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Examination of Thermoplastic Polymers for Splicing and Bending 热塑性聚合物的拼接和弯曲检验
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2023-02-03 DOI: 10.4028/p-8myjhn
P. H. Tjahjanti, Iswanto, E. Widodo, Sholeh Pamuji
Materials of thermoplastic polymer when they break is usually thrown away, or is recycled which requires a long process. The purpose of this study is splicing the broken thermoplastic polymer using hot gas hand welding with different variations of welding wire/electrodes. Materials of thermoplastic polymer used are Polyethylene (PE), Polypropylene (PP), and Polyvinyl chloride (PVC) by using welding wire like the three materials. The method is carried out by using hot gas hand welding, there are two materials that cannot be connected, namely PE with PVC welding wire, and PP with PVC welding wire. The permeable liquid penetrant test is PP with PE welding wire, and PVC with PE welding wire. The longest elongation is PE with PE welding wire is 15.96% and the best of bending result is PVC with PVC welding wire reach value 181.2 kgf/mm2. The microstructure was all described in Scanning Electron Microscopy (SEM) observations.
热塑性聚合物材料破裂后通常被扔掉,或者需要一个漫长的过程来回收。本研究的目的是用不同的焊丝/电极,用热气手焊将破碎的热塑性聚合物进行拼接。热塑性聚合物使用的材料是聚乙烯(PE),聚丙烯(PP)和聚氯乙烯(PVC),采用焊丝和这三种材料一样。该方法采用热气手焊进行,有两种材料不能连接,即PE用PVC焊丝,PP用PVC焊丝。可渗透液体渗透试验是PP与PE焊丝,PVC与PE焊丝。伸长率最长的是PE, PE焊丝的伸长率为15.96%;弯曲效果最好的是PVC, PVC焊丝的伸长率可达181.2 kgf/mm2。显微结构均通过扫描电镜(SEM)观察得到。
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引用次数: 0
Ab Initio Calculations of the Atomic Structure, Stability, and Electronic Properties of (C6H10O5)2 Encapsulation into Hydrogen-Doped Carbon Nanotube (C6H10O5)2包封在掺杂氢碳纳米管中的原子结构、稳定性和电子性质的从头计算
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2023-02-03 DOI: 10.4028/p-3uk80a
A. A. Pido, A. Munio, Leo Cristobal C. Ambolode II
This research investigated the Hydrogen doping of the single-walled carbon nanotube (HCNT) with encapsulated cellulose, (C6H10O5)2, and provide theoretical predictions on the properties of the resulting complex system. After full structural optimization, two different bond lengths and angles in the HCNT and (C6H10O5)2/HCNT system were calculated. Further, it was found that substitutional H atoms acted as charge acceptors and drove necessary rearrangements in the valence region. The (C6H10O5)2 caused some peaks at the valence band mainly caused by the p orbitals of the oxygen atoms. A bandgap decrease has been observed for the (C6H10O5)2/HCNT system. The results are consistent with the previous works which demonstrated the possibility of band gap engineering in CNTs.
本研究对单壁碳纳米管(HCNT)与包封纤维素(C6H10O5)2的氢掺杂进行了研究,并对所得到的复合体系的性能进行了理论预测。经过充分的结构优化,计算了HCNT和(C6H10O5)2/HCNT体系中两种不同的键长和键角。此外,还发现取代的H原子充当电荷受体,并在价区驱动必要的重排。(C6H10O5)2在价带上产生了一些峰,主要是由氧原子的p轨道引起的。(C6H10O5)2/HCNT体系的带隙减小。结果与前人的研究结果一致,证明了碳纳米管中带隙工程的可能性。
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引用次数: 6
Low Velocity Impact Behaviour of Composite Laminates Containing TiC and ZrC Nanoparticles in Resin System 含TiC和ZrC纳米颗粒复合层压板在树脂体系中的低速冲击性能
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2023-02-03 DOI: 10.4028/p-ul755z
Pelin Alabay, F. Elaldi
Composite structures utilized in defence and aerospace applications might be subjected to impacts due to bird strike, tool dropping and bullet penetration. One of the approaches to this problem is to add nano tubes and nano particles to resin systems in order to improve bonding between fibres and matrix materials. Different nano-particles or nano-tubes of clays, alumina, silica, carbon and graphene have been analysed in composite systems in the literature so far because of the improved mechanical properties. In this study, the low velocity impact behaviour of the aramid fibre reinforced epoxy composite plates, containing two new nano-particles of TiC and ZrC which are not studied formerly, are searched experimentally. After the low velocity impact tests, it is concluded that plates containing titanium carbide nano-particles and zirconium nano-particles yielded 19 % and 4 % respectively less penetration in comparison with particle free plates. In other words, titanium carbide nano-particles contained plates showed more resistance against the impact by 19 % against to particle free plates. These results showed that TiC and ZrC nano particles might be also good contributors for the impact resistance of composite structure.
