Pub Date : 2024-01-30DOI: 10.1007/s00126-024-01249-4
Abstract
The Zhazixi deposit hosted in sedimentary rocks is a major Sb-W deposit in South China. The mineral scheelite, which can be dated by the U-Pb method, commonly occurs in both tungsten (W)-dominated and antimony (Sb)-dominated ore veins of the deposit. Cathodoluminescence (CL) images reveal the presence of three distinct stages of scheelite (Sch-I, Sch-II and Sch-III) within the deposit. These three scheelites were dated using in-situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), yielding U-Pb ages of 158.1±5.4 Ma and 157.6 ± 4.9 Ma for Sch-I, 155 ± 11 Ma for Sch-II, and 151.3±6.1 Ma for Sch-III. These data suggest that the Zhazixi Sb-W deposit formed during the Late Jurassic (160–150 Ma) rather than the Late Triassic as previously suggested. Considering the temporal similarity with low-temperature hydrothermal Sb deposits in the Xiangzhong metallogenic province (XZMP), the formation of the Sb-W deposit may have followed a similar genetic model, where meteoric groundwater circulated to depth and extracted metals from fertile basement rocks through fluid-rock interaction, resulting in the generation of ore fluids. This study highlights that Late Jurassic low-temperature hydrothermal Sb-polymetallic mineralization in the XZMP is likely more extensive than previously perceived.
{"title":"Scheelite U–Pb dating constraints on the timing of the formation of the Zhazixi Sb-W deposit in South China","authors":"","doi":"10.1007/s00126-024-01249-4","DOIUrl":"https://doi.org/10.1007/s00126-024-01249-4","url":null,"abstract":"<h3>Abstract</h3> <p>The Zhazixi deposit hosted in sedimentary rocks is a major Sb-W deposit in South China. The mineral scheelite, which can be dated by the U-Pb method, commonly occurs in both tungsten (W)-dominated and antimony (Sb)-dominated ore veins of the deposit. Cathodoluminescence (CL) images reveal the presence of three distinct stages of scheelite (Sch-I, Sch-II and Sch-III) within the deposit. These three scheelites were dated using in-situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), yielding U-Pb ages of 158.1±5.4 Ma and 157.6 ± 4.9 Ma for Sch-I, 155 ± 11 Ma for Sch-II, and 151.3±6.1 Ma for Sch-III. These data suggest that the Zhazixi Sb-W deposit formed during the Late Jurassic (160–150 Ma) rather than the Late Triassic as previously suggested. Considering the temporal similarity with low-temperature hydrothermal Sb deposits in the Xiangzhong metallogenic province (XZMP), the formation of the Sb-W deposit may have followed a similar genetic model, where meteoric groundwater circulated to depth and extracted metals from fertile basement rocks through fluid-rock interaction, resulting in the generation of ore fluids. This study highlights that Late Jurassic low-temperature hydrothermal Sb-polymetallic mineralization in the XZMP is likely more extensive than previously perceived.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139644119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-17DOI: 10.1007/s00126-023-01243-2
Le Wang, Ming-Jian Cao, Shen Gao, Massimo Chiaradia, Pete Hollings, Ke-Zhang Qin, Xin-Yu Zou, Guo-Xue Song, Xu-Yong Pang, Guang-Ming Li
The origin of propylitic fluids in intermediate sulfidation mineralization has not been investigated in detail. Here, we present an extensive petrographic, geochemical, and isotopic (O-H-Sr) study of propylitic epidote, chlorite, and calcite from the Zhengguang intermediate sulfidation epithermal Au-Zn deposit, NE China. Propylitic minerals can be divided into three main types based on their different textural occurrences, namely interstitial cement of clasts of hydrothermal breccia, replacement of primary plagioclase or hornblende, and vein infill of cracks, with late, minor calcite as amygdules in vesicles of andesite representing a fourth textural occurrence. The H-O isotope compositions and mass balance calculations suggest that most propylitic epidote records a dominant (> 50%) contribution of magmatic fluids. The decrease of the average δ18({mathrm O}_{{mathrm H}_2mathrm O};)values equilibrated with different types of epidote (cement 6.8 ± 0.7‰, replacement 5.1 ± 1.1‰, vein 4.5 ± 1.4‰, 1 SD), and the decreasing content of high-temperature elements (e.g., Cu-Mo) from cement, through replacement to vein epidote and chlorite, collectively indicates a decreasing role of magmatic fluids. Replacement epidote and chlorite are enriched in Sr-Mn-Y-Sb, whereas replacement epidote and calcite record similar (87Sr/86Sr)i values to the andesitic host rock, suggesting that replacement minerals inherit certain elements from plagioclase and hornblende, and the Sr isotope signature of the wall rocks. We highlight that propylitic alteration in epithermal deposits can involve significant proportions of magmatic fluids and texturally different alteration mineral types should be considered when using mineral isotopic or chemical compositions to track fluid sources or to vector towards the location of intrusive centers.
