首页 > 最新文献

Mining, Metallurgy & Exploration最新文献

英文 中文
The Value of Drilling—A Chance-Constrained Optimization Approach 钻探的价值--机会约束优化方法
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-22 DOI: 10.1007/s42461-024-01061-8
Rick Jeuken, Michael Forbes

Managing uncertainty is a core challenge in mine planning. Mine planners often represent various planning variables, such as equipment performance and geological parameters, as random variables due to inherent uncertainties. This paper looks at geological uncertainty and its impact on mine planning. Some traditional approaches to manage this uncertainty include using conditional simulations or mathematical programming in the planning process. Drilling additional holes, despite its cost, is a common method to reduce uncertainty using additional samples to reduce deposit variance. In this paper, we first outline an ore blending optimization model which uses chance-constrained programming to manage property limit risk when selecting the order of ore feed into a processing facility. In coal mining, in tactical planning horizons, the order of coal seam removal is usually predetermined, allowing a blending model to ensure optimal feed properties. Using chance-constrained programming allows us to blend the uncertainties from geological models to maximize plant output while adhering to property constraints. We use the chance-constrained blending model to determine the value of additional information from infill drilling. The model prioritizes drilling locations that reduce uncertainty and improve blending outcomes. A case study on a coking coal mine in Queensland, Australia, demonstrates the model’s application, highlighting significant improvements in blending by reducing the variance of high-quality blocks. The study concludes that targeting high-quality blocks for variance reduction can better accommodate lower-quality material, offering a more valuable approach than the traditional focus of reducing uncertainty in low-quality blocks. This approach provides insights for improving mine planning strategies and showcases the potential of chance constraints in optimizing ore blending under uncertainty.

管理不确定性是矿山规划的核心挑战。由于固有的不确定性,矿山规划人员通常将设备性能和地质参数等各种规划变量表示为随机变量。本文探讨地质不确定性及其对矿山规划的影响。管理这种不确定性的一些传统方法包括在规划过程中使用条件模拟或数学编程。钻探额外的钻孔尽管成本高昂,但却是利用额外样本减少不确定性以降低矿床差异的常用方法。在本文中,我们首先概述了一种矿石混合优化模型,该模型在选择进入选矿设施的矿石给料顺序时,使用机会受限编程来管理属性限制风险。在煤矿开采中,在战术规划范围内,煤层采掘顺序通常是预先确定的,因此可以使用混矿模型来确保最佳给矿特性。利用机会约束编程,我们可以混合地质模型的不确定性,在遵守属性约束的同时,最大限度地提高工厂产量。我们使用机会约束混合模型来确定填充钻探的额外信息的价值。该模型可优先选择可减少不确定性并改善混煤结果的钻探位置。对澳大利亚昆士兰炼焦煤矿的案例研究证明了该模型的应用,通过减少优质区块的差异,显著改善了混合效果。研究得出结论,针对优质区块减少差异可以更好地适应低质材料,提供了比传统的减少低质区块不确定性更有价值的方法。这种方法为改进矿山规划战略提供了启示,并展示了机会约束在不确定情况下优化矿石混合的潜力。
{"title":"The Value of Drilling—A Chance-Constrained Optimization Approach","authors":"Rick Jeuken, Michael Forbes","doi":"10.1007/s42461-024-01061-8","DOIUrl":"https://doi.org/10.1007/s42461-024-01061-8","url":null,"abstract":"<p>Managing uncertainty is a core challenge in mine planning. Mine planners often represent various planning variables, such as equipment performance and geological parameters, as random variables due to inherent uncertainties. This paper looks at geological uncertainty and its impact on mine planning. Some traditional approaches to manage this uncertainty include using conditional simulations or mathematical programming in the planning process. Drilling additional holes, despite its cost, is a common method to reduce uncertainty using additional samples to reduce deposit variance. In this paper, we first outline an ore blending optimization model which uses chance-constrained programming to manage property limit risk when selecting the order of ore feed into a processing facility. In coal mining, in tactical planning horizons, the order of coal seam removal is usually predetermined, allowing a blending model to ensure optimal feed properties. Using chance-constrained programming allows us to blend the uncertainties from geological models to maximize plant output while adhering to property constraints. We use the chance-constrained blending model to determine the value of additional information from infill drilling. The model prioritizes drilling locations that reduce uncertainty and improve blending outcomes. A case study on a coking coal mine in Queensland, Australia, demonstrates the model’s application, highlighting significant improvements in blending by reducing the variance of high-quality blocks. The study concludes that targeting high-quality blocks for variance reduction can better accommodate lower-quality material, offering a more valuable approach than the traditional focus of reducing uncertainty in low-quality blocks. This approach provides insights for improving mine planning strategies and showcases the potential of chance constraints in optimizing ore blending under uncertainty.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"1 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting the Stability of Rock Slopes in the Presence of Diverse Joint Networks and External Factors Using Machine Learning Algorithms 利用机器学习算法预测存在不同连接网络和外部因素的岩石斜坡的稳定性
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-19 DOI: 10.1007/s42461-024-01060-9
Sudhir Kumar Singh, Subodh Kumar, Debashish Chakravarty

