Pub Date : 2023-01-01DOI: 10.1051/matecconf/202337701018
Abdul Zahir, Perumal Kumar, A. Saptoro, A. N. T. Tiong, Samreen Hameed, M. Shah
Rotating packed bed (RPB) belongs to a HIGee technology, a process intensification device that can provide better mass transfer rate due to the generation of hyper-gravity under the influence of centrifugal force. While determining the efficiency of the RPB, the MRT of the liquid plays a vital role. The MRT of the RPB is very small and can be tuned in accordance with the mass transfer rate of the solvent to achieve the required outlet concentration of the absorbed gas. There exist two methods, i.e., empirical correlation and the residence time distribution (RTD) method. The applicability of both methods still needs to be investigated for better prediction of MRT in RPB. The current study compares the MRT of the two of the most widely employed techniques, i.e., MRT by empirical correlation and the RTD approach using the Computational Fluid Dynamics (CFD). The difference between the MRT by both methods lies between 30-38%. The results show that the RTD better predicts the MRT in the RPB as compared to the Burns empirical correlation.
{"title":"Liquid mean residence time (MRT) in rotating packed bed (RPB) by empirical correlation and residence time distribution (RTD) method using computational fluid dynamics (CFD) simulation","authors":"Abdul Zahir, Perumal Kumar, A. Saptoro, A. N. T. Tiong, Samreen Hameed, M. Shah","doi":"10.1051/matecconf/202337701018","DOIUrl":"https://doi.org/10.1051/matecconf/202337701018","url":null,"abstract":"Rotating packed bed (RPB) belongs to a HIGee technology, a process intensification device that can provide better mass transfer rate due to the generation of hyper-gravity under the influence of centrifugal force. While determining the efficiency of the RPB, the MRT of the liquid plays a vital role. The MRT of the RPB is very small and can be tuned in accordance with the mass transfer rate of the solvent to achieve the required outlet concentration of the absorbed gas. There exist two methods, i.e., empirical correlation and the residence time distribution (RTD) method. The applicability of both methods still needs to be investigated for better prediction of MRT in RPB. The current study compares the MRT of the two of the most widely employed techniques, i.e., MRT by empirical correlation and the RTD approach using the Computational Fluid Dynamics (CFD). The difference between the MRT by both methods lies between 30-38%. The results show that the RTD better predicts the MRT in the RPB as compared to the Burns empirical correlation.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"24 3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78661899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202338201018
Duo Wang
The research on electromechanical transient stability of power systems is of great significance. Analyzing the parameters of the simulation system and its improved system with typical short-circuit faults, this paper studies the transient stability of power systems and its improvement. Firstly, based on the SIMULINK of MATLAB, a double-loop simulation with the single-machine-infinite-bus system is built. The simulation experiments of the system under the circumstances of three-phase short circuit and single-phase grounding short circuit faults are then carried out to analyze the parameters such as limit cutting time and voltage. Besides, this paper explores how the controllable series capacitor compensation device and reducing mechanical power output by prime mover improve the transient stability of the system. Experiments show that the stability after fault is under conditions where the fault is removed before the critical clearing time, which can increase the threshold to gain more response time for relay protection devices. Thus, the value of researching and improving system transient stability is proved.
{"title":"Research and Improvement of Electromechanical Transient Performance of Power System Based on SIMULINK","authors":"Duo Wang","doi":"10.1051/matecconf/202338201018","DOIUrl":"https://doi.org/10.1051/matecconf/202338201018","url":null,"abstract":"The research on electromechanical transient stability of power systems is of great significance. Analyzing the parameters of the simulation system and its improved system with typical short-circuit faults, this paper studies the transient stability of power systems and its improvement. Firstly, based on the SIMULINK of MATLAB, a double-loop simulation with the single-machine-infinite-bus system is built. The simulation experiments of the system under the circumstances of three-phase short circuit and single-phase grounding short circuit faults are then carried out to analyze the parameters such as limit cutting time and voltage. Besides, this paper explores how the controllable series capacitor compensation device and reducing mechanical power output by prime mover improve the transient stability of the system. Experiments show that the stability after fault is under conditions where the fault is removed before the critical clearing time, which can increase the threshold to gain more response time for relay protection devices. Thus, the value of researching and improving system transient stability is proved.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76249954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202337901005
S. Braccio, H. Phan, N. Tauveron, Nolwenn Le Pierrès
Given the ever-increasing global demand for energy and the attention to be paid to environmental issues and climate change, research is developing more and more about new cold production technologies using renewable sources or recovery. This cooling demand is mainly covered by technologies conventional machines, in particular vapor compression machines, which leads to a high increased demand for electricity. In this context, absorption systems (Herold et al. 2016), lend themselves well to the recovery of heat at low temperature for the production of cold. The advantage of these machines is that the mechanical compression is replaced by a compression thermochemical that uses heat. Although characterized by a low level of maturity technology (TRL 3-4), an even more ambitious study concerns combined systems based on exploitation of thermal energy at low temperatures, in which electrical power and cooling are produced in the same cycle. The present work focuses on the analysis of a pilot installation (Figure 1) of combined production cooling and electricity (CFE) in parallel, from a low temperature source [80 -150°C] and from maximum thermal power of the generator 15 kW.