{"title":"The magmatic origin of propylitic alteration of the Zhengguang epithermal Au-Zn deposit, Heilongjiang, China: evidence from mineral compositions and H–O-Sr isotopes","authors":"Le Wang, Ming-Jian Cao, Shen Gao, Massimo Chiaradia, Pete Hollings, Ke-Zhang Qin, Xin-Yu Zou, Guo-Xue Song, Xu-Yong Pang, Guang-Ming Li","doi":"10.1007/s00126-023-01243-2","DOIUrl":"https://doi.org/10.1007/s00126-023-01243-2","url":null,"abstract":"<p>The origin of propylitic fluids in intermediate sulfidation mineralization has not been investigated in detail. Here, we present an extensive petrographic, geochemical, and isotopic (O-H-Sr) study of propylitic epidote, chlorite, and calcite from the Zhengguang intermediate sulfidation epithermal Au-Zn deposit, NE China. Propylitic minerals can be divided into three main types based on their different textural occurrences, namely interstitial cement of clasts of hydrothermal breccia, replacement of primary plagioclase or hornblende, and vein infill of cracks, with late, minor calcite as amygdules in vesicles of andesite representing a fourth textural occurrence. The H-O isotope compositions and mass balance calculations suggest that most propylitic epidote records a dominant (> 50%) contribution of magmatic fluids. The decrease of the average δ<sup>18</sup><span>({mathrm O}_{{mathrm H}_2mathrm O};)</span>values equilibrated with different types of epidote (cement 6.8 ± 0.7‰, replacement 5.1 ± 1.1‰, vein 4.5 ± 1.4‰, 1 SD), and the decreasing content of high-temperature elements (e.g., Cu-Mo) from cement, through replacement to vein epidote and chlorite, collectively indicates a decreasing role of magmatic fluids. Replacement epidote and chlorite are enriched in Sr-Mn-Y-Sb, whereas replacement epidote and calcite record similar (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> values to the andesitic host rock, suggesting that replacement minerals inherit certain elements from plagioclase and hornblende, and the Sr isotope signature of the wall rocks. We highlight that propylitic alteration in epithermal deposits can involve significant proportions of magmatic fluids and texturally different alteration mineral types should be considered when using mineral isotopic or chemical compositions to track fluid sources or to vector towards the location of intrusive centers.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139489427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-13DOI: 10.1007/s00126-023-01242-3
Pan-Pan Niu, Manuel Muñoz, Olivier Mathon, Suo-Fei Xiong, Shao-Yong Jiang
The world-class Huize deposit hosts significant germanium (Ge) resources in the Sichuan–Yunan–Guizhou (SYG) Mississippi Valley-type (MVT) Pb–Zn province of China. The distribution and enrichment mechanism of Ge is still poorly understood. In the main ore-forming stage of Huize, we identified six sphalerite colors from C1 (black) to C6 (white) in transmitted light. Two color sequences are confirmed, including C1 → C2 → C3 → C6 and C1 → C2 → C4 → C5 → C6. We used multiple analytical methods to reveal the Ge distribution and incorporation mechanism into sphalerite and the possible enrichment factors. Our results show that Ge occurs as argutite (GeO2), and in the sphalerite crystal lattice, C1 and C3 sphalerite has up to 593 ppm Ge. Two substitution mechanisms, i.e., Ge4+ + □(vacancy) → 2Zn2+ (e.g., C1 and C2) and Ge4+ + 2Cu+ → 3Zn2+ (e.g., C2, C3, C4, and C5), are inferred from the Huize sphalerite. They show different spatial structures of sphalerite and a weak shift of the white line observed by high-resolution X-ray absorption near-edge structure (XANES) spectroscopy. The trace-element composition of sphalerite suggests that reduced sulfur content of the ore-forming fluid contributes to Ge enrichment, followed by high temperature (> 300 °C).
