Weifeng Wei, Zhengping Ding, Cheng Chen, Chenggong Yang, Bo Han, Lei Xiao, C. Liang, P. Gao, Kyeongjae Cho
Structural degradation is the principal driving force for rapid voltage decay and capacity fading of Ni-rich layered oxide (NLO) cathode materials upon cycling, but its working mechanism is not yet fully elucidated. Here we apply multi-scale electron microscopy/spectroscopy techniques and theoretical calculations on both polycrystalline and single-crystal NLOs, and describe their structural evolution upon cycling. We discover that both the intergranular and intragranular cracks initiate along polar (001) basal plane due to its large elastic anisotropy upon cycling and surface structure evolution and transition metal dissolution occur on nonpolar (104) fresh surface. With this surface-dependent stress-corrosion coupling effect, severe intergranular cracking that accumulates within the polycrystalline NLO aggregates accounts mostly for the fast voltage decay and capacity fading, whereas minor intragranular cracking and less surface damage lead to substantial improvements on cyclability and reversible capacity of single-crystal NLOs. A universal understanding of the surface-dependent degradation in both polycrystalline and single-crystal NLOs provides clues on designing new cathode materials with high energy density and long cycle life through grain-boundary engineering.
{"title":"Surface-Dependent Stress-Corrosion Cracking in Ni-Rich Layered Oxide Cathodes","authors":"Weifeng Wei, Zhengping Ding, Cheng Chen, Chenggong Yang, Bo Han, Lei Xiao, C. Liang, P. Gao, Kyeongjae Cho","doi":"10.2139/ssrn.3680384","DOIUrl":"https://doi.org/10.2139/ssrn.3680384","url":null,"abstract":"Structural degradation is the principal driving force for rapid voltage decay and capacity fading of Ni-rich layered oxide (NLO) cathode materials upon cycling, but its working mechanism is not yet fully elucidated. Here we apply multi-scale electron microscopy/spectroscopy techniques and theoretical calculations on both polycrystalline and single-crystal NLOs, and describe their structural evolution upon cycling. We discover that both the intergranular and intragranular cracks initiate along polar (001) basal plane due to its large elastic anisotropy upon cycling and surface structure evolution and transition metal dissolution occur on nonpolar (104) fresh surface. With this surface-dependent stress-corrosion coupling effect, severe intergranular cracking that accumulates within the polycrystalline NLO aggregates accounts mostly for the fast voltage decay and capacity fading, whereas minor intragranular cracking and less surface damage lead to substantial improvements on cyclability and reversible capacity of single-crystal NLOs. A universal understanding of the surface-dependent degradation in both polycrystalline and single-crystal NLOs provides clues on designing new cathode materials with high energy density and long cycle life through grain-boundary engineering.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73513305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Foster Kwame Kholi, Grace Esu-Ejemot Aquah, Hariharan Kallath, J. Min
This study explored the vast scale of produced brine available and novel pathways to convert offshore carbon dioxide (CO2) to valuable products. Carbonate structures were selected as host materials...
{"title":"Monetization of Carbon Dioxide and Oil and Gas Production Brine: From Waste to Usable Products","authors":"Foster Kwame Kholi, Grace Esu-Ejemot Aquah, Hariharan Kallath, J. Min","doi":"10.2139/ssrn.3689796","DOIUrl":"https://doi.org/10.2139/ssrn.3689796","url":null,"abstract":"This study explored the vast scale of produced brine available and novel pathways to convert offshore carbon dioxide (CO2) to valuable products. Carbonate structures were selected as host materials...","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75192192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-08-31DOI: 10.15587/2706-5448.2020.210373
Mykhailo Kinaschuk
The object of research is a set of screen-exhaust devi ces (SED) as part of the Mi-8MSB-V helicopter (Ukrai-nian version of the modernization of the Soviet multipurpose Mi-8 helicopter, developed by Motor Sich JSC, Zaporizhzhia, Ukraine). The SED set is designed to reduce the infrared signature of helicopters equipped with TV3-117 turboshaft engines of all modifications for the Mi-8MSB-V, Mi-8MT, Mi-14 and Mi-24.
One of the problem areas is the lack of methods for solving the problem of determining the parameters and tactical and technical characteristics when examining SED as part of an aircraft during testing and research, which must be carried out in accordance with the approved Technical Operation Manual.
