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The Knowledge Management Landscape in the Greek Coal Mining Industry 希腊煤矿业的知识管理格局
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-16 DOI: 10.1007/s42461-024-00958-8

Abstract

Coal mining operations are large-scale, long-term frameworks of high complexity. Mining organizations accumulate, develop, and leverage knowledge from diverse scientific and technological fields as a result of these operations. Both practical experience and existing literature indicate that knowledge management (KM) methods within the mining industry primarily target solving immediate technical challenges and operational requirements. However, they are not commonly regarded as strategic tools to enhance the performance and competitiveness of mining companies. Empirical evidence from the Greek mining industry suggests that the management of available knowledge is intricate, less effective, and dysfunctional. This paper presents a methodology based on the principles of quantitative research (QNR), collaboratively conducted with a group of mining experts, to assess the KM landscape in the Greek mining industry. The methodology involves a structured data collection framework using questionnaires, subsequent statistical analysis, a discussion on critical methodological aspects, and an interpretation of results focusing on key aspects useful for planners and designers of KM systems in the mining industry. Finally, the paper concludes by summarizing the methodology’s outcomes and proposing further perspectives for research.

摘要 煤矿开采是一项大规模、长期、高度复杂的工作。采矿组织在运营过程中会积累、开发和利用来自不同科技领域的知识。实践经验和现有文献都表明,采矿业的知识管理(KM)方法主要以解决眼前的技术挑战和运营需求为目标。然而,这些方法并未被普遍视为提高矿业公司业绩和竞争力的战略工具。来自希腊采矿业的经验证据表明,现有知识的管理错综复杂、效率较低、功能失调。本文介绍了一种基于定量研究(QNR)原则的方法,该方法是与一组采矿专家合作开展的,旨在评估希腊采矿业的知识管理状况。该方法包括使用调查问卷的结构化数据收集框架、随后的统计分析、对关键方法论方面的讨论,以及对结果的解释,重点是对采矿业知识管理系统的规划者和设计者有用的关键方面。最后,本文总结了该方法的成果,并提出了进一步的研究视角。
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引用次数: 0
The Effect of Different Magnetic Separation Procedures of a Korean VTM Ore on Combined Pyro-hydrometallurgical Vanadium Recovery Behavior 韩国钒钛矿石的不同磁选程序对火法-湿法冶金联合提钒行为的影响
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-15 DOI: 10.1007/s42461-024-00943-1
Rina Kim, Yuik Eom, Yeongjin Ahn, Kyeong Woo Chung, Sujeong Lee, Min-seuk Kim, Byunghun Go, Hong-In Kim, Ho-Seok Jeon

The study focused on the recovery of vanadium from a Korean vanadium-bearing titaniferous magnetite (VTM) ore, examining the behaviors of magnetic separation and Na2CO3 roasting-water leaching. Two concentrates were prepared using single-stage dry magnetic separation and three-step wet magnetic separation, resulting in V2O5 grades of 0.8% and 1.0% and major gangue mineral SiO2 contents of 6.5% and 1.7%, respectively. These concentrates were subsequently roasted at 1050 °C with the addition of Na2CO3 and then water-leached at 25 °C. Various stoichiometric ratios of V2O5 to Na2CO3 were tested, ranging from 1:1 to 1:40 of the theoretically required amount. As the amount of Na2CO3 increased, the vanadium leaching efficiency showed fluctuations between 4 and 35% for ratios of 1:1 to 1:10, while it linearly increased from 4 to 82% for ratios of 1:10 to 1:40 in the leaching of the low-grade concentrate. In contrast, the leaching efficiency increased from 47 to 74% for ratios of 1:1 to 1:8 and then sharply rose to 84% at a ratio of 1:10 in the leaching of the high-grade concentrate. Subsequently, it reached a plateau of 92 to 94% for ratios of 1:20 to 1:40. The difference in leaching efficiency was primarily due to the reaction of gangue minerals with Na2CO3, which hindered vanadium leaching from the VTM concentrates. This hindrance was notably more pronounced in the low-grade concentrate with the lower salt ratio, as the gangue minerals exhibited a preference for consuming Na2CO3 over vanadium. The mineral formation was analyzed in detail using XRD and MLA to shed light on the mechanism of different vanadium leaching behavior depending on the concentrate grade and vanadium to salt ratio. Based on the results of this study, it is evident that applying a proper magnetic separation procedure is significant to achieving satisfactory vanadium recovery with less salt amount by removing gangue minerals ahead.

