulose-fiber-based paper can absorb appropriate visible wavelengths to display specific colors and effectively reflect near-infrared lights to reduce solar heating, which synchronously achieves effective radiative cooling and aesthetic varieties.
被动日间辐射冷却(PDRC)通过同时反射阳光并通过地球大气窗口向寒冷的外层空间热辐射热量来冷却物体。然而,在实际应用中,目前的PDRC材料面临着前所未有的挑战,如复杂和昂贵的制造方法以及表面污染引起的性能下降。在这里,我们通过空气喷涂乙醇聚四氟乙烯(PTFE)微颗粒悬浮液嵌入纤维素纤维的微孔中,开发了具有优异自清洁和自冷却能力的可扩展纤维素纤维基分层复合材料。形成的超疏水PTFE涂层不仅可以保护纤维素纤维基纸免受水润湿和灰尘污染,还可以通过阳光后向散射增强其太阳反射率。在太阳直接辐照度为834 W/m2和671 W/m2时,其亚环境制冷性能为5℃,辐射制冷功率为104 W/m2。分层复合材料的自清洁表面延长了其使用寿命,并在室外应用中保持了良好的冷却性能。此外,染色的纤维素纤维纸可以吸收适当的可见光波长以显示特定的颜色,并有效反射近红外光以减少太阳加热,从而同步实现有效的辐射冷却和审美多样性。
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引用次数: 0
Development of Technological Restrictions When Operating Disc Polymer-Abrasive Brushes 盘式聚合物磨料刷操作技术限制的发展
Pub Date : 2020-12-11 DOI: 10.15587/1729-4061.2020.212820
P. Tryshyn, N. Honchar, Eduard Kondratiuk, D. Stepanov
Polymer-abrasive brush rotating tools are increasingly used for finishing operations in automated manufacturing. Given this, studying the process of their fibers’ wear has become important; and such a type of wear as the detachment of a whole fiber at the point of fixing has not been investigated in detail up to now. This phenomenon can lead to the disruption of stable equipment operation and the catastrophic wear of brushes. Therefore, it is a relevant task to search for and identify those limitations that could prevent fibers from detachment. This study involved the disc and cylindrical polymer-abrasive brushes as the most common in production. The current study has established that the detachment occurs at an unfavorable combination of the processing regimes and brushes’ parameters at rotations close to the limits specified by the manufacturer. When checking the temperature level at the fiber anchoring point, it was determined that the heating of the fibers in this region during operation was not enough to melt the polymeric base of the fibers and detach them. It has been established that the reason for the detachment of fibers is the accumulation of fatigue changes, which significantly accelerate under the limit modes. Studying the cyclical durability of fibers has made it possible to determine the ratios of critical processing modes to the tool parameters, which lead to the fatigue destruction of fibers at their fixing point. The following technological restrictions have been defined to warrant that fibers are not detached: ‒ it is not recommended to use circumferential cutting speeds exceeding 40 m/s; ‒ the tension during operation should not exceed 10 % of the fibers’ overhang magnitude. These limitations ensure the integrity of the tool, its high durability, as well as the stability of the process of parts’ finishing machining under an automated mode
聚合物磨料刷旋转工具越来越多地用于自动化制造的精加工操作。鉴于此,研究其纤维的磨损过程变得非常重要;而对于整根纤维在固定点脱落的磨损,目前还没有详细的研究。这种现象会导致设备稳定运行的中断和电刷的灾难性磨损。因此,寻找和识别那些可能阻止纤维脱离的限制是一项相关的任务。本研究涉及到生产中最常见的圆盘和圆柱形聚合物磨料刷。目前的研究已经确定,在接近制造商规定的极限旋转时,在加工制度和电刷参数的不利组合下发生分离。在检查纤维锚定点的温度水平时,确定在操作过程中该区域的纤维加热不足以熔化纤维的聚合物基并使其分离。结果表明,纤维脱落的原因是疲劳变化的累积,疲劳变化在极限模态下显著加速。研究纤维的循环耐久性可以确定关键加工方式与刀具参数的比值,从而导致纤维在固定点处的疲劳破坏。为保证纤维不脱落,定义了以下技术限制:-不建议使用超过40米/秒的周向切割速度;-运行时的张力不应超过纤维悬垂量的10%。这些限制保证了刀具的完整性、高耐用性以及在自动化模式下零件精加工过程的稳定性