随着全球对能源需求的不断增长以及对环境问题和气候变化的关注，利用可再生能源或可回收的新型冷生产技术的研究越来越多。这种冷却需求主要由传统机器技术来满足，特别是蒸汽压缩机器，这导致电力需求的大幅增加。在这种情况下，吸收系统(Herold et al. 2016)可以很好地在低温下回收热量以产生冷。这些机器的优点是机械压缩被利用热量的压缩热化学物所取代。尽管其特点是技术成熟度较低(TRL 3-4)，但一项更雄心勃勃的研究涉及基于低温热能开采的联合系统，其中电力和冷却在同一循环中产生。目前的工作重点是分析一个试验装置(图1)，该装置采用低温源[80 -150°C]和发电机的最大热功率为15 kW，并将生产冷却和电力(CFE)并联。
{"title":"Energy and exergy analysis of a pilot plant for the co-production of cold and electricity","authors":"S. Braccio, H. Phan, N. Tauveron, Nolwenn Le Pierrès","doi":"10.1051/matecconf/202337901005","DOIUrl":"https://doi.org/10.1051/matecconf/202337901005","url":null,"abstract":"Given the ever-increasing global demand for energy and the attention to be paid to environmental issues and climate change, research is developing more and more about new cold production technologies using renewable sources or recovery. This cooling demand is mainly covered by technologies conventional machines, in particular vapor compression machines, which leads to a high increased demand for electricity. In this context, absorption systems (Herold et al. 2016), lend themselves well to the recovery of heat at low temperature for the production of cold. The advantage of these machines is that the mechanical compression is replaced by a compression thermochemical that uses heat. Although characterized by a low level of maturity technology (TRL 3-4), an even more ambitious study concerns combined systems based on exploitation of thermal energy at low temperatures, in which electrical power and cooling are produced in the same cycle. The present work focuses on the analysis of a pilot installation (Figure 1) of combined production cooling and electricity (CFE) in parallel, from a low temperature source [80 -150°C] and from maximum thermal power of the generator 15 kW.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"71 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87730587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202337701010
Emmanuel Yahaya, J. Nandong, Wan sieng Yeo
Biohydrogen production from renewable resources using dark fermentation has become an increasingly attractive solution in sustainable global energy supply. So far, there has been no report on the controllability analysis of biohydrogen production using dark fermentation. Process controllability is a crucial factor determining process feasibility. This paper presents a new criterion for assessing biohydrogen process controllability based on PI control. It proposes the critical loop gain derived via Routh stability analysis as a measure of process controllability. Results show that the dark fermentation using the bacteria from anaerobic dairy sludge and substrate source from sugarcane vinasse can lead to a highly controllable process with a critical loop gain value of 4.3. For the two other cases, an increase of substrate concentration from 10 g/L to 40 g/L substantially reduces the controllability. The proposed controllability criterion is easily adopted to assess the process feasibilty based on experimental data.
{"title":"Biohydrogen production: A new controllability criterion for analyzing the impacts of dark fermentation conditions","authors":"Emmanuel Yahaya, J. Nandong, Wan sieng Yeo","doi":"10.1051/matecconf/202337701010","DOIUrl":"https://doi.org/10.1051/matecconf/202337701010","url":null,"abstract":"Biohydrogen production from renewable resources using dark fermentation has become an increasingly attractive solution in sustainable global energy supply. So far, there has been no report on the controllability analysis of biohydrogen production using dark fermentation. Process controllability is a crucial factor determining process feasibility. This paper presents a new criterion for assessing biohydrogen process controllability based on PI control. It proposes the critical loop gain derived via Routh stability analysis as a measure of process controllability. Results show that the dark fermentation using the bacteria from anaerobic dairy sludge and substrate source from sugarcane vinasse can lead to a highly controllable process with a critical loop gain value of 4.3. For the two other cases, an increase of substrate concentration from 10 g/L to 40 g/L substantially reduces the controllability. The proposed controllability criterion is easily adopted to assess the process feasibilty based on experimental data.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"64 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86513011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202337809001
A. Jefferson, B. Freeman
This study investigates the ability of a coupled finite element model to simulate Microbially Induced Calcium Carbonate Precipitation (MICP) and associated healing behaviour in cementitious samples. This recent coupled 3D model was first developed for simulating the behaviour of autonomic healing systems in cementitious structural elements. It employs a cohesive zone constitutive model for simulating the damage-healing behaviour of an embedded interface within 3D continuum elements. Fluid flow is simulated using a mass balance equation and Darcy’s law. Healing is computed via a generalised curing front model that simulates the accumulation of healed material within a crack. The research reported in this article demonstrates that the curing front model can be calibrated to predict healing from MICP in cementitious specimens with good accuracy.