该研究侧重于从韩国含钒钛磁铁矿(VTM)中回收钒,考察了磁选和 Na2CO3 焙烧-水浸出的行为。采用单级干式磁选和三步湿式磁选制备了两种精矿,其V2O5品位分别为0.8%和1.0%,主要煤矸石矿物SiO2含量分别为6.5%和1.7%。这些精矿随后在加入 Na2CO3 的情况下在 1050 °C 下进行焙烧,然后在 25 °C 下进行水浸。测试了 V2O5 与 Na2CO3 的各种化学计量比,从理论需要量的 1:1 到 1:40。随着 Na2CO3 含量的增加,在低品位精矿的浸出过程中,1:1 至 1:10 比例的钒浸出效率在 4% 至 35% 之间波动,而 1:10 至 1:40 比例的钒浸出效率则在 4% 至 82% 之间线性增加。相反,在浸出高品位精矿时,比例为 1:1 至 1:8 的浸出效率从 47% 上升到 74%,比例为 1:10 时,浸出效率急剧上升到 84%。随后,当比例为 1:20 至 1:40 时,浸出效率达到 92% 至 94%。浸出效率的差异主要是由于煤矸石矿物与 Na2CO3 的反应,阻碍了 VTM 精矿中钒的浸出。这种阻碍在盐比较低的低品位精矿中更为明显,因为煤矸石矿物表现出更喜欢消耗 Na2CO3 而不是钒。利用 XRD 和 MLA 对矿物的形成进行了详细分析,以揭示根据精矿品位和钒盐比不同的钒浸出行为的机理。根据这项研究的结果,可以明显看出,采用适当的磁选程序,通过提前去除矸石矿物,以较少的盐量获得令人满意的钒回收率是非常重要的。
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引用次数: 0
The Road to Zero: The 50-Year Effort to Eliminate Roof Fall Fatalities from US Underground Coal Mines 零死亡之路:美国地下煤矿消除屋顶坠落死亡事故的 50 年努力
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-12 DOI: 10.1007/s42461-024-00956-w
Christopher Mark

Six decades ago, the most dangerous job in the USA was mining coal underground. Roof falls were responsible for half of the deaths, killing about 100 miners every year. Fast forward to 2016 and zero roof fall fatalities. Just three miners were killed by roof falls during the following 6 years. How did the mining community achieve this historic goal? This paper starts by analyzing the roof fall fatalities in 1968, categorizing them by their fundamental cause. Then, it shows how each type of roof fall was reduced over time, using snapshots of the fatalities occurring in subsequent decades. Along the way, it evaluates the influence of the regulatory environment, changing mining methods, and better ground control technology. The study found that in 1968 more than half of roof fall fatalities at large mines were attributable to an inadequate safety culture. The immediate effect of the 1969 Coal Mine Health and Safety Act was to reduce the riskiest activities, like needlessly going under unsupported roof. Other hazards, like large roof falls, required technological developments before they were brought under control. Roof Control Plans, which the US Bureau of Mines had been advocating since the 1920s, played a significant role throughout the process.