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引用次数: 4
Giant Heterogeneous Magnetostriction Induced by Charge Accumulation-Mediated Nanoinclusion Formation in Dual-Phase Nanostructured Systems 电荷积累介导的双相纳米结构体系中纳米包裹体形成诱导的巨非均相磁致伸缩
Pub Date : 2020-12-04 DOI: 10.2139/ssrn.3742924
Yijun Chen, Z. Fu, Yuye Wu, Yichen Xu, Yu Xiao, Jingmin Wang, Ruifeng Zhang, Chengbao Jiang
The fundamental origin of the giant magnetostriction in the dual-phase nanostructured systems is under energetic discussion in recent years. Previous studies have revealed that the formation of tetragonal nanoinclusions induced the enlargement in local magnetocrystalline anisotropy, leading to a strengthened magneto-elastic coupling coefficient, which was considered to promote magnetostriction. As the other key factor of magnetostriction, the influence of the nanoinclusions on the elastic constants of the lattices is still unnoticeably. In this work, we propose a mechanism based on the experimental and theoretical results of binary and rare-earth (RE) doped FeGa single-crystals. Doping traces of RE atoms effectively increase the density of nanoinclusions in the A2 matrix, because of the high selectivity of RE atoms so that they possess stronger bonding interaction with Fe atoms rather than Ga atoms. As a sequence, the elastic constant ς 12 significantly increases with the rising density of tetragonal nanoinclusions as opposed to a constant ς 11, resulting in a remarkable enhancement in magnetostriction due to the inversely proportional relationship between magnetostriction (λ 001) and ς 11 - ς 11. A superior magnetostriction of 390 ppm is obtained in the RE-doped single-crystal due to the lattice softening induced by the nanoinclusions. This model sheds light into the contribution of RE atoms to magnetostriction in FeGa single-crystals, and establishes a foundation for developing new-generation dual-phase magnetostrictive materials to achieve unprecedented levels of magnetostriction.
近年来,双相纳米结构体系中巨磁致伸缩的根本原因一直是人们讨论的热点。先前的研究表明,四方纳米包裹体的形成导致局部磁晶各向异性的增大,导致磁弹性耦合系数的增强,这被认为是促进磁致伸缩的原因。作为磁致伸缩的另一个关键因素,纳米包裹体对晶格弹性常数的影响仍然不明显。在这项工作中,我们提出了一种基于二元和稀土掺杂FeGa单晶的实验和理论结果的机制。微量稀土原子的掺杂有效地增加了A2基体中纳米包裹体的密度,因为稀土原子的高选择性使得它们与Fe原子而不是Ga原子具有更强的键合作用。从序列上看,相对于ς 11,弹性常数ς 12随着四边形纳米内含物密度的增加而显著增加,导致磁致伸缩显著增强,这是由于磁致伸缩(λ 001)与ς 11 - ς 11成反比关系。由于纳米包裹体引起晶格软化,稀土掺杂单晶的磁致伸缩率达到390ppm。该模型揭示了稀土原子对FeGa单晶磁致伸缩的贡献,为开发新一代双相磁致伸缩材料以达到前所未有的磁致伸缩水平奠定了基础。
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引用次数: 17
Heterogeneous Lamella Design to Tune the Mechanical Behaviour of a New Cost-Effective Compositionally Complicated Alloy 非均相片层设计以调整一种新型高效复合合金的力学行为
Pub Date : 2020-12-01 DOI: 10.2139/ssrn.3751555
Yu Yin, Qiyang Tan, Qiang Sun, W. Ren, Jingqi Zhang, Shiyang Liu, Yingang Liu, M. Bermingham, Houwen Chen, Mingxing Zhang
