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Rare earth mineralogy in tailings from Kiirunavaara iron ore, northern Sweden: Implications for mineral processing 瑞典北部Kiirunavaara铁矿尾矿中的稀土矿物学:对矿物加工的影响
Q2 Materials Science Pub Date : 2017-11-01 DOI: 10.19150/MMP.7859
C. Wanhainen, Bertil I. Pålsson, O. Martinsson, Y. Lahaye
Four main and three minor rare-earth-element (REE)-bearing minerals were identified and quantified in the Kiirunavaara apatite iron ore tailings using optical microscopy, an electron probe microanalyzer (EPMA) and a mineral liberation analyzer, and their chemical compositions were analyzed by the EPMA and laser ablation inductively coupled plasma-mass spectrometry. REEs are shown to be contained in the minerals apatite, monazite, allanite, titanite, zircon, thorite and synchysite. In zircon, thorite and synchysite, they occurred in only trace amounts and contributed limited amounts to the total REE budget, and these are consequently of minor importance. Monazite occurred as inclusions in apatite and as free particles, 90 percent liberated. Allanite occurred to some degree in mixed grains with magnetite but also as free particles. Monazite mainly reported to the apatite concentrate, while allanite and titanite largely went to the tailings, the latter preferably to those fractions smaller than 38 µm. The amount of titanite in the finest tailings fraction was 2.3 weight percent, containing close to 1 percent REEs, with heavy rare earth elements (HREEs) making up 28 percent of the total REEs. However, a texturally distinct group of titanite grains showed an HREE/REE ratio of up to 67 percent. Furthermore, titanum dioxide analyses indicate that titanite is preferentially released into the tailings from the secondary magnetic separation step in the concentrator. Our data therefore suggest that titanite, occasionally enriched in HREEs, can be extracted from the processing stream and might thus be considered a new source for REEs at Kiirunavaara and similar deposits.
采用光学显微镜、电子探针微量分析仪(EPMA)和矿物解离分析仪对Kiirunavaara磷灰石铁矿尾矿中的4种主要矿物和3种次要矿物进行了鉴定和定量,并采用电子探针微量分析仪和激光烧蚀电感耦合等离子体质谱分析了它们的化学成分。稀土元素主要存在于磷灰石、独居石、allanite、钛矿、锆石、钍矿和合晶石中。在锆石、钍矿和合石中,它们仅以微量存在,对总稀土收支的贡献有限,因此它们的重要性较小。独居石以磷灰石包裹体和自由颗粒的形式出现,90%是游离的。Allanite在一定程度上以与磁铁矿混合颗粒的形式存在,但也以自由颗粒的形式存在。独居石主要进入磷灰石精矿,褐褐石和钛矿主要进入尾矿,后者优先进入小于38µm的组分。细粒尾矿中钛矿的含量为2.3%,稀土含量接近1%,重稀土元素(hree)占总稀土元素的28%。然而,一组结构独特的钛矿颗粒显示出高达67%的HREE/REE比率。此外,二氧化钛分析表明,在选矿厂的二次磁选步骤中,钛矿优先释放到尾矿中。因此,我们的数据表明,钛矿偶尔富含稀土元素,可以从加工流中提取出来,因此可能被认为是Kiirunavaara和类似矿床稀土元素的新来源。
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引用次数: 2
Recovering rare earths from waste phosphors using froth flotation and selective flocculation 泡沫浮选和选择性絮凝从废磷中回收稀土
Q2 Materials Science Pub Date : 2017-11-01 DOI: 10.19150/MMP.7855
M. Yu, G. Mei, Y. Li, D. Liu, Y. Peng
This study explores froth flotation and selective flocculation methods to recycle waste phosphors containing several rare earth elements, namely, yttrium (Y), europium (Eu), cerium (Ce) and terbium (Tb). The effects of the presence or absence of collector and of flocculant and their dosages, as well as the pH, were investigated. Reverse flotation resulted in concentrates with grade of 27.03 percent and recovery rate of 71.36 percent, while flocculation resulted in concentrates with grade of 31.43 percent and recovery rate of 91.28 percent. The flotation and flocculation behaviors were further analyzed by X-ray diffraction analysis, zeta potential measurements, particle size distribution and other methods. The successful separation of rare earth minerals by flotation was attributed to the selective adsorption of the collector onto quartz, making it particularly recoverable by reverse flotation so as to be separated from the valuable materials. The analysis of the particle aggregation process indicated that its better flocculation performance was due to the selective adsorption of flocculants onto the unwanted materials, enlarging the flocculant sizes by forming aggregations and facilitating the separation of rare earth minerals from waste materials based on different settling rates.
