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Cyanidation tests and pretreatments to recover gold from a refractory ore in Colombia 从哥伦比亚难选矿石中回收黄金的氰化试验和预处理
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7621
C. Vanegas, F. Muñoz
Background The extraction and purification of precious metals from refractory ore, is extremely poor due to the ore sulfides and complex sulfides within the refractory ore. These sulfides contain concealed or microscopic gold, which inhibits the transformation of metallic gold in solution. The cyanidation of these minerals results in low gold recoveries, which in turn results in economic losses. Therefore, it is necessary to research optimal theoretical and practical alternatives. To increase recovery and reduce economic losses, pretreatments such as roasting pretreatments and pressure oxidation in autoclave were used to render the gold occluded in the sulfide minerals. The occluded gold will be amenable to extraction by cyanide leaching.
难选矿石中存在硫化物和复杂硫化物,这些硫化物中含有隐伏或微细的金,抑制了金属金在溶液中的转化,对难选矿石中贵金属的提取和纯化效果极差。这些矿物的氰化反应导致金回收率低,从而导致经济损失。因此,有必要研究最优的理论和实践方案。为了提高回收率,减少经济损失,采用焙烧预处理和高压釜压力氧化等预处理方法使金包裹在硫化矿物中。被遮挡的金可以用氰化浸出法提取。
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引用次数: 1
Process evaluation and flowsheet development for the recovery of rare earth elements from coal and associated byproducts 从煤及其副产品中回收稀土元素的工艺评价和流程制定
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7610
R. Honaker, J. Groppo, R. Yoon, G. Luttrell, A. Noble, J. Herbst
Coal and coal byproducts produced annually contain a sufficient amount of rare earth elements (REEs) to meet current U.S. demand. The REEs exist in the form of minerals, ion-adsorbed elements associated with clays, and chemically bonded elements within the organic coal matrix or host mineral. Researchers at three universities collaborated to evaluate the effectiveness of existing physical and chemical concentration processes for the recovery of the REEs. The efforts found that physical separation processes can increase the total REE content in the thickener underflow material collected from a Central Appalachian coal cleaning facility from around 300 ppm to values greater than 17,500 ppm on an ash basis. Leaching followed by solvent extraction was found to be the most effective to recover the REEs from coarse middlings materials collected from multiple coal basins, as indicated by recovery values exceeding 80 percent. Based on material characterization data and process evaluations conducted for several potential feed coal sources, economic recovery of the REEs will require byproduct production of both clean coal and REE concentrate using a process flowsheet that is unique for each source.
每年生产的煤和煤副产品含有足够数量的稀土元素(ree),可以满足美国目前的需求。稀土元素以矿物、与粘土结合的离子吸附元素和有机煤基质或寄主矿物中的化学结合元素的形式存在。三所大学的研究人员合作评估了回收稀土元素的现有物理和化学浓缩过程的有效性。研究发现,物理分离过程可以将从阿巴拉契亚中部煤炭净化设施收集的浓密机底流材料中的总REE含量从300 ppm左右增加到大于17500 ppm的灰分值。从多个煤盆地收集的粗中矿中,采用浸出+溶剂萃取的方法回收稀土的效果最好,回收率超过80%。根据对几种潜在原料煤来源进行的材料表征数据和工艺评估,稀土元素的经济回收将需要使用每种来源独特的工艺流程图生产洁净煤和稀土精矿的副产品。
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引用次数: 43
The effect of polysaccharides on bubble attachment at talc surfaces 多糖对滑石表面气泡附着的影响
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7617
V. Atluri, Jan D. Miller
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引用次数: 0
A novel approach to alkali pug bake for the extraction of rare earth elements from monazite concentrate 一种从独居石精矿中提取稀土元素的新方法
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7618
J. Galvin, M. Safarzadeh
Background Rare earth elements (REEs) play an important role in many technological advances in the modern world. With applications including hydrogen cars, computer hard drives and wind turbines, REEs are needed in numerous highly technical applications and will be needed more in the future. Monazite and bastnäsite are the two most essential sources of REEs. Bastnäsite is a fluorocarbonate mineral, but monazite is a phosphate mineral, making it much more difficult to decompose. Its stable structure can only be broken down under extreme extraction conditions. A common method to accomplish this has been through the use of sodium hydroxide at high temperatures and extended baking times. However, substituting potassium hydroxide for sodium hydroxide could potentially be a more economically favorable method. The sodium hydroxide method currently in practice produces sodium phosphate that can be sold as a fertilizer (Panda et al., 2014). However, the potassium hydroxide method would produce potassium phosphate, which would be a more effective and valuable fertilizer (Val’kov, et al., 2010).
