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Constitution of Ni rich alloys in Ni–Mo–Ta system Ni - mo - ta体系中富镍合金的组成
Pub Date : 1983-12-01 DOI: 10.1179/030634583790420439
S. Chakravorty, D. West
AbstractAn investigation has been made of the constitution of the Ni–Mo–Ta system within the range 0–100 at.-%Mo and 0–40 at.-%Ta. The data are presented mainly as isothermal sections at 1523 and 1273 K, determined primarily by electron probe microanalysis and X-ray diffraction; some data for 1173 K are also included. The phases covered by the investigation are as follows: the Ni based solid solution γ, the Mo–Ta based solid solution, and intermetallic compounds based on Ni8Ta, Ni3Ta, Ni2Ta, Ni3Mo, and NiMo. A notable feature of the equilibria is the extensive solid solubility of Mo (up to ∼11 at.-%) in orthorhombic Ni3Ta in the range 1523–1173 K. In contrast to a previous report in the literature, it has also been shown that Ni3Ta and Ni3Mo do not form a continuous series of solid solutions at 1173 K. At 1523 and 1273 K, γ enters into equilibria with the following phases: Ni8(Ta, Mo), Ni3(Ta, Mo), and NiMo. The Ni3(Ta, Mo) phase enters into equilibria with γ, Ni8(Ta, Mo), Ni2Ta, NiMo, the Mo–Ta based sol...
摘要研究了0 ~ 100 at范围内Ni-Mo-Ta体系的组成。-%Mo和0-40 at.-%Ta。数据主要为1523和1273 K的等温切片,主要由电子探针显微分析和x射线衍射确定;1173 K的一些数据也包括在内。所研究的相包括:Ni基固溶体γ、Mo-Ta基固溶体以及Ni8Ta、Ni3Ta、Ni2Ta、Ni3Mo和NiMo等金属间化合物。该平衡的一个显著特征是Mo在1523-1173 K的正交Ni3Ta中具有广泛的固溶性(高达~ 11at .-%)。与先前的文献报道相反,也表明Ni3Ta和Ni3Mo在1173 K时不会形成连续的一系列固溶体。在1523和1273 K时,γ与以下相进入平衡:Ni8(Ta, Mo), Ni3(Ta, Mo)和NiMo。Ni3(Ta, Mo)相与γ、Ni8(Ta, Mo)、Ni2Ta、NiMo、Mo - Ta基溶胶进入平衡态。
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引用次数: 11
Effect of initial grain size on dynamic recrystallization of copper 初始晶粒尺寸对铜动态再结晶的影响
Pub Date : 1983-12-01 DOI: 10.1179/030634583790420448
L. Błaż, T. Sakai, J. Jonas
AbstractOxygen free high conductivity (OFHC) and electrolytic tough pitch (ETP) copper specimens of different grain sizes (10–800 μm) were tested at various constant true strain rates in a modified Instron testing machine. The temperature range investigated was 725–1075 K. The effect of initial grain size on the transition from multiple to single peak flow was studied. The dependence of the stable dynamic grain size on the temperature corrected strain rate and the steady state stress was determined, as were the density of twins and of deformation bands. The density of twins decreased as the initial grain size was increased and when the recrystallization mechanism changed from static to dynamic. The density of deformation bands increased markedly with initial grain size. As the deformation bands are preferential nucleation sites for new dynamic grains, the results indicate that the initial effective grain size D o *
摘要:在改良的Instron试验机上,对不同晶粒尺寸(10 ~ 800 μm)的无氧高导电性(OFHC)和电韧性(ETP)铜试样进行了恒应变速率下的测试。实验温度范围为725 ~ 1075 K。研究了初始晶粒尺寸对多峰流向单峰流转变的影响。确定了稳定动态晶粒尺寸与温度修正应变速率和稳态应力的关系,以及孪晶和变形带的密度。孪晶密度随着初始晶粒尺寸的增大和再结晶机制由静态向动态转变而减小。变形带密度随初始晶粒尺寸的增大而显著增大。由于变形带是新动态晶粒的优先形核位置,结果表明,初始有效晶粒尺寸D o *
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引用次数: 143
Microstructural aspects of extrusion of rapidly solidified Al–10Mg alloy powder 挤压快速凝固Al-10Mg合金粉末的显微组织研究
Pub Date : 1983-12-01 DOI: 10.1179/030634583790420411
T. Sheppard, M. Zaidi, G. H. Tan
AbstractThe microstructures of rapidly solidified Al–10Mg alloy powders have been observed by optical microscopy, scanning electron microscopy, and transmission electron microscopy. A technique is described which enabled individual powder particles to be made electron transparent. The alloy powders were then consolidated by cold compaction followed by hot extrusion using a wide range of temperature compensated strain rates. The microstructures evolved are reported and it is shown that there is a correlation between the microstructures and the process parameters. It is also shown that the initial powder structure is an important variable. Magnesium is retained in solid solution in the extrudate but is metastable at room temperature leading to decomposition over long periods of time. However, the very fine grain size observed (1–3 μm) is thermally stable up to 300°C and aging processes may be utilized to obtain acceptable structures.