The presence of joints in rocks significantly impacts the mechanical behavior and stability of a slope. A better comprehension of the relationship between jointed rock masses and slope stability has been made possible by recent advances in machine learning algorithms and numerical modelling. The purpose of this research is to predict the stability of slopes in the presence of different types of joints (parallel deterministic, cross jointed, Baecher, Veneziano, and Voronoi) with the help of classification-based machine learning algorithms. In order to achieve this goal, 40,290 different cases have been utilized, following numerical simulation using shear strength reduction (SSR) technique in RS2. Geomechanical properties, parameters defining slope geometry, structural properties of joints including properties of filling materials, and the influence of certain external factors have been considered. For these datasets, classification algorithms such as random forest, k-nearest neighbor, support vector machine, logistic regression, decision tree, and Naive Bayes have been utilized. Additionally, the synthetic minority oversampling technique (SMOTE) has been implemented in order to address imbalanced class problems. The results exhibit an encouraging level of accuracy, with random forest and decision tree both achieving 0.98 as an overall accuracy.

岩石中存在的节理会对斜坡的机械行为和稳定性产生重大影响。近年来,机器学习算法和数值建模技术的进步使人们能够更好地理解节理岩体与边坡稳定性之间的关系。本研究的目的是在基于分类的机器学习算法的帮助下,预测存在不同类型节理(平行确定性节理、交叉节理、Baecher 节理、Veneziano 节理和 Voronoi 节理)时斜坡的稳定性。为了实现这一目标,在 RS2 中使用剪切强度降低(SSR)技术进行数值模拟后,利用了 40,290 个不同的案例。其中考虑了地质力学特性、定义斜坡几何形状的参数、接缝的结构特性(包括填充材料的特性)以及某些外部因素的影响。对于这些数据集,采用了随机森林、k-近邻、支持向量机、逻辑回归、决策树和奈维贝叶斯等分类算法。此外,还采用了合成少数超采样技术(SMOTE)来解决不平衡类问题。结果表明,随机森林和决策树的总体准确率都达到了 0.98,准确率水平令人鼓舞。
{"title":"Predicting the Stability of Rock Slopes in the Presence of Diverse Joint Networks and External Factors Using Machine Learning Algorithms","authors":"Sudhir Kumar Singh, Subodh Kumar, Debashish Chakravarty","doi":"10.1007/s42461-024-01060-9","DOIUrl":"https://doi.org/10.1007/s42461-024-01060-9","url":null,"abstract":"<p>The presence of joints in rocks significantly impacts the mechanical behavior and stability of a slope. A better comprehension of the relationship between jointed rock masses and slope stability has been made possible by recent advances in machine learning algorithms and numerical modelling. The purpose of this research is to predict the stability of slopes in the presence of different types of joints (parallel deterministic, cross jointed, Baecher, Veneziano, and Voronoi) with the help of classification-based machine learning algorithms. In order to achieve this goal, 40,290 different cases have been utilized, following numerical simulation using shear strength reduction (SSR) technique in RS2. Geomechanical properties, parameters defining slope geometry, structural properties of joints including properties of filling materials, and the influence of certain external factors have been considered. For these datasets, classification algorithms such as random forest, k-nearest neighbor, support vector machine, logistic regression, decision tree, and Naive Bayes have been utilized. Additionally, the synthetic minority oversampling technique (SMOTE) has been implemented in order to address imbalanced class problems. The results exhibit an encouraging level of accuracy, with random forest and decision tree both achieving 0.98 as an overall accuracy.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"285 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of Crown Pillar Thickness in the Stress Relaxation Zone Surrounding Sub-Level Open Stopes 优化地下露天止水带周围应力松弛区的冠状柱厚度
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-14 DOI: 10.1007/s42461-024-01058-3
Vishal Babu Guggari, Gnananandh Budi

The excavation of steeply dipping ore deposits using sub-level mining techniques with delayed backfill can cause stress relaxation and concentration in the stope hanging wall and footwall at deeper depths. Designing adequate crown pillars that can withstand significant horizontal stress and prevent the collapse of the hanging wall and footwall is crucial for ensuring safe mining operations. This study developed a methodology for predicting the appropriate crown pillar thickness for depths between 510 and 1000 m based on 240 non-linear numerical models with Mohr–coulomb elastoplastic failure criteria under plane strain conditions with five parameters affecting crown pillar stability. A precise and reliable empirical equation has been devised to compute the safety factor (SF) of the crown pillar. The equation has a high predictive capability with an R2 value of 0.85. Design charts were developed for various geo-mining conditions and working depths to estimate the optimal crown pillar thickness.

