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Assessing Apparent Equilibrium Concentrations in Cementation of Trace Pd, Pt, Au, and Rh from Nitrate Solutions Using Mg, Al, Fe, and Zn 利用镁、铝、铁和锌评估硝酸盐溶液中痕量钯、铂、金和铑固结的表观平衡浓度
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.3390/met14090990
Konrad Wojtaszek, Adrianna Pach, Tomasz Michalek, Kamil Dudek, Marek Wojnicki
This study explores the impact of nitrate ions on the efficiency of cementing noble metals from diluted waste solutions at a temperature of 30 °C. The research involved measuring the effectiveness of different cementing metals (such as Zn, Al, Mg, and Fe) in the presence of nitrate ions by assessing the change in metal ion concentrations before and after the cementation process using spectrometric analysis. Initial concentrations of noble metals ware Pt = 5 ppm, Au = 7.5 ppm, Pd = 5 ppm, and Rh = 1 ppm. Kinetic studies revealed that 24 h is adequate to achieve apparent equilibrium in solutions with pH 2 and 1 M nitrate ion content. The study identified significant recovery losses for gold and platinum in nitrate solutions, underlining the necessity of nitrate-free solutions in recycling. Zinc and magnesium were effective in cementing Pd and Rh, while aluminum was efficient for Pt reduction in each condition. Complete removal of Au was not achieved with any tested metal, indicating a need for alternative methods.
本研究探讨了硝酸根离子对在 30 °C 温度下从稀释废液中固结贵金属效率的影响。研究包括利用光谱分析评估金属离子浓度在固结过程前后的变化,从而测量不同固结金属(如锌、铝、镁和铁)在硝酸根离子存在下的有效性。贵金属的初始浓度为 Pt = 5 ppm、Au = 7.5 ppm、Pd = 5 ppm 和 Rh = 1 ppm。动力学研究表明,在 pH 值为 2、硝酸根离子含量为 1 M 的溶液中,24 小时足以达到表面平衡。研究发现,在硝酸盐溶液中,金和铂的回收损失很大,这说明在回收过程中必须使用不含硝酸盐的溶液。锌和镁能有效固化钯和铑,而铝在各种条件下都能有效还原铂。任何测试金属都无法完全去除金,这表明需要采用替代方法。
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引用次数: 0
Effect of the Addition of Cu and Al on the Microstructure, Phase Composition and Properties of a Ti-6Al-4V Alloy Obtained by Selective Laser Melting 添加铜和铝对通过选择性激光熔化获得的 Ti-6Al-4V 合金的微观结构、相组成和性能的影响
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.3390/met14090991
Galina M. Zeer, Yuri I. Gordeev, Elena G. Zelenkova, Artur K. Abkaryan, Evgeny V. Gerasimov, Mikhail Yu. Kuchinskii, Sergey M. Zharkov
The present study considers the samples of an Ti-6Al-4V alloy obtained by selective laser melting with the addition of a 10% Cu-Al powder mixture. The microstructure, elemental composition and phase composition, as well as the physico-chemical properties, have been investigated by the methods of electron microscopy, X-ray phase analysis, and bending testing. The obtained samples have a relative density of 98.5 ± 0.1%. The addition of the Cu-Al powder mixture facilitates supercooling during crystallization and solidification, which allows decreasing the size and changing the shape of the initial β-Ti grains. The constant cooling rate of the alloy typical for the SLM technology has been shown to be able to prevent martensitic transformation. The formation of a structure that consists of β-Ti grains, a dispersed eutectoid mixture of α-Ti and Ti2Cu grains, and a solid solution of Al in Cu has been revealed. In the case of doping by the 10% Cu-Al mixture, the physico-mechanical properties are improved. The hardness of the samples amounts to 390 HRC, with the bending strength being 1550 ± 20 MPa and deformation of 3.5 ± 0.2%. The developed alloy can be recommended for applications in the production of parts of jet and car engines, implants for medicine, and corrosion-resistant parts for the chemical industry.