摘要采用光学显微镜、扫描电镜和透射电镜观察了Al-10Mg合金快速凝固粉末的显微组织。描述了一种使单个粉末颗粒具有电子透明的技术。合金粉末然后通过冷压巩固,然后使用大范围的温度补偿应变率热挤压。结果表明,显微组织与工艺参数之间存在一定的相关性。研究还表明,初始粉末结构是一个重要的变量。镁在挤出物中以固溶体形式保留,但在室温下是亚稳态的,经过长时间后会分解。然而,观察到的极细晶粒尺寸(1-3 μm)在300°C下是热稳定的,并且可以利用时效工艺获得可接受的组织。
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引用次数: 20
Cleavage fracture of low carbon ferritic steels with fine grain size 细晶粒低碳铁素体钢解理断裂
Pub Date : 1983-12-01 DOI: 10.1179/030634583790420420
N. Okumura
AbstractMicromechanisms of transgranular cleavage fracture in ferritic steels have been investigated, particular attention being paid to the dependence of cleavage fracture stress σf on grain size over the range from 3·5 to 34·3 μm. It is found that σf increases less than linearly with d−1/2, where d is the grain diameter, whereas the Hall–Petch relation holds for the yield stress. Based on the experimental results, where σf was measured in the steels and their grain size and carbide size were changed independently, it is suggested that in the grain size range cited, the predominant mechanism was the propagation of a microcrack, which formed in the discrete carbide, into contiguous ferrite grains. The measured values of σf were discussed in a quantitative manner based on a model into which an equilibrium distribution of dislocations produced by the double pile-up mechanism was incorporated.
摘要研究了铁素体钢穿晶解理断裂的微观机理,重点研究了3.5 ~ 34.3 μm范围内解理断裂应力σf随晶粒尺寸的变化规律。结果表明,σf随d−1/2 (d为晶粒直径)的增加不呈线性增长,而屈服应力的变化符合Hall-Petch关系。通过测量钢的σf值,发现钢的晶粒尺寸和碳化物尺寸是独立变化的,表明在上述晶粒尺寸范围内,主要机制是由离散碳化物中形成的微裂纹扩展为连续的铁素体晶粒。在考虑双堆积机制产生的位错平衡分布的模型基础上,定量讨论了σf的测量值。
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引用次数: 29
Solute redistributions associated with nucleation and growth of α1 plates in Cu–Zn and Au–Cu–Zn alloys Cu-Zn和Au-Cu-Zn合金中溶质重分布与α1板形核和长大的关系
Pub Date : 1983-12-01 DOI: 10.1179/030634583790420394
P. Doig, P. Flewitt
Abstract The formation of α1 plates during isothermal aging of quenched, β′ phase, non-ferrous alloys has been taken to occur by a combined shear and diffusion regulated process. Cu–Zn alloy specimens (∼40 at.-%Zn) containing additions of Au up to ∼9 at.-% have been quenched to retain the β′ phase (B2) and isothermally aged in the temperature range 523–973 K to produce α1 plates and α rods. These precipitates have been examined using optical and transmission electron microscopy, and their compositions studied using high spatial resolution, STEM–EDS X-ray microanalysis on thin foil samples. The initially formed α1 plates have crystallographic characteristics similar to those of the martensitic product and are in agreement with the predictions of the phenomenological theory for martensite formation. The solute distributions between the parent β′ phase and the product α1 plates have been measured and these are discussed in relation to the mechanism for growth of the α1 plates.
