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Efficient Separation of Iron and Alumina in Red Mud Using Reduction Roasting and Magnetic Separation 利用还原焙烧和磁分离高效分离赤泥中的铁和氧化铝
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-05-02 DOI: 10.1007/s42461-024-00990-8
Hongyang Wang, Yuqi Zhao, Zhiyong Lin, Leiting Shen

Gibbsite-type bauxite is the main material for alumina extraction by Bayer process globally, while the iron in red mud is difficult to use for the high alumina content. Therefore, the efficient separation of iron and alumina is the premise for the resource utilization of red mud. In this work, the separation of iron and alumina in red mud containing 47.45% Fe and 11.58% Al2O3 was studied through reduction roasting followed by magnetic separation. The analysis methods of XRD, VSM, SEM, and EDS were used to investigate the phase transformation of red mud during reduction roasting. Results show that hematite can be firstly reduced into magnetite, and alumogoethite into magnetite and alumina. Then, the magnetite reduction undergoes the process of Fe3O4→FeO→Fe, while alumina can react with FeO to form hercynite. The hercynite is ultimately reduced into metallic iron and alumina at elevated temperature. The specific saturation magnetization of reduced product is closely related to its main minerals, that is, the specific saturation magnetization of magnetite and metallic iron is higher than that of wustite and hercynite. The mass ratio of Fe to Al2O3 in magnetic concentrate increases with roasting temperature, from 4.55 at 600 °C to 10.27 at 1200 °C. Therefore, efficient separation of iron and alumina in red mud could be achieved through deep reduction-magnetic separation.

吉布斯特型铝土矿是全球拜耳法提取氧化铝的主要原料,而赤泥中的铁因氧化铝含量高而难以利用。因此,高效分离铁和氧化铝是赤泥资源化利用的前提。本研究通过还原焙烧法和磁选法研究了含铁 47.45% 和 Al2O3 11.58% 的赤泥中铁和氧化铝的分离。采用 XRD、VSM、SEM 和 EDS 等分析方法研究了赤泥在还原焙烧过程中的相变。结果表明,赤铁矿可首先还原成磁铁矿,铝镁土可还原成磁铁矿和氧化铝。然后,磁铁矿还原成 Fe3O4→FeO→Fe 的过程,而氧化铝可与 FeO 反应生成蛭石。在高温下,hercynite 最终会还原成金属铁和氧化铝。还原产物的比饱和磁化率与其主要矿物密切相关,即磁铁矿和金属铁的比饱和磁化率高于乌云母和蛭石。磁性精矿中铁与 Al2O3 的质量比随着焙烧温度的升高而增加,从 600 °C 时的 4.55 增加到 1200 °C 时的 10.27。因此,可通过深度还原-磁选实现赤泥中铁和氧化铝的高效分离。
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引用次数: 0
Impacts of Grade Distribution and Economies of Scale on Cut-off Grade and Capacity Planning 等级分布和规模经济对截止等级和容量规划的影响
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-29 DOI: 10.1007/s42461-024-00982-8
Mehmet Balci, Mustafa Kumral

Strategic mine planning centers on solving cut-off grade selection, capacity planning, and block sequencing. Even though significant knowledge has been accumulated on mine planning over the last decades, there is still potential to add value to mineral sourcing by addressing various aspects. To this end, this paper addresses two issues. The effects of (1) grade/metal distribution within a mineral deposit and (2) the economies of scale (EoS) are explored in cut-off grade selection and capacity planning. In doing so, the interdependency between cut-off grade selection and capacity planning is also considered. A case study is implemented on a metallic deposit whose grade distribution exhibits lognormal distribution to detect if grade/metal distribution influences cut-off grade selection. Also, based on the same ore tonnage and metal quantity, six different datasets are generated with different shape and scale factors. The research outcomes indicate that deposits with lower shape and scale factors of lognormal distribution are more sensitive to metal price and discount rate changes because slight cut-off grade variations significantly change net present value (NPV). While the NPV of the deposit with the largest shape factor is $3,208,112,841 with a cut-off grade of 0.058 oz/tonne, the NPV of the deposit with the smallest shape factor is $93,617,240 with a cut-off grade of 0.027 oz/tonne. Furthermore, the case study is directed to investigate the effect of EoS on a project’s value, with a specific emphasis on the ratio of variable cost to total cost (capacity factor). Two different regression analyses are conducted based on the proposed model for optimal capacity planning and cut-off grade selection, respectively. In the first one, the absolute standardized beta values for EoS of mining and mineral processing costs are 0.736 and 0.425, meaning that capacity planning is highly sensitive to the EoS of mining and mineral processing operating costs. Meanwhile, the absolute standardized beta value for grade variability is 0.054 which means that the effects of grade variability and metal distribution are almost negligible for capacity planning. However, EoS is the most critical variable for capacity optimization. In the second regression analysis, the standardized beta values for grade variability and EoS of mineral processing operating cost are 0.573 and 0.522, so their effects on cut-off grade selection become vital.