{"title":"The application of a curing front model to simulate healing in a cementitious microbial system","authors":"A. Jefferson, B. Freeman","doi":"10.1051/matecconf/202337809001","DOIUrl":"https://doi.org/10.1051/matecconf/202337809001","url":null,"abstract":"This study investigates the ability of a coupled finite element model to simulate Microbially Induced Calcium Carbonate Precipitation (MICP) and associated healing behaviour in cementitious samples. This recent coupled 3D model was first developed for simulating the behaviour of autonomic healing systems in cementitious structural elements. It employs a cohesive zone constitutive model for simulating the damage-healing behaviour of an embedded interface within 3D continuum elements. Fluid flow is simulated using a mass balance equation and Darcy’s law. Healing is computed via a generalised curing front model that simulates the accumulation of healed material within a crack. The research reported in this article demonstrates that the curing front model can be calibrated to predict healing from MICP in cementitious specimens with good accuracy.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"89 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83884808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202338102007
Asad Ali, Muhammad Jawad, M. Jahanzaib
This study aims to evaluate the microstructure and mechanical behavior of aluminum 2024 and stainless steel 304 dissimilar joints. The gas tungsten arc welding (GTAW) process has been employed to weld base metals by inserting copper-nickel-based (Cu-10%Ni) filler metal. The effects of GTAW parameters such as welding current, welding speed, and gas flow on microstructure and tensile strength have been analyzed through the Taguchi method. Results revealed that tensile strength is primarily influenced by welding current, followed by speed and gas flow rate. The excellent joint strength of 138 MPa has been achieved by using Cu-10%Ni filler metal. The optimal combination of parameters, i.e., welding current of level 2 (80 A), welding speed of level 1 (100 mm/min), and gas flow rate of level 3 (10 l/min), has been obtained through SN ratio optimization. Microstructure and EDS analysis depicted that the weld zone of a high-strength joint contained fine dendrites and CuAl and NiAl solid solutions, while the weld zone of a low-strength joint featured coarse dendrites and brittle FeAl phases.
{"title":"Evaluation of microstructure and mechanical behavior of Aluminum 2024 and Stainless steel 304 GTAW joints","authors":"Asad Ali, Muhammad Jawad, M. Jahanzaib","doi":"10.1051/matecconf/202338102007","DOIUrl":"https://doi.org/10.1051/matecconf/202338102007","url":null,"abstract":"This study aims to evaluate the microstructure and mechanical behavior of aluminum 2024 and stainless steel 304 dissimilar joints. The gas tungsten arc welding (GTAW) process has been employed to weld base metals by inserting copper-nickel-based (Cu-10%Ni) filler metal. The effects of GTAW parameters such as welding current, welding speed, and gas flow on microstructure and tensile strength have been analyzed through the Taguchi method. Results revealed that tensile strength is primarily influenced by welding current, followed by speed and gas flow rate. The excellent joint strength of 138 MPa has been achieved by using Cu-10%Ni filler metal. The optimal combination of parameters, i.e., welding current of level 2 (80 A), welding speed of level 1 (100 mm/min), and gas flow rate of level 3 (10 l/min), has been obtained through SN ratio optimization. Microstructure and EDS analysis depicted that the weld zone of a high-strength joint contained fine dendrites and CuAl and NiAl solid solutions, while the weld zone of a low-strength joint featured coarse dendrites and brittle FeAl phases.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80722854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202338101004
Z. Zia, Faisal Ami, Mudasir Hussain, Zia ur Rehman, Shahazadi Arzak Semab
This study concerns the two-dimensional structure computational results of renal artery stenosis. In this paper, the turbulent flow of the stenosed vessel is stimulated and correlates the different stages of stenosis with each other. As we know that the blood flow in most blood vessels is laminar, but in case of stenosed vessel, the blood flow becomes turbulent; this is due to the blockage that blood does not flow linearly and produces chaos. Several liquid parameters are analyzed, such as pressure, velocity, turbulence kinetic energy, density, and shear rate. The inlet and outlet flow are especially concerning. For this purpose, we explored the stenosed behavior by the software COMSOL Multiphysics which provided us with a complete examination of the Computational fluid dynamics. With an increase in renal artery stenosis, there is a decrease in the blood flow which will automatically affect the pressure of the blood and can cause serious kidney diseases and, in some cases, permanent damage to the kidney sometimes. This paper highlights the early stages of renal artery stenosis, which are likely to be cured. Also, it shows the behavior of the severe late stages, which we consider nearly impossible to cure. The result explains that how different parameters vary according to stated cases.