{"title":"Mechanism of germanium enrichment in the world-class Huize MVT Pb–Zn deposit, southwestern China","authors":"Pan-Pan Niu, Manuel Muñoz, Olivier Mathon, Suo-Fei Xiong, Shao-Yong Jiang","doi":"10.1007/s00126-023-01242-3","DOIUrl":"https://doi.org/10.1007/s00126-023-01242-3","url":null,"abstract":"<p>The world-class Huize deposit hosts significant germanium (Ge) resources in the Sichuan–Yunan–Guizhou (SYG) Mississippi Valley-type (MVT) Pb–Zn province of China. The distribution and enrichment mechanism of Ge is still poorly understood. In the main ore-forming stage of Huize, we identified six sphalerite colors from C1 (black) to C6 (white) in transmitted light. Two color sequences are confirmed, including C1 → C2 → C3 → C6 and C1 → C2 → C4 → C5 → C6. We used multiple analytical methods to reveal the Ge distribution and incorporation mechanism into sphalerite and the possible enrichment factors. Our results show that Ge occurs as argutite (GeO<sub>2</sub>), and in the sphalerite crystal lattice, C1 and C3 sphalerite has up to 593 ppm Ge. Two substitution mechanisms, i.e., Ge<sup>4+</sup> + □<sub>(vacancy)</sub> → 2Zn<sup>2+</sup> (e.g., C1 and C2) and Ge<sup>4+</sup> + 2Cu<sup>+</sup> → 3Zn<sup>2+</sup> (e.g., C2, C3, C4, and C5), are inferred from the Huize sphalerite. They show different spatial structures of sphalerite and a weak shift of the white line observed by high-resolution X-ray absorption near-edge structure (XANES) spectroscopy. The trace-element composition of sphalerite suggests that reduced sulfur content of the ore-forming fluid contributes to Ge enrichment, followed by high temperature (> 300 °C).</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139436814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Banded iron formations (BIFs) are chemical sediments that reflect the composition of the seawater from which they were deposited. Therefore, they provide a key part of the evidence for the modern scientific understanding of paleoenvironmental conditions in Archean and Paleoproterozoic times. Although BIFs have been extensively studied, many aspects (e.g., specific mechanisms controlling iron (Fe) and silicon (Si) precipitations) of their origin still remain enigmatic because of the lack of modern analogues. In China, abundant BIFs occur throughout within the late Neoarchean volcanic and sedimentary succession and therefore are the principal source of Fe for the Chinese steel industry. Here, we examine the ~ 2.53 Ga Qidashan BIF, one of the most extensive BIFs in China, by conducting a detailed petrographic and multi-proxy investigation to well constrain its formation mechanism. The BIF consists mainly of magnetite and quartz with lesser amounts of calcite and various types of silicate minerals, of which the content of Al-rich minerals (i.e., chlorite) is rare, coupled with a low abundance of detrital geochemical indicators (e.g., Al and Ti), suggesting that the BIF is relatively pure with insignificant terrigenous contamination. A wide range of Nd isotope compositions and shale-normalized patterns and specific anomalies of rare earth elements, especially highly positive Eu anomalies, indicate that the BIF precipitated from seawater imprinted by high-temperature hydrothermal fluids. Furthermore, there is a significantly negative correlation between Nd isotope values and total Fe contents of the BIF. This suggests that such enhanced hydrothermal activity provided vast volumes of dissolved Fe(II) necessary for the formation of the BIF via alteration of ancient continental crust. In addition, the Qidashan BIF was deposited under pervasively anoxic conditions, as revealed by the absence of shale-normalized Ce anomalies and the presence of consistently positive Fe isotope values. Hence, anoxygenic photosynthesis is the most plausible mechanism responsible for Fe(II) oxidation. Given that Fe─Si bonding has a strong impact on Si isotope fractionation, the formation of primary Fe(III) oxyhydroxides should have exerted a first-order control on the negative Si isotope signatures observed in the studied BIF samples. It is also noted that the BIF possesses a variation of negative Si isotope values, further implying that diagenetic dissolution and reprecipitation of silica took place after primary Si precipitation associated with Fe.
带状铁地层(BIFs)是一种化学沉积物,反映了沉积时海水的成分。因此,它们为现代科学了解阿新世和古近代的古环境条件提供了重要证据。尽管对 BIFs 进行了广泛的研究,但由于缺乏现代类似物,其起源的许多方面(如控制铁(Fe)和硅(Si)沉淀的具体机制)仍然是个谜。在中国,新元古代晚期的火山岩和沉积岩演替中遍布着丰富的 BIFs,因此它们是中国钢铁工业的主要铁元素来源。在此,我们通过详细的岩石学和多代理研究,对中国范围最广的BIF之一--约2.53 Ga的齐大山BIF进行了研究,以充分确定其形成机制。该BIF主要由磁铁矿和石英组成,含有少量方解石和各种硅酸盐矿物,其中富铝矿物(如绿泥石)含量稀少,且碎屑地球化学指标(如Al和Ti)含量较低,表明该BIF较为纯净,土著污染不明显。广泛的钕同位素组成和页岩归一化模式以及稀土元素的特定异常,特别是高正 Eu 异常,表明 BIF 是由高温热液注入的海水沉淀而成。此外,BIF 的钕同位素值与总铁含量之间存在明显的负相关。这表明,这种增强的热液活动提供了大量溶解的铁(II),这是通过改变古大陆地壳形成 BIF 所必需的。此外,齐大山 BIF 是在普遍缺氧的条件下沉积的,这一点从页岩归一化 Ce 异常值的缺失和铁同位素值持续为正值可以看出。因此,缺氧光合作用是造成铁(II)氧化的最合理机制。鉴于 Fe─Si 键对 Si 同位素分馏有很大影响,原生 Fe(III)氧氢氧化物的形成应该对在所研究的 BIF 样品中观察到的负 Si 同位素特征有一阶控制作用。我们还注意到,BIF 具有负硅同位素值的变化,这进一步表明,在与铁有关的原生硅沉淀之后,硅发生了成岩溶解和再沉淀。