战略性矿山规划的核心是解决边界品位选择、产能规划和区块排序等问题。尽管在过去的几十年中,人们已经积累了大量关于矿山规划的知识,但通过解决各方面的问题,仍有可能为矿产采购带来更多价值。为此,本文探讨了两个问题。本文探讨了(1)矿床内品位/金属分布和(2)规模经济(EoS)在边界品位选择和产能规划中的影响。在此过程中,还考虑了边界品位选择和产能规划之间的相互依存关系。对品位分布呈现对数正态分布的金属矿床进行了案例研究,以检测品位/金属分布是否会影响边界品位选择。此外,基于相同的矿石吨位和金属量,生成了六个不同形状和比例因子的数据集。研究结果表明,对数正态分布形状和规模因子较低的矿床对金属价格和贴现率的变化更为敏感,因为边际品位的细微变化会显著改变净现值(NPV)。形状系数最大的矿床的净现值为 3,208,112,841 美元(边界品位为 0.058 盎司/吨),而形状系数最小的矿床的净现值为 93,617,240 美元(边界品位为 0.027 盎司/吨)。此外,案例研究还旨在调查 EoS 对项目价值的影响,重点是可变成本与总成本的比率(产能系数)。根据所提出的模型,分别进行了两种不同的回归分析,以优化产能规划和边界品位选择。在第一个回归分析中,采矿和选矿成本 EoS 的绝对标准化贝塔值分别为 0.736 和 0.425,这意味着产能规划对采矿和选矿运营成本的 EoS 高度敏感。同时,品位变化的绝对标准化贝塔值为 0.054,这意味着品位变化和金属分布对产能规划的影响几乎可以忽略不计。然而,EoS 是产能优化最关键的变量。在第二次回归分析中,选矿运营成本中品位变化和 EoS 的标准化贝塔值分别为 0.573 和 0.522,因此它们对截止品位选择的影响变得至关重要。
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引用次数: 0
Research on the Mechanical Characteristics of Thick Alluvium on the Surface Subsidence Features of Thin Bedrock Deposits at Depth 厚冲积层力学特征对薄基岩深部沉积地表沉降特征的影响研究
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-28 DOI: 10.1007/s42461-024-00989-1
Shanxi Wu, Zhaohui Wang, Jialong Li, Haoyu Hu, Bochao An, Jiqing He, Shenyi Zhang

There are a large number of thick alluvium and thin bedrock deposits at depth in the Henan coal base. The degree of surface mining is high, and the surface environment is seriously damaged. Using indoor experiments, numerical simulation, and field measurement, it is studied the influence of the mechanical properties of thick alluvium on the surface subsidence characteristics of thick alluvium thin bedrock deposits at depth, taking Zhaogu No. 2 coal mine as the research background. The results show that the compressive strength and elastic modulus of the alluvial layer are linearly negatively correlated with the alluvial layer particle size, linearly positively correlated with the confining pressure, and nonlinearly positively correlated with the loading rate. The thickness of the alluvial layer has the greatest influence on the displacement of surface subsidence and the range of surface subsidence. The advancing mining rate of the working face has the greatest influence on the surface horizontal displacement. The mechanical properties of the alluvial layer affect the evolution characteristics of the caving arch and towering roof beam. The influence range of the 11012 working face is about 550 m, β is about 55.5°, and the maximum subsidence rate of the surface is 12 mm/day. The mining process and separation grouting can be adjusted to control the overburden displacement to reduce surface disturbance and protect the surface ecological environment. The research results of this paper can provide a research basis for the study of surface subsidence under similar geological conditions.