本研究探讨了泡沫浮选和选择性絮凝法回收含钇(Y)、铕(Eu)、铈(Ce)和铽(Tb)等几种稀土元素的废荧光粉。考察了捕收剂和絮凝剂的存在或不存在、投加量以及pH值的影响。反浮选精矿品位为27.03%,回收率为71.36%,絮凝精矿品位为31.43%,回收率为91.28%。通过x射线衍射分析、zeta电位测量、粒度分布等方法分析了浮选絮凝行为。捕收剂对石英的选择性吸附,使其在反浮选过程中具有特别的可回收性,从而与有价物分离。颗粒聚集过程分析表明,絮凝剂较好的絮凝性能是由于絮凝剂选择性吸附在不需要的物料上,通过形成团聚体增大絮凝剂的粒径,并根据不同的沉降速率促进稀土矿物从废料中分离。
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引用次数: 10
Exploring blast furnace slag as a secondary resource for extraction of rare earth elements 探索高炉矿渣作为稀土元素提取的二次资源
Q2 Materials Science Pub Date : 2017-11-01 DOI: 10.19150/MMP.7857
Abhilash, P. Meshram, S. Sarkar, T. Venugopalan
To explore blast furnace slag as a secondary resource for rare earth elements (REEs), blast furnace slag containing lanthanum (La), cerium (Ce), erbium (Er) and neodymium (Nd) in concentrations of 17, 16, 4 and 44 ppm, respectively, was processed with sulfuric acid while optimizing the parameters of acid concentration, temperature and pulp density. The experiments showed that recovery rates of 92, 36, 35 and 52 percent for La, Ce, Nd and Er, respectively, were achieved at 1 to 5 weight/volume (w/v) percent pulp density using particles smaller than 250 µm and treating with 1 M sulfuric acid for one hour at room temperature. Raising the temperature to 95 °C promoted the dissolutions of Ce and Nd to 89 and 84 percent, respectively, for the same 1 M acid concentration and one-hour duration at 5 w/v percent pulp density. Cyanex 923 was preferred over Cyanex 301 for the purification of REEs from leach liquor. In another route, the leach liquor was subjected to precipitation with 0.5 to 1 M oxalic acid, resulting in a product with 4 to 5 percent concentration of REEs.
为了探索高炉矿渣作为稀土元素的二次资源,在优化酸浓度、温度和矿浆密度参数的同时,用硫酸处理了浓度分别为17、16、4和44ppm的镧(La)、铈(Ce)、铒(Er)和钕(Nd)高炉矿渣。实验表明,La、Ce、Nd和Er的回收率分别为92%、36%、35%和52%,使用小于250µm的颗粒,在1至5重量/体积(w/v)%的纸浆密度下,并在室温下用1M硫酸处理1小时。在相同的1M酸浓度和5 w/v%纸浆密度下1小时的持续时间下,将温度提高到95°C可分别将Ce和Nd的溶解率提高到89%和84%。在从浸出液中纯化稀土元素方面,优选Cyanex 923而不是Cyanex 301。在另一种途径中,用0.5至1M草酸对浸出液进行沉淀,得到REE浓度为4%至5%的产物。
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引用次数: 15
Rare earths recovery and gypsum upgrade from Florida phosphogypsum 从佛罗里达磷石膏中回收稀土和提升石膏
Q2 Materials Science Pub Date : 2017-11-01 DOI: 10.19150/MMP.7860
H. Liang, P. Zhang, Z. Jin, D. DePaoli
Phosphogypsum is a byproduct created during the production of industrial wet-process phosphoric acid. This study focused on recovering rare earth elements (REEs) from a Florida phosphogypsum sample and investigated the effects of removing detrimental impurities such as phosphorus pentoxide (P2O5), uranium (U) and fluorine (F) during the leaching process. Experimental results indicated that REE leaching efficiency increased rapidly, reached a maximum and then began to decrease with sulfuric acid concentrations ranging from 0 to 10 percent and temperatures ranging from 20 to 70 °C. At a sulfuric acid concentration of 5 percent and leaching temperature of 50 °C, REE leaching efficiency obtained a maximum value of approximately 43 percent. Increasing the leaching time or liquid/solid ratio increased the leaching efficiency. The leaching efficiencies of P2O5, U and F consistently increased with sulfuric acid concentration, temperature, leaching time and liquid/solid ratio within the testing ranges. A fine-grain gypsum concentrate, sized smaller than 40 µm, was separated from leached phosphogypsum through elutriation, in which the P2O5, U and F content levels were reduced by 99, 70 and 83 percent, respectively, from their content levels in fresh phosphogypsum.