A novel heterogeneous lamella (HL) design strategy was proposed to improve mechanical properties of a new cost-effective Fe 35 Ni 35 Cr 25 Mo 5 compositionally complicated alloy (CCA). A HL structure was produced by single-step heat treatment (800 °C for 1h) after cold rolling. This HL structure consists of alternative lamellae regions of coarse-grained FCC matrix (5∼20 μm), and regions containing ultra-fine grains or subgrains (200∼500 nm) together with nanoprecipitates (20-500 nm) and annealing twins. The 800 °C annealed sample with HL structure demonstrated a superior tensile property, with yield strength over 1.0 GPa and ductility of ~13%. Formation of the annealing twins and nanoprecipitates decorated HL structure was a result of the concurrent partial recrystallization and precipitation of σ phase at the shear bands with a high density of lattice defects (e.g. high-density dislocation walls and deformation twins). The latter restricted the growth of recrystallized grains, leading to the formation of ultrafine subgrains within the HL structure. The high yield strength resulted from the multistage hetero-deformation induced (HDI) strengthening and precipitation strengthening associated with heterogeneous lamella structures containing nanoprecipitates. The ductility was originated from the coexistence of multiple deformation mechanisms, which started with dislocation slip and formation of stacking faults at the initial stage, followed by nano-twinning at the higher strain level. This HL design strategy, comprising of composition and thermomechanical process designs, and the resultant microstructure tuning, open a broader window for development of cost-effective CCAs with enhanced performance.
为了提高Fe 35 Ni 35 Cr 25 Mo 5复合合金(CCA)的力学性能,提出了一种新的非均相片层(HL)设计策略。冷轧后单步热处理(800℃,保温1h)得到HL组织。这种HL结构由粗晶FCC基体(5 ~ 20 μm)的交替片层区域和含有超细晶粒或亚晶粒(200 ~ 500 nm)以及纳米沉淀物(20 ~ 500 nm)和退火孪晶的区域组成。经800℃退火后的HL组织试样具有优异的抗拉性能,屈服强度大于1.0 GPa,延展性为~13%。退火孪晶和装饰HL结构的纳米沉淀的形成是在具有高密度晶格缺陷(如高密度位错壁和变形孪晶)的剪切带处σ相的部分再结晶和析出同时发生的结果。后者限制了再结晶晶粒的生长,导致在HL组织内形成超细亚晶粒。高屈服强度是由含有纳米沉淀物的非均相片层结构引起的多级异质变形诱导(HDI)强化和沉淀强化引起的。延性源于多种变形机制的共存,在初始阶段始于位错滑移和层错的形成,随后在高应变水平上发生纳米孪晶。这种HL设计策略,包括成分和热机械工艺设计,以及由此产生的微观结构调整,为开发具有更高性能的成本效益的cca打开了更广阔的窗口。
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引用次数: 15
Precise Measurement of Activation Parameters for Individual Dislocation Nucleation During in Situ Tem Tensile Testing of Single Crystal Nickel 镍单晶原位拉伸试验中单个位错成核激活参数的精确测量
Pub Date : 2020-11-25 DOI: 10.2139/ssrn.3737304
Xiaoqing Li, A. Minor
Abstract Nucleation of crystalline defects such as dislocations lies at the heart of mechanical deformation. Here, we demonstrate a technique for observing the nucleation of individual dislocations during in situ transmission electron microscopy (TEM) tensile testing and measuring fundamental parameters relevant for plasticity from the individual events. Our method relies on systematic detection of dislocation slip traces with automated image analysis in an oriented single crystal Ni sample. Using the identification of individual defect traces from in situ testing, a cumulative probabilistic function is applied to correlate the relationship between a dislocation nucleation event and the corresponding stress level. Our analysis allows for the extrapolation of the activation parameters for individual dislocation nucleation events using the data on one sample in one tensile test. Precise and quantitative correlation of activation parameters for dislocation nucleation from in situ TEM nanomechanical testing can provide direct quantitative measurements useful for computational models of plasticity.