When constructing the developed methodology, the rules of the Technical Operation Manual and the Heli-copter Flight Operation Manual were applied, which allows testing in compliance with flight safety standards. Flight tests serve as a source of information for analytical calculations, the SED models and verification of their reliability by checking the convergence of the parameters of the functioning process under the same conditions using simulation and flight experiments.
The developed technique of research and testing of a set of screen-exhaust devices makes it possible to check the performance of a specific sample in all flight modes. The technique makes it possible to determine the level of engine power losses in different operating modes using the parameters of the on-board informa-tion collection facilities in conjunction with SED. This makes it possible to obtain a characteristic of fuel con-sumption in the case of a set of screen-exhaust devices installed on board and without it. The technique takes into account the possibility of simultaneously conducting both flight and ground tests of SED to construct an infrared radiation indicatrix and determine the distances and angles of target capture by the homing head of portable anti-aircraft missile systems.
Analysis of the data obtained made it possible to determine the direction of further computational and experimental studies aimed at improving the flow path of the SED.
{"title":"Development of Method of Testing a Set of Screen-Exhaust Devices in the Helicopter Mi-8MSB-B","authors":"Mykhailo Kinaschuk","doi":"10.15587/2706-5448.2020.210373","DOIUrl":"https://doi.org/10.15587/2706-5448.2020.210373","url":null,"abstract":"The object of research is a set of screen-exhaust devi ces (SED) as part of the Mi-8MSB-V helicopter (Ukrai-nian version of the modernization of the Soviet multipurpose Mi-8 helicopter, developed by Motor Sich JSC, Zaporizhzhia, Ukraine). The SED set is designed to reduce the infrared signature of helicopters equipped with TV3-117 turboshaft engines of all modifications for the Mi-8MSB-V, Mi-8MT, Mi-14 and Mi-24.<br><br>One of the problem areas is the lack of methods for solving the problem of determining the parameters and tactical and technical characteristics when examining SED as part of an aircraft during testing and research, which must be carried out in accordance with the approved Technical Operation Manual.<br><br>When constructing the developed methodology, the rules of the Technical Operation Manual and the Heli-copter Flight Operation Manual were applied, which allows testing in compliance with flight safety standards. Flight tests serve as a source of information for analytical calculations, the SED models and verification of their reliability by checking the convergence of the parameters of the functioning process under the same conditions using simulation and flight experiments.<br><br>The developed technique of research and testing of a set of screen-exhaust devices makes it possible to check the performance of a specific sample in all flight modes. The technique makes it possible to determine the level of engine power losses in different operating modes using the parameters of the on-board informa-tion collection facilities in conjunction with SED. This makes it possible to obtain a characteristic of fuel con-sumption in the case of a set of screen-exhaust devices installed on board and without it. The technique takes into account the possibility of simultaneously conducting both flight and ground tests of SED to construct an infrared radiation indicatrix and determine the distances and angles of target capture by the homing head of portable anti-aircraft missile systems.<br><br>Analysis of the data obtained made it possible to determine the direction of further computational and experimental studies aimed at improving the flow path of the SED.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74368445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Vītola, V. Lahti, I. Bite, A. Spustaka, D. Millers, M. Lastusaari, L. Petit, K. Smits
SrAl2O4: Eu, Dy, B particles were added in a phosphate glass (90NaPO3-10NaF (in mol%)) using the direct doping method. For the first time, the composition of the particles prior to and after embedding them in the glass was analysed using EPMA analysis. Boron was found to be incorporated in already distorted surroundings creating new trapping centers in the particles which are thought to be favourable for the tunnelling process and so for the afterglow at 10K. Despite the partial decomposition of the particles, the glass exhibit afterglow at low temperature confirming to be promising materials for low temperature applications.
