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Study of dechlorination by natural adsorbents (chitin and chitosan) 天然吸附剂(甲壳素和壳聚糖)的脱氯研究
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.21865
El Mostafa Erradi, A. Cherrat, K. Jaafari
This study aim to the preparation of three adsorbent natural materials: crude chitin, chitin and chitosan extracted from shellfish, to study the elimination of Chlorides from a synthetic effluent. The process of adsorption of chlorides on these supports is described following the linearized method of the model described by Freundlich and Langmuir. The study of the influence of some physico-chemical parameters on the dechlorination process has been undertaken.And in order to approach the conditions of water dechlorination, we were also interested in the study of the influence of the presence of the counter-ions on the ability to remove chloride ions on chitosan. Moreover, we looked for the optimal conditions of desorption using a basic solution.
本研究旨在制备三种天然吸附剂:粗甲壳素、壳聚糖和壳聚糖,研究合成废水中氯化物的去除。根据Freundlich和Langmuir模型的线性化方法,描述了氯化物在这些载体上的吸附过程。研究了一些理化参数对脱氯过程的影响。为了接近水脱氯的条件,我们也有兴趣研究反离子的存在对壳聚糖去除氯离子能力的影响。此外,我们还寻找了使用碱性溶液解吸的最佳条件。
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引用次数: 1
Synthesis of functionalized alkenes via Knoevenagel condensation using Marine Fish Scales as a new efficient and eco-friendly catalyst 以海洋鱼鳞为新型高效环保催化剂的Knoevenagel缩合法合成功能化烯烃
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.23058
M. A. Taleb
The preparation of Marine Fish Scales (MFS) and its analog doped with NaNO 3 (NaNO 3 /MFS) as new catalysts was discussed in this work. Then, these materials were characterized by ATG/ATD, X-ray diffraction, SEM, EDX, and IR spectrophotometer. The MFSand NaNO 3 /MFS can be used as eco-friendly catalysts for the Knoevenagel condensation and led to the functionalized alkenes in high yields with short reaction time. The tests show that 100 mg is the optimum mass, as well as the suitable solvent, is ethanol for the condensation of Knoevenagel. These parameters led to excellent yields (between 87 % and 99 % using NaNO 3 /MFS). These catalysts can be also reused for several times.
本文讨论了以NaNO3/MFS为新型催化剂制备海洋鱼鳞(MFS)及其类似物的方法。然后,用ATG/ATD、X射线衍射、SEM、EDX和IR分光光度计对这些材料进行了表征。MFSand-NaNO3/MFS可作为Knoevenagel缩合反应的环保催化剂,并在短反应时间内以高产率制备功能化烯烃。试验表明,100 mg是Knoevenagel缩合的最佳质量,并且合适的溶剂是乙醇。这些参数导致了优异的产率(使用NaNO3/MFS在87%和99%之间)。这些催化剂也可以重复使用多次。
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引用次数: 0
Adsorption of Iron (II) from Textile Industry Effluent uing Luffa Cylindrica 丝瓜纺织废水对铁的吸附(Ⅱ)
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.21663
K. Nwosu‐Obieogu, G. Dzarma, B. Okolo, K. N. Akatobi
Abstract This research investigated the efficiency of luffa cylindrica activated carbon as adsorbent material in the removal of iron (II) from the textile industry effluent in a batch adsorption experiment. The adsorption process was studied as a function of contact time, pH of the solution and adsorbent dosage. At room temperature, the batch adsorption experiment showed maximum adsorption of iron (II) at a pH of 6, a contact time of 60 minutes and an adsorbent dosage of 1g/L. The effluent was characterized using the standard method (atomic absorption spectrometry) while the adsorbent was prepared, carbonated and characterized using SEM and FTIR. The SEM findings revealed a highly porous morphology. The FTIR revealed the presence of various functional groups (OH, CH, C=C and C-C). The findings of the batch adsorption experiment were fitted using Langmuir and Freundlich isotherm models and Langmuir model gave a better fit. The kinetic data of iron (II) was evaluated using pseudo-first-order and pseudo-second-order kinetic models. The batch adsorption experimental data conforms more to the pseudo-first-order kinetic model.
