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Effect of tungsten doping on the properties of PZN-PT single crystals 钨掺杂对PZN-PT单晶性能的影响
Pub Date : 2021-09-13 DOI: 10.1063/5.0060880
B. Srimathy, J. Kumar, P. R. Babu
Single crystals of tungsten doped lead zinc niobate-lead titanate (W:PZN-PT) were grown by high temperature solution growth technique and their properties were investigated. Formation of perovskite phases were confirmed from X-Ray diffraction analysis. Temperature dependent dielectric properties demonstrated an increase in the value of dielectric constant (e’) and a decrease in Curie temperature TC compared to undoped PZN:PT. Enhanced ferroelectric and piezoelectric properties were observed, thus promising them as excellent materials to be used as soft ferroelectrics.
采用高温固相生长技术制备了钨掺杂铌酸铅锌钛酸铅(W:PZN-PT)单晶,并对其性能进行了研究。x射线衍射分析证实了钙钛矿相的形成。与未掺杂的PZN:PT相比,PZN:PT的介电常数(e′)增加,居里温度(TC)降低。观察到铁电和压电性能的增强,从而有望成为软铁电材料。
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引用次数: 1
Investigation on chemical instability and optical absorption of ion bombarded Si surfaces 离子轰击硅表面的化学不稳定性和光学吸收研究
Pub Date : 2021-09-13 DOI: 10.1063/5.0060833
J. Mukherjee, D. Bhowmik, P. Karmakar
Ion beam induced nano ripple formation has gained enormous interest for its potential applications in different fields like DNA origami, magnetic anisotropy, anti-reflection coating, tuning hydrophobicity etc. The ripple pattern formation on solid surface is explained as an instability generation due to sputtering of surface atoms, mass redistribution, and chemical instability owing to preferential sputtering. In the present framework, we have investigated how the variation of chemical phase formation by NO+, N2+ and O2+ion bombardment alters the chemical instability, which influencesthe ripple pattern formation on surface.In case of NO+ ion bombardment, silicon oxide and nitride (which later turned into oxynitride in presence of ripple)are simultaneously formed, whereas in case of N2+ or O2+ bombardment, either silicon nitride or silicon oxide is formed. Hence, the instability generation due to sputtering of both elemental silicon and its two compounds (oxide and nitride) causes additional instability generation in case of NO+ than N2+ or O2+, resulting in early ripple formation.The sputtering yield of pure Si and its compounds in each cases are calculated using SRIM freeware. Surface chemical nature, detected using X-ray photo electron spectroscopy, confirms the formation ofsilicon nitride and silicon oxide respectively in case of nitrogen and oxygen bombardment, whereas the NO+ bombardment causes the formation of silicon oxide with silicon oxynitride. The optical absorption of such structurally and chemically modified surfaces, examined by UV-VIS spectroscopy, reveals more absorbance of UV-VIS spectra (200-800 nm) for N2+ bombarded and NO+ bombarded surfaces than virgin and O2+ bombarded Si surfaces. Hence, N2 and NO+ bombarded Si surfaces are more suitable for anti-reflective coating surface.
离子束诱导的纳米纹波在DNA折纸、磁各向异性、增透涂层、调谐疏水性等领域的潜在应用引起了人们的极大兴趣。固体表面波纹图案的形成被解释为由于表面原子溅射、质量重分布和优先溅射引起的化学不稳定性而产生的不稳定性。在目前的框架下,我们研究了NO+, N2+和O2+离子轰击化学相形成的变化如何改变化学不稳定性,从而影响表面波纹图案的形成。在NO+离子轰击的情况下,氧化硅和氮化物(后来在纹波的存在下变成氮化氧)同时形成,而在N2+或O2+轰击的情况下,要么形成氮化硅,要么形成氧化硅。因此,由于单质硅及其两种化合物(氧化物和氮化物)的溅射而产生的不稳定性,在NO+的情况下会比N2+或O2+产生更多的不稳定性,导致早期波纹形成。用SRIM软件计算了每种情况下纯硅及其化合物的溅射产率。利用x射线光电子能谱检测表面化学性质,证实了氮轰击和氧轰击分别形成氮化硅和氧化硅,而NO+轰击导致氧化硅与氮化硅形成氧化硅。通过紫外-可见光谱检测了这种结构和化学修饰表面的光学吸收,发现N2+轰击和NO+轰击表面的紫外-可见光谱(200-800 nm)的吸光度高于原始和O2+轰击的Si表面。因此,N2和NO+轰击Si表面更适合作为抗反射涂层表面。
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引用次数: 0
Effect of D-block element Co 2+ substitution on structural and vibrational properties of spinel ferrites d嵌段元素Co 2+取代对尖晶石铁氧体结构和振动性能的影响
Pub Date : 2021-09-13 DOI: 10.1063/5.0061248
K. Patil, S. Phadke, A. Mishra
A series of Cu-C o ferrite based bulk particles (Cu (1-x) Co(x)Fe2O4) in which x is varied from 0.0 to 0.6 were prepared by Solid State reaction route. The influence of the Co content on the structural properties of cubic Nickel ferrites (CuFe2O4) was investigated using Raman spectroscopy. Slight reduction in the lattice parameter of Co doped CuFe2O4 has been observed as compared to the parent CuFe2O4. From Raman scattering spectra, a shoulder like feature has been observed in both parent and doped com pounds which reveals that octahedral site is occupied by Co, Cu and Fe ions and tetrahedral site is occupied by only Feion.