使用延迟回填的底层采矿技术挖掘陡倾角矿床时,可能会在较深的斜坡悬壁和底壁上造成应力松弛和集中。设计能承受巨大水平应力并防止悬壁和底壁坍塌的适当顶柱对于确保采矿作业安全至关重要。本研究基于 240 个非线性数值模型,采用平面应变条件下的莫尔-库仑弹塑性破坏标准,并结合影响冠状支柱稳定性的五个参数,开发了一套方法,用于预测深度在 510 米至 1000 米之间的冠状支柱的适当厚度。设计了一个精确可靠的经验方程来计算冠状支柱的安全系数(SF)。该方程具有较高的预测能力,R2 值为 0.85。针对不同的地质采矿条件和工作深度绘制了设计图表,以估算最佳冠状支柱厚度。
{"title":"Optimization of Crown Pillar Thickness in the Stress Relaxation Zone Surrounding Sub-Level Open Stopes","authors":"Vishal Babu Guggari, Gnananandh Budi","doi":"10.1007/s42461-024-01058-3","DOIUrl":"https://doi.org/10.1007/s42461-024-01058-3","url":null,"abstract":"<p>The excavation of steeply dipping ore deposits using sub-level mining techniques with delayed backfill can cause stress relaxation and concentration in the stope hanging wall and footwall at deeper depths. Designing adequate crown pillars that can withstand significant horizontal stress and prevent the collapse of the hanging wall and footwall is crucial for ensuring safe mining operations. This study developed a methodology for predicting the appropriate crown pillar thickness for depths between 510 and 1000 m based on 240 non-linear numerical models with Mohr–coulomb elastoplastic failure criteria under plane strain conditions with five parameters affecting crown pillar stability. A precise and reliable empirical equation has been devised to compute the safety factor (<i>SF</i>) of the crown pillar. The equation has a high predictive capability with an <i>R</i><sup>2</sup> value of 0.85. Design charts were developed for various geo-mining conditions and working depths to estimate the optimal crown pillar thickness.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"65 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Gaussian Process Regression for Bench Blasting Rock Fragmentation Prediction and Optimization at Wolongan Open-Pit Mine 卧龙岗露天矿台阶爆破岩石破碎预测与优化中的高斯过程回归应用
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-14 DOI: 10.1007/s42461-024-01050-x
Eric Munene Kinyua, Zhang Jianhua, Gang Huang, Randriamamphionona M. Dinaniaina, Richard M. Kasomo, Sami Ullah

This study developed a Gaussian process regression (GPR) model to predict and optimize blast fragmentation at Wolongan Mine by using the primary data from the mine and secondary data from other mines. The blast data comprised 125 datasets, each containing seven blast design parameters as inputs and the muckpile mean fragment size as the model output. Additionally, the study developed artificial neural networks (ANNs), support vector regression (SVR), and multiple linear regression (MLR) models, and compared their prediction performances with the GPR model. The models’ accuracies were evaluated using five statistical metrics, including coefficient of determination (({R}^{2})), root mean square error (RMSE), variance accounted for (VAF), mean absolute bias error (MABE), and mean absolute percentage error (MAPE). The GPR model outperformed the other models, with ({R}^{2}), RMSE, VAF, MABE, and MAPE values of 0.9302, 0.0487, 93.2670, 0.0383, and 13.9405, respectively, for the test data. Based on the top-down correlation and Kendall’s coefficient of concordance analyses on the four sensitivity analysis methods used, the study found that the in situ block size and Young’s modulus of the rock were the most important parameters affecting fragmentation. Using the GPR model, the study showed that reducing the blast burden by 13–23% could decrease the mean fragment size of the muckpile at Wolongan Mine by 6–12%, leading to a significant reduction in the percentage of boulders.

本研究利用卧龙庵煤矿的原始数据和其他煤矿的二手数据,建立了一个高斯过程回归(GPR)模型,用于预测和优化卧龙庵煤矿的爆破破碎率。爆破数据由 125 个数据集组成,每个数据集包含七个爆破设计参数作为输入,泥堆平均破碎尺寸作为模型输出。此外,研究还开发了人工神经网络 (ANN)、支持向量回归 (SVR) 和多元线性回归 (MLR) 模型,并将其预测性能与 GPR 模型进行了比较。研究使用五个统计指标评估了模型的准确性,包括决定系数(({R}^{2}))、均方根误差(RMSE)、方差占比(VAF)、平均绝对偏差误差(MABE)和平均绝对百分比误差(MAPE)。对于测试数据,GPR 模型的 ({R}^{2})、RMSE、VAF、MABE 和 MAPE 值分别为 0.9302、0.0487、93.2670、0.0383 和 13.9405,优于其他模型。根据对所使用的四种灵敏度分析方法进行的自上而下的相关性和 Kendall 协整系数分析,研究发现原位块度和岩石的杨氏模量是影响破碎的最重要参数。通过使用 GPR 模型,研究表明减少 13-23% 的爆破负荷可使卧龙庵矿区泥石堆的平均碎块尺寸减少 6-12%,从而显著降低巨石的比例。
{"title":"Application of Gaussian Process Regression for Bench Blasting Rock Fragmentation Prediction and Optimization at Wolongan Open-Pit Mine","authors":"Eric Munene Kinyua, Zhang Jianhua, Gang Huang, Randriamamphionona M. Dinaniaina, Richard M. Kasomo, Sami Ullah","doi":"10.1007/s42461-024-01050-x","DOIUrl":"https://doi.org/10.1007/s42461-024-01050-x","url":null,"abstract":"<p>This study developed a Gaussian process regression (GPR) model to predict and optimize blast fragmentation at Wolongan Mine by using the primary data from the mine and secondary data from other mines. The blast data comprised 125 datasets, each containing seven blast design parameters as inputs and the muckpile mean fragment size as the model output. Additionally, the study developed artificial neural networks (ANNs), support vector regression (SVR), and multiple linear regression (MLR) models, and compared their prediction performances with the GPR model. The models’ accuracies were evaluated using five statistical metrics, including coefficient of determination (<span>({R}^{2})</span>), root mean square error (RMSE), variance accounted for (VAF), mean absolute bias error (MABE), and mean absolute percentage error (MAPE). The GPR model outperformed the other models, with <span>({R}^{2})</span>, RMSE, VAF, MABE, and MAPE values of 0.9302, 0.0487, 93.2670, 0.0383, and 13.9405, respectively, for the test data. Based on the top-down correlation and Kendall’s coefficient of concordance analyses on the four sensitivity analysis methods used, the study found that the in situ block size and Young’s modulus of the rock were the most important parameters affecting fragmentation. Using the GPR model, the study showed that reducing the blast burden by 13–23% could decrease the mean fragment size of the muckpile at Wolongan Mine by 6–12%, leading to a significant reduction in the percentage of boulders.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"38 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Incorporating Operational Modes into long-Term Open-Pit Mine Planning Under Geological Uncertainty: An Optimization Combining Variable Neighborhood Descent with Linear Programming 在地质不确定性条件下将运营模式纳入露天矿长期规划:可变邻域后裔与线性规划相结合的优化方法
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-13 DOI: 10.1007/s42461-024-01052-9
Aldo Quelopana, Alessandro Navarra

