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Preparation of water‐based flexography printing ink by KMnO4 modified activated carbon for fruit ripening control application KMnO4改性活性炭制备水性柔印油墨的研究
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-29 DOI: 10.1002/pts.2758
Pachanat Nasomboon, Noppon Somsesta, Intatch Hongrattanavichit
Ethylene is a type of gas that fruits and vegetables can produce naturally. The release of ethylene gas from fruits and vegetables causes them to ripen and undergo physical, chemical and biological changes, such as changes in the appearance in terms of shape and colour, changes in firmness and texture, changes in taste and changes in nutritional value. Furthermore, it also facilitates the growth of microorganisms. These changes lead to spoilage if the fruit or vegetables are left to over ripen. Therefore, the prevention and reduction of damage caused by the ripening of fruits and vegetables entail reducing or slowing down the release of ethylene gas produced by them. This research project aimed to study the properties of activated carbon and potassium permanganate (KMnO4) modified activated carbon, applied as a printing layer on plastic materials for bananas, in terms of their adsorption and decomposition of ethylene. Active and water‐based flexography printing inks were prepared from water‐based binder and ethylene adsorbing and scavenging agents (activated carbon and KMnO4 modified activated carbon) at various concentrations of active agents, that is, 0.0, 5.0, 7.5 and 10.0%w/v. Then, those inks were printed on polypropylene plastic substrate. The delayed ripening of fruits results showed that the plastic materials coated with modified activated carbon inks delayed the physiology disorder (colour and firmness changing about 250% and 226%) and prolonged the storage time up to 14 days when compared with control. In addition, the functional ink layer also presented a high efficiency of abrasion resistance of about 75 cycles of rubbing at 1.8 kg. The products that stem from this research can be applied as packaging for fruits and vegetables in the form of bags, stickers and product pads that can help extend the life and slow the ripening of fruits and vegetables.
乙烯是水果和蔬菜可以自然产生的一种气体。从水果和蔬菜中释放的乙烯气体使它们成熟并发生物理、化学和生物变化,例如形状和颜色的外观变化,硬度和质地的变化,味道的变化和营养价值的变化。此外,它也有利于微生物的生长。如果水果或蔬菜过度成熟,这些变化会导致腐败。因此,预防和减少水果和蔬菜成熟造成的损害需要减少或减缓它们产生的乙烯气体的释放。本课题旨在研究活性炭和高锰酸钾(KMnO4)改性活性炭作为香蕉塑料材料印刷层对乙烯的吸附和分解性能。以水基粘结剂和乙烯吸附清除剂(活性炭和KMnO4改性活性炭)为原料,在不同浓度的活性剂(0.0、5.0、7.5和10.0%w/v)下制备活性和水性柔印油墨。然后,将这些油墨印刷在聚丙烯塑料基板上。结果表明,与对照相比,涂覆改性活性炭油墨的塑料材料延缓了果实的生理紊乱(颜色和硬度变化分别为250%和226%),延长了果实的贮藏时间,最长可达14天。此外,该功能墨层还表现出了在1.8 kg下约75次摩擦的高耐磨性。这项研究产生的产品可以应用于水果和蔬菜的包装,以袋、贴纸和产品垫的形式,可以帮助延长水果和蔬菜的寿命,减缓成熟。
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引用次数: 0
Improved criteria for evaluating impact targets in regulative drop tests of dangerous goods packagings 改进了危险货物包装管制跌落试验中评价冲击目标的标准
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-29 DOI: 10.1002/pts.2759
Nikolaos Lengas, K. Müller, Eva Schlick‐Hasper, Marcel Neitsch, Sergej Johann, M. Zehn
For dangerous goods packagings, drop testing onto an essential unyielding target can be used to assess the mechanical resistance to impact loads. Adopted regulations like Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)/Regulation concerning the International Carriage of Dangerous Goods by Rail (RID) require that the impact surface provided shall be integral with a mass at least 50 times than that of the heaviest package to be tested. The problem is that many manufacturers do not possess impact targets that satisfy the required 50 times mass ratio for regulative drop tests during series production. The objective of this work is to verify existing and define improved criteria for impact target structures based on systematic investigations. Previous evidence highlights the relevance of other parameters in addition to the mass ratio. Therefore, in this research, a variation of drop test parameters was carried out experimentally. Furthermore, numerical vibration analysis was applied to investigate the deformability of the impact surface. The results conclude that the mass ratio of 1:50 cannot be defined as a decisive criterion. In order to determine the influence of further drop test parameters, the research findings were used to validate a parametric model that assesses impact target deflection. An approximation quality of over 90% was achieved. As a result, new evaluation criteria are proposed. First, a method for identifying critical impact target designs is provided. Second, a new comprehensive formula compares the approximated maximum deflection of a real impact target to the respective theoretical threshold derived from a worst‐case assumption. In practice, this leads to great advantages in the evaluation of already installed impact targets for dangerous goods packagings.