背景稀土元素在现代世界的许多技术进步中发挥着重要作用。随着氢汽车、计算机硬盘驱动器和风力涡轮机等应用的发展,稀土元素在许多高技术应用中都是必需的,而且未来还会有更多的需求。独居石和巴斯坦矿是稀土元素最重要的两个来源。巴斯坦矿是一种氟碳酸盐矿物,但独居石是一种磷酸盐矿物,使其更难分解。其稳定的结构只有在极端的提取条件下才能被破坏。实现这一点的常用方法是在高温下使用氢氧化钠并延长烘焙时间。然而,用氢氧化钾代替氢氧化钠可能是一种经济上更有利的方法。目前实践中的氢氧化钠法生产的磷酸钠可以作为肥料出售(Panda等人,2014)。然而,氢氧化钾法会产生磷酸钾,这将是一种更有效、更有价值的肥料(Val’kov等人,2010)。
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引用次数: 0
Solvent extraction and separation of cerium(III) and samarium(III) from mixed rare earth solutions using PC88A 用PC88A从混合稀土溶液中萃取和分离铈(III)和钐(III)
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7612
V. Agarwal, M. Safarzadeh
The solvent extraction of cerium(III) and samarium(III) from mixed solutions of all rare earth elements (REEs) except promethium using PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), an acidic extractant, was investigated. The effects of aqueous equilibrium pH, various acids (sulfuric acid (H2 SO4), hydrochloric acid (HCl) and nitric acid (HNO3)), initial metal ion concentration and extractant concentration on the solvent extraction of Ce(III) and Sm(III) were systematically studied. From the experimental results, HNO3 and HCl were found to be the preflerred aqueous media for the solvent extraction of both Sm(III) and Ce(III). The most promising experimental conditions of pH, PC88A concentration and metal ion concentration were identified for the extraction of Ce(III) and Sm(III). Separation results showed that H2 SO4 at pH 2 provided the best separation between Sm(III) and Ce(III).
研究了用酸性萃取剂PC88A(2-乙基己基膦酸单-2-乙基己基酯)从除promthim外的所有稀土元素的混合溶液中萃取铈(III)和钐(III)的方法。系统地研究了水平衡pH、各种酸(硫酸(H2SO4)、盐酸(HCl)和硝酸(HNO3))、初始金属离子浓度和萃取剂浓度对溶剂萃取Ce(III)和Sm(Ⅲ)的影响。实验结果表明,HNO3和HCl是溶剂萃取Sm(III)和Ce(Ⅲ)的首选水性介质。确定了最有前景的pH、PC88A浓度和金属离子浓度的实验条件用于提取Ce(III)和Sm(III。分离结果表明,H2 SO4在pH为2时对Sm(III)和Ce(Ⅲ)的分离效果最好。
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引用次数: 17
Physical chemistry considerations in the selective flotation of bastnaesite with lauryl phosphate 十二烷基磷酸酯选择性浮选氟碳铈矿的物理化学考虑
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7611
Weiping Liu, Weiping Liu, Xuming Wang, H. Xu, Jan D. Miller
Bastnaesite is one of the important mineral resources for the production of rare earth materials, and it is typically associated with calcite and quartz as gangue minerals. Fatty acid or hydroxamic acid are recommended collectors for bastnaesite flotation. In this research, potassium lauryl phosphate was expected to provide a stronger flotation response for bastnaesite than for the calcite and quartz gangue minerals. Using potassium lauryl phosphate as collector, the results of captive bubble contact angle measurements, zeta potential determinations and microflotation experiments for bastnaesite, calcite and quartz are reported. Greater selectivity for bastnaesite was achieved using potassium lauryl phosphate than using octyl hydroxamate as collector. These results indicate that potassium lauryl phosphate might be a promising collector in the flotation of bastnaesite ores. The computation results of universal force feld (UFF) interaction energies for the mineral-reagent interactions are also reported and were found to correlate well with the experimental microflotation results.