摘要本研究采用丝瓜活性炭作为吸附材料,对纺织废水中的铁(Ⅱ)进行了分批吸附实验。研究了吸附过程与接触时间、溶液pH值和吸附剂用量的关系。在室温下,分批吸附实验显示,在pH为6、接触时间为60分钟和吸附剂用量为1g/L时,铁(II)的吸附最大。使用标准方法(原子吸收光谱法)对流出物进行表征,同时制备吸附剂,碳酸化并使用SEM和FTIR进行表征。SEM的发现揭示了高度多孔的形态。FTIR揭示了各种官能团(OH、CH、C=C和C-C)的存在。用Langmuir和Freundlich等温线模型拟合了间歇吸附实验的结果,Langmuir模型拟合较好。使用伪一阶和伪二阶动力学模型评估铁(II)的动力学数据。间歇吸附实验数据更符合拟一阶动力学模型。
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引用次数: 0
Experimental and theoretical studies on corrosion inhibitory action of Peganum harmala (L.) seeds extract on carbon steel in 1M HCl 骆驼蓬种子提取物在1M盐酸中对碳钢缓蚀作用的实验与理论研究
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.22928
I. Ghazi, S. Jorio, M. Siniti, R. Fdil, H. Elattari
The objective of this study is to test the inhibitory efficiency of the methanol extract of P. harmala against the corrosion of carbon steel C38 in 1M hydrochloric acid by gravimetric method and electrochemical measurements. The results indicated that the methanol extract of P. harmala is a good inhibitor of carbon steel. The inhibition efficiency increases with the increase of the concentration of the inhibitor. The nature of adsorption of the extract on carbon steel surface was in conformity with Langmuir isotherm. Both kinetic and thermodynamic parameter of adsorption allows us to suggest chemical adsorption of this inhibitor on the metal. Potentiodynamic polarization measurements show that P. harmala acts as mixed type inhibitor.   The result of EIS was correlating with the result of polarization measurement. A theoretical study was done in solution for major alkaloids isolated from P. harmala seeds, and was investigated using density functional theory (DFT) at the B3LYP/6-31G(d,p) basis set level through the relationship between their molecular and electronic structure. The quantum chemical parameters such as E HOMO (highest occupied molecular orbital energy), E LUMO (lowest unoccupied molecular orbital energy), energy gap (ΔE), dipole moment (μ), absolute hardness (η), absolute softness (S), the absolute electronegativity (χ), the fractions of electrons transferred from the inhibitor molecule to the metallic atom (ΔN) and the electrophilicity index (ω) were calculated. The local selectivity and reactivity has been analyzed through the Fukui function indices in order to compare the possible sites for nucleophilic and electrophilic attacks.
本研究的目的是通过重量法和电化学测量来测试骆驼蓬甲醇提取物对碳钢C38在1M盐酸中的腐蚀的抑制效率。结果表明,骆驼蓬甲醇提取物对碳钢具有良好的缓蚀作用。抑制效率随着抑制剂浓度的增加而增加。提取物在碳钢表面的吸附性质符合Langmuir等温线。吸附的动力学和热力学参数都使我们能够提出这种抑制剂在金属上的化学吸附。电位动力学极化测定结果表明,骆驼蓬具有混合型抑制剂的作用。EIS的结果与极化测量的结果相关。对骆驼蓬种子中的主要生物碱在溶液中进行了理论研究,并利用密度泛函理论(DFT)在B3LYP/6-31G(d,P)基组水平上研究了它们的分子结构和电子结构之间的关系。量子化学参数如E HOMO(最高占据分子轨道能量)、E LUMO(最低占据分子轨道能)、能隙(ΔE)、偶极矩(μ)、绝对硬度(η)、绝对柔软度(S)、绝对电负性(χ),计算了从抑制剂分子转移到金属原子的电子分数(ΔN)和亲电指数(ω)。通过Fukui函数指数分析了局部选择性和反应性,以比较亲核和亲电攻击的可能位点。
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引用次数: 1
STUDY OF THE BEHAVIOR OF AN EPOXY COATING FOOD CONTACT 环氧涂层食品接触性能的研究
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.22253
Z. Kadri
Epoxies have been used in the internal coating of cans to endure a long shelf life for canned goods; several types of interactions exist between this kind of packaging (container) and the packed product (contained). This container/contained contact can influence the properties of the packed product, we are interested in this study to contribute to the development of a new formulation in order to prepare an Epoxy coating able to come in contact with foodstuffs, thus our studies based on a selective choice of raw materials that respect the international regulation of food contact, while taking into account the stoichiometric parameters to have a well-cross-linked and resistant polymer. However, the aim of this work is to study the behavior of this developed epoxy coating in contact with different simulant, which represent three categories of food. Within this study, we have characterized the epoxy paint by infra-red, and we have follow the mass variation and the sorption’s kinetics of water, acid acetic, and ethanol in contact with epoxy film by the gravimetric technique, the results allowed us to calculate the diffusion coefficient of each simulant, and then compute the activation energy and thermodynamic parameters. Moreover, the results of the gravimetric method show that the temperature impact the kinetics of diffusion more than the contact time do, the mass transfer depends on the nature of the simulant in contact and on its physic-chemical properties, it concluded also the mass stability of the epoxy coating from 25°C to 40°C.