采用固相反应法制备了一系列以Cu- c - o铁氧体为基的体积颗粒(Cu (1-x) Co(x)Fe2O4),其中x在0.0 ~ 0.6之间变化。利用拉曼光谱研究了Co含量对立方镍铁氧体(CuFe2O4)结构性能的影响。与母体CuFe2O4相比,Co掺杂CuFe2O4的晶格参数略有降低。从拉曼散射光谱上看,在母晶和掺杂晶中均观察到肩状特征,表明Co、Cu和Fe离子占据了八面体位置,而四面体位置仅被Feion占据。
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引用次数: 2
Ceramic synthesis and X-ray diffraction characterization of copper ferrite 铁氧体铜的陶瓷合成及x射线衍射表征
Pub Date : 2021-09-13 DOI: 10.1063/5.0061009
V. K. Surashe, N. N. Waghule, A. V. Raut, A. A. Pandit, R. Dorik, K. M. Jadhav
Copper ferrite (CuFe2O4) particles have been synthesized by the standard ceramic technique. The prepared copper ferrite particles were sintered at 800 ℃ for 12h. The pre-sintered sample is again reground in fine powder and pelletized using a hydraulic press. These pallets were finally sintered at 1050 °C for 12 h and the structural properties of copper ferrite were investigated and reported in this work. The X-ray diffraction analysis revealed that synthesized copper ferrite particles possess a single phase cubic spinel structure. A keen observation of the X-ray diffraction pattern showed the average crystallite size (t) of the copper ferrite obtained from Scherrer's formula as 140 nm. The lattice constant (a) and other structural parameters are in the reported range.
采用标准陶瓷技术合成了铜铁氧体(CuFe2O4)颗粒。制备的铁素体铜颗粒在800℃下烧结12h。预烧结的样品再次重新研磨成细粉,并使用液压机制成球团。最后在1050℃下烧结12 h,对铁素体铜的结构性能进行了研究。x射线衍射分析表明,合成的铁素体铜颗粒具有单相立方尖晶石结构。对x射线衍射图的仔细观察表明,根据Scherrer公式得到的铁氧体铜的平均晶粒尺寸(t)为140 nm。晶格常数(a)及其他结构参数均在报告范围内。
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引用次数: 1
Temperature dependent AC conductivity of multiwall carbon nanotube-polystyrene micro-thick composite films 多壁碳纳米管-聚苯乙烯微厚复合薄膜的温度依赖性交流电导率
Pub Date : 2021-09-13 DOI: 10.1063/5.0062249
Reena Rani, M. Sharma, S. Rani, I. Sameera, Ravi Bhatia
Light weight electrically conducting materials that can be fabricated at low cost and are important for certain applications like electromagnetic shielding and field emission devices; carbon nanotubes based-composite materials are most suited for such applications. However, it is quite important to study the temperature dependent electrical behaviour. Here, we are presenting the experimental results on temperature dependent AC conductivity of few hundred micron-thick multiwall carbon nanotube-polystyrene (MWCNT-PS) composites (0.5 & 1.0 wt.%), in the temperature and frequency ranges of 154-293 K and 10 Hz-10 MHz, respectively. The free standing MWCNT-PS composite films were prepared by a simple and cost-effective solution approach, and their good quality was ascertained after characterizing by field emission scanning electron microscopy.For 0.5 wt. % composite film, the conductivity did not show any variation up to 1 MHz at all the temperatures whereas it monotonically increased from 1 MHz to 10 MHz; it followed Jonscher's law. Further, the threshold frequency shifted towards higher frequency with the temperature. The DC conductivity was observed to decrease from 34 µS/cm to 22 µS/cm with variation of temperature from 293 to 154 K, respectively; this decrease of DC conductivity is attributed to increase of activation energy of charge carriers at low temperatures. Interestingly, AC conductivity of 1.0 wt. % sampledid not exhibit any frequency dependence at any temperature; however, DC conductivity reduced to 37 µS/cm (154 K) from 70 µS/cm (293 K).