氟碳铈矿是生产稀土材料的重要矿产资源之一,通常与方解石、石英伴生为脉石矿物。脂肪酸或羟肟酸是推荐的氟碳铈矿浮选捕收剂。在本研究中,与方解石和石英脉石矿物相比,磷酸月桂酰钾有望为氟碳铈矿提供更强的浮选响应。以十二烷基磷酸钾为捕收剂,对氟碳铈矿、方解石和石英进行了俘获泡接触角测定、zeta电位测定和微浮选实验。使用磷酸十二烷基钾比使用羟辛酯作为捕收剂对氟碳醚具有更高的选择性。这些结果表明,磷酸十二烷基钾可能是一种很有前途的氟碳铈矿浮选捕收剂。本文还报道了矿物-试剂相互作用的通用力场(UFF)相互作用能的计算结果,并发现其与微浮选实验结果具有良好的相关性。
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引用次数: 16
Concentration of rare earth minerals from coal by froth flotation 泡沫浮选法从煤中富集稀土矿物
Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.19150/MMP.7613
Wencai Zhang, R. Honaker, J. Groppo
Rare earth elements (REEs) found in coal are in the form of minerals, ion-adsorbed onto clay surfaces or inner layers, or organically bound. Rare earth minerals such as monazite exist in coal and have grain sizes smaller than 5 µm. In this study, froth flotation was successful in concentrating rare earth minerals existing in a thickener underflow material derived from Fire Clay seam coal that contained around 431 ppm of total rare earth elements (TREE) on a dry ash basis. Conditioning with fatty acid followed by processing using multiple stages of conventional flotation produced a final concentrate containing 2,300 ppm TREE. Using a laboratory flotation column to limit hydraulic entrainment, the TREE content was further enriched to around 4,700 ppm, which equated to an enrichment ratio of 10:1..
在煤中发现的稀土元素以矿物的形式存在,离子吸附在粘土表面或内层上,或有机结合。稀土矿物如独居石存在于煤中,颗粒尺寸小于5µm。在本研究中,泡沫浮选成功地富集了来自Fire Clay煤层煤的浓缩机底流材料中的稀土矿物,该材料在干灰基础上含有约431 ppm的总稀土元素(TREE)。用脂肪酸进行调理,然后采用常规浮选的多个阶段进行处理,最终精矿的TREE含量为2300 ppm。使用实验室浮选柱限制水力夹带,进一步将TREE含量富集到约4700 ppm,相当于10:1的富集比。
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引用次数: 34
Comparative analysis of the effect of microwave pretreatment on the milling and liberation characteristics of mineral matters of different morphologies 微波预处理对不同形态矿物研磨和释放特性影响的对比分析
Q2 Materials Science Pub Date : 2017-05-01 DOI: 10.19150/MMP.7506
V. Singh, R. Venugopal, S. K. Tripathy, V. K. Saxena
This study was carried out to understand the impact of variation in material morphology on the efficacy of microwave pretreatment. Three different types of mineral matter — coal, iron ore and manganese ore — were treated with microwaves at different energy levels, from 180 to 900 W, for different time durations of one to five minutes. The treated samples were subjected to microscopic, milling and liberation studies. Coal is a porous and amorphous material with low dielectric constant, and grinding of the microwave-pretreated coal samples resulted in an 18.18 percent reduction in the 80 percent of passing particle size, or d80, and a 17.1 percent increase in carbon recovery. The microwave-pretreated soft and friable manganese ore samples showed a 47.82 percent reduction in d80 during grinding and higher manganese recovery of 42.46 percent during liberation analysis. The microwave pretreatment and milling of hard and banded iron ore reduced the d80 by 20.83 percent, but no improvement was observed in mineral liberation. Coal showed better results during treatment at lower energy levels of 180 W for one to three minutes, whereas the minerals needed higher energy of 900 W for five minutes. Particle size analysis indicated rapid size reduction up to an energy input of 25 Wh. This effect diminished with increased energy input.