环氧树脂已被用于罐头的内涂层,以延长罐头食品的保质期;这种包装(容器)和被包装的产品(容器)之间存在几种类型的相互作用。这种容器/容器接触会影响包装产品的性能,我们对这项研究感兴趣的是为开发一种新配方做出贡献,以制备一种能够与食品接触的环氧涂层,因此我们的研究基于对原料的选择性选择,尊重国际食品接触法规,同时考虑到化学计量参数,以获得交联良好且耐腐蚀的聚合物。然而,本工作的目的是研究所开发的环氧涂料与代表三类食品的不同模拟剂接触的行为。在本研究中,我们用红外光谱对环氧涂料进行了表征,并通过重量法跟踪了水、醋酸、乙醇与环氧膜接触时的质量变化和吸附动力学,计算了每种模拟物的扩散系数,进而计算了活化能和热力学参数。此外,重量法的结果表明,温度对扩散动力学的影响大于接触时间,传质取决于接触模拟物的性质及其物理化学性质,也得出了25℃至40℃环氧涂层的质量稳定性。
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引用次数: 1
Adsorption of a basic dye, Methylene Blue, in aqueous solution on bentonite 膨润土对碱性染料亚甲基蓝水溶液的吸附
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.23303
Hanane Ait Hmeid
The dyes are used in many industrial sectors such as textiles, paper and leather dyeing, as well as in the food and cosmetics industry. Dyes are known to be toxic and persistent in the environment and require physico-chemical techniques to degrade them.  This work deals with the study of the adsorption of the cationic dye methylene blue on raw bentonite from the region of Nador (Morocco). The physico-chemical properties show that our bentonite indicates a very high alkalinity.  The amplitude of swelling shows that this bentonite is very high is sensitive to water. The SEM shows petaloid-shaped aggregates of the grains in spherical form with heterogeneous dimensions. Various experimental parameters were analyzed; initial concentration of the dye, pH, mass of the adsorbent and temperature. Adsorption tests showed that the maximum duration of this cationic dye on bentonite is established after 80 minutes. Experimental results showed that the adsorption of the methylene blue dye on raw bentonite depends on the pH of the solution and the initial concentration of the dye. Although the amount of methylene blue adsorbed decreases with increasing temperature, this indicates that adsorption is an exothermic process. The adsorption capacity was determined using the Langmuir, Freundlich, Elovich and Temkin isotherms. The binding of methylene blue follows Freundlich's law.
这些染料被用于许多工业部门,如纺织、造纸和皮革染色,以及食品和化妆品行业。众所周知,染料在环境中是有毒和持久的,需要物理化学技术来降解它们。本文研究了阳离子染料亚甲基蓝在纳多尔(摩洛哥)地区原料膨润土上的吸附。理化性质表明膨润土具有很高的碱度。膨胀幅度表明该膨润土对水非常敏感。扫描电镜观察到晶粒呈花瓣状球形聚集体,尺寸不均匀。对各种实验参数进行了分析;染料的初始浓度,pH值,吸附剂的质量和温度。吸附试验表明,该阳离子染料在膨润土上的最大停留时间为80分钟。实验结果表明,原料膨润土对亚甲基蓝染料的吸附取决于溶液的pH值和染料的初始浓度。虽然亚甲基蓝的吸附量随着温度的升高而减少,但这表明吸附是一个放热过程。采用Langmuir、Freundlich、Elovich和Temkin等温线测定吸附量。亚甲基蓝的结合遵循弗伦德利希定律。
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引用次数: 7
Effect of ammonium citrate concentration variation on the carbon dots colistin modification for Escherichia coli detection 柠檬酸铵浓度变化对碳点粘菌素修饰检测大肠杆菌的影响
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.23191
S. Suherman, Yoga Nurwijaya, E. Wahyuni, D. Siswanta, K. Morita, Y. Oki
World Health Organization (WHO) mentioned that diarrhea is one of the main causes of under-five mortality in developing countries due to Escherichia coli ( E. coli ) bacteria. Synthesis of colistin-conjugated-carbon dots using ammonium citrate as a precursor for E. coli detection has been carried out to study its application for detection in water samples from urban population wells. Synthesis of carbon dots (CDs) was carrried out using conventional pyrolisis method. Ammonium citrate with mass variation of 10; 15; 20; and 25 mg were added to 2.5 g colistin and heated at 180 C for 1 h. Brown residue was yielded; more over the functional groups and morphology were characterized by FT-IR and TEM. The brown residue is further diluted by distilled water, centrifuged at 8000 rpm for 10 min. The absorbances were analyzed using spectrophotometer UV-Vis. Carbon dots colistin with different concentration of ammonium citrate variations were analyzed using spectrophotometer fluorescence at 310-450 nm and the highest intensity would be used for E. coli detection. From the experimental part, it was found that CDs colistin has spherical morphology with diameter around 3-10 nm. The highest intensity was achieved at excitation wavelength of 360 nm from CDs colistin with 20 mg ammonium citrate. In the detection process of three household urban wells water in Yogyakarta-Indonesia, it was concluded that one sample was found to contain E. coli whose concentration was higher than the permitted limit of 235 cfu per 100 mL set by Ministry of Health-Republic of Indonesia.