{"title":"Simulation and Analyses of Turbulent Flow in Different Phases of Stenosed Renal Artery","authors":"Z. Zia, Faisal Ami, Mudasir Hussain, Zia ur Rehman, Shahazadi Arzak Semab","doi":"10.1051/matecconf/202338101004","DOIUrl":"https://doi.org/10.1051/matecconf/202338101004","url":null,"abstract":"This study concerns the two-dimensional structure computational results of renal artery stenosis. In this paper, the turbulent flow of the stenosed vessel is stimulated and correlates the different stages of stenosis with each other. As we know that the blood flow in most blood vessels is laminar, but in case of stenosed vessel, the blood flow becomes turbulent; this is due to the blockage that blood does not flow linearly and produces chaos. Several liquid parameters are analyzed, such as pressure, velocity, turbulence kinetic energy, density, and shear rate. The inlet and outlet flow are especially concerning. For this purpose, we explored the stenosed behavior by the software COMSOL Multiphysics which provided us with a complete examination of the Computational fluid dynamics. With an increase in renal artery stenosis, there is a decrease in the blood flow which will automatically affect the pressure of the blood and can cause serious kidney diseases and, in some cases, permanent damage to the kidney sometimes. This paper highlights the early stages of renal artery stenosis, which are likely to be cured. Also, it shows the behavior of the severe late stages, which we consider nearly impossible to cure. The result explains that how different parameters vary according to stated cases.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81033577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202338201032
Binrong Zhu, G. Huang, Zhigang Su, Bin Chen, Hailin Liao
transmission towers have been subjected to alternating loads caused by the galloping of iced conductors for a long time, and their fastening bolts are easy to loosen or break, which seriously threatens the safe operation of transmission lines. Through the transverse vibration test of M20 bolts commonly used in transmission towers, the vibration frequency and amplitude are changed, and the change law of the preload of bolt joints is studied. The results show that with the increase of the initial preload, the decline speed of bolt clamping force decreases significantly; The clamping force drop curve of M20 bolt is fitted by shivakumar crews model, which is very consistent with the actual test curve.
{"title":"Study on looseness characteristics of bolted joints of transmission towers under lateral vibration","authors":"Binrong Zhu, G. Huang, Zhigang Su, Bin Chen, Hailin Liao","doi":"10.1051/matecconf/202338201032","DOIUrl":"https://doi.org/10.1051/matecconf/202338201032","url":null,"abstract":"transmission towers have been subjected to alternating loads caused by the galloping of iced conductors for a long time, and their fastening bolts are easy to loosen or break, which seriously threatens the safe operation of transmission lines. Through the transverse vibration test of M20 bolts commonly used in transmission towers, the vibration frequency and amplitude are changed, and the change law of the preload of bolt joints is studied. The results show that with the increase of the initial preload, the decline speed of bolt clamping force decreases significantly; The clamping force drop curve of M20 bolt is fitted by shivakumar crews model, which is very consistent with the actual test curve.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81065881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202337802010
Claire Riordan, D. Palmer, A. Al-Tabbaa
Capsule-based self-sealing in cementitious systems is an advantageous methodology which has the potential to decrease water ingress and thus enhance a system’s durability and extend its lifespan. If capsule-based self-sealing is to be considered as an industrial solution, production must be scaled while capsule quality and batch reproducibility are maintained. In this study, polyurethane-shelled microcapsules containing a commercially available water repellent agent were produced using membrane emulsification equipment, supplied by Micropore Technologies, followed by interfacial polymerisation. Production was scaled across three different cross-flow membrane emulsification devices, the AXF-1, the AXF-3, and the AXF-4, increasing production output to a maximum of 850 L/hr of capsule suspension. Following production, capsules were characterised, measuring average size and size distribution, as well as integrated into a cementitious matrix. The results highlight the key parameters that govern capsule size, the versatility of the equipment, and the consistent quality of capsules produced. It is hoped that this scaled production of capsules will help to develop the commercial viability of capsule-based self-sealing cementitious systems.
