Materials最新文献

The increasing need for sustainable construction materials has prompted research into alternatives to Ordinary Portland Cement (OPC), a major contributor to global CO₂ emissions. Geopolymers, synthesized via alkali activation of aluminosilicate precursors such as metakaolin and fly ash, are a promising alternative, reducing up to 80% of carbon emissions. However, their long-term durability in aggressive chemical environments, particularly when up against organic acids, remains insufficient. While mineral and inorganic acid resistance have been studied, the impact of naturally occurring organic acids like oxalic acid (Ox)-commonly found in soils and organic-rich sediments-has received limited attention. Ox is known to chelate metal ions and alter mineral phases, potentially affecting the integrity of geopolymer matrices. This study investigates the degradation behavior of geopolymers under continuous exposure to Ox (0.2, 0.4, and 0.6 M) at 25 °C using a flow-through reactor. Mass loss over time was monitored to determine reaction kinetics, while SEM, FT-IR, XRD, and EDS analyses were conducted to evaluate microstructural and chemical changes. The results revealed significant alterations in the geopolymers' structures due to Ox exposure, providing key insights into their vulnerability to organic acid attack. These findings indicate the importance of considering organic acid interactions in long-term performance assessments of geopolymers.

Maxillary sinus augmentation is a key procedure for rehabilitating the atrophic posterior maxilla and enabling predictable implant-supported restorations. Although autogenous bone remains the biological gold standard due to its osteogenic potential, its clinical use has declined because of donor-site morbidity, limited availability, and increased surgical burden. Deproteinized bovine bone mineral (DBBM) is currently the most widely used substitute, providing excellent biocompatibility and long-term volumetric stability. However, its inert nature, limited bioactivity, and slow resorption have driven the development of next-generation graft materials. Recent biomaterial innovations aim to enhance vascularization, accelerate osteogenesis, modulate immune responses, and achieve controlled resorption while maintaining favorable handling properties. These include ion-releasing bioactive ceramics, growth factor-enhanced allografts, polysaccharide-hydroxyapatite composites, smart hydrogels, and synthetic scaffolds with tunable degradation profiles. Given the complexity of bone regeneration, effective clinical translation requires an integrated framework combining in vitro assays, animal models, and human clinical studies. This review synthesizes evidence published since 2018 on emerging biomaterials for sinus floor elevation, critically evaluating their potential to overcome the limitations of DBBM and highlighting the importance of a coordinated preclinical-to-clinical research continuum.

An electrochemical evaluation of the corrosion resistance of the Al-alloy EN AW-5454-D and its welded joints made by MIG (Metal Inert Gas) and by laser hybrid (LH) welding was performed in this study. All the tested samples had a thickness of 4 mm, whereby all the samples' surfaces were cleaned with a plasma cleaning process before the electrochemical testing to reduce the impact of contamination. The electrochemical behaviour was investigated in a 3.5 wt.% NaCl electrolyte over exposure periods of 1 h, 7 days, and 30 days using electrochemical methods and surface examination. The results demonstrate that the welding processes (MIG and LH) caused microstructural heterogeneities that reduce the corrosion resistance of the weld. The MIG-welded specimen showed worse properties than the LH-welded specimen in the electrochemical tests, as it had a higher corrosion current density, lower polarisation resistance, and higher layer capacitance. Due to long-term exposure to the immersion solution, despite the reduced susceptibility to uniform corrosion, the Al-alloy samples and their welds remained susceptible to pitting corrosion.

The rapid development of the lithium battery industry resulted in a large accumulation of spodumene mining residue (SMR). This paper explored the feasibility of using SMR as mineral admixtures in cement mortar. The properties of cement mortar, including flexural strength, compressive strength, fluidity, hydration characteristics, and durability, were studied. The interaction mechanism between SMR and cement mortar had been explored using the Dinger-Funk model, isothermal calorimetry, X-Ray Diffraction (XRD), fourier Transform Infrared Spectroscopy (FTIR), and thermogravimetry (TG) methods. Additionally, the environmental impact of cement mortar was quantitatively evaluated by the life cycle assessment method. The results showed that, while the dosage of SMR was no more than 20 wt.% replaced cement, the flexural strength, compressive strength, and anti-carbonation and sulfate corrosion resistance properties of S2 and S3 cement mortar were similar to that of the blank group. After curing for 28 d, the compressive strength of S1, S2, and S3 were 44.2 MPa, 43.15 MPa, and 40.32 MPa, respectively. SMR powder could improve the workability and reduce the cumulative hydration heat of cement mortar, which confirmed its application potential in large-volume concrete projects. The appropriate content of SMR incorporation into cement mortar could improve the structure and properties of cement-based materials through particle filling, the induced nucleation effect, and the pozzolanic effect. In addition, the utilization of SMR reduced the environmental emissions and resource consumption of cement-based materials. Using 1 m³ cement mortar as an example, for every 10 wt.% increase in SMR powder replacing cement, the energy consumption, the emissions of CO₂, CO, C_xH_y, NO_x, SO₂, dust, and resource consumption of cement mortar were decreased by approximately 342 MJ, 40 kg, 8.1 g, 5.55 g, 88.3 g, 5.24 g, 1.80 kg, and 74.3 kg, respectively. The research findings of this paper are expected to promote the resource utilization of SMR and reduce the carbon emissions of the building materials industry.