世界卫生组织(世界卫生组织)提到,腹泻是发展中国家因大肠杆菌(E.coli)细菌而导致的未成年人死亡的主要原因之一。以柠檬酸铵为前体合成粘菌素偶联碳点,用于大肠杆菌检测,研究其在城市人口水井水样检测中的应用。采用传统的热解法合成碳点。质量变化为10的柠檬酸铵;15;20;和25mg加入到2.5g粘菌素中并在180℃下加热持续1小时。得到棕色残留物;通过FT-IR和TEM对更多的官能团和形貌进行了表征。用蒸馏水进一步稀释棕色残留物,以8000rpm离心10分钟。使用分光光度计UV-Vis分析吸光度。在310-450nm处使用分光光度计荧光分析具有不同柠檬酸铵浓度变化的碳点粘菌素,最高强度将用于大肠杆菌检测。从实验部分发现,CDs粘菌素具有直径约3-10nm的球形形态。用20mg柠檬酸铵从CDs粘菌素在360nm的激发波长下获得最高强度。在对印度尼西亚日惹的三个家庭城市井水的检测过程中,得出的结论是,一个样本中含有大肠杆菌,其浓度高于印度尼西亚卫生部规定的每100毫升235 cfu的允许限值。
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引用次数: 0
Comparative study of the mineral composition of carob pulp (Ceratonia siliqua L.) from various regions in Morocco 摩洛哥不同地区角豆果肉(Ceratonia siliqua L.)矿物成分的比较研究
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.21872
Kaoutar El Oumlouki
Ceratonia siliqua L. ou la caroube est une espece agro-forestiere-pastorale avec d'enormes interets socio-economiques et ecologiques. Il a longtemps ete cultive pour l'alimentation humaine et animale. Actuellement, il est de plus en plus utilise par les secteurs alimentaires, pharmaceutiques et dietetiques. C'est une espece typiquement mediterraneenne et elargie distribuee au Maroc. Afin de caracteriser et valoriser la caroube du Maroc, une etude comparative de la composition minerale de la pulpe de caroube de quatre regions du Maroc (Beni-Mellal, Chaoun, Tafraoute et Taounate) pour l’elite de la region pour la region chaque element mineral, les resultats de ces travaux comportent une difference significative pour tous les parametres chimiques et physico-chimiques entre les regions etudiees. La caracterisation a montre une gamme de variation en termes de teneur en eau, + = 1121,1-1300,2 mg / 100g, P = 41,9-57., 2 mg / 100g, Ca 2+ = 270,4- 305,3 mg / 100g, Mg 2+ = 40,4- 144, 8 mg / 100g et Na + = 31,6-81,7 mg / 100g Fe 2+ = 5,26-6,66 mg / 100g, Zn 2+ = 1,80-2,61 mg / 100g, Mn 2+ = 0., 60-0,75 mg / 100g, Cu 2+ = 0,42-0,56 mg / 100g).