{"title":"Low Temperature Afterglow from SrAl 2O 4: EU, Dy, B Containing Glass","authors":"V. Vītola, V. Lahti, I. Bite, A. Spustaka, D. Millers, M. Lastusaari, L. Petit, K. Smits","doi":"10.2139/ssrn.3642926","DOIUrl":"https://doi.org/10.2139/ssrn.3642926","url":null,"abstract":"SrAl2O4: Eu, Dy, B particles were added in a phosphate glass (90NaPO3-10NaF (in mol%)) using the direct doping method. For the first time, the composition of the particles prior to and after embedding them in the glass was analysed using EPMA analysis. Boron was found to be incorporated in already distorted surroundings creating new trapping centers in the particles which are thought to be favourable for the tunnelling process and so for the afterglow at 10K. Despite the partial decomposition of the particles, the glass exhibit afterglow at low temperature confirming to be promising materials for low temperature applications.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91327101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Miao, C. Slone, S. Dasari, M. Ghazisaeidi, R. Banerjee, E. George, M. Mills
Abstract A CrCoNi based medium entropy alloy with small additions of Ti, Al and Nb (denoted as (CrCoNi)93Al4Ti2Nb) in the as-quenched condition, exhibits tensile properties comparable to those of the equiatomic CrCoNi alloy at room temperature. Dark field transmission electron microscopy (TEM), atomic resolution high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with atom probe tomography (APT) show that spatially-localized long range ordering (LRO) L12 domains exist in this alloy. The evolution of deformation substructure with plastic deformation in this alloy was characterized using electron backscatter diffraction (EBSD), electron channeling contrast imaging (ECCI) and STEM based techniques including the recently developed weak beam dark field STEM imaging. Plastic deformation occurs by the slip of a/2 dislocations, which are narrowly dissociated into Shockley partial dislocations on {111} slip planes. Their dissociation distances in the (CrCoNi)93Al4Ti2Nb alloy are much smaller than the widths of the corresponding partials in the equiatomic CrCoNi alloy due to one or more of the minor alloying elements (Al, Ti, Nb). Dislocation slip in this alloy has a pronounced planar character. The leading dislocations in slip bands glide as pairs due to the existence of LRO domains. Multipoles were formed through the slip of dislocations with opposite signs on adjacent {111} slip planes. Those multipoles serve as building blocks for the formation of subgrain structures consisting of fine slip bands. The distances between slip bands were continuously refined during plastic deformation and dynamic refinement of slip bands plays a crucial role in strain hardening. The effects of LRO domains on planar dislocation slip, the deactivation of deformation twinning and strain hardening of this alloy are discussed.
{"title":"Ordering Effects on Deformation Substructures and Strain Hardening Behavior of a CrCoNi Based Medium Entropy Alloy","authors":"J. Miao, C. Slone, S. Dasari, M. Ghazisaeidi, R. Banerjee, E. George, M. Mills","doi":"10.2139/ssrn.3655861","DOIUrl":"https://doi.org/10.2139/ssrn.3655861","url":null,"abstract":"Abstract A CrCoNi based medium entropy alloy with small additions of Ti, Al and Nb (denoted as (CrCoNi)93Al4Ti2Nb) in the as-quenched condition, exhibits tensile properties comparable to those of the equiatomic CrCoNi alloy at room temperature. Dark field transmission electron microscopy (TEM), atomic resolution high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with atom probe tomography (APT) show that spatially-localized long range ordering (LRO) L12 domains exist in this alloy. The evolution of deformation substructure with plastic deformation in this alloy was characterized using electron backscatter diffraction (EBSD), electron channeling contrast imaging (ECCI) and STEM based techniques including the recently developed weak beam dark field STEM imaging. Plastic deformation occurs by the slip of a/2 dislocations, which are narrowly dissociated into Shockley partial dislocations on {111} slip planes. Their dissociation distances in the (CrCoNi)93Al4Ti2Nb alloy are much smaller than the widths of the corresponding partials in the equiatomic CrCoNi alloy due to one or more of the minor alloying elements (Al, Ti, Nb). Dislocation slip in this alloy has a pronounced planar character. The leading dislocations in slip bands glide as pairs due to the existence of LRO domains. Multipoles were formed through the slip of dislocations with opposite signs on adjacent {111} slip planes. Those multipoles serve as building blocks for the formation of subgrain structures consisting of fine slip bands. The distances between slip bands were continuously refined during plastic deformation and dynamic refinement of slip bands plays a crucial role in strain hardening. The effects of LRO domains on planar dislocation slip, the deactivation of deformation twinning and strain hardening of this alloy are discussed.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83961626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
New metallic alloys were developed based on lattice occupancy project employing 9 distinct elements. Chromium equivalent equation is the key parameter on selecting the alloy elements in the sense that higher coefficient of chosen element will expand and stabilize the body centred cubic field. Other assumed concept in the alloy project considers one same element repeated 3 times at molar base, reducing the number of elements to 7. The alloys were characterized by scanning electron microscopy and X-ray diffraction, revealing there are 2 or 3 main crystalline body centred cubic phases. As-cast and carburized alloys of extreme hardness were obtained from 1420 HV to 2507 HV with reasonable toughness. The new alloys are the hardest metallic materials known to mankind, with promising applications.