本研究考虑的是通过选择性激光熔化获得的 Ti-6Al-4V 合金样品,其中添加了 10% 的铜铝混合粉末。通过电子显微镜、X 射线相分析和弯曲测试等方法,对其微观结构、元素组成、相组成以及物理化学特性进行了研究。所得样品的相对密度为 98.5 ± 0.1%。铜铝粉末混合物的加入促进了结晶和凝固过程中的过冷,从而减小了初始 β-Ti 晶粒的尺寸并改变了其形状。事实证明,SLM 技术典型的合金恒定冷却速度能够防止马氏体转变。结果表明,合金结构由 β-Ti 晶粒、α-Ti 和 Ti2Cu 晶粒的分散共晶混合物以及铝在铜中的固溶体组成。在掺入 10% Cu-Al 混合物的情况下,物理机械性能得到了改善。样品的硬度达到 390 HRC,弯曲强度为 1550 ± 20 MPa,变形量为 3.5 ± 0.2%。所开发的合金可推荐用于生产喷气式飞机和汽车发动机部件、医药植入物以及化学工业中的耐腐蚀部件。
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引用次数: 0
The Interplay between Nucleation and the Rates of Chemical Reduction in the Synthesis of Bimetallic Nanoparticles in Microemulsions: A Computer Study 微乳液中双金属纳米粒子合成过程中成核与化学还原速率之间的相互作用:计算机研究
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090987
Concha Tojo
Monte Carlo simulations were conducted to investigate the interaction between nucleation and the rates of chemical reduction in Au/Ag, Au/Pt and Au/Pd nanoparticles prepared in microemulsions using a one-pot method. The impact of nucleation on final nanostructure depends on the critical nucleus size value: at a high critical nucleus size, nucleation becomes the main factor in determining the final nanostructure, even with a very large difference in reduction rates, as seen in the Au/Pd pair. However, when the critical nucleus size is small, the difference in reduction rates of the two metals becomes the key parameter determining the final nanostructure. Furthermore, the relevance of heteroatomic nucleation on the mechanism of nanoparticle formation depends on the difference between the reduction rates of the two metals. Smaller differences, such as in the Au/Ag or Au/Pt pairs, result in a greater impact of heteroatomic nucleation on the final nanostructure. In contrast, in the Au/Pd pair, heteroatomic nucleation becomes less important due to the low availability of Pd until late stages of synthesis. This study provides deeper insight into the complex mechanisms that govern reactions in microemulsions.
蒙特卡洛模拟研究了采用一锅法在微乳液中制备金/银、金/铂和金/钯纳米粒子时,成核与化学还原率之间的相互作用。成核对最终纳米结构的影响取决于临界晶核尺寸值:在临界晶核尺寸较高时,成核成为决定最终纳米结构的主要因素,即使还原率相差很大,如金/钯对。然而,当临界核尺寸较小时,两种金属的还原率差异就成为决定最终纳米结构的关键参数。此外,异原子成核与纳米粒子形成机制的相关性取决于两种金属还原速率的差异。差异越小,如金/银或金/铂对,异原子成核对最终纳米结构的影响越大。相比之下,在金/钯对中,由于直到合成后期钯的供应量较低,异原子成核变得不那么重要。这项研究让我们更深入地了解了微乳液中反应的复杂机理。
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引用次数: 0
The Effect of Multiple Solder Reflows on the Formation of Cu6Sn5 Intermetallics and the Decomposition of SnAg3.0Cu0.5 Solder Joints in the Framework of Rework and Reuse of MLCC Components 在返修和重复使用 MLCC 组件的框架内,多次焊料回流对 Cu6Sn5 金属间化合物形成和 SnAg3.0Cu0.5 焊点分解的影响
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090986
Erik Wiss, Steffen Wiese
A rework of electronic assemblies and the reuse of electronic components are the most effective ways to reduce electronic waste. Since neither components nor substrates were developed with the intention of multiple usage, the question of how the integrity of lead-free solder joints is affected by multiple reflow operations is crucial for the implementation of any reuse strategy. Therefore, various types of 1206 multilayer ceramic capacitors (MLCCs) differing in their capacitance value and dielectric type (X5R, X7R, Y5V, NP0) were soldered on test printed circuit boards (PCBs) having a pure Cu-metallization surface in order to investigate the intermetallic reactions during multiple reflows. The metallization system on the MLCC-component side consisted of a thick film of Ni covered by galvanic-deposited Sn. The reflow experiments were conducted using a hypoeutectic SnAgCu solder. The results show the formation of a Cu6Sn5 intermetallic phase on both metallizations, which grows homogeneously with the number of reflows. Moreover, an ongoing decomposition of the solder into Ag-enriched and depleted zones was observed. The effect of these microstructural changes on the functionality of the solder joint was investigated by mechanical shear experiments and electrical four-point capacitance measurements.