角豆是一种具有巨大社会经济和生态利益的农林畜牧物种。长期以来,它一直被种植作为人类和动物的食物。目前,它越来越多地用于食品、制药和饮食行业。它是一种典型的地中海和广泛的物种,分布在摩洛哥。以caracteriser和珍惜摩洛哥,一个比较统一的角豆豆果肉与矿物质成分,是摩洛哥的四个区域(Beni-Mellal Chaoun、地区抽取l’elite Tafraoute陶纳特省),并为每个元素mineral region),这些工作的结果相当之差,对于所有的化学和物理化学参数etudiees区域之间。特征a显示了含水量的变化范围,+ = 1121,1- 13002 mg / 100g, P = 41.9 -57。钙2+ = 270.4 - 305.3 mg / 100g, mg 2+ = 40.4 - 144.8 mg / 100g, Na + = 31.6 - 81.7 mg / 100g, Fe 2+ = 5.26 - 6.66 mg / 100g, Zn 2+ = 1.80 - 2.61 mg / 100g, Mn 2+ = 0。, 60- 0.75 mg / 100g, cu2 + = 0.42 - 0.56 mg / 100g)。
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引用次数: 3
Combined antimicrobial effect of bacteriocins of LAB isolated from a traditional brine table olives and essential oils against foodborne pathogens 从传统卤水橄榄中分离的乳酸菌素与精油对食源性致病菌的联合抑菌作用
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.22091
S. Gaamouche
The study aimed to determine the antimicrobial activity of bacteriocinogenic lactic acid bacteria isolated from olive brine and three essential oils (Thyme, Rosemary and Oregano Eos) alone and in combination against the Gram-positive L. monocytogenes and the Gram-negative E. coli O157: H7. The antimicrobial activity was determined by evaluation of minimum inhibitory concentration (MIC) and the minimum bactericidal concentration (MBC) of the tested antimicrobial agents. The evaluation demonstrates that the two CFSs of lactic strains and the purified bacteriocins inhibit the growth of both L. monocytogenes and E. coli . The results showed that thyme EO is most effective followed by rosemary and Oregano Eos. Thus, all combination executed against L. monocytogenes using the checkerboard technique showed an additive effect unless the CFSs of LAB in combination with Thyme EO which showed no interactive effect. Whereas the combination against E. coli, only two bacteriocins in combination with Thyme EO and ELBC02 bacteriocin in combination with Rosemary EO that showed an additive effect. The results obtained in these studies coupled with the right knowledge opens the way to the combination as a new field of application whose goal is confined to conservation and the safety of food.
本研究旨在测定从橄榄盐水和三种精油(百里香、迷迭香和牛至)中分离的致病菌乳酸菌单独或联合对革兰氏阳性单核细胞增多性李斯特菌和革兰氏阴性大肠杆菌O157:H7的抗菌活性。通过评价所测试的抗微生物剂的最小抑菌浓度(MIC)和最小杀菌浓度(MBC)来确定抗微生物活性。评价表明,乳酸菌株的两种CFS和纯化的细菌素抑制了单核细胞增多性李斯特菌和大肠杆菌的生长。结果表明,百里香EO最有效,其次是迷迭香和牛至。因此,使用棋盘技术对单核细胞增多性李斯特菌进行的所有组合都显示出相加效应,除非LAB的CFS与百里香-EO组合没有显示出交互作用。而针对大肠杆菌的组合,只有两种细菌素与百里香EO和ELBC02细菌素与迷迭香EO组合显示出相加作用。这些研究中获得的结果加上正确的知识,为组合开辟了道路,成为一个新的应用领域,其目标仅限于食品的保护和安全。
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引用次数: 1
Investigation of the Fluoroperovskite LiBaF3, Examining the Optical, Elastic, Electronic and Structural Properties: DFT Study. 氟钙钛矿LiBaF3的光学、弹性、电子和结构性质的研究:DFT研究。
IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2021-08-07 DOI: 10.48317/IMIST.PRSM/MORJCHEM-V9I3.23461
E. Olawale
The Structural, electronic, elastic and optical properties of the fluoroperovskite LiBAF 3  are obtained using the plane-wave pseudopotential implementation of the PWscf code method in the framework of density functional theory (DFT), with the local density approximation (LDA) and the generalized gradient approximation (GGA). The result shows LiBAF3 compound has a direct band gap with 6.7eV and 6.5ev using PBE-GGA and PBEsol-GGA respectively. It satisfies the Born’s stability condition and thus implies the compound is stable. Refractive index, coefficient of extinction and dielectric function have all been computed.
在密度泛函理论(DFT)框架下,采用局部密度近似(LDA)和广义梯度近似(GGA),利用PWscf编码方法的平面波伪势实现了氟钙钛矿libaf3的结构、电子、弹性和光学性质。结果表明,采用PBE-GGA和PBEsol-GGA制备的LiBAF3化合物具有6.7eV和6.5ev的直接带隙。它满足玻恩的稳定性条件,因此表明该化合物是稳定的。计算了折射率、消光系数和介电函数。
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引用次数: 0
期刊
Moroccan Journal of Chemistry
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