{"title":"Development of Extreme Hardness Alloys by Lattice Occupancy Project","authors":"Thomaz Augusto Guisard Restivo, G. Restivo","doi":"10.2139/ssrn.3639787","DOIUrl":"https://doi.org/10.2139/ssrn.3639787","url":null,"abstract":"New metallic alloys were developed based on lattice occupancy project employing 9 distinct elements. Chromium equivalent equation is the key parameter on selecting the alloy elements in the sense that higher coefficient of chosen element will expand and stabilize the body centred cubic field. Other assumed concept in the alloy project considers one same element repeated 3 times at molar base, reducing the number of elements to 7. The alloys were characterized by scanning electron microscopy and X-ray diffraction, revealing there are 2 or 3 main crystalline body centred cubic phases. As-cast and carburized alloys of extreme hardness were obtained from 1420 HV to 2507 HV with reasonable toughness. The new alloys are the hardest metallic materials known to mankind, with promising applications.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81099508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The purpose of this article is to identify, classify and contrast several types of online manufacturing platforms (OMPs), which are virtual platforms that connect and facilitate the interaction between two or more entities (e.g., firms and customers) in the manufacturing domain. We propose a taxonomy of OMPs emerging from the empirical data. To do so, we implement a multiple case study, triangulating data available on the web with interviews. We also use a novel type of experiential research: we perform some transactional activities (e.g., order the design and manufacture of a product) to better understand how the firms and their OMPs work. We select and assess the platforms of 71 firms in 21 different countries. The results suggest that there are closed online manufacturing platforms (COMPs), which optimize the industrial equipment and installations of major manufacturers and their clients, and multi-sided online manufacturing platforms (MOMPs), which connect customers with independent fabricators. This study provides insights that can help us to better understand the diversity and potential of OMP and the synergies that are created between them and manufacturing firms.
{"title":"Online Manufacturing Platforms: Closed vs Multisided Platforms to Support Fabrication","authors":"J. Montes","doi":"10.2139/ssrn.3640832","DOIUrl":"https://doi.org/10.2139/ssrn.3640832","url":null,"abstract":"The purpose of this article is to identify, classify and contrast several types of online manufacturing platforms (OMPs), which are virtual platforms that connect and facilitate the interaction between two or more entities (e.g., firms and customers) in the manufacturing domain. We propose a taxonomy of OMPs emerging from the empirical data. To do so, we implement a multiple case study, triangulating data available on the web with interviews. We also use a novel type of experiential research: we perform some transactional activities (e.g., order the design and manufacture of a product) to better understand how the firms and their OMPs work. We select and assess the platforms of 71 firms in 21 different countries. The results suggest that there are closed online manufacturing platforms (COMPs), which optimize the industrial equipment and installations of major manufacturers and their clients, and multi-sided online manufacturing platforms (MOMPs), which connect customers with independent fabricators. This study provides insights that can help us to better understand the diversity and potential of OMP and the synergies that are created between them and manufacturing firms.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83350246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-30DOI: 10.15587/1729-4061.2020.206014
A. Karakurkchi, M. Sakhnenko, M. Ved’, Mykhailo Tulenko, Anatolii Dzheniuk
Technological approaches to surface electrochemical treatment of aluminum alloys are analyzed. It is shown that directed modification of the carrier surface allows expanding the functional properties of the treated material. The mechanisms of treatment of aluminum alloys of different composition are investigated and technological models of processes using generalized phenomenological schemes are developed. Methods surface forming treatment of aluminum alloys by pulse current forming in chloride-containing electrolytes and plasma electrolytic oxidation in alkaline solutions of diphosphates are proposed. It is shown that the use of pulse electrolysis promotes the formation of a developed mesh and porous structure. Control methods and factors of the treatment process are generalized. The resulting systems can be used as carriers of catalytic material provided that a secondary catalytically active layer is applied. It is found that using plasma electrolytic oxidation, it is possible to change the shape and homogenize the surface layers of the carrier and apply a tightly adhered layer of catalytic material in one technological process. It is shown that the characteristic parameters of PEO depend on the composition of the treated material. It is revealed that the morphology and phase structure of surface oxide layers change during PEO. The formed oxide coatings consist of α-Al 2 O 3 and have a high degree of surface development, which is a prerequisite for increasing their functional properties. The proposed approach can be used in surface engineering technology and for obtaining materials for environmentally friendly technologies
