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Study on the Influence of Grouting Treatment on the Movement and Deformation of Surface in Longwall Coal Mining Goaf Areas 灌浆处理对长壁式采煤沼泽区地表移动和变形的影响研究
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-28 DOI: 10.1007/s42461-024-01026-x
Qian Hao, QiYin Zheng, ShaoWei Liu, WeiGuo Hao, Xiong Wu

The grouting treatment of the old goaf in a coal mine is an essential measure to ensure the safety of the road above it. A novel calculation model is proposed to more accurately determine the appropriate treatment range for the goaf on the road. Compared with traditional mining subsidence calculation models, this new model demonstrates improved fitting to the observed deformation in experimental studies. The deformation of the grouted area is caused by the residual deformation of the untreated goaf areas, and the deformation of the treated area is different from that of the area above the coal wall in the mining stage, which is made by the grouting reinforcement body after grouting treatment. The walking rule (walking probability) of the random medium theoretical walking model is enhanced in this paper to describe this distinction, and a calculation model suitable for quantitative analysis of surface residual deformation in road goaf after grouting reinforcement is established. The standard recommended method, the probability integral method, and a newly derived improved calculation formula are compared in this study. The treatment width predicted by the standard recommended method is the widest, reaching 182 m. The probability integral method predicts a narrower width of 139 m; while the improved calculation formula predicts the narrowest width of 124 m. Compared to the former two, the improved calculation formula not only considers factors such as the depth of the goaf, the overlying strata lithology but also the residual deformation and the grouting reinforcement body. An innovative and effective method for calculating the surface deformation of goaf areas after grouting treatment is developed, thereby offering a basis for designing more precise goaf treatment schemes.

煤矿老巷道的灌浆处理是确保其上方道路安全的必要措施。本文提出了一种新的计算模型,以更准确地确定道路上羊肠小道的适当处理范围。与传统的采矿沉陷计算模型相比,这一新模型与实验研究中观测到的变形的拟合程度更高。灌浆区域的变形是由未处理羊肠小道区域的残余变形引起的,而处理区域的变形不同于开采阶段煤壁上方区域的变形,它是由灌浆处理后的灌浆加固体引起的。本文增强了随机介质理论行走模型的行走规则(行走概率),以描述这种区别,并建立了适合于灌浆加固后巷道煤层表面残余变形定量分析的计算模型。本研究比较了标准推荐法、概率积分法和新推导的改进计算公式。标准推荐法预测的处理宽度最宽,达到 182 米;概率积分法预测的宽度较窄,为 139 米;改进计算公式预测的宽度最窄,为 124 米。这为计算灌浆处理后鹅卵石区域的表面变形提供了一种创新而有效的方法,从而为设计更精确的鹅卵石处理方案提供了依据。
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引用次数: 0
Stochastic Optimization for Long-Term Planning of a Mining Complex with In-Pit Crushing and Conveying Systems 矿坑破碎和输送系统采矿综合体长期规划的随机优化
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-27 DOI: 10.1007/s42461-024-01005-2
Liam Findlay, Roussos Dimitrakopoulos

Semi-mobile in-pit crushing and conveying (IPCC) systems can help reduce truck haulage in open-pit mines by bringing the crusher closer to the excavation areas. Optimizing a production schedule with semi-mobile IPCC requires integrating extraction sequence, destination policy, crusher relocation, conveyor layout, and truck fleet investment decisions. A mining complex with multiple mines and IPCC systems should be optimized simultaneously to find an optimal schedule for the entire value chain. An integrated stochastic optimization framework is proposed to produce long-term production schedules for mining complexes using multiple semi-mobile IPCC systems. The optimization model has flexibility to select the crusher locations and conveyor routes from anywhere inside the pits. The framework uses simulated orebody realizations to consider multi-element grade uncertainty and manage associated risk. A hybrid metaheuristic solution approach based on simulated annealing and evolutionary algorithms is implemented. The method is demonstrated using an iron ore mining complex.