六十年前,美国最危险的工作是在地下采煤。每年约有 100 名矿工死于屋顶坠落,占死亡人数的一半。时至 2016 年,屋顶坠落造成的死亡人数为零。在随后的 6 年中,仅有 3 名矿工死于屋顶坠落。矿业界是如何实现这一历史性目标的?本文首先分析了1968年的屋顶坠落死亡事故,并根据其根本原因进行了分类。然后,利用随后几十年发生的死亡事故快照,说明每种类型的屋顶坠落事故是如何随着时间的推移而减少的。研究还评估了监管环境、采矿方法的变化以及更好的地面控制技术的影响。研究发现,1968 年,大型煤矿半数以上的顶板坠落死亡事故是由于安全文化不足造成的。1969 年《煤矿健康与安全法》的直接效果是减少了最危险的活动,如不必要地进入无支撑顶板。而其他一些危险活动,例如大面积的顶板坠落,在得到控制之前还需要技术的发展。美国矿务局自 20 世纪 20 年代起就开始倡导的顶板控制计划在整个过程中发挥了重要作用。
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引用次数: 0
A Novel Approach in Predicting Dump Truck Tyre Life in a Mine Based on Multilayer Perceptron Neural Network Optimised with Particle Swarm Optimisation 基于多层感知器神经网络和粒子群优化的矿井自卸卡车轮胎寿命预测新方法
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-11 DOI: 10.1007/s42461-024-00954-y
Solomon Evans Kweku Koomson, Victor Amoako Temeng, Yao Yevenyo Ziggah

Tyre hours/life deficit is a major operational challenge facing the mining industry which adversely affects materials production and costs. An accurate forecast of the tyre life is key in addressing this menace. This study for the first time employed the hybrid intelligent technique by utilising three metaheuristic optimisation algorithms, including particle swarm optimisation (PSO), genetic algorithm (GA), and whale optimisation algorithm (WOA), as trainers for the parametric weights and biases to optimise multilayer perceptron neural network (MLPNN) for enhancing prediction of on-site dump truck tyre life in the mine. Four hybrid models known as PSO-MLPNN, WOA-MLPNN, GA-MLPNN, and BP-MLPNN were developed using a total of 157 tyre dataset records obtained from a surface mine in Ghana. In assessing the prediction performances for the models developed, five statistical performance metrics of variance accounted for (VAF), Nash–Sutcliffe efficiency index (NASH), coefficient of determination (r2), mean absolute percentage error (MAPE), and correlation coefficient (r) were utilised. Moreover, ranking, uncertainty analysis and Bayesian information criterion (BIC) techniques were utilised to establish the most effective hybrid model, whereas sensitivity analysis was conducted on the input parameters. Results achieved showed that PSO-MLPNN was the best for prediction because it had the least MAPE value of 1.196% and relatively high values of VAF (99.642%), NASH (0.996), r2 (0.996), and r (0.998). Besides, PSO-MLPNN had the best selection criteria values of 6, 7.1725, and 444.834 for the ranking, uncertainty analysis and BIC respectively. Hence, PSO-MLPNN is recommended for the prediction of on-site dump truck tyre life for the studied mine.

轮胎使用时间/寿命不足是采矿业面临的一项重大运营挑战,对材料生产和成本产生了不利影响。准确预测轮胎寿命是解决这一问题的关键。本研究首次采用了混合智能技术,利用三种元启发式优化算法,包括粒子群优化算法(PSO)、遗传算法(GA)和鲸鱼优化算法(WOA),作为参数权重和偏差的训练器,优化多层感知器神经网络(MLPNN),以提高矿山现场倾卸卡车轮胎寿命的预测。利用从加纳一个露天矿获得的总共 157 条轮胎数据集记录,开发了四种混合模型,即 PSO-MLPNN、WOA-MLPNN、GA-MLPNN 和 BP-MLPNN。在评估所开发模型的预测性能时,使用了五个统计性能指标,即方差占比(VAF)、纳什-苏特克利夫效率指数(NASH)、判定系数(r2)、平均绝对百分比误差(MAPE)和相关系数(r)。此外,还利用排序、不确定性分析和贝叶斯信息准则(BIC)技术建立了最有效的混合模型,并对输入参数进行了敏感性分析。结果表明,PSO-MLPNN 的 MAPE 值最小(1.196%),VAF 值(99.642%)、NASH 值(0.996)、r2 值(0.996)和 r 值(0.998)相对较高,因此预测效果最佳。此外,PSO-MLPNN 在排序、不确定性分析和 BIC 方面的最佳选择标准值分别为 6、7.1725 和 444.834。因此,推荐使用 PSO-MLPNN 对所研究矿山的现场自卸卡车轮胎寿命进行预测。
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引用次数: 0
Experimental and Numerical Simulation Studies on the Atomization Characteristics of the Internal Mixing Nozzle and Its Field Application 内部混合喷嘴雾化特性的实验和数值模拟研究及其现场应用
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-09 DOI: 10.1007/s42461-024-00955-x
Wenpu Li, Yiyi Zheng, He Shao, Xin Wang, Xi Chen, Yurong Gao