电子组件的再加工和电子元件的再利用是减少电子废物的最有效方法。由于元件和基板的开发都没有考虑到多次使用,因此无铅焊点的完整性如何受到多次回流焊操作的影响,是实施任何再利用战略的关键。因此,在具有纯铜金属化表面的测试印刷电路板(PCB)上焊接了电容值和介质类型(X5R、X7R、Y5V、NP0)不同的各种类型 1206 多层陶瓷电容器(MLCC),以研究多次回流过程中的金属间反应。MLCC 元件一侧的金属化系统由电镀沉积锡覆盖的厚镍膜组成。回流实验使用的是次共晶锡银铜焊料。结果表明,在两个金属化面上都形成了 Cu6Sn5 金属间相,该金属间相随着回流次数的增加而均匀增长。此外,还观察到焊料不断分解成富集析银区和贫化析银区。通过机械剪切实验和四点电容测量,研究了这些微观结构变化对焊点功能的影响。
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引用次数: 0
Fatigue Response of Additive-Manufactured 316L Stainless Steel 添加剂制造的 316L 不锈钢的疲劳响应
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090988
Melody Chepkoech, Peter Omoniyi, Gbadebo Owolabi
This study investigated the fatigue performance of 316L stainless steel fabricated via laser powder bed fusion (LPBF). Stress-controlled fatigue tests were performed at different stress amplitudes on vertically built samples using a frequency of 15 Hz and a stress ratio of 0.1. The stress amplitudes were varied to provide the cyclic response of the materials under a range of loading conditions. The average fatigue strength was determined to be 92.94 MPa, corresponding to a maximum stress of 185.87 MPa. The microstructures were observed through scanning electron microscopy (SEM) with the aid of electron backscattered diffraction (EBSD), and the average grain size of the as-built samples was determined to be 15.6 µm, with most grains having a <110> preferred crystallographic orientation. A higher kernel average misorientation value was measured on the deformed surfaces, revealing the increased misorientation of the grains. Defects were observed on the fractured surfaces acting as crack initiators while deflecting the crack propagation paths. The fatigue failure mode for the LPBF 316L samples was ductile, as illustrated by the numerous dimples on fracture surfaces and fatigue striations.
本研究调查了通过激光粉末熔床(LPBF)制造的 316L 不锈钢的疲劳性能。在频率为 15 Hz、应力比为 0.1 的条件下,对垂直制造的样品进行了不同应力振幅的应力控制疲劳试验。应力振幅的变化提供了材料在一系列加载条件下的循环响应。平均疲劳强度为 92.94 兆帕,对应的最大应力为 185.87 兆帕。通过扫描电子显微镜(SEM)和电子反向散射衍射(EBSD)对微观结构进行了观察,确定雏形样品的平均晶粒大小为 15.6 微米,大多数晶粒具有优先结晶取向。在变形表面测得的内核平均错向值较高,表明晶粒的错向增加。在断裂表面观察到的缺陷既是裂纹的起始点,又偏转了裂纹的传播路径。LPBF 316L 样品的疲劳失效模式是韧性的,断裂表面的大量凹痕和疲劳条纹说明了这一点。
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引用次数: 0
Structural Relaxation and Delayed Yielding in Cyclically Sheared Cu-Zr Metallic Glasses 循环剪切 Cu-Zr 金属玻璃中的结构松弛和延迟屈服
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090984
Nikolai V. Priezjev
The yielding transition, structural relaxation, and mechanical properties of metallic glasses subjected to repeated loading are examined using molecular dynamics simulations. We consider a poorly annealed Cu-Zr amorphous alloy periodically deformed in a wide range of strain amplitudes at room temperature. It is found that low-amplitude cyclic loading leads to a logarithmic decay of the potential energy, and lower energy states are attained when the strain amplitude approaches a critical point from below. Moreover, the potential energy after several thousand loading cycles is a linear function of the peak value of the stress overshoot during startup continuous shear deformation of the annealed sample. We show that the process of structural relaxation involves collective, irreversible rearrangements of groups of atoms whose spatial extent is most pronounced at the initial stage of loading and at higher strain amplitudes. At the critical amplitude, the glass becomes mechanically annealed for a number of transient cycles and then yields via the formation of a shear band. The yielding transition is clearly marked by abrupt changes in the potential energy, storage modulus, and fraction of atoms with large nonaffine displacements.