{"title":"Geochemistry and Sm─Nd─Fe─Si isotope compositions as insights into the deposition of the late Neoarchean Qidashan banded iron formation, North China Craton","authors":"Changle Wang, Zidong Peng, Xiaoxue Tong, Liang Gao, Lianchang Zhang","doi":"10.1007/s00126-024-01245-8","DOIUrl":"https://doi.org/10.1007/s00126-024-01245-8","url":null,"abstract":"<p>Banded iron formations (BIFs) are chemical sediments that reflect the composition of the seawater from which they were deposited. Therefore, they provide a key part of the evidence for the modern scientific understanding of paleoenvironmental conditions in Archean and Paleoproterozoic times. Although BIFs have been extensively studied, many aspects (e.g., specific mechanisms controlling iron (Fe) and silicon (Si) precipitations) of their origin still remain enigmatic because of the lack of modern analogues. In China, abundant BIFs occur throughout within the late Neoarchean volcanic and sedimentary succession and therefore are the principal source of Fe for the Chinese steel industry. Here, we examine the ~ 2.53 Ga Qidashan BIF, one of the most extensive BIFs in China, by conducting a detailed petrographic and multi-proxy investigation to well constrain its formation mechanism. The BIF consists mainly of magnetite and quartz with lesser amounts of calcite and various types of silicate minerals, of which the content of Al-rich minerals (i.e., chlorite) is rare, coupled with a low abundance of detrital geochemical indicators (e.g., Al and Ti), suggesting that the BIF is relatively pure with insignificant terrigenous contamination. A wide range of Nd isotope compositions and shale-normalized patterns and specific anomalies of rare earth elements, especially highly positive Eu anomalies, indicate that the BIF precipitated from seawater imprinted by high-temperature hydrothermal fluids. Furthermore, there is a significantly negative correlation between Nd isotope values and total Fe contents of the BIF. This suggests that such enhanced hydrothermal activity provided vast volumes of dissolved Fe(II) necessary for the formation of the BIF via alteration of ancient continental crust. In addition, the Qidashan BIF was deposited under pervasively anoxic conditions, as revealed by the absence of shale-normalized Ce anomalies and the presence of consistently positive Fe isotope values. Hence, anoxygenic photosynthesis is the most plausible mechanism responsible for Fe(II) oxidation. Given that Fe─Si bonding has a strong impact on Si isotope fractionation, the formation of primary Fe(III) oxyhydroxides should have exerted a first-order control on the negative Si isotope signatures observed in the studied BIF samples. It is also noted that the BIF possesses a variation of negative Si isotope values, further implying that diagenetic dissolution and reprecipitation of silica took place after primary Si precipitation associated with Fe.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139400502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-06DOI: 10.1007/s00126-023-01244-1
David I. Groves, M. Santosh, Qingfei Wang, Liang Zhang, Hesen Zhao
Orogenic gold systems are arguably the most variable mineral system globally in terms of an extreme range of depositional depths, corresponding P–T conditions and wallrock alteration assemblages, structural controls and styles, and element associations. This diversity has ignited controversy on genetic models for the two decades since orogenic gold became a widely accepted term. From the diverse genetic models proposed, the two groups of fluid-source models that meet most genetic constraints are the following: (1) deposition from crustal fluids via metamorphic devolatilization at the amphibolite-greenschist transition, or potentially even deeper under specific tectonic conditions, and (2) deposition from sub-crustal fluids either by direct devolatilization of subducted oceanic crust and overlying sediment wedge or of previously metasomatized and fertilized mantle lithosphere. Both models normally postulate gold deposition within a geodynamic system that evolves from extension through compression into syn-gold transpression. Crustal metamorphic models normally invoke subduction-driven geodynamic systems that involve advection of crustal metamorphic fluids up crustal-scale faults. In contrast, sub-crustal devolatilization models involve subduction-related processes as both geodynamic drivers and gold sources with fault-controlled fluid conduits extending to below the Moho. The overall lack of orogenic gold and other subduction-related mineral systems during the unique Boring Billion (1.8–0.8 Ga) period provides an important constraint on this genetic debate. Boring Billion orogens had varying geodynamic drivers, asthenosphere upwelling, and low-P metamorphic terranes with crustal-scale faults, all parameters consistent with formation of orogenic gold systems, during subduction-independent accordion-type tectonics. The absence of orogenic gold during the Boring Billion provides critical evidence against the crustal metamorphic model and furthers the sub-crustal model which requires subduction as both the geodynamic driver and auriferous fluid source.