磷石膏是工业湿法磷酸生产过程中产生的副产品。本研究的重点是从佛罗里达磷石膏样品中回收稀土元素,并研究了在浸出过程中去除有害杂质如五氧化二磷(P2O5)、铀(U)和氟(F)的效果。实验结果表明,在0~10%的硫酸浓度和20~70°C的温度范围内,稀土元素浸出效率迅速提高,达到最大值后开始下降。在5%的硫酸浓度和50°C的浸出温度下,REE的浸出效率最高约为43%。增加浸出时间或液固比可提高浸出效率。在试验范围内,P2O5、U和F的浸出效率随着硫酸浓度、温度、浸出时间和液固比的增加而不断提高。通过淘析从浸出的磷石膏中分离出尺寸小于40µm的细粒石膏精矿,其中P2O5、U和F的含量水平分别比新鲜磷石膏中的含量水平降低了99%、70%和83%。
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引用次数: 32
Chemical extraction of rare earth elements from coal ash 煤灰中稀土元素的化学萃取
Q2 Materials Science Pub Date : 2017-11-01 DOI: 10.19150/MMP.7856
M. Peiravi, Louis Ackah, R. Guru, M. Mohanty, Jia Liu, B. Xu, X. Zhu, L. Chen
The overall goal of this study is to develop a suitable flow sheet to extract rare earth elements (REEs) from coal ash. A total of 14 coal samples of different ranks were examined for REE concentration, and an anthracite coal sample with the highest REE concentration of more than 700 ppm in the coal ash was selected for REE extraction tests. This paper reports on the results of the experimental program completed in the first part of the study, which included high-temperature leaching with nitric acid followed by solvent extraction tests using various organic extractants, namely, tributyl phosphate, Cyanex 572, di-(2-ethylhexyl)phosphoric acid (D2EHPA) and their combinations. A 4×2×2 experimental design was used to conduct a total of 32 high-temperature leaching tests by varying acid molarity at four levels, solids content at two levels and leaching time at two levels. The highest recovery rates of 90 percent for light rare earth elements (LREEs) and 94 percent for heavy rare earth elements (HREEs) were obtained from the optimum leaching test conditions while maintaining impurity recovery to the leachate at less than 40 percent. D2EHPA was found to be the best extractant in this solvent extraction test series, providing an REE recovery rate of nearly 99 percent.
本研究的总体目标是开发一种从煤灰中提取稀土元素的合适流程图。共检测了14个不同等级的煤样品的REE浓度,并选择了煤灰中REE最高浓度超过700ppm的无烟煤样品进行REE提取试验。本文报告了研究第一部分完成的实验程序的结果,其中包括用硝酸进行高温浸出,然后使用各种有机萃取剂进行溶剂萃取试验,即磷酸三丁酯、Cyanex 572、二-(2-乙基己基)磷酸(D2EHPA)及其组合。采用4×2×2实验设计,通过改变四个水平的酸摩尔浓度、两个水平的固体含量和两个水平下的浸出时间,共进行了32次高温浸出试验。在最佳浸出试验条件下,轻稀土元素(LREEs)和重稀土元素(HREEs)的最高回收率分别为90%和94%,同时将浸出液中的杂质回收率保持在40%以下。D2EHPA被发现是该溶剂萃取测试系列中最好的萃取剂,提供了近99%的REE回收率。
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引用次数: 48
Characterizing rare earth elements in Alaskan coal and ash 阿拉斯加煤和灰中稀土元素的特征
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7614
T. Gupta, T. Ghosh, G. Akdogan, V. Srivastava
In recent years, the demand for rare earth elements (REEs) has grown due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources, with coal and coal byproducts as possibilities. Coals from certain parts of the world can be rich in REEs and can approach a total concentration of 1,000 ppm. Two Alaskan coal samples, from Healy and Wishbone Hill, were investigated for the effects of density and particle size on REE concentrations for three selected size fractions, and flotation tests were conducted on finer fractions. Additionally, bottom ash and fly ash samples from a power plant were examined for their REE concentrations. The results show that the upgrade potential for REEs on an ash basis from a whole-coal basis ranges from 2:1 for the Wishbone Hill samples to 4:1 for the Healy coal samples. Flotations of the finer fractions of the two coal samples, conducted under similar conditions, revealed higher concentrations of REEs in the tailings. Both coal samples had comparatively higher contents of light-group rare earth elements (LREEs) than heavy-group rare earth elements (HREEs). REE content trends for the power-plant products on an ash basis indicate that fly ash has slightly higher concentrations of both LREEs and HREEs than bottom ash.