半移动式坑内破碎和输送(IPCC)系统可使破碎机更靠近挖掘区域,从而有助于减少露天矿的卡车运输量。利用半移动式坑内破碎和输送系统优化生产计划需要综合考虑开采顺序、目的地政策、破碎机搬迁、输送机布局和卡车车队投资决策。一个拥有多个矿山和 IPCC 系统的采矿综合体应同时进行优化,以找到整个价值链的最佳时间表。本文提出了一个综合随机优化框架,为使用多个半移动 IPCC 系统的采矿联合企业制定长期生产计划。该优化模型可以灵活地从矿坑内的任何位置选择破碎机位置和输送机路线。该框架使用模拟矿体实景来考虑多元素品位的不确定性并管理相关风险。基于模拟退火和进化算法的混合元启发式求解方法得以实现。该方法通过一个铁矿石开采综合体进行了演示。
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引用次数: 0
An Information Entropy–based Risk (IER) Index of Mining Safety Using Clustering and Statistical Methods 利用聚类和统计方法构建基于信息熵的采矿安全风险(IER)指数
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-26 DOI: 10.1007/s42461-024-01024-z
Dharmasai Eshwar, Snehamoy Chatterjee, Rennie Kaunda, Hugh Miller, Aref Majdara

In recent decades, the mining industry in the United States has made significant strides in reducing accidents and injuries. While these improvements are commendable, interpreting these statistics can be challenging due to concurrent declines in workforce size, employee hours, productivity, and operating systems. The Mine Safety and Health Administration (MSHA) of the United States has instituted tools like the Pattern of Violation (POV) and Significant & Substantial (S&S) calculator to monitor safety in mines. However, both have their respective limitations. Various risk indices have been proposed to address these limitations, leveraging multiple matrices from MSHA databases. Yet, the primary challenge lies in effectively integrating these diverse matrices into a cohesive risk index. This research endeavors to develop an information entropy–based risk (IER) index through the optimization of weights assigned to these sometimes-conflicting matrices. The seven-dimensional risk indicators considered for IER index computation encompass (a) citations, (b) orders, (c) significant & substantial citations, (d) penalties, (e) incidents with no lost time, (f) lost time injuries, and (g) proposed penalty for violation. The efficacy of the proposed IER index was assessed using data from MSHA’s underground mines spanning from 2011 to 2020. Validation of the IER index was conducted through application of the BIRCH clustering algorithm in tandem with rigorous statistical analysis. The clustering performance was evaluated using the multivariate analysis of variance (MANOVA) test, followed by post hoc analysis. Box plots and univariate analysis of variance (ANOVA) tests were then employed to substantiate the statistical significance of mean differences in IER index values across clusters. The MANOVA test and subsequent post hoc results underscore the successful clustering of the seven-dimensional risk indices across all time periods using the BIRCH algorithm. The ANOVA test unequivocally demonstrates that the mean risk index values of at least one cluster are statistically distinct from the others at a 95% confidence level for all periods. Post hoc analysis further confirms the statistical significance of differences in mean risk indices between clusters. These findings were further supported by the results obtained from the box plots. Finally, the proposed approach was applied to an underground coal mine to illustrate its practical effectiveness. This study demonstrates that the proposed approach can empower mining companies to comprehensively assess their safety performance and implement necessary measures for improvement.