This study utilized experimental and numerical simulation methods to investigate and analyze the atomization characteristics of three internal air–water mixed atomizers under different operating conditions. By comparing the research results, the effective dust control working parameters for the application of the selected atomizer in the engineering field were determined. Firstly, the atomization characteristics of the three atomizers were studied using a customized experimental system. The results indicated that nozzle 2 had a wide atomization range, a small atomization distance, and small droplet size; nozzle 3 had a narrow atomization range, large droplet size, and fast atomization speed; and nozzle 1 not only had a large atomization range but also could produce droplets of dry mist size with fast atomization speed, meeting the dust reduction requirements of the Majiliang Coal Preparation Plant. Secondly, Fluent software was used to simulate the atomization process and particle size distribution of the three internal mixed atomizers, determining the working conditions of the atomizers, the required number of atomizers, and the application angle of the atomizers in the internal mixed dust removal system. Finally, the atomized dust control system was applied on-site, achieving a total dust removal efficiency of 90.72% and a respirable dust removal efficiency of 89.75%.

本研究利用实验和数值模拟方法,研究分析了三种内部空气-水混合雾化器在不同工作条件下的雾化特性。通过对比研究结果,确定了所选雾化器在工程领域应用的有效防尘工作参数。首先,利用定制的实验系统研究了三种雾化器的雾化特性。结果表明,喷嘴 2 的雾化范围宽、雾化距离小、雾滴粒径小;喷嘴 3 的雾化范围窄、雾滴粒径大、雾化速度快;喷嘴 1 不仅雾化范围大,而且雾化速度快,能产生干雾粒径的雾滴,满足马家梁选煤厂的降尘要求。其次,利用 Fluent 软件模拟了三个内部混合雾化器的雾化过程和粒度分布,确定了内部混合除尘系统中雾化器的工作条件、所需雾化器的数量以及雾化器的作用角度。最后,将雾化粉尘控制系统应用于现场,实现了 90.72% 的总除尘效率和 89.75% 的可吸入粉尘除尘效率。
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引用次数: 0
Quantitative Criterion and Applications for Assessing the Impact of Coal Seam Mining on Overlying Strata 评估煤层开采对上覆地层影响的定量标准及应用
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-08 DOI: 10.1007/s42461-024-00953-z
Yang Li, Nan Wang, Yifei Song, Xinghai Lei, Tiezheng Li, Lingyun Zou

The stability of key strata is of utmost importance in ensuring safe and effective coal seam mining operations. To minimize disturbance impacts on these strata and ensure their stability, it is crucial to assess the degree of disturbance caused by mining activities. This study proposes the evaluation index “disturbance degree of key stratum (KSDD)” and establishes a quantitative KSDD criterion to measure the degree of disturbance on key strata. To facilitate the assessment process, an intelligent calculation system for KSDD is developed. The classification criteria are derived by combining the measured three-zone heights from multiple mines. The reliability and accuracy of the KSDD quantitative criterion are validated using field measurement data. Furthermore, the KSDD quantitative criterion is applied to the Meihuajing mining area No. 23, and the distribution characteristics of KSDD are analyzed. The findings of this study can serve as a valuable reference for reducing disturbance and enhancing the stability of key strata during subsequent mining operations. Overall, this work contributes to the field of ground control in coal seam mining by providing a comprehensive approach to assess and mitigate the disturbance caused by mining activities on key strata.

