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X-ray diffraction, infra-red spectroscopy and magnetic properties of Ni0.7Zn0.3Fe2O4+0.6wt%V2O5 prepared via ceramic method 陶瓷法制备Ni0.7Zn0.3Fe2O4+0.6wt%V2O5的x射线衍射、红外光谱和磁性能
Pub Date : 2021-01-01 DOI: 10.1063/5.0061108
M. S. Patil
In view of the growing demand to the additives, we promote the compound formation of Ni0.7Zn0.3Fe2O4 loaded with 0.6wt%V2O5 by ceramic technique. The structural analysis and magnetic were determined by diverse characterization techniques. The phase formation and purity over the addition of V2O5 was identified by XRD pattern. In IR studied, the functional group scrutiny of Ni0.7Zn0.3Fe2O4+0.6wt%V2O5 was examined by locating the intrinsic vibrational bands and confirmed the phase formation. The lattice constant (a) and x-ray density (dx) were calculated from the post-examination of XRD data. We noted an inflation in the Saturation magnetization (Ms), Remanence magnetization (Mr) and magneton number (nB) of Ni0.7Zn0.3Fe2O4+0.6wt%V2O5 as a principle cause of V2O5 loading. Admitting that, the rate of coercivity (Hc) was drastically declined suggesting the alternated magnetic parameters. This inspection was focused on the characteristic ramification of additive 0.6wt%V2O5 on physical properties of Ni0.7Zn0.3Fe2O4 ferrite.
鉴于对添加剂的需求日益增长,我们采用陶瓷技术促进了负载0.6wt%V2O5的Ni0.7Zn0.3Fe2O4的复合形成。结构分析和磁性是通过不同的表征技术来确定的。用XRD谱分析了添加V2O5后的相形成和纯度。在红外光谱中,通过定位Ni0.7Zn0.3Fe2O4+0.6wt%V2O5的本征振动带,对Ni0.7Zn0.3Fe2O4+0.6wt%V2O5的官能团进行了检查,并确定了相的形成。通过对XRD数据的事后检验,计算了晶格常数(a)和x射线密度(dx)。我们注意到Ni0.7Zn0.3Fe2O4+0.6wt%V2O5的饱和磁化强度(Ms)、剩磁磁化强度(Mr)和磁子数(nB)的膨胀是V2O5加载的主要原因。承认,矫顽力率(Hc)急剧下降,表明交替磁参数。研究了添加0.6wt%V2O5对Ni0.7Zn0.3Fe2O4铁氧体物理性能的影响。
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引用次数: 0
Effect of constriction width on hysteresis in superconducting weak links and micro-SQUIDs 缩窄宽度对超导薄弱环节和微乌贼磁滞的影响
Pub Date : 2021-01-01 DOI: 10.1063/5.0062494
N. Kumar, Bharat K. Gupta, Anjan K. Gupta
We have fabricated and characterized niobium film based superconducting weak link (WL) devices and micron-size superconducting quantum interference devices (μ-SQUIDs) with superconducting WLs as Josephson Junctions. Here we discuss the effect of WL width on the hysteresis and crossover temperature (Th) while keeping the other dimensions fixed. We find that the critical current reduces linearly with the width and thus Th reduces with decreasing width. This makes some of the devices non-hysteretic down to 1.3K.We also discuss the observed excess current in the current-voltage characteristics of these devices, in terms of Andreev reflection.
我们制备并表征了铌薄膜超导弱链(WL)器件和微米级超导量子干涉器件(μ- squid)。在保持其他维度不变的情况下,我们讨论了WL宽度对迟滞和交叉温度(Th)的影响。我们发现临界电流随宽度线性减小,因此Th随宽度减小而减小。这使得一些设备的非迟滞低至1.3K。我们还根据安德烈夫反射讨论了在这些器件的电流-电压特性中观察到的过量电流。
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引用次数: 0
Development of plasma system for the seeds treatment to improve germination and growth 等离子体处理系统的研制,提高种子萌发和生长
Pub Date : 2021-01-01 DOI: 10.1063/5.0061690
Kundan Viliya, U. Sharma, S. S. Chauhan, J. Sharma, R. Rane, J. Ghosh, K. Guruprasad
Pre-sowing treatment of seeds to improve germination, growth and yield of crops has been in use in agriculture traditionally by physical and chemical treatments. In recent times, treatment of seeds with low magnetic fields has been shown to improve growth and yield of crop plants. Physical treatment of seeds with low magnetic field of 100 – 200 mT strength improves germination and early seedling growth of soybean and maize seeds. There have been several studies on the impact of plasma on the seeds since plasma treatment improves germination of seeds and subsequent growth of the seedlings. This has been observed in the seeds of wheat, soybean, clover, rye, barley, pea and lapin. After plasma treatment shoot weight increased by 30% in wheat under experimental conditions. The mechanism of plasma induced bio-stimulation of germination and growth of seeds is yet to be analyzed in detail. There are different methods to increase the germination and growth of seeds by plasma treatment like DC Glow discharge plasma, RF Glow discharge plasma, Dielectric Barrier Discharge plasma (DBD) and plasma activated water (PAW) .We at center of excellence for plasma research have developed a plasma glow discharge system for the Germination and Growth of seeds with glow discharge plasma treatment.