用于国防和航空航天应用的复合材料结构可能受到鸟击、工具掉落和子弹穿透的影响。解决这个问题的方法之一是在树脂体系中加入纳米管和纳米颗粒,以改善纤维和基体材料之间的结合。不同的纳米颗粒或纳米管粘土、氧化铝、二氧化硅、碳和石墨烯在复合系统中进行了分析,因为它们的力学性能得到了改善。本文通过实验研究了含TiC和ZrC两种新型纳米颗粒的芳纶纤维增强环氧复合材料板的低速冲击性能。低速冲击试验表明,含碳化钛纳米颗粒和锆纳米颗粒的板的侵彻率分别比无颗粒板低19%和4%。也就是说,含碳化钛纳米颗粒的板对冲击的抵抗能力比无颗粒的板高19%。这些结果表明,TiC和ZrC纳米颗粒也可能是复合材料结构抗冲击性能的良好贡献者。
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引用次数: 0
Evaluation of Nanolime-Silica Core-Shell for Consolidation of Egyptian Limestone Samples with Application on an Archaeological Object 纳米石灰-二氧化硅核-壳对埃及石灰石固结的评价及其在考古对象上的应用
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-ant5zg
Mohamed Kamal Khalaf, Ahmed Roshdy Elsakhry, Sameh H. Ismail, M. Abdel-Hamied, G. Mohamed
The most of limestone objects in museums, storehouses and archaeological sites suffered from fragility and weakness which lead to the degradation of these artifacts. The present paper aims to evaluate the use of some nanolime-silica core-shell for consolidation process of these weak limestone artifacts. Two concentrations (5% and 10% w/w) were prepared for consolidating the aged limestone cubic samples. After complete drying, the cubic stones were exposed to the accelerated heat aging. The evaluation of consolidation process for the treated and aged treated samples was performed by some analytical methods such as measurement of physical properties and compressive strength. While, the investigation of surface morphology was carried out by scanning electron microscope (SEM) and measurement of contact angle. The characterization process for the prepared core-shell showed the smoothness and spherical shape of the grains with approximate size of 72 nm. The results of physical properties revealed that the treated samples with 10% of nanolime-silica core-shell gave the lowest porosity (15.57%) and water absorption (6.26%). Additionally, the treated samples with 10% concentration of nanolime-silica core-shell gave the highest values of compressive strength (21.23 Cm2/ Kg) and contact angle (122.78°). Moreover, the investigation using SEM revealed that the smoothness and good penetration for the treated sample with 10% concentration of nanolime-silica core-shell. The results of the present study revealed that the efficiency of consolidation process was maximum using 10% concentration of nanolime-silica core-shell and hence it was applied for consolidation of an archaeological limestone octagonal column, Egypt.
博物馆、仓库和考古遗址中的大多数石灰石物品都很脆弱,导致这些文物的退化。本文的目的是评估一些纳米石灰-二氧化硅核-壳在这些弱石灰岩人工制品固结过程中的应用。配制了5%和10% w/w的固结浓度,用于固结石灰石立方样。在完全干燥后,对立方石进行加速热老化。通过物理性能和抗压强度的测量等分析方法对处理后和时效处理后试样的固结过程进行了评价。同时,通过扫描电子显微镜(SEM)和接触角测量对表面形貌进行了研究。对所制备的核壳进行了表征,结果表明所制备的核壳颗粒光滑,呈球形,尺寸约为72 nm。物理性能结果表明,纳米石灰-二氧化硅核-壳掺量为10%时,孔隙率和吸水率最低,分别为15.57%和6.26%。当纳米石灰-二氧化硅核-壳浓度为10%时,试样的抗压强度和接触角最高,分别为21.23 Cm2/ Kg和122.78°。此外,通过扫描电镜研究发现,当纳米石灰-二氧化硅核-壳浓度为10%时,处理后的样品具有良好的光滑度和穿透性。本研究结果表明,当纳米石灰-二氧化硅核-壳浓度为10%时,固结过程的效率最高,因此它被应用于埃及考古石灰岩八角形柱的固结。
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引用次数: 1
Preliminary Research on the Analysis of Chromium(III) Based on Digital Image Processing Method Utilizing Gold Nanoparticles as Colorimetric Sensor 基于纳米金比色传感器的数字图像处理方法分析铬(III)的初步研究
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-t3ga7q
Pratyangga Surya Dyaninggar, S. J. Santosa, B. Rusdiarso