我们利用分子动力学模拟研究了金属玻璃在重复加载条件下的屈服转变、结构松弛和机械性能。我们考虑了一种退火较差的 Cu-Zr 非晶合金,它在室温下以很宽的应变振幅周期性地变形。研究发现,低振幅周期性加载会导致势能的对数衰减,当应变振幅从下往上接近临界点时,势能会达到较低的能量状态。此外,退火样品在启动连续剪切变形过程中,数千次加载循环后的势能是应力过冲峰值的线性函数。我们的研究表明,结构松弛过程涉及原子团的集体不可逆重排,其空间范围在加载初始阶段和较高应变振幅时最为明显。在临界振幅下,玻璃会在若干瞬态周期内发生机械退火,然后通过形成剪切带而屈服。屈服转变的明显特征是势能、存储模量和具有较大非石蜡位移的原子比例的突然变化。
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引用次数: 0
Microstructure Control for Enhancing the Combination of Strength and Elongation in Ti-6Al-4V through Heat Treatment 通过热处理控制微结构以提高 Ti-6Al-4V 的强度和伸长率组合
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090985
Seongji Seo, Minsu Jung, Jiyong Park
For the application of Ti-6Al-4V alloys in urban air mobility, safety is very important, so achieving excellent strength and toughness is essential to prevent fractures. Regarding toughness, which is a combination of strength and ductility, it is necessary to derive the optimal heat treatment conditions for this combination of Ti-6Al-4V alloy and further understand its microstructure and fracture characteristics. For this purpose, this study investigated the microstructure in terms of grain size, plate thickness, and element distribution, as well as mechanical properties, including phase hardness and tensile properties, of Ti-6Al-4V alloy subjected to solution treatment and aging (STA) heat treatment under various aging conditions. As a result, this study suggests that solution treatment followed by aging at 630 °C for 480 min can achieve approximately 26% higher toughness than the just-solution treatment process. This is because there is little difference in hardness between the equiaxed α and basketweave structures, and β plates, which contain an excessive V between α plates, function like fibers and delay fracture.
对于 Ti-6Al-4V 合金在城市空中交通中的应用而言,安全性非常重要,因此获得优异的强度和韧性对于防止断裂至关重要。韧性是强度和延展性的结合,因此有必要为 Ti-6Al-4V 合金的这一组合推导出最佳热处理条件,并进一步了解其微观结构和断裂特性。为此,本研究调查了在不同时效条件下进行固溶处理和时效(STA)热处理的 Ti-6Al-4V 合金在晶粒尺寸、板厚和元素分布方面的微观结构,以及包括相硬度和拉伸性能在内的机械性能。研究结果表明,固溶处理后在 630 °C 下时效 480 分钟比单纯的固溶处理工艺可提高约 26% 的韧性。这是因为等轴α结构和篮织结构之间的硬度差别不大,而且α板之间含有过量V的β板具有类似纤维的功能,可延迟断裂。
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引用次数: 0
Behaviour of Dissimilar Welded Connections of Mild Carbon (S235), Stainless (1.4404), and High-Strength (S690) Steels under Monotonic and Cyclic Loading 低碳钢 (S235)、不锈钢 (1.4404) 和高强度钢 (S690) 的异种焊接连接在单调和循环载荷下的行为
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090989
Anna Ene, Aurel Stratan, Ioan Both
In the context of an increasing interest in the use of high-performance steels in the construction industry due to their superior mechanical properties, understanding the behaviour and assessing the performance of dissimilar welded connections becomes essential. When several steel grades are adopted for fabrication of the same dissipative element, dissimilar welded connections have a decisive importance regarding the seismic performance of the structural member. This paper presents the experimental results of monotonic and low-cycle fatigue (LCF) tests on dissimilar welded connections. The welded connections are designed to reproduce the loading state that occurs between the web and the flanges of dissipative links in an eccentrically braced frame, and represent combinations of S235 mild carbon steel, 1.4404 austenitic stainless steel, and S690 high-strength steel. The obtained experimental results provide a better understanding of the behaviour of dissimilar welded connections through the evaluation of their strength, ductility, and failure mechanisms, providing a basis for finite element (FE) models’ calibration for further numerical simulations. This study contributes to the evaluation of the feasibility of connections between dissimilar steels in seismic-resistant steel structures.