本研究旨在了解材料形态变化对微波预处理效果的影响。三种不同类型的矿物质——煤、铁矿石和锰矿石——用180至900W的不同能量水平的微波处理,持续时间为1至5分钟。对处理过的样品进行显微镜、研磨和释放研究。煤是一种具有低介电常数的多孔和无定形材料,对微波预处理的煤样品进行研磨可使80%的通过粒度(d80)减少18.18%,碳回收率增加17.1%。微波预处理的软锰矿和易碎锰矿样品在研磨过程中d80降低了47.82%,在释放分析过程中锰回收率提高了42.46%。微波预处理和研磨硬质和带状铁矿石使d80降低了20.83%,但矿物释放没有改善。煤在180W的较低能量水平下处理一到三分钟时表现出更好的效果,而矿物需要900W的较高能量处理五分钟。粒度分析表明,在能量输入为25Wh的情况下,粒度迅速减小。这种影响随着能量输入的增加而减弱。
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引用次数: 8
Heap leach modeling — A review of approaches to metal production forecasting 堆浸建模——金属产量预测方法综述
Q2 Materials Science Pub Date : 2017-05-01 DOI: 10.19150/MMP.7505
J. Marsden, M. Botz
Heap leaching is responsible for approximately 21 percent — 3.9 million metric tonnes — of copper production and 9 percent — 270 metric tonnes or 8.7 million ounces — of gold production worldwide. Given metal price assumptions of $2.25/lb for copper and $1,250/oz for gold, these portions of global production generate revenues of $19 billion and $11 billion, respectively. For heap leaching operations, small changes in metal extraction efficiency drive substantial changes in operating cash flow margins and affect project viability. Variances in actual metal production from budgetary forecast estimates can mean the difference between success (value creation) and failure (value destruction) for a heap leach project. Despite the importance of heap leaching for copper, gold and silver production worldwide, there are no clear standards or guidelines for developing heap leach metal production forecasts. There is considerable variation among copper and gold producers that apply heap leaching technology as to how such modeling and forecasting is applied at the operational level. There are a variety of different modeling approaches that can be utilized for this purpose. However, these vary in cost, complexity, time to implement, accuracy and credibility. This paper explores the options available for heap leach modeling, discusses the advantages and disadvantages of each approach, and provides guidelines/recommendations for an effective approach to modeling metal production at existing or planned heap leach operations. The paper also provides expected ranges of variation between actual and modeled production.
堆浸法约占全球铜产量的21%,即390万公吨,黄金产量的9%,即270公吨,即870万盎司。考虑到铜和黄金的金属价格分别为2.25美元/磅和1250美元/盎司,这些部分的全球生产分别产生190亿美元和110亿美元的收入。对于堆浸作业,金属提取效率的微小变化会导致经营现金流利润率的大幅变化,并影响项目的可行性。实际金属产量与预算预测估计的差异可能意味着堆浸项目的成功(价值创造)和失败(价值破坏)之间的差异。尽管堆浸对世界各地的铜、金和银生产很重要,但没有明确的标准或指南来制定堆浸金属产量预测。应用堆浸技术的铜和金生产商在如何在运营层面应用这种建模和预测方面存在很大差异。有多种不同的建模方法可以用于此目的。然而,这些在成本、复杂性、实施时间、准确性和可信度方面各不相同。本文探讨了堆浸建模的可用选项,讨论了每种方法的优缺点,并为在现有或计划的堆浸操作中建模金属生产的有效方法提供了指南/建议。论文还提供了实际生产和建模生产之间的预期变化范围。
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引用次数: 17
System dynamics and discrete event simulation of copper smelters 铜冶炼厂系统动力学与离散事件仿真
Q2 Materials Science Pub Date : 2017-05-01 DOI: 10.19150/MMP.7510
A. Navarra, H. Marambio, F. Oyarzun, R. Parra, F. Mucciardi
Discrete event simulation (DES) is an appropriate framework for the plant-wide analysis of copper smelters. These smelters apply a common set of chemical reactions: copper-iron sulfides are blasted with oxygen-enriched air, sending the iron into a slag phase and the sulfur into the offgas. Moreover, conventional copper smelters exhibit similar operational dynamics: a smelting furnace operates continually, feeding into an alternating set of converters that produce batches of blister copper. The thermochemical and operational commonalities of copper smelters are integrated within the DES framework. This serves as a common basis to begin evaluating the system dynamics of individual smelters. For complex problems, the simulation framework should be developed in phases, incorporating feedback from different personnel who have complementary perspectives. Sample computations are provided in this paper based on the Hernán Videla Lira smelter, whose production is constrained by meteorological conditions.
离散事件模拟(DES)是对铜冶炼厂进行全厂分析的合适框架。这些冶炼厂采用一套常见的化学反应:用富氧空气对铜铁硫化物进行爆破,使铁进入炉渣阶段,硫进入废气。此外,传统的铜冶炼厂也表现出类似的操作动态:一个熔炼炉连续运行,向一组交替的转炉输送铜,这些转炉生产出一批又一批的泡铜。铜冶炼厂的热化学和操作共性被整合到DES框架内。这可以作为开始评估单个冶炼厂系统动力学的共同基础。对于复杂的问题,应分阶段开发模拟框架,并纳入具有互补观点的不同人员的反馈。本文以生产受气象条件约束的Hernán Videla Lira冶炼厂为例进行了实例计算。
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引用次数: 15
期刊
Minerals & Metallurgical Processing
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