可以以低成本制造的轻质导电材料,对电磁屏蔽和场发射装置等某些应用很重要;碳纳米管基复合材料最适合这种应用。然而,研究与温度相关的电学行为是非常重要的。在这里,我们展示了几百微米厚的多壁碳纳米管-聚苯乙烯(MWCNT-PS)复合材料(0.5 & 1.0 wt.%)在154-293 K和10 Hz-10 MHz的温度和频率范围内的温度相关的交流电导率的实验结果。采用简单、经济的溶液法制备了独立的MWCNT-PS复合薄膜,并通过场发射扫描电镜对其进行了表征。对于0.5 wt. %的复合薄膜,在所有温度下,电导率在1 MHz以内没有任何变化,而在1 MHz至10 MHz之间单调增加;它遵循琼舍尔定律。随着温度的升高,阈值频率向高频偏移。在293 ~ 154 K温度范围内,直流电导率分别从34µS/cm下降到22µS/cm;直流电导率的降低是由于低温下载流子活化能的增加。有趣的是,1.0 wt. %样品的交流电导率在任何温度下都没有表现出任何频率依赖性;然而,直流电导率从70µS/cm (293 K)降低到37µS/cm (154 K)。
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引用次数: 0
Preparation and characterization of vanadium oxide nanostructure 氧化钒纳米结构的制备与表征
Pub Date : 2021-09-13 DOI: 10.1063/5.0061223
S. Manhas, Ginni, S. Bisoyi, A. D. Acharya, S. Moghe, V. K. Hinge
The different fundamental properties of nanostructure strongly depend on their shapes, sizes. By controlling such parameters one can achieve the desired properties of the nanoparticles. In the present study different shape of Vanadium oxide (V2O5) nanostructures were synthesized using solution cast method. Morphological and structural properties of the prepared samples were studied by using field effect scanning electron microscopy (FESEM) and X-ray diffraction (XRD) techniques. FESEM images reveal the flower and rod shape of nanoparticles. XRD peaks showed the orthorhombic structure of V2O5.
纳米结构的不同基本性质在很大程度上取决于它们的形状和大小。通过控制这些参数,可以获得纳米颗粒所需的性能。采用溶液浇铸法制备了不同形状的氧化钒纳米结构。采用场效应扫描电镜(FESEM)和x射线衍射(XRD)技术对制备的样品进行了形貌和结构表征。FESEM图像显示了纳米颗粒的花状和棒状。XRD峰显示了V2O5的正交结构。
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引用次数: 0
Ultrasonic attenuation measurement in the mixture of cyclohexane and methanol 环己烷与甲醇混合物的超声衰减测量
Pub Date : 2021-09-13 DOI: 10.1063/5.0060949
R. Thete, M. Shanti
Ultrasonic technique is a powerful tool for the study of inter and intra-molecular interactions in a mixture. It is a non-destructive testing tool. Low amplitude ultrasonic propagation, as is used for the present work, does not change the molecular structure of a liquid. This technique is the most preferred one as it will not allow local heating. Liquid mixtures behave critically with the change in temperature and concentration in any of the component. In the present work, physical properties of mixture of cyclohexane and methanol are studied using ultrasonic pulse echo technique. Ultrasonic attenuation is measured to study mixture of cyclohexane and methanol. Present system is operated at 5 MHz frequency and the mixture is studied in the controlled temperature environment by using Thermostat (Julabo F32) with an accuracy of ±0.10C. Non-linearity in ultrasonic attenuation with maxima and minima is observed due to concentration fluctuations in the given mixture.