{"title":"Investigation of Membrane Emulsification for the Scaled Production of Microcapsules for Self-sealing Cementitious Systems","authors":"Claire Riordan, D. Palmer, A. Al-Tabbaa","doi":"10.1051/matecconf/202337802010","DOIUrl":"https://doi.org/10.1051/matecconf/202337802010","url":null,"abstract":"Capsule-based self-sealing in cementitious systems is an advantageous methodology which has the potential to decrease water ingress and thus enhance a system’s durability and extend its lifespan. If capsule-based self-sealing is to be considered as an industrial solution, production must be scaled while capsule quality and batch reproducibility are maintained. In this study, polyurethane-shelled microcapsules containing a commercially available water repellent agent were produced using membrane emulsification equipment, supplied by Micropore Technologies, followed by interfacial polymerisation. Production was scaled across three different cross-flow membrane emulsification devices, the AXF-1, the AXF-3, and the AXF-4, increasing production output to a maximum of 850 L/hr of capsule suspension. Following production, capsules were characterised, measuring average size and size distribution, as well as integrated into a cementitious matrix. The results highlight the key parameters that govern capsule size, the versatility of the equipment, and the consistent quality of capsules produced. It is hoped that this scaled production of capsules will help to develop the commercial viability of capsule-based self-sealing cementitious systems.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"166 1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83327959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1051/matecconf/202338201005
Yongxiu Sun, Zhijie Li
Single-atom catalysts (SACs) for the hydrogen evolution reaction (HER) is an efficient electrochemical pathway to produce the green production. However, the development of HER process is hampered by the lack of high-performance electrocatalysts. In this work, we proposed a new π-d conjugated structure of the Ti3B3N3S6 monolayer as the single-atom catalysts for the HER process by using the density functional theory (DFT) calculations. The calculated results show that the Ti atom is active site of the Ti3B3N3S6 monolayer with the high catalytic activity (ΔGH = –0.14 eV) for HER. The electronic properties of the Ti3B3N3S6 monolayer were explored by the electron localization function (ELF), Bader charge analysis and the polarized density of states (PDOS) density analysis. The Ti3B3N3S6 monolayer can promote the electronic transfer during the HER process, which indicates taht the Ti3B3N3S6 monolayer can is considered to investigate the catalytic activity for HER. The Gibbs free energy of H atoms adsorption on the Ti3B3N3S6 monolayer is –0.14 eV. Furthermore, the origin of high catalytic activity for the Ti3B3N3S6 monolayer was explored by the analysis the PDOS of the H adsorption on the Ti3B3N3S6 monolayer. Therefore, our work propose a new and high catalytic single-atom catalyst for the HER.
{"title":"High catalyst performance of two-dimensional Ti3B3N3S6 for hydrogen evolution reaction","authors":"Yongxiu Sun, Zhijie Li","doi":"10.1051/matecconf/202338201005","DOIUrl":"https://doi.org/10.1051/matecconf/202338201005","url":null,"abstract":"Single-atom catalysts (SACs) for the hydrogen evolution reaction (HER) is an efficient electrochemical pathway to produce the green production. However, the development of HER process is hampered by the lack of high-performance electrocatalysts. In this work, we proposed a new π-d conjugated structure of the Ti3B3N3S6 monolayer as the single-atom catalysts for the HER process by using the density functional theory (DFT) calculations. The calculated results show that the Ti atom is active site of the Ti3B3N3S6 monolayer with the high catalytic activity (ΔGH = –0.14 eV) for HER. The electronic properties of the Ti3B3N3S6 monolayer were explored by the electron localization function (ELF), Bader charge analysis and the polarized density of states (PDOS) density analysis. The Ti3B3N3S6 monolayer can promote the electronic transfer during the HER process, which indicates taht the Ti3B3N3S6 monolayer can is considered to investigate the catalytic activity for HER. The Gibbs free energy of H atoms adsorption on the Ti3B3N3S6 monolayer is –0.14 eV. Furthermore, the origin of high catalytic activity for the Ti3B3N3S6 monolayer was explored by the analysis the PDOS of the H adsorption on the Ti3B3N3S6 monolayer. Therefore, our work propose a new and high catalytic single-atom catalyst for the HER.","PeriodicalId":18309,"journal":{"name":"MATEC Web of Conferences","volume":"23 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88669107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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