{"title":"Analysis of Technological Approaches to Electrochemical Surface Treatment of Aluminum Alloys","authors":"A. Karakurkchi, M. Sakhnenko, M. Ved’, Mykhailo Tulenko, Anatolii Dzheniuk","doi":"10.15587/1729-4061.2020.206014","DOIUrl":"https://doi.org/10.15587/1729-4061.2020.206014","url":null,"abstract":"Technological approaches to surface electrochemical treatment of aluminum alloys are analyzed. It is shown that directed modification of the carrier surface allows expanding the functional properties of the treated material. The mechanisms of treatment of aluminum alloys of different composition are investigated and technological models of processes using generalized phenomenological schemes are developed. Methods surface forming treatment of aluminum alloys by pulse current forming in chloride-containing electrolytes and plasma electrolytic oxidation in alkaline solutions of diphosphates are proposed. It is shown that the use of pulse electrolysis promotes the formation of a developed mesh and porous structure. Control methods and factors of the treatment process are generalized. The resulting systems can be used as carriers of catalytic material provided that a secondary catalytically active layer is applied. It is found that using plasma electrolytic oxidation, it is possible to change the shape and homogenize the surface layers of the carrier and apply a tightly adhered layer of catalytic material in one technological process. It is shown that the characteristic parameters of PEO depend on the composition of the treated material. It is revealed that the morphology and phase structure of surface oxide layers change during PEO. The formed oxide coatings consist of α-Al 2 O 3 and have a high degree of surface development, which is a prerequisite for increasing their functional properties. The proposed approach can be used in surface engineering technology and for obtaining materials for environmentally friendly technologies","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89869059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-30DOI: 10.15587/1729-4061.2020.203664
V. Papchenko, T. Matveeva, S. Bochkarev, A. Belinska, Ekaterina Kunitsia, A. Chernukha, Oleg Bezuglov, O. Bogatov, Dmytro Polkovnychenko, Sergey Shcherbak
The analysis of the main methods of increasing the nutritional and biological value of wheat flour has been conducted. Considerable attention is paid to the issue of adjusting the protein content in flour due to additives. The relevance of improving the amino acid composition of flour protein is emphasized. The feasibility of comprehensive studies for the development of food system formulations with a balanced amino acid composition based on wheat flour and oilseed meal is substantiated. The amino acid content has been experimentally determined and the biological value of raw materials proteins for food systems which are sunflower and soybean meal has been calculated. The mixture composition of sunflower and soybean meal with an improved amino acid composition has been scientifically substantiated. It has been found that the protein composition of the meal mixture is maximally close to the reference in terms of the content of leucine, lysine and the amount of sulfur-containing amino acids (methionine, cystine). The score of isoleucine, tryptophan, phenylalanine and tyrosine in the protein composition of oilseed meal is 1.1–1.47 times higher than the reference. The amino acid composition has been calculated and the biological value of the protein of food systems containing 80–90 % wheat flour and 10–20 % composition of soybean and sunflower meal with improved amino acid composition has been determined. It has been found that the formulation of the food system containing 20 % of the composition of meal mixture and 80 % of wheat flour has the greatest biological value in comparison with wheat flour. In this food system, the limited amino acids – lysine and sulfur-containing (methionine and cystine) are the closest to the reference one and are 67.68 % and 70.12 %. The fatty acid composition has been experimentally determined. The biological effectiveness of the fats of the developed food systems has been calculated. The closest to the fatty acid ratio recommended by nutritionists is the food system with a ratio of meal mixture: wheat flour of 20:80. The resulting formulations of food systems will be useful in technologies of flour products with high biological value.