超声技术是研究混合物分子间和分子内相互作用的有力工具。它是一种无损检测工具。低振幅超声传播,如用于本工作,不会改变液体的分子结构。这种技术是最受欢迎的,因为它不允许局部加热。液体混合物随其任一组分的温度和浓度的变化而变化。本文利用超声脉冲回波技术研究了环己烷与甲醇混合物的物理性质。对环己烷与甲醇的混合物进行了超声衰减测量。本系统工作频率为5mhz,使用恒温器(Julabo F32)在温度控制环境下对混合物进行研究,温度控制精度为±0.10C。由于给定混合物中浓度的波动,超声波衰减具有极大值和极小值的非线性。
{"title":"Ultrasonic attenuation measurement in the mixture of cyclohexane and methanol","authors":"R. Thete, M. Shanti","doi":"10.1063/5.0060949","DOIUrl":"https://doi.org/10.1063/5.0060949","url":null,"abstract":"Ultrasonic technique is a powerful tool for the study of inter and intra-molecular interactions in a mixture. It is a non-destructive testing tool. Low amplitude ultrasonic propagation, as is used for the present work, does not change the molecular structure of a liquid. This technique is the most preferred one as it will not allow local heating. Liquid mixtures behave critically with the change in temperature and concentration in any of the component. In the present work, physical properties of mixture of cyclohexane and methanol are studied using ultrasonic pulse echo technique. Ultrasonic attenuation is measured to study mixture of cyclohexane and methanol. Present system is operated at 5 MHz frequency and the mixture is studied in the controlled temperature environment by using Thermostat (Julabo F32) with an accuracy of ±0.10C. Non-linearity in ultrasonic attenuation with maxima and minima is observed due to concentration fluctuations in the given mixture.","PeriodicalId":18837,"journal":{"name":"NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020","volume":"45 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77191616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis, characterization and antimicrobial activity of copper nanoparticles derived from Fusarium oxysporum 尖孢镰刀菌铜纳米颗粒的绿色合成、表征及抗菌活性研究
Pub Date : 2021-09-13 DOI: 10.1063/5.0061299
K. Gupta, T. Chundawat
The formation of nanoparticles from microbes has received special attention in wide range of applications like antimicrobial activities, less toxic to environment and many others. The present research uses fungus Fusarium oxysporum for the extracellular synthesis of copper nanoparticles from copper acetate solution. The UV-Vis spectroscopy and change in solution color was used as a confirmation for formation of nanoparticles. The copper nanoparticles characterization was performed by using XRD, FTIR and SEM. FTIR results indicates possible functional groups involved in reduction of copper ions into copper nanoparticles and their stabilization. XRD pattern cleared that the biosynthesized nanoparticles had face-centered cubic (FCC) geometry with crystalline nature. The size and morphology of as-synthesized nanoparticles was determined by using SEM micrographs. Antimicrobial activity against different bacterial strains such as Pseudomonas aeruginosa, Escherichia coli, Klebsiella pneumoniae, and Staphylococcus aureus was studied by measuring the zone of inhibition and Minimum inhibitory concentration was also studied.
微生物形成的纳米颗粒在抗菌活性、对环境的低毒性等方面的广泛应用受到了人们的特别关注。本研究利用尖孢镰刀菌对醋酸铜溶液进行细胞外合成纳米铜。紫外可见光谱和溶液颜色的变化证实了纳米颗粒的形成。采用XRD、FTIR和SEM对铜纳米颗粒进行了表征。FTIR结果表明可能的官能团参与了铜离子还原成铜纳米粒子及其稳定。XRD图谱表明,合成的纳米颗粒具有面心立方(FCC)结构,具有晶体性质。利用扫描电镜(SEM)对合成的纳米颗粒的大小和形貌进行了测定。通过测定抑菌带,研究了其对铜绿假单胞菌、大肠杆菌、肺炎克雷伯菌、金黄色葡萄球菌等不同菌株的抑菌活性和最低抑菌浓度。
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引用次数: 2
Dielectric properties and AC conductivity of green synthesized nano La2O3/La(OH)3 绿色合成纳米La2O3/La(OH)3的介电性能和交流电导率
Pub Date : 2021-09-13 DOI: 10.1063/5.0061274
Marymol Moothedan, K. B. Sherly
In this study nano lanthanum oxide (La2O3) was synthesized by starch template method. The physicochemical characterization of La2O3 was carried out by versatile techniques like TGA-DTG/DSC, XRD and FT-IR. The XRD analysis confirms the pure phase and hexagonal structure of La2O3. Thermal analysis of La2O3 precursors proved to be useful to understand the mechanism of thermal degradation behaviour during the formation of La2O3. The synthesized La2O3 was chemically unstable in ambient air due to its hygroscopic nature and a complete transformation into hexagonal lanthanum hydroxide (La(OH)3) was detected. Investigations of dielectric parameters viz. capacitance, dielectric constant, dielectric loss and ac conductivity measurements of La2O3 and La(OH)3 were done using impedance spectroscopy. La(OH)3 found to have high capacitance, high dielectric constant and high ac conductivity with almost same dissipation factor compared to La2O3.