位错等晶体缺陷的成核是机械变形的核心问题。在这里,我们展示了一种技术,可以在原位透射电子显微镜(TEM)拉伸测试中观察单个位错的成核,并从单个事件中测量与塑性相关的基本参数。我们的方法依赖于用自动图像分析系统检测取向单晶Ni样品中的位错滑移痕迹。利用原位测试中单个缺陷轨迹的识别,应用累积概率函数来关联位错成核事件与相应应力水平之间的关系。我们的分析允许外推单个位错成核事件的激活参数,使用一个样品在一次拉伸试验中的数据。原位TEM纳米力学测试中位错成核激活参数的精确定量关联可以为塑性计算模型提供直接的定量测量。
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引用次数: 6
Using Entropy Weight and Over All Evaluation Criteria Optimize the Parameters in EDM of Al–20 Wt. % SICP MMC 利用熵权和总体评价标准对al - 20wt . % SICP MMC电火花加工工艺参数进行优化
Pub Date : 2020-11-23 DOI: 10.2139/ssrn.3735855
R. Bhuyan, A. Parida, P. Behera
The paper has been described one of the recent effective optimization technique i.e. Over all Evaluation Criteria (OEC) to controlling the process parameter during Electrical discharge machining (EDM) of Al – 20 wt.% SiCP metal matrix composite (MMC). The MMC is one of the advance material in compare to the conventional material. To exploit the industrial application of this material with EDM it needs to optimize the process parameter for reliable and economical production of this process. For that the experiment is carried out by Central composite design (CCD) method by considering the input process parameters like peak current, pulse on time and flushing pressure and the output are material removal rate, tool wear rate, radial over cut and surface roughness (Ra). In order to optimize the process parameter a combine effect of Entropy weight measurement method and Over all Evaluation Criteria (OEC) is used to get a single numerical index. Finally, the present work.is is carried out by confirmation test to analyse the desirable approach of the selected model.
本文介绍了一种新的有效的优化技术,即全面评价准则(OEC)来控制Al - 20wt .% SiCP金属基复合材料(MMC)电火花加工过程中的工艺参数。与传统材料相比,MMC是一种先进的材料。为了开发该材料的电火花加工工业应用,需要对工艺参数进行优化,以实现该工艺的可靠、经济生产。为此,采用中心复合设计(CCD)方法,考虑峰值电流、脉冲开启时间和冲洗压力等输入工艺参数,输出工艺参数为材料去除率、刀具磨损率、径向过切量和表面粗糙度(Ra)。为了优化工艺参数,采用熵权度量法和综合评价准则(OEC)相结合的方法得到单一的数值指标。最后,对目前的工作进行了阐述。通过验证试验对所选模型的理想方法进行了分析。
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引用次数: 2
Children Longitudinal Face Recognition Using Random Forest 使用随机森林的儿童纵向人脸识别
Pub Date : 2020-11-23 DOI: 10.2139/ssrn.3735819
S. R., D. S. Guru, Manjunath Aradhya, Anitha Raghavendra
The children face recognition system plays a vital role in application towards the track and recognize the children who are missing at a young age due to child trafficking or kidnapping. In this study, an attempt is made to find the rate of recognition of a young child face images from age 1 to 15 years, where the frequency of facial growth is higher in this interval. To study the effectiveness of the problem, a dimensionality reduction technique is adopted such as PCA followed by random forest classifier as one method and deep convolutional neural network as another method. The proposed model was vindicated with a relatively large dataset that was created to address this problem. The total number of longitudinal face images of 47 children each 12-15 years was 685 and each year consists of a single sample. Experimentation was carried out by varying the number of decision trees and the number of classes for efficacious analysis of the problem. The procured results were promising with deep learning classification techniques with 93% of mini-batch accuracy.