摘要:α1板在淬火β′相有色合金等温时效过程中的形成是剪切和扩散共同调控的过程。Cu-Zn合金样品(~ 40 at.-%Zn)含有高达~ 9 at的Au添加量。-%经过淬火以保留β′相(B2),并在523 ~ 973 K的温度范围内等温时效,得到α1板和α棒。使用光学和透射电子显微镜检查了这些沉淀物,并使用高空间分辨率研究了它们的成分,对薄片样品进行了STEM-EDS x射线微分析。初步形成的α1板具有与马氏体产物相似的结晶学特征,符合马氏体形成的现象学理论预测。测定了母体β′相与产物α1板之间的溶质分布,并对α1板的生长机理进行了讨论。
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引用次数: 12
Creep–structural relationship in steel alloy 800 H at 900–1000°C 钢合金800 H在900-1000℃时的蠕变-组织关系
Pub Date : 1983-11-01 DOI: 10.1179/030634583790420475
V. Guttmann, R. Bürgel
AbstractThe creep properties of the 32Ni–20Cr steel alloy 800 H have been investigated in the temperature range 900–1000°C. The results show that the creep behaviour is characterized by various irregularities. Structural analyses performed for selected creep conditions have revealed that significant structural instabilities become relevant during the creep process. As a result of the continuous ripening of the carbide precipitates the density of carbide pinned dislocations, which are assumed to provide an important contribution to strength, decreases as the creep process advances. In correlation with creep crack formation, a nitriding effect can occur during long term testing in air which is accompanied by an increase of the creep resistance.
摘要研究了32Ni-20Cr钢合金800 H在900 ~ 1000℃范围内的蠕变性能。结果表明,蠕变行为具有多种不规则性。在选定的蠕变条件下进行的结构分析表明,在蠕变过程中,显著的结构不稳定性变得相关。随着蠕变过程的进行,碳化物析出相的不断成熟导致对强度起重要作用的碳化物钉住位错密度降低。与蠕变裂纹形成有关的是,在空气中长期试验中会出现氮化效应,并伴随着蠕变阻力的增加。
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引用次数: 4
Effects of alloying elements on σ phase precipitation in δ–γ duplex phase stainless steels 合金元素对δ -γ双相不锈钢中σ相析出的影响
Pub Date : 1983-11-01 DOI: 10.1179/030634583790420457
Y. Maehara, Y. Ohmori, J. Murayama, N. Fujino, T. Kunitake
AbstractThe effects of alloying elements on σ phase precipitation in δ–γ duplex phase stainless steels have been studied with particular emphasis on the partitioning of alloying elements. Sigma phase precipitation occurred mainly through the eutectoid decomposition of δ into σ and γ phases. The concentrations of Cr, Mo, W, and Si in each phase decreased in the order σ, δ, then γ phase, while those of Ni and Mn decreased in the reverse order. The increase of Cr and Mo contents increased both the rate and the maximum amount of σ phase precipitation, while the increase of Ni content reduced the maximum amount of σ phase precipitation, though the rate of the precipitation was also accelerated. The effect of Ni can be explained in terms of the reduction in the δ phase fraction before aging, resulting in the enrichment of σ forming elements in the ferrite.
摘要本文研究了合金元素对δ -γ双相不锈钢中σ相析出的影响,重点研究了合金元素的分配。σ相的析出主要是通过δ析出为σ相和γ相的共析析出。各相中Cr、Mo、W、Si的浓度依次为σ、δ、γ相降低,而Ni、Mn的浓度依次为相反的顺序降低。Cr和Mo含量的增加增加了σ相的析出速率和最大析出量,而Ni含量的增加降低了σ相的最大析出量,但也加快了析出速率。Ni的作用可以解释为时效前δ相分数的降低,导致铁素体中σ形成元素的富集。
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引用次数: 63
Changes in dislocation structures adjacent to fatigue crack tips induced by intermittent overstressing 间歇性超应力引起疲劳裂纹尖端附近位错结构的变化
Pub Date : 1983-11-01 DOI: 10.1179/030634583790420493
K. Katagiri, R. Koterazawa, T. Yamada, T. Tsuboi
Abstract A study was made on the effects of intermittent overstressing on fatigue crack propagation using Fe specimens in as-normalized and as-stretched to 10% strain conditions. A few cycles of fully reversed overstress applied intermittently during very large numbers of cycles of understress below the threshold stress intensity caused significant acceleration of crack propagation. Ultrahigh voltage electron microscopic observation of the dislocation structures adjacent to fatigue crack tips revealed the occurrence of remarkable recovery during understressing and the formation of a radial band structure within the recovered region on overstressing. These structure changes induced by varying the stress are thought to be responsible for the acceleration of crack propagation in the material. The previously reported characteristics of acceleration of crack propagation under intermittent overstressing: (i) the increase of acceleration ratio R ac as the number of cycles of understress n 1 increases, and the sa...