河南煤炭基地深部有大量厚冲积层和薄基岩矿床。地表开采程度高,地表环境破坏严重。以赵固二号煤矿为研究背景,采用室内试验、数值模拟、野外实测等方法,研究了厚冲积层力学性质对深部厚冲积薄基岩矿床地表沉陷特征的影响。结果表明,冲积层的抗压强度和弹性模量与冲积层粒径呈线性负相关,与圈闭压力呈线性正相关,与加载速率呈非线性正相关。冲积层厚度对地表下沉位移和地表下沉范围的影响最大。工作面推进开采速度对地表水平位移影响最大。冲积层的力学性质影响崩落拱和高耸顶梁的演化特征。11012 工作面的影响范围约为 550 米,β 约为 55.5°,地表最大下沉速率为 12 毫米/天。通过调整开采工艺和分离注浆,可以控制覆土位移,减少地表扰动,保护地表生态环境。本文的研究成果可为类似地质条件下的地表沉陷研究提供研究依据。
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引用次数: 0
A Preliminary Study on the Beneficiation and Recovery of Valuable Metals from Municipal Solid Waste Incineration Bottom Ash 从城市固体废物焚烧底灰中选矿和回收有价金属的初步研究
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-27 DOI: 10.1007/s42461-024-00966-8
Bin Ji, Sharon Pedraza, Aaron Noble, Wencai Zhang, Sidi Deng, Subodh Das, Michael Van Brunt

In this study, a MSWI bottom ash sample was assessed to evaluate the feasibility of various physical beneficiation processes in concentrating valuable elements prior to chemical leaching. The raw sample was initially assayed to determine the content and economic value of various metals present in the material. The potential recoverable value (PRV) of the sample was calculated, and the result showed that the total PRV of the sample was 483 $/ton, with Ti, Sc, Fe, Cu, and Zn being the most valuable metals. Next, various physical separation processes, including size fractionation, froth flotation, magnetic separation, and gravity separation, were conducted to determine the extent to which the valuable elements can be concentrated. The results were compiled into an element-by-beneficiation enrichment ratio (er) matrix that was used to develop suitable beneficiation flowsheets for further consideration. The result clearly show delineation of four products, including a Fe-rich product that can be isolated by magnetic separation (er = 5.0), a Cu/Zn-rich product that can be isolated by flotation (er = 5.3 to 9.4), a Sc-rich product that can be isolated by gravity separation (er = 0.6), and a Ti–rich product that is produced in the residue. Lastly, the leachability of valuable elements from the bottom ash sample was determined by acid leaching tests. The results indicated that it is viable to employ hydrometallurgical methods to recover and purify the valuable metals. This work provides a reference for the recovery of valuable metals from MSWI bottom ash from both the technical and economic aspects.

在本研究中,对 MSWI 底灰样本进行了评估,以评价在化学沥滤前浓缩有价元素的各种物理选矿工艺的可行性。首先对原始样本进行化验,以确定材料中各种金属的含量和经济价值。计算了样品的潜在可回收价值(PRV),结果显示样品的总可回收价值为 483 美元/吨,其中 Ti、Sc、Fe、Cu 和 Zn 是最有价值的金属。接下来,进行了各种物理分离过程,包括粒度分选、浮选、磁选和重力分离,以确定有价元素的浓缩程度。研究结果被汇编成元素逐个富集比(er)矩阵,用于制定合适的选矿流程,以供进一步考虑。结果清楚地显示了四种产品的划分,包括可通过磁选分离的富铁产品(er = 5.0)、可通过浮选分离的富铜/锌产品(er = 5.3 至 9.4)、可通过重力分离分离的富钪产品(er = 0.6),以及在残渣中产生的富钛产品。最后,通过酸浸出试验确定了底灰样品中有价元素的可浸出性。结果表明,采用湿法冶金方法回收和提纯有价金属是可行的。这项工作从技术和经济两方面为从 MSWI 底灰中回收有价金属提供了参考。
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引用次数: 0
A Heuristic Methodology for Economic and Geomechanical Optimization in Sublevel Open Stoping Mining Method 次水平开停采矿法中经济和地质力学优化的启发式方法
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-27 DOI: 10.1007/s42461-024-00980-w
Diogo Peixoto Cordova, Andre Cezar Zingano, Italo Gomes Gonçalves