近几十年来,美国采矿业在减少事故和伤害方面取得了长足进步。虽然这些进步值得称赞,但由于劳动力规模、员工工时、生产率和操作系统同时下降,解释这些统计数据可能具有挑战性。美国矿山安全与健康管理局(MSHA)已经制定了违规模式(POV)和重大违规(S&S)计算器等工具来监控矿山安全。然而,这两种工具都有各自的局限性。为了解决这些局限性,人们利用 MSHA 数据库中的多个矩阵,提出了各种风险指数。然而,主要的挑战在于如何有效地将这些不同的矩阵整合成一个具有凝聚力的风险指数。本研究致力于通过优化这些有时相互冲突的矩阵的权重,开发基于信息熵的风险(IER)指数。计算 IER 指数时考虑的七维风险指标包括:(a) 引文,(b) 订单,(c) 重要 & 重大引文,(d) 处罚,(e) 无损失工时事件,(f) 损失工时伤害,以及 (g) 违规处罚建议。利用 MSHA 地下矿山 2011 年至 2020 年的数据,对拟议 IER 指数的有效性进行了评估。通过应用 BIRCH 聚类算法和严格的统计分析,对 IER 指数进行了验证。使用多变量方差分析 (MANOVA) 测试评估聚类性能,然后进行事后分析。然后采用箱形图和单变量方差分析(ANOVA)检验来证实不同聚类之间 IER 指数平均值差异的统计意义。MANOVA 检验和随后的事后分析结果表明,使用 BIRCH 算法成功地对所有时间段的七维风险指数进行了聚类。方差分析测试明确表明,在 95% 的置信水平下,所有时期至少有一个群组的平均风险指数值在统计上与其他群组不同。事后分析进一步证实了组群间平均风险指数差异的统计意义。箱形图得出的结果进一步证实了这些结论。最后,建议的方法被应用于一个地下煤矿,以说明其实际效果。这项研究表明,所提出的方法可以帮助矿业公司全面评估其安全绩效,并实施必要的改进措施。
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引用次数: 0
An Efficient Sample Selection Methodology for a Geometallurgy Study Utilizing Statistical Analysis Techniques 利用统计分析技术进行地质冶金研究的高效样本选择方法
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-25 DOI: 10.1007/s42461-024-01011-4
Muhammad Usman Siddiqui, Kevin Erwin, Shaihroz Khan, Rajiv Chandramohan, Connor Meinke

A geometallurgy study aims to link metallurgy and geology to reduce technical risk and enhance the economic performance of a mineral-processing plant. It does so by accounting for variability in a deposit to develop cash flow models with variable throughput rates. High-quality sample selection for metallurgical test work that are representative of the deposit is an essential component of a geometallurgy study, but the large multi-dimensional dataset makes sample selection a daunting task, as classifying the dataset while respecting its heterogeneity is difficult. This paper presents a streamlined approach for sample selection, utilizing statistical analysis techniques in Python. It cuts down time to select samples from around 1200 s per drillhole to about 60 s per drillhole for data classification and from 12 h to 8 h for handpicking samples from the classified dataset, translating to cost savings. The cumulative sum method and k-means clustering method are used in the methodology to elegantly classify the data and select representative samples. The effectiveness of the methodology is demonstrated by presenting data from a pre-feasibility study of a copper-iron mine in which 40 samples were selected for flotation test work.

地质冶金学研究旨在将冶金学和地质学联系起来,以降低技术风险,提高选矿厂的经济效益。它通过考虑矿床的可变性来建立具有可变吞吐率的现金流模型。为冶金测试工作选择能代表矿床的高质量样本是地质冶金研究的重要组成部分,但庞大的多维数据集使得样本选择成为一项艰巨的任务,因为在尊重数据集异质性的同时对其进行分类是非常困难的。本文介绍了一种利用 Python 统计分析技术进行样本选择的简化方法。在数据分类时,它将样本选择时间从每个钻孔约 1200 秒缩短到约 60 秒,而从分类数据集中手工挑选样本的时间则从 12 小时缩短到 8 小时,从而节省了成本。该方法采用累积和法和 k-means 聚类法对数据进行优雅的分类,并选出具有代表性的样本。通过展示一个铜铁矿预可行性研究中的数据,证明了该方法的有效性,该研究选取了 40 个样本进行浮选测试工作。
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引用次数: 0
Study on Mechanical Properties of Water-Immersed Mudstone Based on Nanoindentation Tests 基于纳米压痕测试的水浸泥岩力学性能研究
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-24 DOI: 10.1007/s42461-024-01027-w
Junjie Zheng, Yanqi Song, Fuxin Shen, Zhixin Shao, Chuanpeng Liu, Juntao Yang