采用归一化状态和拉伸至10%应变状态的铁试样,研究了间歇性超应力对疲劳裂纹扩展的影响。在大量低于阈值应力强度的欠应力循环期间,间歇性地施加几次完全反向的超应力循环会显著加速裂纹扩展。在超高压电镜下观察疲劳裂纹尖端附近的位错组织,发现在欠应力时出现了明显的恢复,在过度应力时恢复区域内形成了径向带状结构。这些由应力变化引起的结构变化被认为是材料中裂纹扩展加速的原因。前人报道的间歇性超应力作用下裂纹扩展的加速特性:(1)随着欠应力循环次数的增加,加速比R ac增大,裂纹扩展速度随应力循环次数的增加而增大。
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引用次数: 7
Cracking in M2 high speed steel M2高速钢开裂
Pub Date : 1983-11-01 DOI: 10.1179/030634583790420466
P. W. Shelton, A. Wronski
AbstractCracked carbides (non-propagating microcracks) were observed in M2 type high speed steels deformed in four-point bending in the temperature range 17–600°C to ∼0·7% of the yield strain, i.e. to below the stress for macroscopic yielding and ductile or brittle fracture. Although the sintered M2 steel underwent a brittle–ductile transition at ∼300°C, no associated significant change in the fracture mechanism was detected. In all samples studied, cracking of individual carbides (nucleation of failure) was followed by the subcritical linking of these microcracks through the matrix, i.e. growth, and only then by catastrophic propagation, as a Griffith crack from an approximately semielliptical edge (or corner facet) fracture initiating region. Fracture mechanics analyses indicate the depth of this region to be in excess of the Griffith–Irwin flaw size, except for the brittle specimens. The region of subcritical crack growth is compared to the process zone reported for ceramics.
在17-600℃至屈服应变的~ 0.7%(即低于宏观屈服应力和延性或脆性断裂)温度范围内,在四点弯曲变形的M2型高速钢中观察到裂纹碳化物(非扩展微裂纹)。虽然烧结后的M2钢在~ 300°C时经历了脆-韧转变,但断裂机制没有发现相关的显著变化。在所研究的所有样品中,单个碳化物的开裂(失效形核)之后是这些微裂纹通过基体的亚临界连接,即生长,然后才发生灾难性扩展,作为格里菲斯裂纹从大约半椭圆边缘(或角面)断裂起始区域开始。断裂力学分析表明,除脆性试样外,该区域的深度均超过Griffith-Irwin缺陷尺寸。亚临界裂纹扩展区域与陶瓷的工艺区进行了比较。
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引用次数: 22
Effect of dispersoids on fatigue crack propagation in aluminium alloys 分散体对铝合金疲劳裂纹扩展的影响
Pub Date : 1983-11-01 DOI: 10.1179/030634583790420501
L. Edwards, J. Martin
Abstract The fatigue crack propagation characteristics of three peak aged Al–Mg–Si alloys have been determined. One was of essentially ternary composition, the others contained increasing volume fractions of 0·1 μm dia. dispersoid particles. The stress intensity thresholds for fatigue crack propagation ∆K TH increased with increasing volume fraction of dispersoid. At low and intermediate values of stress intensity ∆K, the crack growth rate decreased as the volume fraction of dispersoid increased. However, at high values of ∆K, void coalescence around coarse particles could outweigh the beneficial effect of the dispersoids. The degree of intergranular fracture occurring in the alloys was shown to be dependent on the maximum stress intensity in the fatigue cycle K max. The micromechanism of intergranular fracture was identified as microvoid coalescence along the grain boundary precipitate free zone. The concept of a semicohesive zone ahead of the fatigue crack tip is shown to be useful in modelling the micr...
研究了三种峰时效Al-Mg-Si合金的疲劳裂纹扩展特性。其中一种基本为三元组成,其他两种的体积分数均为0.1 μm。分散体粒子。随着弥散体体积分数的增加,疲劳裂纹扩展的应力强度阈值∆K TH增大。在低、中应力强度∆K值下,裂纹扩展速率随分散体体积分数的增加而减小。然而,在较高的∆K值下,粗颗粒周围的空洞聚并可能超过分散体的有益作用。合金的晶间断裂程度与疲劳循环的最大应力强度kmax有关。晶间断裂的微观机制是沿晶界无析出带的微孔洞聚结。在疲劳裂纹尖端前面的半粘结区概念在模拟微裂纹的过程中是有用的。
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引用次数: 11
期刊
Metal science
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