The top-down extraction sequence in the sublevel open stope method leaves rib pillars to support the excavations, so the stability of the pillars and stopes makes dilution control critical in this method. This work introduces an integrated methodology for the net profit and geomechanical optimization of the layout of open stopes and rib pillars with the use of a genetic algorithm. Parameters such as the minimum size of stopes, minimum size of pillars, maximum accepted dilution, and maximum acceptable percentage of pillar failure need to be informed by the user. A profit function capable of attributing economic value to the geometric set analyzed, including the geomechanical performance, is established. The geomechanical performance of the geometric sets is obtained by autonomous numerical models in the FLAC3D software and includes the average percentage of pillar failure and the potential dilution. The algorithm is verified using a case study of a mining panel of an underground gold mine with a top-down mining sequence. An 8% increase in net profit was obtained relative to the engineer’s design method, considering 70% of hangingwall support efficiency for both methods. The percentage of pillar failure decreased threefold. When considering no hangingwall support, the net profit increase is 22% relative to the engineer’s design method. The proposed methodology proved that it is possible to carry out an integrated optimization, considering the costs inherent to mining and the cost of the geomechanical performance, reducing the need for secondary support compared to the engineer’s methodology.

下伏露天开采法中自上而下的开采顺序留下了支撑挖掘的肋柱,因此肋柱和止水带的稳定性使得稀释控制在这种方法中至关重要。这项工作介绍了一种综合方法,利用遗传算法对露天止水带和肋柱的布局进行净利润和地质力学优化。用户需要了解的参数包括:最小止水带尺寸、最小岩柱尺寸、可接受的最大稀释度以及可接受的最大岩柱失效百分比。建立一个利润函数,该函数能够为所分析的几何集合(包括地质力学性能)赋予经济价值。几何集的地质力学性能是通过 FLAC3D 软件中的自主数值模型获得的,其中包括支柱坍塌的平均百分比和潜在的稀释。该算法通过一个地下金矿采矿面板的案例研究进行了验证,该采矿面板采用自上而下的采矿顺序。与工程师的设计方法相比,两种方法的净利润增加了 8%,并考虑了 70% 的挂壁支撑效率。支柱失效的百分比降低了三倍。如果不考虑挂壁支护,净利润比工程师设计方法增加了 22%。所提出的方法证明,在考虑采矿固有成本和地质力学性能成本的情况下,可以进行综合优化,与工程师方法相比,减少了对二次支护的需求。
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引用次数: 0
Prediction of Ground Vibration at Surface for Ring Blasting in Sublevel Stoping Through Empirical Approach, k-Nearest Neighbor, and Random Forest Model 通过经验法、k-近邻法和随机森林模型预测分层停层环形爆破的地表地面振动
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-20 DOI: 10.1007/s42461-024-00976-6
Ashish Kumar Vishwakarma, Vivek Kumar Himanshu, Kaushik Dey