在农业中,传统上通过物理和化学处理对种子进行播前处理,以提高作物的发芽、生长和产量。近年来,用低磁场处理种子已被证明可以改善作物的生长和产量。100 ~ 200mt强度的低磁场对种子进行物理处理,有利于大豆和玉米种子的萌发和幼苗的早期生长。由于等离子体处理可以提高种子的萌发和幼苗的生长,因此已经有一些关于等离子体对种子影响的研究。这在小麦、大豆、三叶草、黑麦、大麦、豌豆和lapin的种子中都有观察到。在试验条件下,等离子体处理后小麦茎重增加30%。血浆诱导的生物刺激种子萌发和生长的机制尚未得到详细的分析。通过等离子体处理提高种子萌发和生长的方法有直流辉光放电等离子体、射频辉光放电等离子体、介质阻挡放电等离子体和等离子体活性水等,我们在等离子体研究卓越中心开发了一种等离子体辉光放电系统,用于辉光放电等离子体处理种子的萌发和生长。
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引用次数: 1
Decay study of monument sand stones 纪念性砂石的衰变研究
Pub Date : 2021-01-01 DOI: 10.1063/5.0061210
ra Kuri, S. Dadami, Manjula V. Katageri
Selected ancient sandstone monuments (56 th centuries) from Aihole, Pattadakal from Bagalkot district, local quarries stone and sandstone sample of Akkaragall quarries of India were characterized for their mineralogical and physical properties. X-ray diffraction (XRD) coupled with scanning electron microscopy (SEM) are used to discuss the ancient ceramic technology and composition. From XRD analysis we observed that Durga temple and Iranna padi quarry sand stone sample contains Quartz & chromium whereas Akkaragall quarry sand stone sample contains Quartz and silica. Particular attention were given to the analysis of composition of monuments stone with quarries stone and its decay.
从巴加尔科特地区的Aihole, Pattadakal,当地采石场的石头和印度Akkaragall采石场的砂岩样本中选择了56世纪的古代砂岩纪念碑,对其矿物学和物理性质进行了表征。利用x射线衍射(XRD)和扫描电子显微镜(SEM)分析了古代陶瓷的工艺和成分。通过XRD分析,我们发现Durga寺和Iranna padi采石场的砂岩样品含有石英和铬,而Akkaragall采石场的砂岩样品含有石英和二氧化硅。特别注意的是对纪念碑石与采石场石的组成及其衰变的分析。
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引用次数: 0
To study the synthesis mechanism and structural properties of nickel doped SnO2 nanostructured materials with variation of dopant concentration 研究不同掺杂浓度下镍掺杂SnO2纳米结构材料的合成机理和结构性能
Pub Date : 2021-01-01 DOI: 10.1063/5.0061696
Sonia Arora, Rajesh Sharma
Nanocomposites are those materials which contain multiple domains with the combination of two or more different materials and possessing minimum one phase domain lying in the nanometer range (1nm-100nm). Nanocomposites materials possess so many novel and challenging properties. In present work, nanocomposites of tin oxide doped with nickel oxide were synthesized by simple chemical route method via co precipitation method. Various characterization techniques were employed to characterize the as-synthesized and calcined samples of Ni doped SnO2 nanostructured materials using diffraction by X-ray analysis, Fourier infrared spectroscopy (IR). The crystallite size of samples is determined by using Debye Scherer formulation and with considering the most intense peak. The FTIR spectrograph reveals that different peaks of metal oxides correspond to SnO2 and NiO were present in samples.