To investigate the alterations in mechanical properties and damage mechanisms of water-immersed mudstone, the mudstone from the weak interlayer of an open-pit coal mine in eastern Inner Mongolia, China, was selected as the research focus. Mudstone samples with water contents of 0, 4.12%, 7.96%, 10.17%, and 12.73% were obtained through non-destructive immersion tests. Meso-mechanical tests on mudstone with different water contents were conducted using nanoindentation technology and scanning electron microscopy. The findings reveal a noticeable weakening of meso-mechanical properties of mudstone after water immersion. The elastic modulus, hardness, and fracture toughness all show a trend of non-linear attenuation with the increase of water content. Water-immersed mudstone exhibits changes characterized by volume expansion, decreased mineral cementation ability, reduced pore size, and increased quantity. The alteration in mudstone’s internal structure directly reflects the physical reasons for the weakening of mechanical properties after water immersion.

为了研究浸水泥岩力学性能的变化和破坏机理,研究人员选择了中国内蒙古东部某露天煤矿软弱夹层中的泥岩作为研究对象。通过无损浸水试验获得了含水率分别为 0%、4.12%、7.96%、10.17% 和 12.73% 的泥岩样品。利用纳米压痕技术和扫描电子显微镜对不同含水量的泥岩进行了介观力学测试。结果表明,泥岩在浸水后的中观力学性能明显减弱。随着含水量的增加,弹性模量、硬度和断裂韧性都呈现出非线性衰减的趋势。浸水后的泥岩表现出体积膨胀、矿物胶结能力下降、孔隙缩小和数量增加等变化特征。泥岩内部结构的变化直接反映了浸水后力学性能减弱的物理原因。
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引用次数: 0
Analysis of Raise Boring with Grouting as an Optimal Method for Ore Pass Construction in Incompetent Rock Mass—A Case Study 在不稳定岩体中建造矿石通道的最佳方法--带灌浆的提升钻孔分析--案例研究
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s42461-024-01023-0
Cluber Rojas, Angelina Anani, Eduardo Cordova, Wedam Nyaaba, Edward Wellman, Sefiu O. Adewuyi

The construction of ore pass systems in underground mines is a high-risk activity, especially in an environment with incompetent rock mass. This study aims to investigate the optimal method for ore pass construction in incompetent rock masses. We evaluated the conventional and raise boring (RB) methods based on safety, efficiency, excavation control, and ground support for ore pass construction. We also performed a stability analysis using analytical Q-raise (QR method) and kinematic analysis methods for ore pass construction with a Raise Borer before and after grout injection of the rock mass. As a case study, an ore pass (diameter, 3 m; depth, 100 m) within an incompetent rock mass was considered to gain further insight. The rock mass was characterized according to the classification methods Q Barton, rock quality designation (RQD), rock mass rating (RMR), and geological strength index (GSI). The grout intensity number (GIN) method of grout injection is used. The safety factor (<1.075) obtained before injection was lower than the acceptance criteria in all sections of the rock mass. However, grout injection before Raise Borer excavation resulted in a rock mass safety factor greater than 1.5. Using RB without pre-grouting in the case study indicated that the maximum unsupported diameter (MUSD) of the ore pass was less than the required 3 m. On the contrary, an MUSD of the rock mass post-grouting was equal to or larger than 3 m at all depths.