The accurate prediction of blast-induced ground vibration due to underground ring blasting is a prominent need for ensuring the safety of structures. Different site-specific empirical equations are available for the prediction of ground vibration. These empirical equations are best suited when the monitoring and blasting locations are present in the same medium. The change in the medium alters the behavior of wave propagation. Hence, existing empirical equations have limitations in peak particle velocity (PPV) prediction when the blasting location is an underground hard rock mine and the monitoring location is ground surface. This is because the underground metal mine comprises different levels having void in the form of excavated stope or paste-filled stope. It is very difficult to predict the magnitude of PPV on the surface in such instances. Therefore, this study has been carried out to predict the PPV at surface due to underground blasting. In this paper, PPV data was recorded at surface for 207-ring blasts. Furthermore, the PPV has also been measured at different underground locations for 47-ring blasts. Different empirical equations along with k-nearest neighbor (KNN) and random forest (RF) model of machine learning technique were developed for the prediction of PPV. Most of the empirical models have higher accuracy in the prediction of PPV at an underground location. This shows that scaled distance-based empirical predictors are best suited when the monitoring and blasting media are the same. However, the empirical models do not predict PPV accurately when the monitoring location is ground surface and the blast is conducted underground. The machine learning models are better suited for PPV prediction in such cases. Based on the analysis performed for the case study site, RF model predicts PPV at surface with the highest accuracy. The coefficient of determination and root mean square error for RF model used for predicting PPV at ground surface are 0.94 and 0.438 mm/s respectively. The RF-based model is also the best suited among all the models for predicting PPV at underground locations as well.

准确预测地下环形爆破引起的地面振动是确保结构安全的迫切需要。目前有不同的用于预测地面振动的现场经验方程。当监测点和爆破点处于同一介质中时,这些经验方程最为适用。介质的变化会改变波的传播行为。因此,当爆破地点为地下硬岩矿井,而监测地点为地表时,现有的经验方程在预测峰值颗粒速度 (PPV) 方面存在局限性。这是因为地下金属矿由不同层面组成,其空隙形式为挖掘的斜坡或糊状填充的斜坡。在这种情况下,很难预测地表 PPV 的大小。因此,本研究对地下爆破造成的地表 PPV 进行了预测。本文记录了 207 环爆破的地表 PPV 数据。此外,还在地下不同位置测量了 47 次环形爆破的 PPV。为预测 PPV,开发了不同的经验公式以及机器学习技术的 k-nearest neighbor(KNN)和随机森林(RF)模型。大多数经验模型在地下位置预测 PPV 的准确度较高。这表明,当监测介质和爆破介质相同时,基于比例距离的经验预测模型最合适。然而,当监测地点为地面而爆破在地下进行时,经验模型无法准确预测 PPV。在这种情况下,机器学习模型更适合预测 PPV。根据对案例研究地点进行的分析,射频模型预测地表 PPV 的准确度最高。用于预测地表 PPV 的射频模型的判定系数和均方根误差分别为 0.94 和 0.438 毫米/秒。基于射频的模型也是所有模型中最适合预测地下位置 PPV 的模型。
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引用次数: 0
3D Characterization of Internal Fractures in Rochester Ore Particles Crushed by Plant-Scale HPGR for Various Pressures Using High-Resolution X-Ray Computed Tomography 利用高分辨率 X 射线计算机断层扫描技术对不同压力下工厂规模 HPGR 碾碎的罗切斯特矿石颗粒内部裂缝进行三维表征
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-20 DOI: 10.1007/s42461-024-00981-9
Amanda N. Erskine, Jiaqi Jin, Chen-Luh Lin, Jan D. Miller, Shijie Wang

Recovery of metals from coarse ore particles is a great challenge for heap leaching operations of low-grade precious metal resources. Internal fractures of ore particles like micro-cracks can facilitate subsurface transportation of solution inside particles and leaching of valuable minerals. A plant-scale high-pressure grinding roll (HPGR) unit at Coeur Mining’s Rochester mine was operated at selected specific pressures to crush and prepare various products for crack analysis using high-resolution X-ray computed tomography (XCT). 3D shapes of cracks inside ore particles for selected size fractions reveal different damage mechanisms during HPGR crushing regarding particle size and crushing pressure. Close-to-surface cracks formed by abrasion were found in small 2.5 mm particles. Impact cracks with a high aspect ratio were found in particles of larger size and higher HPGR pressure. The volumetric percentage of internal fractures and the specific crack surface areas of selected ore particles are compared to give quantitative conclusions on particle damage by compression during HPGR crushing.