Sophisticated models have progressively been developed to address the challenges related to long-term, open-pit mine planning under conditions of geological uncertainty. Prior research has acknowledged that strategies for mine planning and the design of mineral concentrators are interdependent; thus, it is highly desirable to optimize them together. However, achieving detailed holistic optimization of the entire mineral value chain remains unresolved because of the inherent limitations associated with mathematical formulations and computational processing capacity. This paper details a method that contributes to bridging these limitations by employing a novel parallelized variable neighborhood descent approach combined with an embedded mass–balance component using linear programming techniques refined through Dantzig–Wolfe decomposition. This approach is exemplified through a case study of a gold deposit, which illustrates the enhanced performance capabilities of the new algorithm. The findings demonstrate significant improvements in the optimization process for mine planning, providing a stronger link between the mine’s output and processing plant’s capabilities.

为了应对地质不确定性条件下长期露天矿规划的挑战,人们逐步开发出了先进的模型。先前的研究已经认识到,矿山规划战略和选矿厂设计战略是相互依存的;因此,将二者结合起来进行优化是非常可取的。然而,由于数学公式和计算处理能力的固有限制,实现整个矿产价值链的详细整体优化仍是一个悬而未决的问题。本文详细介绍了一种有助于弥合这些限制的方法,即采用一种新颖的并行化变量邻域下降方法,结合嵌入式质量平衡组件,使用通过 Dantzig-Wolfe 分解精炼的线性规划技术。该方法通过对金矿的案例研究进行了示范,说明了新算法性能的增强。研究结果表明,矿山规划的优化过程有了明显改善,矿山产出与加工厂能力之间的联系更加紧密。
{"title":"Incorporating Operational Modes into long-Term Open-Pit Mine Planning Under Geological Uncertainty: An Optimization Combining Variable Neighborhood Descent with Linear Programming","authors":"Aldo Quelopana, Alessandro Navarra","doi":"10.1007/s42461-024-01052-9","DOIUrl":"https://doi.org/10.1007/s42461-024-01052-9","url":null,"abstract":"<p>Sophisticated models have progressively been developed to address the challenges related to long-term, open-pit mine planning under conditions of geological uncertainty. Prior research has acknowledged that strategies for mine planning and the design of mineral concentrators are interdependent; thus, it is highly desirable to optimize them together. However, achieving detailed holistic optimization of the entire mineral value chain remains unresolved because of the inherent limitations associated with mathematical formulations and computational processing capacity. This paper details a method that contributes to bridging these limitations by employing a novel parallelized variable neighborhood descent approach combined with an embedded mass–balance component using linear programming techniques refined through Dantzig–Wolfe decomposition. This approach is exemplified through a case study of a gold deposit, which illustrates the enhanced performance capabilities of the new algorithm. The findings demonstrate significant improvements in the optimization process for mine planning, providing a stronger link between the mine’s output and processing plant’s capabilities.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"62 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective Leaching and Separation of Uranium from Ochre-Umm Greifat, Red Sea Coast, Central Eastern Desert, Egypt 从埃及中东部沙漠红海沿岸的赭石-Umm Greifat 中选择性沥滤和分离铀
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-13 DOI: 10.1007/s42461-024-01019-w
El-Sayed A. Manaa, Soliman Abu Elatta Mahmoud, Elham Awny

The Ochre-Umm Greifat area is one of the Red Sea areas with high concentrations of iron and zinc, which is formed from hydrothermal solutions as a result of the structural activity that occurred in the Red Sea Zone during the Pleistocene period. These deposits are also accompanied by deposits of low- to high uranium grade. In addition to Zn, Pb, and Cu anomalies, particularly in fault zones and their branches affecting the study area, although there are numerous zinc minerals in the Ocher-Greifat area, uranium minerals are scarce, with only one mineral, compreignacite, being recorded and the majority of the uranium being present as an adsorbed element on iron and/or clay stones. In addition, uranothorite is extremely rare and occurs as fine grains embedded in rocks. A technological sample was taken from an iron-rich clay area in a fault zone and was found to assay 700-ppm uranium. The leachability of uranium from the used sample was investigated using an alkaline solution based on the chemical and mineralogical composition of the used sample. The selected ore is treated with Na2CO3 and NaHCO3 in the presence of H2O2 as oxidant. Many digestion factors are studied and optimized. Under the optimum leaching conditions, the uranium dissolution efficiency is around 84%. For the uranium separation, the pH of the leach liquor is adjusted at 10, then subjected to a solvent extraction step using 4% Aliquat®336/kerosene in the presence of isodecanol as third-phase prevention. The loaded organic solvent was then treated with NaOH/H2O2 solution as a stripping solution. Finally, the resultant solution is subjected to a precipitation step using ammonia solution.