{"title":"The Boring Billion: A key to resolving controversy on ore-fluid source models for orogenic gold deposits?","authors":"David I. Groves, M. Santosh, Qingfei Wang, Liang Zhang, Hesen Zhao","doi":"10.1007/s00126-023-01244-1","DOIUrl":"https://doi.org/10.1007/s00126-023-01244-1","url":null,"abstract":"<p>Orogenic gold systems are arguably the most variable mineral system globally in terms of an extreme range of depositional depths, corresponding P–T conditions and wallrock alteration assemblages, structural controls and styles, and element associations. This diversity has ignited controversy on genetic models for the two decades since orogenic gold became a widely accepted term. From the diverse genetic models proposed, the two groups of fluid-source models that meet most genetic constraints are the following: (1) deposition from crustal fluids via metamorphic devolatilization at the amphibolite-greenschist transition, or potentially even deeper under specific tectonic conditions, and (2) deposition from sub-crustal fluids either by direct devolatilization of subducted oceanic crust and overlying sediment wedge or of previously metasomatized and fertilized mantle lithosphere. Both models normally postulate gold deposition within a geodynamic system that evolves from extension through compression into syn-gold transpression. Crustal metamorphic models normally invoke subduction-driven geodynamic systems that involve advection of crustal metamorphic fluids up crustal-scale faults. In contrast, sub-crustal devolatilization models involve subduction-related processes as both geodynamic drivers and gold sources with fault-controlled fluid conduits extending to below the Moho. The overall lack of orogenic gold and other subduction-related mineral systems during the unique Boring Billion (1.8–0.8 Ga) period provides an important constraint on this genetic debate. Boring Billion orogens had varying geodynamic drivers, asthenosphere upwelling, and low-P metamorphic terranes with crustal-scale faults, all parameters consistent with formation of orogenic gold systems, during subduction-independent accordion-type tectonics. The absence of orogenic gold during the Boring Billion provides critical evidence against the crustal metamorphic model and furthers the sub-crustal model which requires subduction as both the geodynamic driver and auriferous fluid source.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139112018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-04DOI: 10.1007/s00126-023-01238-z
Isra S. Ezad, Daryl E. Blanks, Stephen F. Foley, David A. Holwell, Jason Bennett, Marco L. Fiorentini
Magmatic Ni–sulfide ore deposits are generally associated with basaltic to komatiitic igneous rocks that originate by partial melting of the mantle, which is usually modelled as a uniform four-phase peridotite. Existing models accept that the key metal contributors to mantle melts are olivine (Ni) and sulfide (Cu, platinum group elements (PGEs) and minor Ni). However, melting in the mantle commonly begins in volumetrically minor mantle assemblages such as hydrous pyroxenites that occur as veins in the peridotite mantle, which are rich in the hydrous minerals phlogopite, amphibole and apatite. The contribution of hydrous pyroxenites to the metal endowment of mantle melts may have been underestimated or overlooked in the past, partly because evidence of their input is partially erased as melting intensifies to involve peridotite.
Here, we compile new results from experiments and natural rocks which demonstrate that the hydrous minerals such as phlogopite, amphiboles and apatite all have high partition coefficients for Ni (3–20) and may be important repositories for Ni in mantle sources of igneous rocks. This implies that hydrous minerals hosted in metasomatic mantle lithologies such as hydrous pyroxenites may be important contributors to some magmatic Ni–sulfide ore systems. Hydrous pyroxenites contain hydrous minerals in large modal abundances up to 30–40 vol% in addition to clinopyroxene and a few vol% of oxide phases, such as rutile and ilmenite. These mantle lithologies are commonly associated with cratonic and continental regions, where low-temperature, low-degree volatile-rich melts commonly modify lithospheric peridotite mantle, depositing variable hydrous pyroxenites.
The lower melting temperatures of hydrous minerals in hydrous pyroxenite lithologies also means that the generation of magmatic ore deposits may not require a major thermal perturbation such as a plume, as the melting temperatures of hydrous pyroxenites lie around 300–350 °C lower than dry peridotites. Partial melts of hydrous pyroxenite are more voluminous at low temperatures than melts of peridotite would be. Furthermore, it is argued in the following that they would contain similar or even higher concentrations of Ni. Thus, predictive exploration models should consider domains of the lithospheric mantle where hydrous pyroxenites may be localised and concentrated, as they may have been episodically melted throughout the long-lived geological evolution of cratonic blocks, yielding Ni-rich melts that may be hosted in conduits of varying size and geometry at various crustal levels.
{"title":"Lithospheric hydrous pyroxenites control localisation and Ni endowment of magmatic sulfide deposits","authors":"Isra S. Ezad, Daryl E. Blanks, Stephen F. Foley, David A. Holwell, Jason Bennett, Marco L. Fiorentini","doi":"10.1007/s00126-023-01238-z","DOIUrl":"https://doi.org/10.1007/s00126-023-01238-z","url":null,"abstract":"<p>Magmatic Ni–sulfide ore deposits are generally associated with basaltic to komatiitic igneous rocks that originate by partial melting of the mantle, which is usually modelled as a uniform four-phase peridotite. Existing models accept that the key metal contributors to mantle melts are olivine (Ni) and sulfide (Cu, platinum group elements (PGEs) and minor Ni). However, melting in the mantle commonly begins in volumetrically minor mantle assemblages such as hydrous pyroxenites that occur as veins in the peridotite mantle, which are rich in the hydrous minerals phlogopite, amphibole and apatite. The contribution of hydrous pyroxenites to the metal endowment of mantle melts may have been underestimated or overlooked in the past, partly because evidence of their input is partially erased as melting intensifies to involve peridotite.</p><p>Here, we compile new results from experiments and natural rocks which demonstrate that the hydrous minerals such as phlogopite, amphiboles and apatite all have high partition coefficients for Ni (3–20) and may be important repositories for Ni in mantle sources of igneous rocks. This implies that hydrous minerals hosted in metasomatic mantle lithologies such as hydrous pyroxenites may be important contributors to some magmatic Ni–sulfide ore systems. Hydrous pyroxenites contain hydrous minerals in large modal abundances up to 30–40 vol% in addition to clinopyroxene and a few vol% of oxide phases, such as rutile and ilmenite. These mantle lithologies are commonly associated with cratonic and continental regions, where low-temperature, low-degree volatile-rich melts commonly modify lithospheric peridotite mantle, depositing variable hydrous pyroxenites.