Materials最新文献

A problem has been noted regarding the admixture of fuel to a low viscosity lubricant in hybrid electric vehicles (HEVs). This is very detrimental to the wear and tear of engine operating components. In this study, the operating conditions of HEVs were analysed. Using X-ray fluorescence spectrometry (XRF), engine oils of two different viscosity classes were compared after the operating process and these data were compared with fresh reference samples. Attention was paid to the content of elements such as Ca, Zn, Mo, Sn, Cd, Fe Pb, Si, Cu, and Ni. The depletion of anti-wear additives, as well as the higher content of metallic wear products relative to the operated 5W30 (engine oil), contributed to the overall assessment of the lubricity of the 0W30 oil, as well as to the tribological results. Then, under laboratory conditions, oil samples contaminated with up to 1 to 8% fuel were subjected to rheological (mini AV-X viscometer) and tribological (four-ball tester) tests. The dependence of the local pressure at the metal-to-metal contact point in the kinematic node on viscosity showed the dissimilar nature of the used and fresh oil and the divergence of the domains for the two groups of samples. Increasing the fuel contamination of used oil above 4% drastically reduces the pressure responsible for maintaining the oil film. In order to improve lubricant performance during HEV operation in urban conditions, it was proposed to carry out extra-urban traffic driving in order to evaporate the fuel from the engine oil. A shorter oil change interval is also recommended.

SiC_p/Al-Fe-V-Si composites exhibit complex deformation behaviors at both room and high temperatures because of the presence of SiC reinforcement particles and numerous fine dispersed Al₁₂(Fe, V)₃Si heat-resistant phases. In this work, an artificial neural network (ANN) constitutive model was established to study the deformation behavior of SiC_p/Al-7.75Fe-1.04V-1.95Si composites over a wide temperature range based on uniaxial compression. Then, microstructural observation, finite element analysis, and processing maps were utilized to investigate the plastic workability. The results showed that the ANN model fit the experimental stress-strain curves with high accuracy, achieving an R² value of 0.999. The ANN model was embedded into finite element software to study plastic deformation behaviors, which indicated that this model could accurately compute the plastic and mechanical response during the compressing process. Finally, a thermomechanical processing diagram was developed, revealing that the optimal processing parameters of the SiC_p/Al-7.75Fe-1.04V-1.95Si composites were a deformation temperature of 450-500 °C and a deformation rate of 0.1-0.2 s^-1.

The diffusion-bonding technique has been utilized to join various Al alloys (AA1060, AA2024, AA3003) to Cu for bimetallic anode application. This process aims to achieve robust metallic continuity to facilitate electron transfer, while carefully managing the growth of the intermetallic layer at the bonding interface. This control preserves the active volume of aluminum and prevents excessive brittleness of the anode. Optimization efforts have focused on different pressures, surface treatments of parent materials, and bonding parameters (temperature 450-500 °C and time 5-60 min). The optimal conditions identified include low bonding pressures (8 MPa), surface treatment involving polishing followed by chemical cleaning of the surfaces to be bonded, and energetic bonding conditions tailored to each specific aluminum alloy. Preliminary electrochemical characterization via cyclic voltammetry (CV) tests has demonstrated high reversibility intercalation/deintercalation reactions for up to seven cycles. The presence of the different alloying elements appears to contribute significantly to maintaining the high intercalation/deintercalation reaction reversibility without considerable modification of the reaction potentials. This effect may be attributed to alloying elements effectively reducing the overall alloy volume expansion, potentially forming highly reversible ternary/quaternary active phases, and creating a porous reaction layer on the exposed aluminum surface. These factors along with the influence of the Cu parent material collectively reduce the stress during volume expansion, which is the responsible phenomenon of the anode degradation in common Al anodes.