赭石-乌姆-格雷法特地区是红海地区铁和锌含量较高的地区之一,这些矿藏是由于更新世时期红海区的构造活动而形成的热液。这些矿床还伴有低到高等级的铀矿床。除了锌、铅和铜异常,特别是在影响研究区域的断层带及其分支中,虽然在奥切尔-格里法特地区有大量的锌矿物,但铀矿物却很少,仅有一种矿物--孔雀石(compreignacite)被记录在案,大部分铀以吸附元素的形式存在于铁和/或粘土石上。此外,铀钍石极为罕见,仅以细粒形式存在于岩石中。从断层带富含铁的粘土区提取的技术样本发现,铀含量为 700ppm。根据所用样本的化学和矿物成分,使用碱性溶液对所用样本中铀的可浸出性进行了研究。选定的矿石在 H2O2 作为氧化剂的情况下,用 Na2CO3 和 NaHCO3 进行处理。对许多消化因素进行了研究和优化。在最佳浸出条件下,铀的溶解效率约为 84%。为了分离铀,先将浸出液的 pH 值调节为 10,然后使用 4% 的 Aliquat®336/ 煤油在异癸醇作为第三相防止剂的存在下进行溶剂萃取。然后用 NaOH/H2O2 溶液作为汽提溶液处理负载有机溶剂。最后,使用氨溶液对所得溶液进行沉淀处理。
{"title":"Selective Leaching and Separation of Uranium from Ochre-Umm Greifat, Red Sea Coast, Central Eastern Desert, Egypt","authors":"El-Sayed A. Manaa, Soliman Abu Elatta Mahmoud, Elham Awny","doi":"10.1007/s42461-024-01019-w","DOIUrl":"https://doi.org/10.1007/s42461-024-01019-w","url":null,"abstract":"<p>The Ochre-Umm Greifat area is one of the Red Sea areas with high concentrations of iron and zinc, which is formed from hydrothermal solutions as a result of the structural activity that occurred in the Red Sea Zone during the Pleistocene period. These deposits are also accompanied by deposits of low- to high uranium grade. In addition to Zn, Pb, and Cu anomalies, particularly in fault zones and their branches affecting the study area, although there are numerous zinc minerals in the Ocher-Greifat area, uranium minerals are scarce, with only one mineral, compreignacite, being recorded and the majority of the uranium being present as an adsorbed element on iron and/or clay stones. In addition, uranothorite is extremely rare and occurs as fine grains embedded in rocks. A technological sample was taken from an iron-rich clay area in a fault zone and was found to assay 700-ppm uranium. The leachability of uranium from the used sample was investigated using an alkaline solution based on the chemical and mineralogical composition of the used sample. The selected ore is treated with Na<sub>2</sub>CO<sub>3</sub> and NaHCO<sub>3</sub> in the presence of H<sub>2</sub>O<sub>2</sub> as oxidant. Many digestion factors are studied and optimized. Under the optimum leaching conditions, the uranium dissolution efficiency is around 84%. For the uranium separation, the pH of the leach liquor is adjusted at 10, then subjected to a solvent extraction step using 4% Aliquat<sup>®</sup>336/kerosene in the presence of isodecanol as third-phase prevention. The loaded organic solvent was then treated with NaOH/H<sub>2</sub>O<sub>2</sub> solution as a stripping solution. Finally, the resultant solution is subjected to a precipitation step using ammonia solution.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"2 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Underground Spot Cooling Installations—Context and Case Study 地下定点冷却装置--背景和案例研究
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-12 DOI: 10.1007/s42461-024-01054-7
Melissa Brown, Chris McGuire, Darryl Witow

This paper presents engineering design and equipment selection for a successful temporary spot cooling installation used to support underground shaft sinking. The cooling system operated over a 22-month period from August 2021 to June 2023. The need for cooling was driven by the depth of shaft sink, which started from greater than 1900 m below surface. The system was subject to many of the common challenges preventing the widespread use of underground spot cooling, including limited process water and dewatering capability, heat rejection equipment placement in the path of blasting fumes, limited airflow quantity for heat rejection, and layout constraints due to the existing and upcoming mine services installations and construction. Use of hybrid cooling towers allowed for increased heat rejection capacity from evaporative cooling while maintaining a fully closed-loop condenser water circuit. Skid-mounting of all components allowed for easy placement and relocation. Use of HDPE piping lashed to existing ground support allowed for maximum layout flexibility and minimized installation time. Performance, operational features, and additional lessons learned, including feedback from operations personnel, are shared.