</p><p>The lower melting temperatures of hydrous minerals in hydrous pyroxenite lithologies also means that the generation of magmatic ore deposits may not require a major thermal perturbation such as a plume, as the melting temperatures of hydrous pyroxenites lie around 300–350 °C lower than dry peridotites. Partial melts of hydrous pyroxenite are more voluminous at low temperatures than melts of peridotite would be. Furthermore, it is argued in the following that they would contain similar or even higher concentrations of Ni. Thus, predictive exploration models should consider domains of the lithospheric mantle where hydrous pyroxenites may be localised and concentrated, as they may have been episodically melted throughout the long-lived geological evolution of cratonic blocks, yielding Ni-rich melts that may be hosted in conduits of varying size and geometry at various crustal levels.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139101442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-29DOI: 10.1007/s00126-023-01240-5
Ryan D. Taylor, Garth E. Graham, Heather A. Lowers
Attempts to geochemically distinguish between metamorphic-hydrothermal systems that form orogenic gold deposits and both reduced and oxidized magmatic-hydrothermal systems using isotopes or metal associations have proven ambiguous, particularly for orogenic gold and reduced intrusion-related gold systems. The absence of conclusive geochemical discriminators and the overlap in geologic characteristics have led to gold deposit models being potentially incorrectly applied, which in turn negatively affect regional mineral exploration and mine planning. In this study, in situ electron microprobe geochemical analyses of hydrothermal monazite and xenotime crystals associated with different types of gold-bearing deposits are shown to be effective geochemical discriminators. There are notable differences in mineral chemistry such as rare earth element (REE) profiles, total light REE, Dy, Er, Pr, Y, Nd/Sm, and La/Sm that distinguish monazite precipitated from metamorphic-hydrothermal fluids that form orogenic gold deposits and those precipitated from magmatic-hydrothermal fluids that form both porphyry Cu-Mo-Au and reduced intrusion-related gold deposits. Notable differences in overall xenotime abundances and concentrations of heavy REEs, Ca, and Sc are distinctive between the different deposit classes for xenotime. The origin of the controversially classified Pogo gold deposit, Tintina gold province, Alaska, which has been characterized as both a reduced intrusion-related and an orogenic gold deposit, is tested based upon the noted chemical differences associated with these hydrothermal phosphates. The findings of this study have implications for exploration and mine development in the Tintina gold province and other areas that contain deposits that are controversially classified as either orogenic or as magmatic-hydrothermal gold deposits.
{"title":"Hydrothermal monazite and xenotime chemistry as genetic discriminators for intrusion-related and orogenic gold deposits: implications for an orogenic origin of the Pogo gold deposit, Alaska","authors":"Ryan D. Taylor, Garth E. Graham, Heather A. Lowers","doi":"10.1007/s00126-023-01240-5","DOIUrl":"https://doi.org/10.1007/s00126-023-01240-5","url":null,"abstract":"<p>Attempts to geochemically distinguish between metamorphic-hydrothermal systems that form orogenic gold deposits and both reduced and oxidized magmatic-hydrothermal systems using isotopes or metal associations have proven ambiguous, particularly for orogenic gold and reduced intrusion-related gold systems. The absence of conclusive geochemical discriminators and the overlap in geologic characteristics have led to gold deposit models being potentially incorrectly applied, which in turn negatively affect regional mineral exploration and mine planning. In this study, in situ electron microprobe geochemical analyses of hydrothermal monazite and xenotime crystals associated with different types of gold-bearing deposits are shown to be effective geochemical discriminators. There are notable differences in mineral chemistry such as rare earth element (REE) profiles, total light REE, Dy, Er, Pr, Y, Nd/Sm, and La/Sm that distinguish monazite precipitated from metamorphic-hydrothermal fluids that form orogenic gold deposits and those precipitated from magmatic-hydrothermal fluids that form both porphyry Cu-Mo-Au and reduced intrusion-related gold deposits. Notable differences in overall xenotime abundances and concentrations of heavy REEs, Ca, and Sc are distinctive between the different deposit classes for xenotime. The origin of the controversially classified Pogo gold deposit, Tintina gold province, Alaska, which has been characterized as both a reduced intrusion-related and an orogenic gold deposit, is tested based upon the noted chemical differences associated with these hydrothermal phosphates. The findings of this study have implications for exploration and mine development in the Tintina gold province and other areas that contain deposits that are controversially classified as either orogenic or as magmatic-hydrothermal gold deposits.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139059722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-21DOI: 10.1007/s00126-023-01239-y
J. Tepsell, Y. Lahaye, F. Molnár, O.T. Rämö, N. Cook
Silver is probably the closest isotopic proxy to track monoisotopic gold and has been shown to have great potential to yield new information on the origin and enrichment processes of gold. This study describes the development of a tailored analytical protocol for accurate analysis of Ag isotopes and provides the first Ag isotope data for the Paleoproterozoic Rajapalot Au-Co deposit, Finnish Lapland. Six native Au samples yield ε109Ag values (relative to NIST SRM 978a) from −6.8 to +2.1 and are within the range of Ag isotopic compositions reported for native Au samples. The mean of the analyzed Au samples is ε109Ag = −3.8 ± 1.7 (2SD) with most of the samples with negative ε109Ag values (−6.7 to −2.0); one sample has a positive ε109Ag value of +2.1 ± 0.5. Silver isotope fractionation in the Rajapalot Au deposit was likely associated with physicochemical processes related to deposition and/or re-mobilization of the ore rather than with source region inheritance. It is suggested that redox reactions involving Ag+ ↔ Ag0 phase change primarily account for the isotopic differences within the deposit. Our results also suggest that the Rajapalot Au-Co deposit was formed via multistage ore-forming processes and/or that the primary ore was re-mobilized, which caused isotope fractionation along fluid pathways. Silver isotope variation within a deposit may mark a fractional crystallization trend with the lightest isotopic composition representing the earliest precipitate. Hence, Ag isotopes show potential as an isotopic vectoring tool in search of Au-enriched domains.