This study evaluated the residual mechanical properties of concrete in which Ordinary Portland Cement (OPC) was partially replaced with non-calcined Hwangto (NHT). Specimens were prepared with two water-to-binder (W/B) ratios (0.41 and 0.33) and three NHT replacement levels (0%, 15%, and 30%). The specimens were exposed to elevated temperatures of 20, 100, 200, 300, 500, and 700 °C at a heating rate of 1 °C/min. The results indicated that while the initial compressive strength at room temperature decreased with increasing NHT content, the residual mechanical performance at high temperatures significantly improved. Notably, temporary strength recovery was observed in the 200-300 °C range due to the internal autoclaving effect. At 700 °C, the NHTC (non-calcined Hwangto concrete)-30 series exhibited the highest thermal stability, retaining 28.2% of its initial compressive strength, whereas the Plain (OPC Concrete) and NHTC-15 series retained only 23.6% and 22.4%, respectively. Regarding energy absorption, the dissipated energy varied with the W/B ratio. In the W/B 41 series, the NHTC-30 specimen demonstrated superior ductility and energy dissipation capacity at 700 °C, outperforming the Plain specimen. This enhanced post-peak performance is attributed to the thermal activation of kaolinite into metakaolin, which preserves microstructural integrity by mitigating the severe degradation of hydration products and inhibiting crack propagation. These findings suggest that incorporating NHT effectively enhances the fire resistance and residual structural integrity of concrete, particularly in normal-strength matrices.

Titanium carbide has developed into an exceptional reinforcement contender in Aluminium Matrix Composites (AMCs) because of its greater characteristics such as elevated hardness, elevated elastic modulus, low heat conductivity, and constancy at moderately elevated temperatures. Furthermore, it is consequently selected as the reinforcing segment in AMCs because of its good thermodynamic and wettability stability inside the aluminium melt pool. In this work, titanium carbide powder was mixed to distinguish AlSi₁₀Mg strengthening by the additive manufacturing (AM) process in the category of powder bed identified as Powder Bed Fusion (PBF). The objective of the study was to have homogeneously mixed powders for processing on the reinforcement of AlSi₁₀Mg with TiC. Different characterisation procedures were carried out, such as scanning electron microscope energy dispersive X-ray spectroscopy (SEM-EDS), pycnometry, and thermogravimetric analysis (TGA). The advancement of powder density from 2.65 to 2.72 g/cm³ and surface area from 0.02 to 0.14 m²/g was accomplished. The modelling findings concurred that the addition of Ti and C increases the density of the alloy, with Ti contributing more to AlSi than C. It was deduced that with Ti and C added to the system, the bulk modulus increases, with Al₆Si₈TiC having the largest value of 80.34 GPa.

A novel auxetic honeycomb (RSSHR) is developed by introducing the arc-shaped structure into the re-entrant star-shaped honeycomb (RSSH). Based on theoretical models and finite element methods, the dynamic crushing responses of RSSH and RSSHR plate (RSSH_P and RSSHR_P) structures are investigated to elucidate the dependence of plateau stress, negative Poisson's ratio (NPR), deformed shape and specific energy absorption (SEA) on crushing velocity. The stress-strain curves of two types of structures are calculated to analyze configuration-mechanical property relationships. The results exhibit that the plateau stress and SEA of the RSSH_P and RSSHR_P structures increase as the crushing velocity increases. Owing to the stress-mitigating effect of the arc-shaped structure, the RSSHR_P structure exhibits a stronger NPR effect. And the SEA of the RSSHR_P structure is higher than that of the RSSH_P structure. In addition, it is also found that at low crushing velocity, the stress-strain curves of the two structures exhibit three distinct stages: the elastic stage (I), the stress plateau stage (II) and the densification stage (III). During the crushing process, there are three deformed shapes. They are the global deformed shape, the local deformed shape and the layer-by-layer deformed shape.