本文介绍了用于支持地下竖井下沉的成功临时定点冷却装置的工程设计和设备选择。从 2021 年 8 月到 2023 年 6 月,冷却系统运行了 22 个月。井筒下沉深度从地表以下 1900 米以上开始,因此需要进行冷却。该系统面临着许多阻碍井下定点冷却广泛应用的常见挑战,包括工艺用水和脱水能力有限、排热设备放置在爆破烟雾路径上、排热气流数量有限,以及现有和即将进行的矿井服务设施安装和施工造成的布局限制。使用混合冷却塔可以提高蒸发冷却的排热能力,同时保持完全闭环的冷凝器水回路。所有组件均采用撬装式安装,便于安置和搬迁。高密度聚乙烯(HDPE)管道绑扎在现有的地面支撑上,实现了最大的布局灵活性,并最大限度地缩短了安装时间。此外,还分享了性能、运行特点和其他经验教训,包括运营人员的反馈意见。
{"title":"Underground Spot Cooling Installations—Context and Case Study","authors":"Melissa Brown, Chris McGuire, Darryl Witow","doi":"10.1007/s42461-024-01054-7","DOIUrl":"https://doi.org/10.1007/s42461-024-01054-7","url":null,"abstract":"<p>This paper presents engineering design and equipment selection for a successful temporary spot cooling installation used to support underground shaft sinking. The cooling system operated over a 22-month period from August 2021 to June 2023. The need for cooling was driven by the depth of shaft sink, which started from greater than 1900 m below surface. The system was subject to many of the common challenges preventing the widespread use of underground spot cooling, including limited process water and dewatering capability, heat rejection equipment placement in the path of blasting fumes, limited airflow quantity for heat rejection, and layout constraints due to the existing and upcoming mine services installations and construction. Use of hybrid cooling towers allowed for increased heat rejection capacity from evaporative cooling while maintaining a fully closed-loop condenser water circuit. Skid-mounting of all components allowed for easy placement and relocation. Use of HDPE piping lashed to existing ground support allowed for maximum layout flexibility and minimized installation time. Performance, operational features, and additional lessons learned, including feedback from operations personnel, are shared.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"15 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142183140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mean Block Size Prediction in Rock Blast Fragmentation Using TPE-Tree-Based Model Approach with SHapley Additive exPlanations 使用基于 TPE 树的模型方法和 SHapley 加性前规划预测岩石爆破碎裂中的平均碎块大小
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-08 DOI: 10.1007/s42461-024-01057-4
Madalitso Mame, Yingui Qiu, Shuai Huang, Kun Du, Jian Zhou

The optimum fragmentation size measures the quality of a blasting operation. Boulders or large fragments can result in more costs because they need secondary blasting, while small fragments can result in ore loss and dilution. Therefore, it is very significant to accurately predict the mean block size to reduce production costs and enhance efficiency. Due to the shortfalls of the empirical models, scholars have been inclined toward artificial intelligence (AI) techniques for fragmentation size prediction over the decades. Firstly, in this study, three tree-based models, i.e., the random forest (RF), extra-trees (ET), and CatBoost (CB), are employed for basic prediction. The model uses eight parameters, seven input parameters, and mean block size (MBS) as the output parameter. Secondly, their performance and hyper-parameters were fine-tuned using Bayesian optimization: tree-structured Parzen estimators (TPE) algorithm using Optuna. Among the three models, the TPE-ET model showed superior performance with the following metric scores on the training dataset: 0.9896, 0.0184, and 0.0003, and on the test dataset with the following metric scores: 0.9463, 0.0415, and 0.0017, i.e., R2, RMSE, and MSE, respectively. In conclusion, analysis by the SHapley Additive ExPlanations approach shows that elastic modulus significantly impacts the model’s prediction of rock fragmentation.

最佳破碎尺寸可衡量爆破作业的质量。大石块或大碎块会导致更多成本,因为它们需要二次爆破,而小碎块则会导致矿石流失和稀释。因此,准确预测平均碎块尺寸对降低生产成本和提高效率意义重大。由于经验模型的不足,几十年来,学者们一直倾向于采用人工智能(AI)技术来预测破碎粒度。首先,本研究采用了三种基于树的模型,即随机森林(RF)、额外树(ET)和 CatBoost(CB),进行基本预测。模型使用八个参数、七个输入参数和平均块大小(MBS)作为输出参数。其次,使用贝叶斯优化法对它们的性能和超参数进行了微调:使用 Optuna 的树状结构 Parzen 估计器(TPE)算法。在这三个模型中,TPE-ET 模型在训练数据集上表现出更优越的性能,其指标得分如下0.9896、0.0184 和 0.0003,在测试数据集上的指标得分分别为0.9463、0.0415 和 0.0017,即 R2、RMSE 和 MSE。总之,SHapley Additive ExPlanations 方法的分析表明,弹性模量对模型的岩石破碎预测有显著影响。
{"title":"Mean Block Size Prediction in Rock Blast Fragmentation Using TPE-Tree-Based Model Approach with SHapley Additive exPlanations","authors":"Madalitso Mame, Yingui Qiu, Shuai Huang, Kun Du, Jian Zhou","doi":"10.1007/s42461-024-01057-4","DOIUrl":"https://doi.org/10.1007/s42461-024-01057-4","url":null,"abstract":"<p>The optimum fragmentation size measures the quality of a blasting operation. Boulders or large fragments can result in more costs because they need secondary blasting, while small fragments can result in ore loss and dilution. Therefore, it is very significant to accurately predict the mean block size to reduce production costs and enhance efficiency. Due to the shortfalls of the empirical models, scholars have been inclined toward artificial intelligence (AI) techniques for fragmentation size prediction over the decades. Firstly, in this study, three tree-based models, i.e., the random forest (RF), extra-trees (ET), and CatBoost (CB), are employed for basic prediction. The model uses eight parameters, seven input parameters, and mean block size (MBS) as the output parameter. Secondly, their performance and hyper-parameters were fine-tuned using Bayesian optimization: tree-structured Parzen estimators (TPE) algorithm using Optuna. Among the three models, the TPE-ET model showed superior performance with the following metric scores on the training dataset: 0.9896, 0.0184, and 0.0003, and on the test dataset with the following metric scores: 0.9463, 0.0415, and 0.0017, i.e., <i>R</i><sup>2</sup>, RMSE, and MSE, respectively. In conclusion, analysis by the SHapley Additive ExPlanations approach shows that elastic modulus significantly impacts the model’s prediction of rock fragmentation.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"26 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141946428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
“From Intuition to Optimization: A Hybrid FAHP-MAUT Model for Informed R&D Investment Decision in Mining” "从直觉到优化:采矿业研发投资知情决策的 FAHP-MAUT 混合模型"
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-06 DOI: 10.1007/s42461-024-01053-8
Haton E. Alhamad, Saud M. Al-Mandil