To study the bearing characteristics of rock-socketed single piles on the southeast coast of Fujian Province, we conducted similar material ratio tests and single pile model tests. Initially, based on the mechanical parameters of strongly weathered granite, 10 groups of similar material samples were prepared using iron concentrate powder, barite powder, and quartz sand as aggregates, with rosin and alcohol as the cementing agents and gypsum as the modulating agent. Through triaxial testing and range and variance analysis, it was determined that the binder concentration has the most significant impact on the material properties. Consequently, Specimen 1 was selected as the simulation material. In the model test, the strongly weathered granite stratum was simulated using the ratio of Specimen 1. A horizontal load was applied using a pulley weight system, and the displacement at the top of the pile was measured with a laser displacement meter, resulting in a horizontal load-displacement curve. The results indicated that the pile foundation remained in an elastic state until a displacement of 2.5 mm. Measurements of the horizontal displacement and bending moment of the pile revealed that the model pile behaves as a flexible pile; the bending moment initially increases along the pile length and then decreases, approaching zero at the pile's bottom. The vertical load test analyzed the relationship between vertical load and settlement of the single pile, as well as its variation patterns. This study provides an experimental basis for the design of single pile foundations in weathered granite formations on the southeast coast of Fujian Province and aids in optimizing offshore wind power engineering practices.

Al-Mg alloys are characterized by permanent solid solution hardening and can additionally be work-hardened. The high mechanical properties of Al-Mg alloys with above-standard Mg content obtained after plastic deformation processes decrease over time. The addition of minor alloying elements like Er or Zr is an alternative method to improve the durability of mechanical properties and increase the strength of Al-Mg alloys due to densely and evenly distributed dispersoids being formed. In this paper, Al-Mg alloys with above-standard Mg content (7 wt.%) and Zr and Er micro-alloying elements and their influence on the microstructure and durability of the mechanical properties were examined. The cast ingots of AlMg7 alloys were characterized by a smooth surface without cracks. The plastic deformation process in a static compression test resulted in an about 60 HBW increase in the Brinell hardness of all the deformed alloys relative to casting. It was revealed that the addition of Er and Zr significantly improved the mechanical properties and durability of the mechanical properties of the Al-Mg after annealing. The addition of Er or Zr slightly restrained the decrease in the Brinell hardness after annealing but did not inhibit it.

The strength of ultra-low carbon maraging stainless steels can be significantly enhanced by precipitating nanoscale intermetallic secondary phases. Retained or reversed austenite in the steel can improve its toughness, which is key to achieving an ideal combination of strength and toughness. Ti and Al are often used as cost-effective strengthening elements in maraging stainless steels but the synergistic toughening and strengthening mechanisms of Ti and Al have not been studied. To investigate the synergistic toughening and strengthening mechanisms of Ti and Al in Co-free maraging stainless steels, this paper focuses on the microstructure and mechanical properties of three alloys: Fe-12Cr-11Ni-1.7Al-0.5Ti (Steel A), Fe-12Cr-11Ni-0.5Ti (Steel B), and Fe-12Cr-11Ni-1.7Al (Steel C). The impact of Ti and Al on the microstructure and mechanical properties was investigated using X-ray diffraction (XRD), high-resolution transmission electron microscopy (TEM), and thermodynamic simulations. The relationship between microstructure, strength, and toughness is also discussed. The results indicated that Steel A, containing both Al and Ti, exhibited the highest strength level after solution treatment at 900 °C, with an ultimate tensile strength reaching 1571 MPa after aging at 540 °C. This is attributed to the simultaneous precipitation of spherical β-NiAl and rod-shaped η-Ni₃Ti phases. Steel B, with only Ti, formed a significant amount of Ni-rich reversed austenite during aging, reducing its ultimate tensile strength to 1096 MPa. Steel C, with only Al, showed a high strength-toughness combination, which was achieved by forming dispersive nano-sized intermetallic precipitates of β-NiAl in the martensitic matrix with a slight amount of austenite. It is highlighted that Al has superior toughening and strengthening effects compared to Ti in the alloy system.

The behavior of airport precast concrete pavement (APCP) involving new design and construction concepts was experimentally analyzed under environmental and moving airplane loads, and the long-term performance of the APCP was evaluated using fatigue failure analysis. The strain characteristics and curling behavior of the APCP under environmental loads were comprehensively analyzed. The APCP slabs exhibited a pronounced curling phenomenon similar to conventional concrete pavement slabs. The dynamic response of the APCP subjected to impact loads was analyzed by performing heavy weight deflectometer tests. The test results confirmed that the vertical deformation of the APCP was small and within the typical range of vertical deformation of conventional concrete pavement. The dynamic strain response of the APCP under moving airplane loads was then analyzed and the strain variation during day and night times was compared. The strains during the day were found to be significantly larger than those at night under airplane loads because of the curling phenomenon of the APCP slabs. Finally, the long-term performance of the APCP was evaluated using fatigue failure analysis based on the obtained behavior. Even using the most conservative fatigue failure prediction model, the service life of the APCP was ascertained to be more than 30 years. Based on the overall results of this study, it is concluded that the APCP, which is designed to reduce slab thickness by placing reinforcing bars in the slabs via reinforced concrete structural design, exhibits typical behavior of concrete pavements and can be successfully applied to airport pavement rehabilitation.