儿童人脸识别系统在追踪和识别因拐卖或绑架而导致的年幼失踪儿童方面具有重要的应用价值。在本研究中,我们试图找出1 - 15岁儿童面部图像的识别率,在这个年龄段,面部生长的频率更高。为了研究问题的有效性,采用了PCA +随机森林分类器和深度卷积神经网络等降维技术。为了解决这个问题而创建的一个相对较大的数据集证明了所提出的模型是正确的。每12-15岁的47名儿童的纵向面部图像总数为685张,每年由一个样本组成。通过改变决策树的数量和类的数量来进行实验,以有效地分析问题。使用深度学习分类技术获得的结果很有希望,具有93%的小批量准确率。
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引用次数: 1
Implementing Trust Aware Routing Protocols for Privacy Preservation in MANET: Implementation & Synthesis 在MANET中实现信任感知路由协议的隐私保护:实现与综合
Pub Date : 2020-11-23 DOI: 10.2139/ssrn.3735719
Shubham Joshi, D. Mishra
In wireless sensor networks, establishing a suitable link between the base station and nodes is an essential task. Link establishing is termed as routing which helps the network for reliable and efficient communication. At the same time attacks in the routing schemes to gain access to the data also increases and it significantly affects the network performance. Privacy preservation, encryption, and authentication can't handle some routing attacks. The trust has recently introduced a mechanism to increase safety and better node interaction. The routing mechanism of trust allows you to avoid that nodes are routed by the solution to be credible. Many trust-based Routing Protocol (RP) use routing that accounts for various routing attacks. This study aims to analyze the recent situation and search open research topics by investigating the existing proposed scheme. The paper presents the trust-based system and routing protocols. Eventually, comparative performance analysis of RP is made using the NS-2 network simulator.
在无线传感器网络中,在基站和节点之间建立合适的链路是一项重要任务。链路建立称为路由,它有助于网络进行可靠和有效的通信。与此同时,利用路由方式获取数据的攻击也越来越多,严重影响了网络的性能。隐私保护、加密和身份验证无法处理某些路由攻击。该信托最近引入了一种机制,以提高安全性和更好的节点交互。信任路由机制允许您避免由解决方案路由的节点是可信的。许多基于信任的路由协议(RP)使用的路由可以应对各种路由攻击。本研究旨在通过对现有方案的调查,分析现状,寻找开放的研究课题。本文介绍了基于信任的系统和路由协议。最后,利用NS-2网络模拟器对RP进行了性能对比分析。
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引用次数: 1
Optimization of CNN Model With Hyper Parameter Tuning for Enhancing Sturdiness in Classification of Histopathological Images 用超参数调整优化CNN模型增强组织病理图像分类的稳健性
Pub Date : 2020-11-23 DOI: 10.2139/ssrn.3735831
Anil Johny, Dr. Madhusoodanan K. N., Dr. Tom J Nallikuzhy
The field of pathology has advanced so rapidly that it is now possible to produce whole slide images (WSI) from glass slides with digital scanners producing high-quality images. Image analysis algorithms applied to such digitized images facilitate automatic diagnostic tasks whilst assisting a medical expert. Successful detection of malignancy in histopathological images largely depends on the expertise of radiologists, though they sometimes disagree with their decisions. Computer-aided diagnosis provides a platform for a second opinion in diagnosis, which can improve the reliability of an expert's opinion. Deep learning provides promising results compared to the conventional approach that relies on manual extraction of features which is time-consuming and labor-intense. Due to the huge size, whole slide images are converted into patches and trained using a Convolutional Neural Network (CNN), a variant of the deep learning model for images. Experimental results show that the proposed native model achieved patch wise classification accuracy of 92.8% and area under ROC curve 0.97 which is close to the values while comparing with the existing pre-trained models.
病理学领域的发展如此之快,以至于现在可以用数字扫描仪从玻璃载玻片上产生高质量的图像。应用于这种数字化图像的图像分析算法有助于自动诊断任务,同时协助医学专家。在组织病理学图像中成功检测恶性肿瘤很大程度上取决于放射科医生的专业知识,尽管他们有时不同意他们的决定。计算机辅助诊断为诊断提供了第二意见的平台,提高了专家意见的可靠性。与依赖于人工提取特征的传统方法相比,深度学习提供了有希望的结果,这种方法既耗时又费力。由于尺寸巨大,整个幻灯片图像被转换成补丁,并使用卷积神经网络(CNN)进行训练,卷积神经网络是图像深度学习模型的一种变体。实验结果表明,与已有的预训练模型相比,本文提出的局部分类模型的分类准确率为92.8%,ROC曲线下面积为0.97,与预训练模型接近。
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引用次数: 3
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Materials Engineering eJournal
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