纳米复合材料是由两种或两种以上不同的材料组合而成的具有多个畴的材料,并且在纳米范围(1nm-100nm)内具有最小一个相畴。纳米复合材料具有许多新颖和具有挑战性的性能。本文采用共沉淀法,采用简单的化学路线合成了氧化锡掺杂氧化镍的纳米复合材料。利用衍射、x射线分析、傅立叶红外光谱(IR)等多种表征技术对Ni掺杂SnO2纳米结构材料的合成和煅烧样品进行了表征。样品的晶粒尺寸采用Debye - Scherer公式,考虑最强峰。红外光谱分析表明,样品中存在与SnO2和NiO相对应的不同金属氧化物峰。
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引用次数: 0
NiO nanoparticles: Phase purification and strain analysis NiO纳米颗粒:相纯化和应变分析
Pub Date : 2021-01-01 DOI: 10.1063/5.0061305
Adiba, V. Pandey, S. Munjal, T. Ahmad
The vast number of applications of transition metal oxide has prompted research in many advanced fields. NiO, which belongs to this category of application oriented research, is discussed in this article. It is confirmed from the XRD analysis that the nanoparticles are in pure phase with space group Fm3m. XRD plot of the intermediate product is also discussed. Average particle size and micro-strain is calculated using Williamson Hall (WH) plot and the results obtained are compared with that obtained from DebyeScherrer equation.
过渡金属氧化物的广泛应用促进了许多先进领域的研究。本文就属于这一面向应用的研究范畴的NiO进行了讨论。XRD分析证实纳米颗粒为纯相,空间基团为Fm3m。并对中间产物的XRD图进行了讨论。采用Williamson Hall (WH)图计算了平均粒径和微应变,并与DebyeScherrer方程进行了比较。
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引用次数: 11
On solar sources of geomagnetic storms of solar cycle 23 and their relation with CMEs 第23太阳周期地磁风暴的太阳源及其与cme的关系
Pub Date : 2021-01-01 DOI: 10.1063/5.0061278
Lavkush Kumar, Vikash Dubey
Geomagnetic storms are disturbances in the Earth’s magnetosphere. Coronal mass ejections (CMEs) and corotating interaction regions (CIRs) are considered as two major sources of geomagnetic disturbances. Here we have studied halo CMEs and, their solar surface sources and associated geomagnetical disturbances from January, 1996 to December, 2007. During the 12-year period of solar cycle-23 SOHO/LASCO detected 396 full halo CMEs. About 60% of these are found to be front side halo CMEs. These front side CMEs are found to produce geomagnetic storms at the Earth. We examine the properties of these CMEs which produce intense geomagnetic storms (DST ≤ -100 nT). The graphical plot between DST index and speed of CME shows a good correlation between them. It is found that front side CMEs associated with flares, which originate close to the central meridian and the southward component of interplanetary magnetic field BZ are the most potential candidates for producing intense geomagnetic storms. Further the occurrence of geomagnetic storms does not vary with the solar cycle and the mass of CMEs is not correlated with the DST index of storm. Our extensive study, based on complete solar cycle 23 data, confirms the results of previous studies.
地磁风暴是地球磁层的扰动。日冕物质抛射(cme)和自旋相互作用区(CIRs)被认为是地磁扰动的两个主要来源。本文对1996年1月至2007年12月的日冕日冕抛射及其太阳表面源和相关地磁扰动进行了研究。在太阳周期23的12年期间,SOHO/LASCO探测到了396次完整的日冕物质抛射。其中大约60%是正面日冕日冕。人们发现这些正面日冕物质抛射会在地球上产生地磁风暴。我们研究了产生强烈地磁风暴(DST≤-100 nT)的日冕物质抛射的性质。DST指数与日冕物质抛射速度的关系图显示两者具有良好的相关性。发现与耀斑相关的正面日冕物质抛射,起源于靠近中央子午线和行星际磁场BZ的南向分量是产生强烈地磁风暴的最有可能的候选者。地磁暴的发生不随太阳活动周期的变化而变化,日冕物质质量与地磁暴的DST指数也不相关。我们的广泛研究,基于完整的太阳周期23的数据,证实了以前的研究结果。
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引用次数: 0
Computational investigation on 4-(2-Oxo-2H-benzo[h] chromen-4-ylmethoxy)-benzaldehyde benzofuran coumarin derivative 4-(2-氧- 2h -苯并[h]铬-4-基甲氧基)-苯甲醛苯并呋喃香豆素衍生物的计算研究
Pub Date : 2021-01-01 DOI: 10.1063/5.0060855
Sucheta Mallikarjunaiah, Pramod Ajjampura Girish, Renuka Challakere Gurumurthy
In this computational investigation on 4-(2-Oxo-2H-benzo[h]chromen-4-ylmethoxy)benzaldehydebenzofuranderivative, the compound is initially optimized to get the clear structure,then it is used for further investigation. The highest occupied molecular orbitals, lowest unoccupied molecular orbitals, theoretical bandgap energy, electrostatic potential map such as total electron density and molecular electrostatic potential map were estimated at the ground state. From the molecular orbital structure, the HOMO value is found to be E=-7.119 eV and the LUMO value is found to be E= -4.999 eV, In view of that, bandgap energy is found to have 2.35 eV in the ground state. The electrostatic potential maps in both the cases revealed the compound showed the most electronegative site at oxygen attached group of the titled benzofuran derivative and showed nucleophilic site at 9C, 10C, 11C, 12C, 14C, 15C, and 18C atoms of the benzofuran derivative.