This paper deals with Barkhausen noise in Trip steel RAK 40/70+Z1000MBO subjected to uniaxial plastic straining under variable strain rates. Barkhausen noise is investigated especially with respect to microstructure alterations expressed in terms of phase composition and dislocation density. The effects of sample heating and the corresponding Taylor-Quinney coefficient are considered as well. Barkhausen noise of the tensile test is measured in situ as well as after unloading of the samples. In this way, the contribution of external and residual stresses on Barkhausen noise can be distinguished in the direction of tensile loading, as well as in the transversal direction. It was found that the in situ-measured Barkhausen noise grows in both directions as a result of tensile stresses and the realignment of domain walls. The post situ-measured Barkhausen noise drops down in the direction of tensile load due to the high opposition of dislocation density at the expense of the growing transversal direction due to the prevailing effect of the realignment of domain walls. The temperature of the sample remarkably grows along with the increasing strain rate which corresponds with the increasing Taylor-Quinney coefficient. However, this effect plays only a minor role, and the density of the lattice imperfection expressed especially in terms of dislocation density prevails.

In order to improve the microwave-absorption performance of barium ferrite and broaden its microwave-absorption band, BaFe₁₂O₁₉, Ba_0.95Ca_0.05Fe₁₂O₁₉, and Ba_0.95Ca_0.05Fe_12-xCo_xO₁₉ (x = 0.1, 0.2, 0.3 and 0.4, respectively) hexaferrites were synthesized by the solid-state reaction method, and the influence of Co ion substitution on the phase composition, microstructure, magnetic properties, and microwave-absorption ability of the ferrites in this system was studied. Introducing minor Co ions (x < 0.2) facilitated sintering and grain growth. At x ≥ 0.2, XRD revealed the emergence of the Co₂X phase alongside the BaM phase. Increasing Co ion concentration and the secondary X-phase led to slight reductions in saturation magnetization (69 to 63.5 emu/g) and substantial decline in coercivity (2107.02 to 111.21 Oe), attributed to grain size growth and Co₂X's soft magnetic nature. Notably, Co₂X incorporation significantly enhanced the microwave absorption and provided a tunable absorption band from the Ku to the C band. For a sample with a thickness of 2.0 mm and a doping level of x = 0.2, a minimum reflection loss of -59.5 dB was achieved at 8.92 GHz, with an effective absorption bandwidth of 3.31 GHz (7.07-10.38 GHz). The simple preparation method and good performance make Ba_0.95Ca_0.05Fe_12-xCo_xO₁₉ (x = 0.1, 0.2, 0.3 and 0.4, respectively) hexaferrites promising microwave-absorbing materials.

Understanding the performance of polymer dielectrics at different temperatures is becoming increasingly important due to the rapid development of electric cars, electromagnetic devices, and new energy production solutions. Cyclic olefin copolymers (COCs) are an attractive material due to their low water absorption, good electrical insulation, long-term stability of surface treatments, and resistance to a wide range of acids and solvents. This work focused on the dielectric and electrical properties of cyclic olefin copolymer (COC)/Al₂O₃ composites over a wide range of temperature and frequency domains, from room temperature to cryogenic temperatures (around 125 K). Permittivity, electrical conductivity, and electrical modulus are given consideration. A composite of up to 50% Al₂O₃ mixed with COC was prepared via a conventional melt-blending method. The final samples were formed in sheets and processed using injection and extrusion moldings. It was found that formulations with Al₂O₃ concentrations ranging from 10 to 50% resulted in higher electrical conductivity while maintaining the viscosity of the composite at a level acceptable for polymer-processing machinery. Our data show that COC/alumina composites present substantial potential as materials for high-frequency applications, even at the regime of cryogenic temperatures.