{"title":"Development of Amino Acid Balanced Food Systems Based on Wheat Flour and Oilseed Meal","authors":"V. Papchenko, T. Matveeva, S. Bochkarev, A. Belinska, Ekaterina Kunitsia, A. Chernukha, Oleg Bezuglov, O. Bogatov, Dmytro Polkovnychenko, Sergey Shcherbak","doi":"10.15587/1729-4061.2020.203664","DOIUrl":"https://doi.org/10.15587/1729-4061.2020.203664","url":null,"abstract":"The analysis of the main methods of increasing the nutritional and biological value of wheat flour has been conducted. Considerable attention is paid to the issue of adjusting the protein content in flour due to additives. The relevance of improving the amino acid composition of flour protein is emphasized. The feasibility of comprehensive studies for the development of food system formulations with a balanced amino acid composition based on wheat flour and oilseed meal is substantiated. The amino acid content has been experimentally determined and the biological value of raw materials proteins for food systems which are sunflower and soybean meal has been calculated. The mixture composition of sunflower and soybean meal with an improved amino acid composition has been scientifically substantiated. It has been found that the protein composition of the meal mixture is maximally close to the reference in terms of the content of leucine, lysine and the amount of sulfur-containing amino acids (methionine, cystine). The score of isoleucine, tryptophan, phenylalanine and tyrosine in the protein composition of oilseed meal is 1.1–1.47 times higher than the reference. The amino acid composition has been calculated and the biological value of the protein of food systems containing 80–90 % wheat flour and 10–20 % composition of soybean and sunflower meal with improved amino acid composition has been determined. It has been found that the formulation of the food system containing 20 % of the composition of meal mixture and 80 % of wheat flour has the greatest biological value in comparison with wheat flour. In this food system, the limited amino acids – lysine and sulfur-containing (methionine and cystine) are the closest to the reference one and are 67.68 % and 70.12 %. The fatty acid composition has been experimentally determined. The biological effectiveness of the fats of the developed food systems has been calculated. The closest to the fatty acid ratio recommended by nutritionists is the food system with a ratio of meal mixture: wheat flour of 20:80. The resulting formulations of food systems will be useful in technologies of flour products with high biological value.","PeriodicalId":18300,"journal":{"name":"MatSciRN: Other Materials Processing & Manufacturing (Topic)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88474826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-19DOI: 10.15587/1729-4061.2020.203947
V. Savenko, V. Honcharenko, Sergii Illiash, Anatoliy Mudrychenko, I. Balashov
The method of expert assessments has been used to substantiate that the most significant factors that significantly influence the mechanism and kinetics of technological processes of the regenerated mixture preparation are the temperature of its preparation and the content of the regenerating additive. We have investigated their influence on the physical-mechanical parameters of regenerated asphalt concrete, obtained using the technology of hot recycling of asphalt concrete pavement applying the «in place» method. The experimental research has established the dependences of the physical and mechanical parameters (water saturation, compressive strength at 0 °С and 50 °С) of regenerated asphalt concrete on the content of an additive and stirring temperature. The mathematical models have been constructed in the form of second-degree polynomials that describe the dependence of water saturation and strength at the compression of regenerated asphalt concrete on the temperature of preparation and the content of a regenerating additive. It has been established that increasing the stirring temperature increases compressive strength at 0 °С; at the same time, compressive strength at 50 °С and the measure of water saturation decreases. The increase in the regenerating additive reduces all the examined physical and mechanical indicators. Based on an analysis of the results obtained, we have determined the regions of rational values of the stirring temperature of loose asphalt-concrete crumbs (125‒135) °С, as well as the content of an additive (0.26‒0.28) %, when preparing hot asphalt concrete mixture. In terms of physical-technical indicators, the resulting mixture meets the requirements set by DSTU B V.2.7-119:2011 «Asphalt concrete mixes and road and airfield asphalt concrete. Technical specifications» for hot fine-grained asphalt mixtures. The reported results could prove useful when devising a technology of hot recycling of asphalt concrete pavement by the «in place» method and for studies related to its improvement
采用专家评价的方法证实，对再生混合料制备工艺过程的机理和动力学影响最大的因素是制备温度和再生添加剂的含量。本文研究了它们对再生沥青混凝土物理力学参数的影响。再生沥青混凝土是利用沥青混凝土路面热回收技术，采用“就地”法获得的。试验研究建立了再生沥青混凝土的物理力学参数(含水饱和度、0°С和50°С抗压强度)与掺量和搅拌温度的关系。以二阶多项式的形式建立了数学模型，描述了再生沥青混凝土的含水饱和度和压缩强度与制备温度和再生添加剂含量的关系。在0°С时，提高搅拌温度可提高抗压强度;同时，在50°С时抗压强度减小，含水饱和度减小。再生添加剂的增加降低了所有检测的物理和机械指标。在对所得结果进行分析的基础上，确定了制备热沥青混凝土混合料时松散沥青-混凝土屑搅拌温度(125-135)°С和添加剂(0.26-0.28)%的合理范围。在物理技术指标方面，所得混合料符合DSTU B V.2.7-119:2011《沥青混凝土混合料和道路和机场沥青混凝土》的要求。热细粒沥青混合料技术规范。所报告的结果在设计“就地”方法热回收沥青混凝土路面的技术以及对其改进的相关研究时可以证明是有用的
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