在地下矿井中建造矿道系统是一项高风险活动,尤其是在岩体不稳定的环境中。本研究旨在探讨在不稳定岩体中建造矿道的最佳方法。我们从安全、效率、挖掘控制和地面支撑等方面对矿石巷道施工的常规方法和提升钻孔(RB)方法进行了评估。我们还使用分析 Q-raise(QR 法)和运动学分析方法,对岩体注浆前后使用提升钻孔机施工矿石通道进行了稳定性分析。作为一项案例研究,我们考虑了在不合格岩体中的矿石通道(直径 3 米,深度 100 米),以获得更深入的了解。根据 Q Barton、岩石质量名称 (RQD)、岩体等级 (RMR) 和地质强度指数 (GSI) 等分类方法对岩体进行了表征。注浆采用注浆强度数(GIN)法。注浆前获得的安全系数(<1.075)低于岩体所有地段的验收标准。然而,在 Raise Borer 挖掘之前注入注浆,岩体安全系数大于 1.5。在案例研究中,在未进行预注浆的情况下使用 RB,矿石通道的最大无支撑直径(MUSD)小于要求的 3 米。
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引用次数: 0
Flotation Mechanism of Lead-Activated Cassiterite with Ricinoleic Acid as a Collector 以链烯酸为捕收剂的铅活化锡石浮选机理
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-19 DOI: 10.1007/s42461-024-01018-x
Qinbo Cao, Yan Yan, Haiyu Zhang, Yanjun Li, Dianwen Liu, Anh V. Nguyen

This paper investigates the flotation of cassiterite (SnO2) from ore using ricinoleic acid (RA) as a collector which is cheap and environmentally friendly. It is shown that the flotation is significantly enhanced by the activation of lead cations at pH 8. The flotation results are explained and supported by further studies to determine the changes in surface properties (hydrophobicity and surface potentials) and adsorption of RA and lead cations using X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and FTIR. The results of surface (zeta) potential measurements and TOF-SIMS indicate that the amount of RA anions on the Pb-activated SnO2 surface was higher than that on the natural SnO2 surface. The XPS results revealed that RA anions were bound to the Sn atoms on the natural SnO2 surface. In contrast, RA anions reacted with the Pb atoms instead of Sn atoms on the activated SnO2 surface, improving the floatability of Pb-activated SnO2. Pb(RA)2 precipitation occurred on the Pb-activated surface, and H bonds were formed between two RA anions in Pb(RA)2, which lead to a tighter assembly of collector species on the SnO2 surface. The outcomes of this research shed light on the application of the cost-effective and environmentally friendly RA collector in cassiterite flotation.

本文研究了以廉价且环保的蓖麻油酸(RA)作为捕收剂从矿石中浮选锡石(SnO2)的过程。通过使用 X 射线光电子能谱 (XPS)、飞行时间二次离子质谱 (TOF-SIMS) 和傅立叶变换红外光谱 (FTIR),进一步研究确定了 RA 和铅阳离子的表面性质(疏水性和表面电位)和吸附的变化,从而解释和支持了浮选结果。表面(zeta)电位测量和 TOF-SIMS 的结果表明,铅活化 SnO2 表面的 RA 阴离子含量高于天然 SnO2 表面。XPS 结果显示,RA 阴离子与天然二氧化锡表面的锡原子结合。相反,在活化的二氧化锡表面,RA 阴离子与铅原子而非锡原子发生反应,从而提高了铅活化二氧化锡的可浮性。在铅活化的表面上出现了 Pb(RA)2 沉淀,Pb(RA)2 中的两个 RA 阴离子之间形成了 H 键,从而使收集物物种在二氧化锡表面更紧密地结合在一起。这项研究成果为成本效益高且环保的 RA 捕收剂在锡石浮选中的应用提供了启示。
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引用次数: 0
Assessment of HEMM Operators’ Risk Exposure due to Whole-Body Vibration in Underground Metalliferous Mines Using Machine Learning Techniques 利用机器学习技术评估地下冶金矿井中 HEMM 操作员因全身振动而暴露的风险
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-17 DOI: 10.1007/s42461-024-01009-y
Vikram Sakinala, P. S. Paul, Janardhan Rao Moparthi