{"title":"Silver isotope analysis and systematics of native gold from the Rajapalot Co-enriched gold deposit, Finnish Lapland","authors":"J. Tepsell, Y. Lahaye, F. Molnár, O.T. Rämö, N. Cook","doi":"10.1007/s00126-023-01239-y","DOIUrl":"https://doi.org/10.1007/s00126-023-01239-y","url":null,"abstract":"<p>Silver is probably the closest isotopic proxy to track monoisotopic gold and has been shown to have great potential to yield new information on the origin and enrichment processes of gold. This study describes the development of a tailored analytical protocol for accurate analysis of Ag isotopes and provides the first Ag isotope data for the Paleoproterozoic Rajapalot Au-Co deposit, Finnish Lapland. Six native Au samples yield ε<sup>109</sup>Ag values (relative to NIST SRM 978a) from −6.8 to +2.1 and are within the range of Ag isotopic compositions reported for native Au samples. The mean of the analyzed Au samples is ε<sup>109</sup>Ag = −3.8 ± 1.7 (2SD) with most of the samples with negative ε<sup>109</sup>Ag values (−6.7 to −2.0); one sample has a positive ε<sup>109</sup>Ag value of +2.1 ± 0.5. Silver isotope fractionation in the Rajapalot Au deposit was likely associated with physicochemical processes related to deposition and/or re-mobilization of the ore rather than with source region inheritance. It is suggested that redox reactions involving Ag<sup>+</sup> ↔ Ag<sup>0</sup> phase change primarily account for the isotopic differences within the deposit. Our results also suggest that the Rajapalot Au-Co deposit was formed via multistage ore-forming processes and/or that the primary ore was re-mobilized, which caused isotope fractionation along fluid pathways. Silver isotope variation within a deposit may mark a fractional crystallization trend with the lightest isotopic composition representing the earliest precipitate. Hence, Ag isotopes show potential as an isotopic vectoring tool in search of Au-enriched domains.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138840175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-19DOI: 10.1007/s00126-023-01241-4
Tuhin Chakraborty, Steffen H. Büttner, Gelu Costin, Charles F. Kankuzi
{"title":"Correction to: The petrogenesis of highly fractionated gem‑bearing pegmatites of Malawi: evidence from mica and tourmaline chemistry and finite step trace element modelling","authors":"Tuhin Chakraborty, Steffen H. Büttner, Gelu Costin, Charles F. Kankuzi","doi":"10.1007/s00126-023-01241-4","DOIUrl":"https://doi.org/10.1007/s00126-023-01241-4","url":null,"abstract":"","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138959931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-19DOI: 10.1007/s00126-023-01221-8
Thomas Monecke, T. James Reynolds, Tsolmon Gonchig, Natsagdorj Batbayar
The evolution of the magmatic-hydrothermal system that formed the Triassic Erdenetiin Ovoo porphyry Cu-Mo deposit, northern Mongolia, is reconstructed through the study of the sequence of stockwork veining and the petrographic characteristics of the veins, as well as the cathodoluminescence and fluid inclusion characteristics of the vein quartz. Early A veins associated with potassic alteration formed at temperatures ≳ 500 °C under lithostatic pressures. The quartz in these veins shows a blue cathodoluminescence emission and is extensively recrystallized. Subhedral to euhedral quartz crystals contained in AB veins precipitated at the ductile to brittle transition at ~ 400–450 °C. The quartz crystals have cores showing a long-lived purple cathodoluminescence color with well-developed growth zoning, whereas the rims of the crystals lack growth banding and have a brownish-red cathodoluminescence emission. Fluid inclusions in the A and AB veins show elevated CO2 concentrations but show no evidence for immiscibility, implying that Erdenetiin Ovoo formed at ≳ 5 km below paleosurface. Quartz in the A and AB veins is crosscut by molybdenite ribbons. The presence of encapsulated molybdenite and sericite grains along growth zones in the quartz rims of the subhedral to euhedral quartz crystals constrains the timing of Mo introduction and suggests an association with the sericite alteration of the host rocks, which affected 50–60% of the deposit. Elevated Cu grades at Erdenetiin Ovoo are linked to the occurrence of C veins, which consist primarily of chalcopyrite and pyrite. These veins surrounded by halos of sericite-chlorite alteration lack quartz as a gangue mineral, suggesting formation at conditions of retrograde quartz solubility at ~ 400 °C and hydrostatic pressures. Late D veins formed at ≲ 375 °C and hydrostatic conditions. The veins consist primarily of pyrite and are associated with texturally destructive sericite alteration of the host rocks. The study demonstrates that hypogene Cu mineralization at Erdenetiin Ovoo was predated and post-dated by sericite alteration, which has important implications to alteration vectoring in porphyry exploration worldwide.