关键地层的稳定性对确保煤层开采作业安全有效至关重要。为了最大限度地减少对关键地层的扰动影响,确保关键地层的稳定性,评估采矿活动对关键地层的扰动程度至关重要。本研究提出了 "关键地层扰动度(KSDD)"评价指标,并建立了 KSDD 定量标准,以衡量关键地层的扰动程度。为方便评估过程,开发了 KSDD 智能计算系统。分类标准是综合多个矿井测量的三区高度得出的。利用实地测量数据验证了 KSDD 定量标准的可靠性和准确性。此外,还将 KSDD 定量标准应用于梅花井 23 号矿区,并分析了 KSDD 的分布特征。本研究的结果可为后续采矿作业中减少扰动和提高关键地层的稳定性提供有价值的参考。总之,本研究为评估和减轻采矿活动对关键地层的扰动提供了一种综合方法,对煤层开采中的地面控制领域做出了贡献。
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引用次数: 0
Separation and Purification of Cesium from High-Rubidium Solution by Zinc Ferrocyanide 用亚铁氰化锌从高铷溶液中分离和提纯铯
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-07 DOI: 10.1007/s42461-023-00813-2
Xie Junjie, Li Kang, Shi Zhuonan, Min Changli, Li Shina, Yin Zichen, Ma Ruixin

Cesium and rubidium were effectively separated by zinc ferrocyanide coprecipitation method, and the effect of precipitant addition amount on the separation of cesium and rubidium was studied. Under the conditions of Zn/Cs molar ratio of 0.45 and Zn/Fe molar ratio of 1, the precipitation rate of cesium is 84.01% and the separation factor of Cs/Rb is 164.65. The thermogravimetric curves of the sediment were measured, and the effects of roasting temperature, roasting time, and leaching liquid/solid ratio on the extraction of cesium were studied. Almost all of the cesium was extracted under optimal conditions: roasting temperature of 600 °C, roasting time of 3 h, leaching temperature of 25 °C, leaching time of 0.5 h, and liquid/solid ratio of 5:1 mL/g. After the leaching process, the leach liquor with high concentration of cesium of 80.17 g/L was obtained. Finally, the leach liquor was further purified by solvent extraction, and the purity of the cesium chloride product reached 99.66%.

Graphical Abstract

采用亚铁氰化锌共沉淀法有效分离了铯和铷,并研究了沉淀剂加入量对铯和铷分离的影响。在 Zn/Cs 摩尔比为 0.45 和 Zn/Fe 摩尔比为 1 的条件下,铯的沉淀率为 84.01%,铯/铷的分离系数为 164.65。测量了沉淀物的热重曲线,研究了焙烧温度、焙烧时间和浸出液/固比对铯提取的影响。在焙烧温度为 600 ℃、焙烧时间为 3 h、浸出温度为 25 ℃、浸出时间为 0.5 h、液固比为 5:1 mL/g 的最佳条件下,几乎所有的铯都被提取出来。浸出过程结束后,得到铯浓度高达 80.17 g/L 的浸出液。最后,浸出液经溶剂萃取进一步提纯,氯化铯产品的纯度达到 99.66%。
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引用次数: 0
CO2-Free Flux for Sustainable Iron Ore Pelletizing 用于可持续铁矿石球团的无二氧化碳助熔剂
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-04 DOI: 10.1007/s42461-024-00949-9
Shaik Mahaboob Basha, Srinivas Dwarapudi, Pulibandla Basaveswara Rao, Indrajit Paul, Surajit Sinha, Shakuntala Tudu