Gold nanoparticles (AuNPs) have been successfully synthesized using L-Ascorbic Acid as a reducing agent and p-Aminobenzoic Acid as a capping agent. These AuNPs were used to detect and quantify Chromium(III) as a pollutant utilizing its unique characteristic called surface plasmon resonance (SPR). The change of SPR and color of AuNPs then was employed to determine the concentration of Cr(III) by using colorimetric and Digital Image Colorimetric methods. Digital Image Colorimetry allowed to development of an easier and cheaper way to detect and quantify Cr(III). AuNPs capped p-aminobenzoic acid (AuNPs-PABA) were synthesized at room temperature without using any heating method. Then synthesized AuNPs-PABA were characterized using UV-Visible spectrometer and Transmission Electron Microscope. This AuNPs-PABA then got contacted to Cr(III) and color-changing happened in AuNPs-PABA was analyzed using UV-Vis Spectrometer and captured for Digital Image Colorimetric. The result showed that Digital Image Colorimetric method has a very big potential to be developed for AuNPs-based detection and quantification of Cr(III) as confirmed by good linearity of AuNPs-PABA-Cr(III) respect with Difference Intensity of Red Color Component, wider dynamic range, and Lower Limit of Detection (LoD).
以l -抗坏血酸为还原剂,对氨基苯甲酸为封盖剂,成功合成了金纳米颗粒(AuNPs)。这些aunp被用来检测和量化铬(III)作为污染物,利用其独特的特性,称为表面等离子体共振(SPR)。然后利用AuNPs的SPR和颜色变化,采用比色法和数字图像比色法测定Cr(III)的浓度。数字图像比色法可以开发一种更容易和更便宜的方法来检测和量化Cr(III)。在室温下合成了AuNPs-对氨基苯甲酸(AuNPs- paba)。利用紫外可见光谱和透射电镜对合成的AuNPs-PABA进行了表征。然后将AuNPs-PABA与Cr(III)接触,用紫外-可见光谱仪分析AuNPs-PABA发生的颜色变化,并将其捕获用于数字图像比色法。结果表明,基于AuNPs-PABA-Cr(III)的数字图像比色法对Cr(III)的检测和定量具有良好的线性关系,具有较宽的动态范围和较低的检测限(LoD),具有很大的发展潜力。
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引用次数: 0
The Effect of Carbon/Oxygen Ratio upon Structure-Property Relationships in Polymer/Graphene Nanocomposites 碳氧比对聚合物/石墨烯纳米复合材料结构-性能关系的影响
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-72519w
H. Aldosari
The oxygen functional group limits the performance of graphene oxide (GO). By raising the Carbon/Oxygen (C/O) ratio, reducing the oxygen functional group may enhance thermal stability. The effects of the (C/O) ratio of graphene derivatives on the structure-properties relationship in metallocene linear low-density polyethylene (PE), homo polypropylene (PP), and blends thereof were investigated in this research. Using reduced graphene oxide (rGO) and pristine graphene (G), the oxygen functional groups were reduced. The effect of raising the C/O ratio of GO, rGO, and G blending with PE and PP synthesized by solution blending is discussed. Solvent processing was used to synthesise these nanocomposites, with dimethylformamide) DMF (and o-xylene served as the solvents for graphene flakes and polymers, respectively, before the two components were combined to form a well-mixed initial state. Wide-angle X-ray diffraction was used to investigate the crystallisation of the nanocomposites (WAXD). X-ray photoelectron spectroscopy (XPS), ultraviolet visible spectroscopy (UVVS), and Raman spectroscopy were used to characterise the chemical structures, with the latter being used to calculate the intensity ratio of D and G band (ID/IG) value for pure graphene specimens. The C/O ratio was calculated as , 4.9 and 2.2 for the G, rGO and GO respectively. While the (ID/IG (increased with increasing the C/O ratio, the ID/IG values were calculated as 0.285, 1.137 and 1.726 for pure GO, rGO and G samples. Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) were used to determine the melting temperature ( ), crystallization temperature ( ) as well as a range of degradation temperatures.