The mining industry has traditionally relied on personal experience and intuition for decision-making since industry managers and leaders are faced with uncertainty, diverse options, and limited resources to make a more objective and rational decision. Multicriteria decision analysis (MCDA) techniques have been introduced to address this challenge, yet the existing methods often focus on simplicity rather than optimality. Therefore, this research aims to develop a hybrid model that combines fuzzy analytical hierarchy process (FAHP) with multi-attribute utility theory (MAUT) to help decision-makers achieve optimal results when faced with diverse investment opportunities and criteria. The study uses data from a private consulting firm. The report consists of 225 projects and 16 attributes. The statistical analysis was performed through SPSS, involving a t-test, one-way ANOVA, Pearson correlation, and regression analysis. FAHP and MAUT were performed via python programming and a sensitivity analysis was conducted to verify the validity of the data. The results demonstrate that the developed model can be utilized as a tool to mitigate subjectivity and provide a more objective and reliable ranking even in the long term. It also highlights the correlation between selected attributes and the context of investment opportunities. Attributes alone are necessary but not sufficient to influence rankings holistically. Ultimately, the study’s findings shed light on the interplay between attributes and investment contexts, emphasizing their interdependence. By adopting this uncommon model as a tool, decision-makers can make more informed choices and enhance their decision-making processes in the mining industry and other sectors.

采矿业传统上依赖个人经验和直觉进行决策,因为行业管理者和领导者面临着不确定性、多种选择和有限的资源,无法做出更加客观和理性的决策。为了应对这一挑战,人们引入了多标准决策分析(MCDA)技术,但现有的方法往往侧重于简单性而非最优性。因此,本研究旨在开发一种混合模型,将模糊分析层次分析法(FAHP)与多属性效用理论(MAUT)相结合,帮助决策者在面对不同的投资机会和标准时取得最优结果。研究使用了一家私营咨询公司的数据。报告包括 225 个项目和 16 个属性。统计分析通过 SPSS 进行,包括 t 检验、单向方差分析、皮尔逊相关性和回归分析。通过 python 编程执行了 FAHP 和 MAUT,并进行了敏感性分析以验证数据的有效性。结果表明,所开发的模型可以作为一种工具来减少主观性,并提供更加客观可靠的排名,即使从长远来看也是如此。它还强调了所选属性与投资机会背景之间的相关性。属性本身是必要的,但不足以影响整体排名。最终,研究结果揭示了属性与投资环境之间的相互作用,强调了它们之间的相互依存关系。通过采用这种不常见的模型作为工具,决策者可以在采矿业和其他行业做出更明智的选择,并改进其决策过程。
{"title":"“From Intuition to Optimization: A Hybrid FAHP-MAUT Model for Informed R&D Investment Decision in Mining”","authors":"Haton E. Alhamad, Saud M. Al-Mandil","doi":"10.1007/s42461-024-01053-8","DOIUrl":"https://doi.org/10.1007/s42461-024-01053-8","url":null,"abstract":"<p>The mining industry has traditionally relied on personal experience and intuition for decision-making since industry managers and leaders are faced with uncertainty, diverse options, and limited resources to make a more objective and rational decision. Multicriteria decision analysis (MCDA) techniques have been introduced to address this challenge, yet the existing methods often focus on simplicity rather than optimality. Therefore, this research aims to develop a hybrid model that combines fuzzy analytical hierarchy process (FAHP) with multi-attribute utility theory (MAUT) to help decision-makers achieve optimal results when faced with diverse investment opportunities and criteria. The study uses data from a private consulting firm. The report consists of 225 projects and 16 attributes. The statistical analysis was performed through SPSS, involving a <i>t</i>-test, one-way ANOVA, Pearson correlation, and regression analysis. FAHP and MAUT were performed via python programming and a sensitivity analysis was conducted to verify the validity of the data. The results demonstrate that the developed model can be utilized as a tool to mitigate subjectivity and provide a more objective and reliable ranking even in the long term. It also highlights the correlation between selected attributes and the context of investment opportunities. Attributes alone are necessary but not sufficient to influence rankings holistically. Ultimately, the study’s findings shed light on the interplay between attributes and investment contexts, emphasizing their interdependence. By adopting this uncommon model as a tool, decision-makers can make more informed choices and enhance their decision-making processes in the mining industry and other sectors.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"27 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141946429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Height Development Characteristics of Water-Conducting Fracture Zone in a Fully Mechanized Longwall Face with a Large Panel Width 大板宽全机械化长壁工作面导水断裂带的高度发展特征
IF 1.9 4区 工程技术 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-05 DOI: 10.1007/s42461-024-01049-4
Han Fang, Shuyun Zhu, Shengjun Zhang