The iron and steel manufacturing sector directly accounts for 7–9% of global CO2 emissions. Raw material preparation, such as iron ore sintering, pelletizing, and cock making, is the major CO2 emitter. As climate change becomes a bigger concern, steel manufacturers need to lower CO2 emissions without hindering efficiency or increasing costs. In recent years, the percentage of iron ore pellets in blast furnaces has increased due to its uniform size, good reducibility, and high tumbler index. Pelletizing is energy-intensive and emits considerable CO2. Around 20% of CO2 emissions during pellet making come from fluxes. In the present work, the authors established a novel CO2-free flux called wollastonite (CaO.SiO2) for sustainable palletization. Pellets with varying percentages of wollastonite (0–6%) are prepared and tested for chemical, physical, and metallurgical properties. Image analysis through an optical microscope is carried out to quantify the phases of fired pellets. SEM–EDS is performed to evaluate the chemical composition of the melt and slag phases. The results showed that the reducibility index (RI) and swelling index (SI) of pellets decreased with an increase in wollastonite dosage. Pellet strength increases with an increase in wollastonite addition up to 1.2% CaO (2.27% wollastonite), and a decrease in strength is observed thereafter. The increase in strength is attributed to the increase in slag bonds. The decrease in strength beyond 1.2% CaO is mainly because of an increase in low melting eutectics and more magnetite content. Pellets with 2.27% wollastonite to get 1.2% CaO showed good physical and metallurgical properties.

Graphical Abstract

钢铁制造业直接排放的二氧化碳占全球总量的 7-9%。原材料制备,如铁矿石烧结、球团和公鸡制造,是主要的二氧化碳排放源。随着气候变化日益受到关注,钢铁制造商需要在不影响效率或增加成本的情况下降低二氧化碳排放量。近年来,由于铁矿石粒度均匀、还原性好、滚揉指数高,高炉中使用铁矿石球团的比例不断增加。球团矿是能源密集型产品,会排放大量二氧化碳。在球团制造过程中,约 20% 的二氧化碳排放来自助熔剂。在本研究中,作者开发了一种新型无二氧化碳助熔剂--硅灰石(CaO.SiO2),用于可持续造粒。制备了不同比例的硅灰石(0-6%)颗粒,并对其化学、物理和冶金特性进行了测试。通过光学显微镜进行图像分析,量化烧制颗粒的相位。通过 SEM-EDS 评估熔体和熔渣相的化学成分。结果表明,随着硅灰石用量的增加,球团的还原指数(RI)和膨胀指数(SI)降低。在 CaO 含量不超过 1.2% (硅灰石含量不超过 2.27%)的情况下,球团强度随硅灰石添加量的增加而增加,之后强度下降。强度的增加归因于熔渣结合力的增加。当 CaO 含量超过 1.2% 时,强度下降的主要原因是低熔共晶的增加和磁铁矿含量的增加。含有 2.27% 硅灰石的球团矿在获得 1.2% CaO 时显示出良好的物理和冶金性能。
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引用次数: 0
Investigation on the Prevention and Treatment Measures of Seepage Failure of the Fine-Grained Tailings Dam: A Case of Iron Tailings Reservoir in China 细粒度尾矿坝渗漏溃坝防治措施研究:中国铁尾矿库案例
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-04 DOI: 10.1007/s42461-024-00951-1
Dayu Long, Changhong Li, Yongyue Hu, Juzhou Li, Yu Wang

To address the problem of seepage failure that affects the stability of the fine-grained tailings dam, two kinds of prevention and treatment measures were proposed involving composite flocculants and composite curing agents. The orthogonal test was conducted to determine the optimal ratio flocculant (ORF) and the optimal ratio curing agent (ORCG). Then, numerical models were established to evaluate the effects of the prevention and treatment measures on the seepage and stability of the tailings dam. The results show that the mechanical properties and microstructure of the tailings are significantly improved by adding the ORF and ORCG. Furthermore, numerical studies suggest that the addition of the ORF and the ORCG to the tailings improves the factor of safety of the tailings dam, but the addition of the ORCG also increases the height of the phreatic line. It is also speculated that the addition of the ORF can prevent the formation of through failure zone in the tailings dam. Therefore, the optimal measure to prevent seepage failure in the tailings dam is adding an appropriate amount of the ORF, as it reduces the height of the dam’s phreatic line and lowers the risk of seepage failure. The typical area susceptible to seepage failure can be treated by adding the ORCG. However, it is important to ensure adequate drainage of the area and to maintain the phreatic line at a reasonable buried depth.