通过对岩浆脉序和岩脉的岩相特征以及岩脉石英的阴极发光和流体包裹体特征的研究,重建了形成蒙古北部三叠纪额尔德尼铁林敖包斑岩铜-钼矿床的岩浆-热液系统的演化过程。与钾盐蚀变有关的早期A型矿脉是在岩石压力下温度≳ 500 °C时形成的。这些矿脉中的石英发出蓝色阴极荧光,并广泛重结晶。AB 矿脉中所含的亚方体到八面体石英晶体是在约 400-450 °C 的韧性到脆性转变过程中析出的。石英晶体的内核显示出长效的紫色阴极荧光,并具有发达的生长带状,而晶体的边缘则缺乏生长带状,并发出棕红色的阴极荧光。A 和 AB 矿脉中的流体包裹体显示二氧化碳浓度升高,但没有显示出不溶解的迹象,这意味着额尔德尼敖包岩是在≳ 5 千米的古地表以下形成的。A 和 AB 矿脉中的石英被辉钼矿带横切。亚方体至八面体石英晶体的石英边缘生长带中存在包裹的辉钼矿和绢云母晶粒,这限制了钼的引入时间,并表明与寄主岩的绢云母蚀变有关,该蚀变影响了 50-60% 的矿床。Erdenetiin Ovoo 铜品位的升高与主要由黄铜矿和黄铁矿组成的 C 矿脉的出现有关。这些被绢云母-绿泥石蚀变晕所包围的矿脉中没有石英这种煤矸石矿物,这表明矿脉是在约 400 °C 的逆行石英溶解度和静水压力条件下形成的。晚期 D 型矿脉是在≲ 375 °C和静水压力条件下形成的。这些矿脉主要由黄铁矿组成,与母岩的纹理破坏性绢云母蚀变有关。该研究表明,绢云母蚀变在 Erdenetiin Ovoo 的下伏铜矿化之前和之后都曾出现过,这对全球斑岩勘探中的蚀变矢量具有重要意义。
{"title":"Evolution of the magmatic-hydrothermal system at the Erdenetiin Ovoo porphyry Cu-Mo deposit, Mongolia: constraints on the relative timing of alteration and mineralization","authors":"Thomas Monecke, T. James Reynolds, Tsolmon Gonchig, Natsagdorj Batbayar","doi":"10.1007/s00126-023-01221-8","DOIUrl":"https://doi.org/10.1007/s00126-023-01221-8","url":null,"abstract":"<p>The evolution of the magmatic-hydrothermal system that formed the Triassic Erdenetiin Ovoo porphyry Cu-Mo deposit, northern Mongolia, is reconstructed through the study of the sequence of stockwork veining and the petrographic characteristics of the veins, as well as the cathodoluminescence and fluid inclusion characteristics of the vein quartz. Early A veins associated with potassic alteration formed at temperatures ≳ 500 °C under lithostatic pressures. The quartz in these veins shows a blue cathodoluminescence emission and is extensively recrystallized. Subhedral to euhedral quartz crystals contained in AB veins precipitated at the ductile to brittle transition at ~ 400–450 °C. The quartz crystals have cores showing a long-lived purple cathodoluminescence color with well-developed growth zoning, whereas the rims of the crystals lack growth banding and have a brownish-red cathodoluminescence emission. Fluid inclusions in the A and AB veins show elevated CO<sub>2</sub> concentrations but show no evidence for immiscibility, implying that Erdenetiin Ovoo formed at ≳ 5 km below paleosurface. Quartz in the A and AB veins is crosscut by molybdenite ribbons. The presence of encapsulated molybdenite and sericite grains along growth zones in the quartz rims of the subhedral to euhedral quartz crystals constrains the timing of Mo introduction and suggests an association with the sericite alteration of the host rocks, which affected 50–60% of the deposit. Elevated Cu grades at Erdenetiin Ovoo are linked to the occurrence of C veins, which consist primarily of chalcopyrite and pyrite. These veins surrounded by halos of sericite-chlorite alteration lack quartz as a gangue mineral, suggesting formation at conditions of retrograde quartz solubility at ~ 400 °C and hydrostatic pressures. Late D veins formed at ≲ 375 °C and hydrostatic conditions. The veins consist primarily of pyrite and are associated with texturally destructive sericite alteration of the host rocks. The study demonstrates that hypogene Cu mineralization at Erdenetiin Ovoo was predated and post-dated by sericite alteration, which has important implications to alteration vectoring in porphyry exploration worldwide.</p>","PeriodicalId":18682,"journal":{"name":"Mineralium Deposita","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138740163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}