从粗矿石颗粒中回收金属是低品位贵金属资源堆浸作业面临的巨大挑战。矿石颗粒的内部裂缝(如微裂缝)可促进溶液在颗粒内部的地下传输,并促进有价值矿物的沥滤。Coeur Mining 公司罗切斯特矿的工厂规模高压辊磨机 (HPGR) 在选定的特定压力下运行,以粉碎和制备各种产品,并使用高分辨率 X 射线计算机断层扫描 (XCT) 进行裂纹分析。选定粒度的矿石颗粒内部裂纹的三维形状揭示了 HPGR 破碎过程中与粒度和破碎压力有关的不同破坏机制。在 2.5 毫米的小颗粒中发现了由磨损形成的近表面裂纹。在粒度较大、HPGR 压力较高的颗粒中发现了高纵横比的冲击裂纹。通过比较选定矿石颗粒内部裂缝的体积百分比和特定裂缝表面积,可以得出关于 HPGR 破碎过程中颗粒受挤压破坏的定量结论。
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引用次数: 0
Mechanical Behaviour and Liquefaction Susceptibility of Tailings: A Case of Gold Tailings 尾矿的力学行为和液化敏感性:黄金尾矿案例
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-19 DOI: 10.1007/s42461-024-00978-4
Ismail Adeniyi Okewale, Hendrik Grobler

Significant factors believed to be responsible for tailings dam failure which can lead to loss of lives, destruction of properties and assets or damage to the environment are the mechanics of material characteristics and static liquefaction. It is therefore essential to understand the tendency for the likely occurrence of liquefaction in tailings dam as well as mechanics behind the behaviour of this tailing materials (inevitable products of ore mining, mineral and metallurgical processes). This study aims to present the mechanical behaviour and susceptibility to liquefaction of a gold tailings sample. Series of oedometer tests were conducted to determine the compression behaviour and the possibility of transitional behaviour or not. Index and physical tests were conducted to determine engineering grading descriptors which was directly linked to compression behaviour and comparisons made with other tailings. Microstructure was studied to understand the effects of fabric on the behaviour of samples and the chemical composition and mineralogy were also investigated. The compression paths slowly converge and the gold tailings might be said to be less transitional. The gold tailing is less dependent on initial state. The loosest gold tailing is more susceptible to liquefaction and compared to other gold tailings, this sample is less susceptible to liquefaction.

尾矿坝溃坝可能导致生命损失、财产和资产毁坏或环境破坏,据信造成尾矿坝溃坝的重要因素是材料特性的力学和静态液化。因此,了解尾矿坝可能发生液化的趋势以及尾矿材料(矿石开采、矿物和冶金过程的必然产物)行为背后的力学原理至关重要。本研究旨在介绍一种黄金尾矿样本的力学行为和液化易感性。为了确定压缩行为和是否存在过渡行为的可能性,进行了一系列气压计测试。还进行了指数和物理测试,以确定与压缩行为直接相关的工程分级描述符,并与其他尾矿进行比较。对微观结构进行了研究,以了解织物对样本行为的影响,同时还对化学成分和矿物学进行了调查。压缩路径缓慢收敛,可以说金尾矿的过渡性较弱。金尾矿对初始状态的依赖性较小。最松散的金尾矿更容易发生液化,与其他金尾矿相比,该样本不易发生液化。
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引用次数: 0
CFD Study on Improvement of Non-uniform Stirring in a Large Bottom-Blown Copper Smelting Furnace 关于改进大型底吹铜熔炼炉中不均匀搅拌的 CFD 研究
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-10 DOI: 10.1007/s42461-024-00968-6
Wei Wang, Liangzhao Mu, Hongliang Zhao, Xiaoyi Cai, Fengqin Liu, Hong Yong Sohn