针对影响细粒尾矿坝稳定性的渗流溃坝问题,提出了复合絮凝剂和复合固化剂两种防治措施。通过正交试验确定了最佳配比絮凝剂(ORF)和最佳配比固化剂(ORCG)。然后,建立了数值模型来评估防治措施对尾矿坝渗流和稳定性的影响。结果表明,添加 ORF 和 ORCG 后,尾矿的机械性能和微观结构得到了明显改善。此外,数值研究表明,在尾矿中添加 ORF 和 ORCG 可提高尾矿坝的安全系数,但 ORCG 的添加也会增加喷涌线的高度。另一种推测是,添加 ORF 可防止尾矿坝形成贯穿溃坝区。因此,防止尾矿坝渗流溃坝的最佳措施是添加适量的 ORF,因为它可以降低坝体喷气线的高度,降低渗流溃坝的风险。可通过添加 ORCG 来处理易发生渗流溃坝的典型区域。不过,重要的是要确保该区域有足够的排水能力,并将喷气线保持在合理的埋设深度。
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引用次数: 0
Sulfur speciation analysis in cyanide leach solutions with liquid chramotography 利用液相色谱法分析氰化浸出液中的硫标度
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-03-02 DOI: 10.1007/s42461-024-00942-2
N. Duru, C. Nesbitt

During the cyanide leaching process, gold and silver ores that come from the transition zones, which typically contains low levels of sulfide, may produce one or more of the following reduced sulfur species: sulfide (HS), polysulfides (Sn2−), thiocyanate (SCN), thiosulfate (S2O32−), trithionate (S3O62−), tetrathionate (S4O62−), pentathionate (S5O62−), hexathionate (S6O62−). The actual speciation of the reduced sulfur species in the circuits will primarily depend on the redox potential, pH, cyanide levels, and existing sulfur species in recycled process water, as well as the presence of other reactive metal species. The development of an accurate analytical method for sulfur species in cyanide leaching units of gold ores where sulfur speciation occurs has an important role in explaining the metal recovery deviations. This study presents the speciation of sulfur species and the development of ion chromatography method to analyze reduced sulfur species thiocyanate (SCN), thiosulfate (S2O32−), trithionate (S3O62−), tetrathionate (S4O62−) in cyanide leaching circuits for gold ores. The method developed has resulted in precise quantification of target sulfur species in leach solutions. Method development and validation results were illustrated on analytical graphs containing each species’ peak number, retention time (min), type, width (min), area (mAU*s), height (mAU), and area distribution (%) of the peak.

在氰化浸出过程中,来自过渡带(通常硫化物含量较低)的金银矿石可能会产生以下一种或多种还原硫:硫化物 (HS-)、多硫化物 (Sn2-)、硫氰酸盐 (SCN-)、硫代硫酸盐 (S2O32-)、三硫酸盐 (S3O62-)、四硫酸盐 (S4O62-)、五硫酸盐 (S5O62-)、六硫酸盐 (S6O62-)。回路中还原硫物种的实际种类主要取决于氧化还原电位、pH 值、氰化物含量、循环工艺水中现有的硫物种以及其他活性金属物种的存在。在金矿氰化浸出过程中,硫的种类会发生变化,因此开发一种准确的硫种类分析方法对于解释金属回收率偏差具有重要作用。本研究介绍了金矿氰化浸出回路中硫的种类和离子色谱分析还原硫硫化物硫氰酸盐(SCN-)、硫代硫酸盐(S2O32-)、三硫酸盐(S3O62-)、四硫酸盐(S4O62-)的方法。所开发的方法可精确定量浸出液中的目标硫种。方法的开发和验证结果在分析图中进行了说明,图中包含每个物种的峰数、保留时间(分钟)、类型、宽度(分钟)、面积(mAU*s)、高度(mAU)和峰面积分布(%)。
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Mining, Metallurgy & Exploration
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