本研究采用淀粉模板法合成了纳米氧化镧(La2O3)。采用tg - dtg /DSC、XRD、FT-IR等多种技术对La2O3进行了理化表征。XRD分析证实了La2O3的纯相和六方结构。对La2O3前驱体的热分析有助于了解La2O3形成过程中热降解行为的机理。合成的La2O3具有吸湿性,在环境空气中化学性质不稳定,完全转变为六方氢氧化镧(La(OH)3)。用阻抗谱法测定了La2O3和La(OH)3的介电参数,即电容、介电常数、介电损耗和交流电导率。与La2O3相比,La(OH)3具有高电容、高介电常数和高交流电导率,且耗散系数几乎相同。
{"title":"Dielectric properties and AC conductivity of green synthesized nano La2O3/La(OH)3","authors":"Marymol Moothedan, K. B. Sherly","doi":"10.1063/5.0061274","DOIUrl":"https://doi.org/10.1063/5.0061274","url":null,"abstract":"In this study nano lanthanum oxide (La2O3) was synthesized by starch template method. The physicochemical characterization of La2O3 was carried out by versatile techniques like TGA-DTG/DSC, XRD and FT-IR. The XRD analysis confirms the pure phase and hexagonal structure of La2O3. Thermal analysis of La2O3 precursors proved to be useful to understand the mechanism of thermal degradation behaviour during the formation of La2O3. The synthesized La2O3 was chemically unstable in ambient air due to its hygroscopic nature and a complete transformation into hexagonal lanthanum hydroxide (La(OH)3) was detected. Investigations of dielectric parameters viz. capacitance, dielectric constant, dielectric loss and ac conductivity measurements of La2O3 and La(OH)3 were done using impedance spectroscopy. La(OH)3 found to have high capacitance, high dielectric constant and high ac conductivity with almost same dissipation factor compared to La2O3.","PeriodicalId":18837,"journal":{"name":"NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020","volume":"133 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73814441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Potential applications of nanoparticles embedded U-bent fiber optic probe 纳米粒子嵌入u型弯曲光纤探头的潜在应用
Pub Date : 2021-09-13 DOI: 10.1063/5.0060856
Revathy Sundara Moorthy, Rohini Rondla, M. Kavitha, P. H. Bindu, C. Pasha, P. M. Reddy
As an emerging interdisciplinary, nanotechnology combined optical technology has drawn phenomenal attention in most of the fields. As a result, many novel sensors of nanoparticles (NPs) embedded U-bent Fiber optic probe have been developed. This paper deals about the spectacular growth of this novel strategythat is based on the evanescent wave signal and the NPs ability to tune LSPR (local surface plasmon resonance) adding more potential. A study has been made on its diverse applications ranging from parameters monitoring down to biomolecule detection till recent pandemic identification are discussed.
纳米技术结合光学技术作为一门新兴的交叉学科,在许多领域引起了极大的关注。因此,许多新型的纳米粒子嵌入u型弯曲光纤探头传感器被开发出来。本文讨论了这种基于倏逝波信号和NPs调节LSPR(局部表面等离子体共振)的能力的新策略的惊人增长。研究了从参数监测到生物分子检测到最近的大流行鉴定的各种应用。
{"title":"Potential applications of nanoparticles embedded U-bent fiber optic probe","authors":"Revathy Sundara Moorthy, Rohini Rondla, M. Kavitha, P. H. Bindu, C. Pasha, P. M. Reddy","doi":"10.1063/5.0060856","DOIUrl":"https://doi.org/10.1063/5.0060856","url":null,"abstract":"As an emerging interdisciplinary, nanotechnology combined optical technology has drawn phenomenal attention in most of the fields. As a result, many novel sensors of nanoparticles (NPs) embedded U-bent Fiber optic probe have been developed. This paper deals about the spectacular growth of this novel strategythat is based on the evanescent wave signal and the NPs ability to tune LSPR (local surface plasmon resonance) adding more potential. A study has been made on its diverse applications ranging from parameters monitoring down to biomolecule detection till recent pandemic identification are discussed.","PeriodicalId":18837,"journal":{"name":"NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020","volume":"29 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79882525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020
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