氧官能团限制了氧化石墨烯(GO)的性能。通过提高碳/氧(C/O)比,减少氧官能团可以提高热稳定性。研究了石墨烯衍生物的碳氧比(C/O)对茂金属线性低密度聚乙烯(PE)、同质聚丙烯(PP)及其共混物结构-性能关系的影响。使用还原氧化石墨烯(rGO)和原始石墨烯(G)还原氧官能团。讨论了溶液共混法合成的PE和PP对提高氧化石墨烯、还原氧化石墨烯和G共混物的碳氧比的影响。采用溶剂法合成这些纳米复合材料,二甲基甲酰胺DMF(和邻二甲苯)分别作为石墨烯薄片和聚合物的溶剂,然后将两种成分结合形成良好混合的初始状态。利用广角x射线衍射研究了纳米复合材料(WAXD)的结晶。利用x射线光电子能谱(XPS)、紫外可见光谱(UVVS)和拉曼光谱(Raman)表征了石墨烯的化学结构,并利用拉曼光谱计算了纯石墨烯样品的D和G波段强度比(ID/IG)值。G、rGO和GO的C/O比值分别为4.9和2.2。随着碳氧比的增加,氧化石墨烯、还原氧化石墨烯和氧化石墨烯样品的ID/IG值分别为0.285、1.137和1.726。采用差示扫描量热法(DSC)和热重分析(TGA)测定了熔融温度()、结晶温度()以及降解温度范围。
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引用次数: 1
GMR Biosensor Based on Spin-Valve Thin Films for Green-Synthesized Magnetite (Fe3O4) Nanoparticles Label Detection 基于自旋阀薄膜的GMR生物传感器用于绿色合成磁铁矿(Fe3O4)纳米颗粒标记检测
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-v5gmkk
Ni’matil Mabarroh, Taufikuddin Alfansuri, N. Istiqomah, Rivaldo Marsel Tumbelaka, E. Suharyadi
The giant magnetoresistance (GMR) thin film with spin valve (SV) structure of Ta (2 nm)/Ir20Mn80(10 nm)/Co90Fe10(3 nm)/Cu (2.2 nm)/Co84Fe10B4(10 nm)/Ta (5 nm)] fabricated by RF magnetron sputtering method with a magnetoresistance (MR) of 6% was used in this work. Green synthesis of Fe3O4 magnetic nanoparticles (MNPs) using Moringa Oleifera (MO) leaf extract have been successfully conducted using the coprecipitation method. Fe3O4 MNPs demonstrated the inverse cubic spinel structure with the average crystallite size of 13.8 nm and decreased to 11.8 nm for Fe3O4/PEG. Fe3O4, as a magnetic label, integrated with a Wheatstone bridge-GMR sensor provides access to GMR-based biosensors. The induced-field increase leads the signal (ΔV) to increase with increasing nanoparticle concentration. It was discovered that a sensor can distinguish different types of magnetic labels. The sensitivity for Fe3O4 and MO-green synthesized Fe3O4 magnetic label was 0.04 and 0.1 mV/g/L, respectively. The GMR sensor performed the highest sensitivity on the MO-green synthesized Fe3O4 label. Thus, the SV thin film as a sensor and the green-synthesized Fe3O4 nanoparticles as a superior magnetic label are an excellent combination for biosensor application.
采用射频磁控溅射法制备了具有自旋阀(SV)结构的巨磁阻(GMR)薄膜,其结构为Ta (2nm)/Ir20Mn80(10nm)/Co90Fe10(3nm)/Cu (2.2 nm)/Co84Fe10B4(10nm)/Ta (5nm)],磁阻(MR)为6%。以辣木叶提取物为原料,采用共沉淀法成功合成了Fe3O4磁性纳米颗粒(MNPs)。Fe3O4 MNPs表现为反立方尖晶石结构,平均晶粒尺寸为13.8 nm, Fe3O4/PEG的晶粒尺寸减小到11.8 nm。Fe3O4作为磁性标签,与惠斯通电桥- gmr传感器集成,可以访问基于gmr的生物传感器。诱导场的增加导致信号(ΔV)随着纳米颗粒浓度的增加而增加。人们发现,一种传感器可以区分不同类型的磁性标签。Fe3O4和MO-green合成Fe3O4磁标签的灵敏度分别为0.04和0.1 mV/g/L。GMR传感器对MO-green合成Fe3O4标签的灵敏度最高。因此,SV薄膜作为传感器和绿色合成的Fe3O4纳米颗粒作为优越的磁标记是生物传感器应用的绝佳组合。
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引用次数: 0
Direct Transfer Manufacturing of Flexible Silicon Carbide Nanowire-Network Prototype Device 柔性碳化硅纳米线网络原型器件的直接转移制造
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-d0o9il
M. S. Onder, K. Teker
Flexible and transparent devices are expected to meet increasing consumer demands for upgrades in wearable devices, smart electronic and photonic applications. In this work, nano-manufacturing of a flexible and powerless silicon carbide nanowire network ultraviolet photodetector (SiCNW-network UVPD) prototype was investigated by a very cost-effective direct transfer method. Indeed, the powerless device exhibited a photo-to-dark current ratio (PDCR) of 15 with a responsivity of 5.92 mA/W at 254 nm wavelength exposure. The reliability and durability of the device was evaluated by bending tests. In fact, the PDCR of the device was still very good even after seventy-five bending cycles (~ 96 % of the rest state). In brief, our flexible, powerless SiCNW-network UVPD device with cost-effectiveness, good performance, and durability can provide feasible alternatives for new generation wearable optoelectronic products.