由于高性能钢材具有优异的机械性能,建筑行业对其使用的兴趣与日俱增,在此背景下,了解异种焊接连接的行为和评估其性能变得至关重要。当采用多种钢材制造同一消能构件时,异种焊接连接对于结构构件的抗震性能具有决定性的重要意义。本文介绍了异种焊接连接的单调和低循环疲劳(LCF)试验结果。焊接连接的设计再现了偏心支撑框架中耗散连接的腹板和翼缘板之间的加载状态,代表了 S235 低碳钢、1.4404 奥氏体不锈钢和 S690 高强度钢的组合。所获得的实验结果通过评估异种焊接连接的强度、延展性和失效机制,使人们更好地了解了其行为,为进一步的数值模拟提供了校准有限元(FE)模型的基础。这项研究有助于评估抗震钢结构中不同钢材之间连接的可行性。
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引用次数: 0
Potentials of Additive Manufacturing for Cutting Tools: A Review of Scientific and Industrial Applications 切削工具增材制造的潜力:科学与工业应用综述
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090982
Tobias Kelliger, Markus Meurer, Thomas Bergs
Additive manufacturing (AM) techniques enable new design concepts for performance improvements and functional integration in a wide range of industries. One promising application is in additively manufactured cutting tools for machining, improving process reliability on the one hand and increasing tool life and process productivity on the other hand. Compared to conventional manufacturing processes, AM allows for new and complex geometrical designs, enables the production of individualized parts, and offers new possibilities for alloy composition and material design. This work gives a comprehensive and systematic review of scientific as well as industrial activities, studies, and solutions regarding AM cutting tools and their fields of application. Four different areas are identified, including cooling and coolant supply, damping and vibrational behavior, lightweight design and topology optimization, and functional integration. Thus, the relevant and promising approaches for the industrialization of AM cutting tools are highlighted, and a perspective is given on where further scientific knowledge is needed.
快速成型制造(AM)技术为各行各业的性能改进和功能集成提供了新的设计理念。其中一个前景广阔的应用领域是用于机械加工的增材制造切削工具,一方面可提高加工可靠性,另一方面可延长工具寿命并提高加工生产率。与传统制造工艺相比,快速成型技术可以实现新的复杂几何设计,生产个性化零件,并为合金成分和材料设计提供新的可能性。本著作全面系统地回顾了有关 AM 切削工具及其应用领域的科学和工业活动、研究和解决方案。其中确定了四个不同的领域,包括冷却和冷却剂供应、阻尼和振动行为、轻量化设计和拓扑优化以及功能集成。因此,重点介绍了实现 AM 切削工具工业化的相关和有前景的方法,并对需要进一步科学知识的领域进行了展望。
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引用次数: 0
The Effect of the Forming Mode on Twinning and Springback in the Bending-Dominated Forming of Magnesium AZ31 Sheet 镁 AZ31 板材弯曲成形中成形模式对孪晶和回弹的影响
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.3390/met14090983
Matthias Weiss, Shiromani Gangoda Desinghe, Peter Hodgson, Hossein Beladi
The sheet metal forming of magnesium is challenging due to the material’s complex springback behaviour, which is due to the tension/compression yield mismatch. In this study, three different AZ31 grain sizes are produced by a special heat treatment, while maintaining the material strength in uniaxial tension at a similar level. Pure, V-die and channel bending tests are combined with roll forming to compare bending scenarios with and without tension applied transverse and parallel to the bending axis. This is complemented with electron backscatter diffraction to measure the twinning type and twinning area fraction (TAF) in the tension and compression bending zones. Our study shows that, like conventional steel, when bending magnesium, springback reduces with the increasing level of the outer fibre bending strain, i.e., when the bend radius is decreased and the TAF increased. It is further shown that when tension is applied, the TAF increases. However, while in some forming cases, the increase in TAF leads to a clear reduction in springback, in other forming cases the effect of the TAF on springback is less pronounced. Overall, this study provides clear evidence that the twinning behaviour in bending magnesium is influenced by the bend deformation mode and that this influences the springback behaviour.
由于镁材料具有复杂的回弹特性,拉伸/压缩屈服不匹配导致了镁板材成型的挑战性。在这项研究中,通过特殊热处理产生了三种不同的 AZ31 晶粒大小,同时将材料的单轴拉伸强度保持在相似水平。纯弯曲试验、V 形模具弯曲试验和槽形弯曲试验与滚压成形相结合,对弯曲轴横向和平行施加拉力和不施加拉力时的弯曲情况进行比较。此外,还辅以电子反向散射衍射法测量拉伸和压缩弯曲区域的孪生类型和孪生面积分数(TAF)。我们的研究表明,与传统钢材一样,当弯曲镁合金时,回弹会随着外层纤维弯曲应力的增加而减少,即当弯曲半径减小、TAF 增加时。进一步表明,当施加拉力时,TAF 会增加。然而,在某些成形情况下,TAF 的增加会导致回弹明显减少,但在其他成形情况下,TAF 对回弹的影响并不明显。总之,这项研究提供了明确的证据,证明镁弯曲时的孪生行为受弯曲变形模式的影响,而这又影响回弹行为。
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引用次数: 0
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