在对4-(2-氧- 2h -苯并[h]铬-4-基甲氧基)苯甲醛苯并呋喃衍生物的计算研究中,首先对化合物进行了优化,得到了清晰的结构,然后将其用于进一步的研究。在基态估计了最高已占据分子轨道、最低未占据分子轨道、理论带隙能、总电子密度和分子静电势图等静电势图。由分子轨道结构可知HOMO值为E=-7.119 eV, LUMO值为E= -4.999 eV,由此可知基态带隙能为2.35 eV。两种情况下的静电势图显示,化合物在苯并呋喃衍生物的氧基团上具有最大的电负性位点,而在苯并呋喃衍生物的9C、10C、11C、12C、14C、15C和18C原子上具有亲核位点。
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引用次数: 0
Supramolecular architectures in salts of thiophene carboxylic acids with nitrogenous bases 含氮基噻吩羧酸盐的超分子结构
Pub Date : 2021-01-01 DOI: 10.1063/5.0060875
O. Prajina, M. S. Babu, D. Geiger, P. T. Muthiah
Predictions on supramolecular interactions are helpful for the design of novel active pharmaceutical products. Thiophene based compounds along with various nitrogeneous bases are used in the preparation of such multi-component crystalline materials. Single crystals of 5-fluoro cytosinium 3-chlorothiophene -2carboxylate (compound I) and 5,5’Dimethyl -2,2’-bipyridinium thiophene -2,5dicarboxylatethiophene -2,5-dicarboxylic acid (2:2:1) (compound II) were synthesized and the supramolecular interactions stabilizing their crystal structures were investigated. R22(8) supramolecular heterosynthon was observed in (I). N-H...O, C-H...Cl, F...π and Cl...π interactions were mainly observed in supramolecular architecture of compound I. Fluorine involving interactions were observed in larger abundance and they are highly directional. N-H...O, O-H...O, C-H...O, C-H...π and π...π interactions stabilizes compound II. Compound II is an example of a structure with symmetric hydrogen bond. Thiophene 2, 5dicarboxylic acid coexisted in both neutral and mono-anionic form in compound II.
超分子相互作用的预测有助于新型活性药物的设计。噻吩基化合物与各种含氮碱一起用于制备这种多组分结晶材料。合成了5-氟胞嘧啶- 3-氯噻吩-2羧酸酯(化合物I)和5,5 '二甲基-2,2 ' -联吡啶噻吩-2,5二羧酸(2:2:1)(化合物II)的单晶,并研究了稳定其晶体结构的超分子相互作用。在(I)中观察到R22(8)超分子异合子。O,碳氢键……Cl, F……π和Cl…π相互作用主要在化合物i的超分子结构中观察到,氟参与相互作用的丰度较大,且具有高度的方向性。- h……啊,地……O,碳氢键……O,碳氢键……π和π…π相互作用稳定化合物II。化合物II是具有对称氢键结构的一个例子。噻吩- 2,5二羧酸在化合物II中以中性和单阴离子形式共存。
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引用次数: 0
Design of a two-dimensional chalcogenide photonic crystal for application as a band pass filter 用于带通滤波器的二维硫系光子晶体的设计
Pub Date : 2021-01-01 DOI: 10.1063/5.0060901
Rajpal Singh, A. Bhargava
In this paper, we have designed a twodimensional (2D) photonic crystal structure using chalcogenide glass for band pass filter application. A two dimensional square lattice structure is taken with chalcogenide rods in air. The filter is formed by creating two linear waveguides on both side of a point defect. The resonant mode is then coupled between the waveguide and point defect, which allows the requisite frequencies to pass. The effect of size of defect on the transmission and electric field distribution is also studied.
在本文中,我们设计了一个二维光子晶体结构的硫系玻璃带通滤波器的应用。在空气中采用硫属化物棒构成二维方形晶格结构。该滤波器是通过在点缺陷的两侧创建两个线性波导形成的。然后,谐振模式耦合在波导和点缺陷之间,从而允许所需的频率通过。研究了缺陷尺寸对透射率和电场分布的影响。
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引用次数: 0
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NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020
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