The bottom-blown smelting technology has been widely adopted in non-ferrous metal smelting industries. The largest bottom-blown smelting furnace used in copper smelting was numerically simulated to improve the stirring effect in the molten bath by optimizing the oxygen injector arrangement and blowing parameters. The results show that a small injector spacing leads to gas jet coalescence, which is detrimental for smelting efficiency, increases copper loss and shortens furnace service life. Three schemes were proposed to improve the uneven stirring and reduce the gas jet coalescence by increasing the axial spacing of the injectors, the radial installation angle and the gas injection angle. Changing the axial spacing of the injectors can significantly reduce the gas jet coalescence, yielding the best stirring effect. The results of simulation suggested that when the axial spacing of the injectors was increased from 0.380 m to 0.610 m, the mean melt velocity in the mixing zone increased to 0.243 m/s, which was 20.9% higher than that before the optimization. Meanwhile the (varvec{RSD}) (relative standard spatial deviation of melt velocity) decreased from 123% to 84%. In the actual production, the matte content in the smelting slag decreased from 6.57% to 3.12% after changing the axial spacing of the injectors from 0.380 m to 0.610 m.

有色金属冶炼行业已广泛采用底吹熔炼技术。对铜冶炼中使用的最大底吹熔炼炉进行了数值模拟,通过优化氧气喷射器布置和吹炼参数来改善熔池中的搅拌效果。结果表明,喷射器间距过小会导致气体喷射凝聚,不利于熔炼效率,增加铜损耗,缩短熔炉使用寿命。我们提出了三种方案,通过增加喷射器的轴向间距、径向安装角度和气体喷射角度来改善不均匀搅拌和减少气体喷射凝聚。改变喷射器的轴向间距可显著减少气体喷射凝聚,获得最佳搅拌效果。模拟结果表明,当喷射器的轴向间距从 0.380 米增加到 0.610 米时,混合区的平均熔体速度增加到 0.243 米/秒,比优化前提高了 20.9%。同时,熔体速度的相对标准空间偏差从 123% 降至 84%。在实际生产中,将喷射器的轴向间距从 0.380 米改为 0.610 米后,冶炼渣中的锍含量从 6.57% 降至 3.12%。
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引用次数: 0
Exploring the Behavior of Quartz-Glauconite-Phosphate Flotation System 探索石英-白云石-磷酸盐浮选系统的行为
IF 1.9 4区 工程技术 Q2 Materials Science Pub Date : 2024-04-05 DOI: 10.1007/s42461-024-00973-9
O. M. Asem, A. A. El-Midany, M. F. Abadir, S. E. El-Mofty

Glauconite is a clay mineral that is most probably mined with phosphate and represents a challenge for phosphate upgrading by flotation. Reverse flotation is a common method for removing silica and silicate from siliceous phosphate. Thus, a systemic study was conducted to determine the effect of clay and its interactions with siliceous phosphate ore components on its cleaning by flotation. The flotation of each mineral (phosphate, quartz, and clay) was tested in terms of product recovery using quaternary amine at pH 9. In addition, the settling behavior of each mineral was investigated with and without quaternary amine. Binary and tertiary systems were studied to investigate the interactions between the main ore-containing minerals. The results of each mineral flotation test showed that quartz has the highest floatability, with low floatability of both phosphate and glauconite by quaternary amine. The presence of glauconite does not affect the phosphate recovery, whereas glauconite reduces the quartz floatability, which deteriorates the quartz removal from phosphate. Finally, the interaction mechanisms in the different systems are illustrated.

芒硝是一种粘土矿物,很可能与磷酸盐一起开采,是浮选法提升磷酸盐的难题。反浮选是从硅质磷酸盐中去除二氧化硅和硅酸盐的常用方法。因此,我们进行了一项系统研究,以确定粘土及其与硅质磷矿成分的相互作用对浮选法净化磷矿的影响。在 pH 值为 9 的条件下,使用季胺测试了每种矿物(磷酸盐、石英和粘土)的浮选产品回收率。研究了二元和三元系统,以调查主要含矿矿物之间的相互作用。每种矿物的浮选试验结果表明,石英的可浮性最高,而磷酸盐和青金石在季胺作用下的可浮性较低。青金石的存在并不影响磷酸盐的回收,而青金石会降低石英的可浮性,从而恶化石英从磷酸盐中的去除效果。最后,说明了不同系统中的相互作用机制。
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Mining, Metallurgy & Exploration
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