To explore the height development characteristics of a water-conducting fracture zone (WCFZ) in a working face with a large panel width, a typical working face with a panel width of 330 m was used as the research background for this study. The lower limit of the height of the WCFZ was preliminarily determined via borehole televiewer observation, and the maximum height of the WCFZ in the working face was further determined via numerical simulation and empirical analysis. The prediction results obtained via the traditional empirical formulas are unsuitable for working faces with large panel widths. For the studied working face, considering its actual geological background, the deformation and failure characteristics of the overlying rock under six different panel width conditions were simulated via numerical simulation, and it was found that the height of the WCFZ exhibits a good natural logarithmic relationship with the panel width. On the basis of the statistics of data collected from 58 cases of fully mechanized coal faces with normal panel widths in the North China-type coal field, the applicability of the logarithmic variation in the in situ data was analysed and compared. The accuracy of the logarithmic variation was verified by theoretical analysis, revealing that the internal factor controlling this variation is the decrease in the burial depth of the unfractured rock stratum. The case study with the panel width of the working face of 330 m extends the applicability of the abovementioned variation to panel widths greater than 300 m in North China-type coalfields, and 300 m was proposed as the threshold panel width at which the development of the WCFZ slows. This variation can provide a reference for safe mining and optimum panel width determination under high-intensity mining conditions.

为了探索大板宽工作面导水断裂带(WCFZ)的高度发育特征,本研究以板宽330米的典型工作面为研究背景。通过钻孔遥视仪观测初步确定了 WCFZ 的下限高度,并通过数值模拟和经验分析进一步确定了工作面 WCFZ 的最大高度。通过传统经验公式得出的预测结果不适合板宽较大的工作面。针对所研究的工作面,结合其实际地质背景,通过数值模拟了六种不同面板宽度条件下的上覆岩石变形和破坏特征,发现 WCFZ 高度与面板宽度呈良好的自然对数关系。在对华北型煤田 58 个板宽正常的全机械化采煤工作面采集的数据进行统计的基础上,分析比较了对数变化在现场数据中的适用性。理论分析验证了对数变化的准确性,揭示了控制这种变化的内部因素是未破裂岩层埋深的减小。工作面面板宽度为 330 m 的案例研究将上述变化的适用范围扩大到华北型煤田大于 300 m 的面板宽度,并提出 300 m 为 WCFZ 发展减缓的临界面板宽度。这一变化可为高强度开采条件下的安全开采和最佳板宽确定提供参考。
{"title":"Height Development Characteristics of Water-Conducting Fracture Zone in a Fully Mechanized Longwall Face with a Large Panel Width","authors":"Han Fang, Shuyun Zhu, Shengjun Zhang","doi":"10.1007/s42461-024-01049-4","DOIUrl":"https://doi.org/10.1007/s42461-024-01049-4","url":null,"abstract":"<p>To explore the height development characteristics of a water-conducting fracture zone (WCFZ) in a working face with a large panel width, a typical working face with a panel width of 330 m was used as the research background for this study. The lower limit of the height of the WCFZ was preliminarily determined via borehole televiewer observation, and the maximum height of the WCFZ in the working face was further determined via numerical simulation and empirical analysis. The prediction results obtained via the traditional empirical formulas are unsuitable for working faces with large panel widths. For the studied working face, considering its actual geological background, the deformation and failure characteristics of the overlying rock under six different panel width conditions were simulated via numerical simulation, and it was found that the height of the WCFZ exhibits a good natural logarithmic relationship with the panel width. On the basis of the statistics of data collected from 58 cases of fully mechanized coal faces with normal panel widths in the North China-type coal field, the applicability of the logarithmic variation in the in situ data was analysed and compared. The accuracy of the logarithmic variation was verified by theoretical analysis, revealing that the internal factor controlling this variation is the decrease in the burial depth of the unfractured rock stratum. The case study with the panel width of the working face of 330 m extends the applicability of the abovementioned variation to panel widths greater than 300 m in North China-type coalfields, and 300 m was proposed as the threshold panel width at which the development of the WCFZ slows. This variation can provide a reference for safe mining and optimum panel width determination under high-intensity mining conditions.</p>","PeriodicalId":18588,"journal":{"name":"Mining, Metallurgy & Exploration","volume":"52 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141946430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Mining, Metallurgy & Exploration
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1