Bismuth-based semiconductors have emerged as a promising class of visible-light-responsive photo(electro)catalysts for environmental remediation owing to their tunable electronic structures, moderate band gaps, and relatively low toxicity. The stereochemically active Bi³⁺ 6s² lone pair and strong Bi-O orbital hybridization tailor valence-band states, enabling enhanced utilization of the solar spectrum and favorable charge-carrier dynamics. In addition, layered, perovskite-like, and aurivillius-type crystal frameworks generate internal electric fields that are advantageous for photoelectrochemical (PEC) operation. This review critically examines advances from 2015 to 2025 in the design, synthesis, modification, and environmental applications of bismuth-based photo(electro)catalysts, with particular emphasis on PEC systems for pollutant degradation. Major material families, including bismuth oxides, oxyhalides, oxychalcogenides, chalcogenides, perovskite-like oxides, and complex metal oxides, are discussed in relation to their structure-property-performance relationships. Key synthesis strategies, such as solid-state, sol-gel, hydro/solvothermal, microwave-assisted, spray pyrolysis, and electrodeposition methods, are compared with respect to morphology control, defect chemistry, and electrode integration. Performance-enhancing approaches, including elemental doping, oxygen-vacancy engineering, and the rational design of type-II, p-n, Z-scheme, and S-scheme heterojunctions, are critically assessed. Practical considerations related to stability, scalability, and techno-economic constraints are highlighted. Finally, current challenges and future directions toward durable and application-ready bismuth-based PEC technologies are outlined.

Nature-based solutions, including green infrastructure (GI), are considered sustainable tools for stormwater treatment. GI elements (rain gardens, green roofs, etc.) are increasingly applied as integrated approaches for climate change mitigation and environmental pollution reduction. This study focused on investigations of rain gardens for reducing stormwater polluted by residual chlorine after the disinfection of outdoor spaces. Laboratory (column test) and field tests were carried out to evaluate the infiltration capacities of an experimental rain garden model, as well as its efficiency for retaining residual chlorine. The experiments were conducted using simulated rain garden layers composed of waste materials that remained after different production processes. The average infiltration coefficient values obtained were 2.55 × 10^-5 m/s, 2.45 × 10^-5 m/s, 2.24 × 10^-5 m/s, 3.4 × 10^-5 m/s, 1.28 × 10^-5 m/s, 1.84 × 10^-5 m/s (laboratory test), and 1.39 × 10^-5 m/s (field test). These values correspond to the characteristics of sand-gravel substrates. A chlorine retention efficiency of 82.5-87% was obtained. Granulometric analysis confirmed fraction size suitability for rain garden filtration. This research indicates the potential of rain gardens for reducing stormwater pollution, providing a basis for future research and practical implementation.

Currently, the non-uniformity of girth weld positions makes their limit state a crucial determinant of pipeline safety. The design method based on the limit state is pivotal in ensuring the integrity and reliability of the pipeline system. Challenges often emerge when determining the limit states of girth welds using semi-empirical formula methods, primarily due to difficulties in accurately identifying influential factors. The quantitative impact of each influence parameter on the crack driving force and the results determined by the semi-empirical formula remain unclear. This study utilizes numerical simulation methods to systematically analyze the quantitative sensitivity laws of critical factors such as crack depth on the crack driving force to address this challenge. The findings revealed that the strength matching coefficient, crack depth, and misalignment are the most significant factors influencing the crack driving force, followed by crack length, softening rate, yield-to-strength ratio, internal pressure, and wall thickness. The effects of tensile strength and outer diameter are relatively minor. A comprehensive database of crack driving forces is constructed using a parameter matrix approach. Combined with the LightGBM machine learning algorithm, a full-scale prediction model for the strain capacity of pipeline girth welds is developed. Predictions for 18 sets of wide-plate test results from the literature confirm the high accuracy of the prediction model, with a prediction accuracy of 6.48%. This research provides a robust reference for accurately determining the limit state of pipeline girth welds and effectively meets the demands of rapidly advancing welding technologies and increasingly complex service environments.