Whole-body vibration (WBV) is a substantial occupational health and safety hazard to heavy earth-moving machinery (HEMM) operators. There is a need to appraise the effect of WBV jeopardize and the factors influencing the WBV risk exposure on the HEMM operators. Seven machine learning (ML) models were tested on 81 data samples collected from seven underground metalliferous mines. The study considered nine factors which have substantial role behind the intensity of the WBV risk exposure of HEMM operators. RReleifF algorithm was used for dimensionality reduction and ranking the features. Compared to other ML techniques, ANN model was determined to be the most effective approach. The nine considered features were reduced to five features using RReleifF algorithm. The ranking of the five features selected was in order of awkward posture, the machine age, haul road condition, speed, and seat thickness based on their weights. Finally, a predictive equation was developed using the aforementioned five features. This study will help the seven underground mines authority to evaluate the WBV risk exposure effortlessly without the usage of scientific instrument and also helps in adopting immediate control measures to mitigate WBV risk exposure of HEMM operators.

全身振动(WBV)对重型土方机械(HEMM)操作人员的职业健康和安全造成了极大的危害。有必要评估全身振动对重型推土机操作员的危害以及影响全身振动风险暴露的因素。七种机器学习(ML)模型在从七个地下冶金矿山收集的 81 个数据样本上进行了测试。研究考虑了九个因素,这九个因素在影响 HEMM 操作员的 WBV 风险暴露强度方面发挥了重要作用。采用 RReleifF 算法进行降维和特征排序。与其他 ML 技术相比,ANN 模型被认为是最有效的方法。使用 RReleifF 算法将考虑的九个特征缩减为五个特征。所选的五个特征根据其权重依次为笨拙的姿势、机器年龄、运输道路状况、速度和座椅厚度。最后,利用上述五个特征建立了一个预测方程。这项研究将有助于七个地下矿山当局在不使用科学仪器的情况下轻松评估 WBV 风险暴露,并有助于立即采取控制措施,以降低 HEMM 操作员的 WBV 风险暴露。
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引用次数: 0
Electrometallurgical Extraction of Silicon Using Solid Oxide Membrane—Molten Salt Electrolysis 利用固体氧化膜-熔盐电解法提取硅的电冶技术
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-03 DOI: 10.1007/s42461-024-00957-9
Aditya Moudgal, Mohammad Asadikiya, Yu Zhong, Adam C. Powell, Uday Pal

This paper describes a computational and experimental approach to electrodeposition of silicon using a MgF2-CaF2-CaO-Y2O3-SiO2 molten salt electrolyte and a yttria-stabilized zirconia solid oxide membrane at the anode. A secondary and tertiary current density distribution model shows anodic current density between 0.5 and 1 A cm−2 with a fairly even distribution along the anode surface except at the ends of the anodes. Finite element analysis of industrial cell magnetohydrodynamics (MHD) shows electrolyte flow to be 23 times slower compared to a calculated analytical model. The experiments demonstrate formation of highly pure silicon in the melt with particle sizes ranging from a few μm to clusters of 2 ~ 3 mm. Finally, the mechanism of Si formation based on a short thermodynamic analysis was discussed.

本文介绍了使用 MgF2-CaF2-CaO-Y2O3-SiO2 熔盐电解质和阳极钇稳定氧化锆固体氧化物膜进行硅电沉积的计算和实验方法。二级和三级电流密度分布模型显示阳极电流密度在 0.5 至 1 A cm-2 之间,除阳极两端外,沿阳极表面分布相当均匀。对工业电池磁流体动力学(MHD)的有限元分析表明,电解液流动速度比计算分析模型慢 23 倍。实验证明在熔体中形成了高纯度的硅,其颗粒大小从几微米到 2 ~ 3 毫米不等。最后,根据简短的热力学分析讨论了硅的形成机制。
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引用次数: 0
Physicochemical Characteristics of Silicomanganese Slag as a Recycling Construction Material: An Overview 作为再生建筑材料的硅锰渣的物理化学特征:概述
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-03 DOI: 10.1007/s42461-024-00987-3
Ngie Hing Wong, Zong Yang Kong, Ratanak Sambo, Chang Saar Chai, Ali Raza Khoso, Jibril Adewale Bamgbade, Jaka Sunarso