近年来,由于需求增加和全球供应短缺,对稀土元素的需求不断增长。这些关键元素的供应短缺促使人们寻找新的来源,煤炭和煤炭副产品是可能的来源。来自世界某些地区的煤可能富含稀土元素,总浓度可接近1000ppm。对来自Healy和Wishbone Hill的两种阿拉斯加煤样品进行了密度和粒度对三种选定粒度组分稀土浓度的影响研究,并对较细粒度组分进行了浮选试验。此外,还检测了电厂底灰和飞灰样品的稀土元素浓度。结果表明,稀土元素在灰分基础上的升级潜力从Wishbone Hill样品的2:1到Healy煤样品的4:1不等。在相似的条件下,对两种煤样品的较细组分进行浮选,发现尾矿中稀土的浓度较高。两种煤样中轻族稀土元素(lree)含量均高于重族稀土元素(hree)。电厂产品在灰分基础上的REE含量趋势表明,飞灰的lree和hree浓度略高于底灰。
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引用次数: 13
Rare-earth leaching from Florida phosphate rock in wet-process phosphoric acid production 湿法磷酸生产中佛罗里达磷矿的稀土浸出
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7615
H. Liang, P. Zhang, Z. Jin, D. DePaoli
Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO43-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO42-), dihydrogen phosphate (H2 PO4-) and hydrogen phosphate (HPO42-) anions as well as the polar molecule H3 PO4, which surrounded the REE cations and formed an ion atmosphere that prevented the PO43- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue.
磷矿是最重要的二次稀土资源。它含有大量的含磷酸盐矿物以及低含量的稀土元素(REEs)。在佛罗里达州,每年开采约1900万吨磷矿,其中大部分用于湿法生产肥料,其中硫酸与磷酸盐反应产生磷酸和磷石膏。在湿法过程中,稀土元素也被浸出到溶液中,最终消失在浸出渣和磷肥中。采用湿法从佛罗里达磷矿中回收稀土,有利于拓宽稀土供应,提高磷酸产品质量,保护环境。研究了湿法操作条件对稀土浸出效率的影响。结果表明:初始矿浆中加入磷酸,稀土浸出效率提高;在温度为75℃、硫酸(H2 SO4)与氧化钙(CaO)的化学计量比为1.05、液固质量比为3.5的条件下,稀土浸出效率达到52.82%的较高值。稀土元素浸出效率的变化趋势与磷酸(P2O5)相似。对浸出渣的大量测试表明,在浸出过程中,约90%的稀土元素从磷矿中释放出来,但只有52.82%的稀土元素最终进入浸出液。这种现象可以归结为两个因素:(1)溶液中磷酸离子(PO43-)的作用,使REE离子形成REE磷酸盐沉淀到浸出渣中;(2)硫酸盐(SO42-)、磷酸二氢(H2 PO4-)、磷酸氢(HPO42-)等大量阴离子以及极性分子H3 PO4的影响,将REE阳离子包围,形成离子气氛,阻止PO43-与REE阳离子接触结合。这两种相反作用的相互作用决定了浸出液和渣中稀土元素的分布。
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引用次数: 23
The influence of starch in amine adsorption by quartz in the reverse flotation of iron ore 铁矿反浮选中淀粉对石英吸附胺的影响
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7616
K. Shrimali, Jan D. Miller
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引用次数: 0
Copper recovery from waste printed circuit boards 从废弃印刷电路板中回收铜
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7619
N. Sánta, V. Salinas
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引用次数: 0
Performance analysis of CMC in high talc copper sulfide flotation systems CMC在高滑石硫化铜浮选系统中的性能分析
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7620
C. O’Connell, A. Noble
The performance of sulfide flotation systems can be considerably hindered by the presence of hydrophobic gangue minerals in the raw product. In certain conditions, the use of depressants can offer notable improvements to final product quality. Talc is one problematic gangue mineral that can reach concentrations exceeding 12 percent in some cases. When combined with low copper concentrations, the presence of high talc can have adverse effects on the flotation process.
硫化浮选系统的性能会受到原料产品中疏水性脉石矿物存在的极大阻碍。在某些条件下,使用抑制剂可以显著提高最终产品的质量。滑石是一种有问题的脉石矿物,在某些情况下浓度可以超过12%。当与低铜浓度结合时,高滑石的存在会对浮选过程产生不利影响。
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引用次数: 0
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Minerals & Metallurgical Processing
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