灵活和透明的设备有望满足消费者对可穿戴设备,智能电子和光子应用升级的日益增长的需求。在这项工作中,研究了柔性和无功率碳化硅纳米线网络紫外线探测器(SiCNW-network UVPD)原型的纳米制造方法。事实上,无功率器件在254 nm波长下的光暗电流比(PDCR)为15,响应度为5.92 mA/W。通过弯曲试验对该装置的可靠性和耐久性进行了评价。事实上,即使经过75次弯曲循环(~ 96%的休息状态),该装置的PDCR仍然很好。总之,我们的柔性无功率sicnw网络UVPD器件具有成本效益、良好的性能和耐用性,可以为新一代可穿戴光电产品提供可行的替代方案。
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引用次数: 0
Study of Structural and Electrical Properties of CuFe-CGN for Renewable Energy Applications 可再生能源用CuFe-CGN结构与电学性能研究
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-co85a8
Amna Siddique, M. Anis-Ur-Rehman
Renewable energy source is a clean energy production source and can overcome climatic challenges caused by the excessive use of fossil fuels. The nanocrystalline material of composition Cu0.2Fe0.2(Ce0.6Gd0.4-xNdx)0.6O2-x has been synthesized by WOWS sol-gel process by varying Neodymium as such x= 0.0, 0.05. These samples were calcined at 500°C for 2 hours and the pellets were sintered at 750°C for 5 hours. X-Ray Diffraction technique confirms the cubic fluorite structure of the material. The doped material has showed high dielectric constant value and low dissipation factor and increased AC conductivity. AC conductivity obeys the Universal Dielectric Response. The material shows the potential for applications such as an electrode/electrolyte for fuel cells or also as a dielectric resonator.
可再生能源是一种清洁的能源生产来源,可以克服化石燃料过度使用带来的气候挑战。采用WOWS溶胶-凝胶法制备了成分为Cu0.2Fe0.2(Ce0.6Gd0.4-xNdx)0.6O2-x的纳米晶材料,改变钕元素x= 0.0, 0.05。这些样品在500℃下煅烧2小时,球团在750℃下烧结5小时。x射线衍射技术证实了材料的立方萤石结构。该掺杂材料具有较高的介电常数值和较低的耗散系数,提高了交流电导率。交流电导率服从通用介电响应。该材料显示了应用的潜力,如燃料电池的电极/电解质或也作为介电谐振器。
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引用次数: 0
2D Strain Mapping in Sub-10nm SiGe Layer with High-Resolution Transmission Electron Microscopy and Geometric Phase Analysis 基于高分辨率透射电镜和几何相位分析的亚10nm SiGe层二维应变映射
IF 0.4 Q4 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2022-08-31 DOI: 10.4028/p-0xgppz
Vandang Hoang, Van Trung Trinh
In this study, strain measurement can be analyzed in sub-10nm SiGe layer (~7 nm) grown on [100] Si substrate by chemical vapor deposition at the nanoscale level. The measurement technique is based on transmission electron microscopy (TEM), in which high-resolution transmission electron microscopy (HRTEM) image is combined with the image processing of geometric phase analysis (GPA) software. In this case, GPA analyzes the HRTEM images formed at the [011] zone axis to obtain information about strain maps along the [100] growth direction of the nanoscale SiGe region. The strain analyzed in the SiGe layer is within 1.6-2.9% with high precision and high spatial resolution.
在本研究中,可以在纳米尺度上通过化学气相沉积在[100]Si衬底上生长的亚10nm (~ 7nm) SiGe层进行应变测量分析。测量技术以透射电子显微镜(TEM)为基础,将高分辨率透射电子显微镜(HRTEM)图像与几何相位分析(GPA)软件的图像处理相结合。在这种情况下,GPA分析了在[011]区轴处形成的HRTEM图像,以获得纳米级SiGe区域沿[100]生长方向的应变图信息。在SiGe层中分析的应变在1.6-2.9%之间,具有高精度和高空间分辨率。
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引用次数: 0
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