Silicomanganese (SiMn) slag is a by-product of ferromanganese and SiMn alloy production poses significant challenges in terms of environmentally sound disposal given its substantial volume. This brief review aims to assess the physicochemical attributes of SiMn slag and explore its potential applications in construction materials recycling. To accomplish this, we systematically evaluated 20 relevant articles, categorizing them into segments covering reutilization methods, key considerations, enhancement strategies, and the recent challenges and prospects associated with SiMn slag reutilization. Our analysis encompassed SiMn slags from five countries, revealing consistent chemical compositions characterized by SiO2, Al2O3, CaO, MnO, MgO, FeO + Fe2O3, and K2O + Na2O at similar proportions. We identified two distinct types of SiMn slag, i.e., air-cooled and water-quenched, each possessing unique physical properties influencing their suitability for reutilization. SiMn slag has been successfully repurposed into various construction materials, including cement paste, mortar, concrete, alkali-activated matrices, bricks, backfill materials, Mn extracts, and binder/cement. Several critical factors must be considered when reutilizing SiMn slag in construction materials, including cooling methods, moisture content, particle size (fineness), equipment, energy requirements, and cost considerations. To enhance the reutilization process, we propose a structured approach consisting of four key steps, i.e., incoming waste assessment, pre-treatment, physical/chemical treatment, and product development. Furthermore, this review suggests several avenues for future research, including the development of industrial-scale recycling applications, exploring environmentally friendly landfilling methods for SiMn slag, and assessing the practicality and feasibility of SiMn-slag-based products in real-world construction projects.

硅锰(SiMn)渣是锰铁和硅锰合金生产过程中产生的一种副产品,由于其数量巨大,在无害环境处置方面面临着巨大挑战。本简要综述旨在评估锰硅渣的物理化学属性,并探讨其在建筑材料回收中的潜在应用。为此,我们系统地评估了 20 篇相关文章,并将其分为若干部分,内容包括再利用方法、主要考虑因素、改进策略以及与锰硅渣再利用相关的最新挑战和前景。我们的分析涵盖了五个国家的锰硅渣,发现其化学成分具有一致性,即二氧化硅(SiO2)、氧化铝(Al2O3)、氧化钙(CaO)、氧化锰(MnO)、氧化镁(MgO)、氧化铁(FeO)+氧化铁(Fe2O3)和氧化钾(K2O)+氧化钠(Na2O)的比例相似。我们确定了两种不同类型的锰硅渣,即空冷渣和水淬渣,每种渣都具有独特的物理性质,影响着它们是否适合再利用。锰硅渣已被成功地重新用于各种建筑材料,包括水泥浆、砂浆、混凝土、碱活性基质、砖块、回填材料、锰萃取物和粘结剂/水泥。在建筑材料中重新利用锰硅渣时必须考虑几个关键因素,包括冷却方法、含水量、粒度(细度)、设备、能源需求和成本因素。为了加强再利用过程,我们提出了一种由四个关键步骤组成的结构化方法,即废渣接收评估、预处理、物理/化学处理和产品开发。此外,本综述还为今后的研究提出了几条途径,包括开发工业规模的回收应用、探索对环境友好的锰硅渣填埋方法,以及评估基于锰硅渣的产品在实际建筑项目中的实用性和可行性。
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引用次数: 0
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Mining, Metallurgy & Exploration
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