对于危险货物包装,在一个基本的不屈服的目标上的跌落试验可以用来评估对冲击载荷的机械阻力。《国际公路危险货物运输协定》(ADR)、《国际铁路危险货物运输条例》(RID)等已通过的法规要求所提供的冲击面质量至少为待测最重包装质量的50倍。问题是,在批量生产过程中,许多制造商没有满足标准跌落试验所需的50倍质量比的冲击指标。这项工作的目的是在系统调查的基础上,验证现有的冲击目标结构标准,并确定改进的标准。先前的证据强调了质量比之外的其他参数的相关性。因此,本研究对跌落试验参数的变化进行了实验研究。此外,采用数值振动分析方法对冲击表面的变形性进行了研究。结果表明,1:50的质量比不能作为决定性的判据。为了确定进一步跌落试验参数的影响,将研究结果用于验证评估撞击目标挠度的参数化模型。达到了90%以上的近似质量。因此,提出了新的评价标准。首先,提供了一种识别关键影响目标设计的方法。其次,一个新的综合公式比较了实际冲击目标的近似最大挠度与从最坏情况假设中得出的各自的理论阈值。在实践中,这在评估已安装的危险货物包装的冲击目标方面具有很大的优势。
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引用次数: 0
Fabrication of antimicrobial colorimetric pad for meat packaging based on polyvinyl alcohol aerogel with the incorporation of anthocyanins and silver nanoparticles 含花青素和纳米银的聚乙烯醇气凝胶制备肉类包装用抗菌比色垫
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-28 DOI: 10.1002/pts.2754
Yue He, Shiguang Chen, Dan Xu, D. Ren, Xiyu Wu
A novel colorimetric pad with porous structure, good antimicrobial activity, and pH‐sensitivity has been developed based on polyvinyl alcohol (PVA), paper fibre, silver nanoparticles (AgNPs) and purple sweet potato anthocyanins (PSPA), aiming for the preservation and freshness indication of fresh meat. The effects of AgNPs content on the structure, physical properties and colour‐changing behaviour in response to pH of the pad were investigated. The results showed that AgNPs physically interacted with polymer matrix and improved the uniformity of the internal pore structure of the pad. The antibacterial capability, DPPH radical scavenging activity and surface hydrophobicity of the pad increased significantly with increasing AgNPs content. However, the pH sensitivity of the pad was maintained with the addition of AgNPs, and the colour change of pad A‐9 with pH was the most distinguishable when AgNPs content was the highest. When pad A‐6 was used in the packaging of minced pork, compared to pad A‐0 without the addition of AgNPs, it showed more significant effects in inhibiting microbial growth, reducing the production of volatile nitrogen compounds, improving the sensory quality of meat (p < 0.05), thereby extending the shelf life from 72 h to 120 h at 4°C. Moreover, A‐6 displayed a visible colour change in response to the spoilage of minced pork in real time. Therefore, the developed pad with dual functions had great potential to be applied as a novel active and intelligent packaging for fresh meat, which would contribute towards reducing food waste and ensuring food safety.
以聚乙烯醇(PVA)、纸纤维、纳米银(AgNPs)和紫甘薯花青素(PSPA)为原料,开发了一种具有多孔结构、良好抗菌活性和pH敏感性的新型比色垫,用于鲜肉的保鲜和保鲜指示。研究了AgNPs含量对电极结构、物理性质和pH值变化行为的影响。结果表明,AgNPs与聚合物基体发生物理相互作用,提高了衬垫内部孔隙结构的均匀性。随着AgNPs含量的增加,衬垫的抗菌能力、DPPH自由基清除能力和表面疏水性均显著提高。然而,AgNPs的加入保持了pad的pH敏感性,当AgNPs含量最高时,pad A‐9的颜色随pH的变化最明显。与未添加AgNPs的pad A‐0相比,pad A‐6在抑制微生物生长、减少挥发性氮化合物的产生、改善肉的感官品质方面表现出更显著的效果(p < 0.05),从而将肉糜在4℃下的保质期从72 h延长到120 h。此外,A‐6实时显示出肉末变质后的明显颜色变化。因此,所开发的具有双重功能的包装垫具有很大的应用潜力,可以作为一种新型的鲜肉活性智能包装,有助于减少食物浪费,确保食品安全。
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引用次数: 0
The influence of clean food labels on consumers' perception 清洁食品标签对消费者认知的影响
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-28 DOI: 10.1002/pts.2757
A. G. A. Sá, Lucas Moreira Carmo, G. A. Valencia
Food marketing uses packaging to attract consumers. Clean labels (CLs) have been proposed as a recent alternative to attract consumers and increase purchasing intention; however, the impact of CL on consumers' perception has not been extensively studied. In this way, the current research aimed to understand the effect of CL used in frequent food consumed by the Brazilian population (cereal bars, sandwich cookies, yogurt, loaf bread, tomato paste and ketchup) and their impact on consumers' perception. A study with 392 volunteers was carried out, and the data were obtained through an online form and analysed using an electronic spreadsheet. Each volunteer compared similar food inside packaging with conventional labels or CL, considering the same price and expiration date. Data derived from consumers' perceptions were analysed using the word association (WA) methodology. Results from volunteers showed that people verify the presence of natural ingredients in food products and prefer processed products with CL. Furthermore, several variables used to develop CL such as product quality, nutritional value and ingredients were mentioned by the volunteers as parameters influencing purchasing intention. Finally, results from WA confirmed the preference of volunteers by food packages with CL; in this way, food products with CL were correlated with sensory and nutritional aspects. This study confirms the importance of CL in processed food packaging and its importance to induce positive feelings in consumers.
食品营销利用包装来吸引消费者。清洁标签(CLs)最近被建议作为吸引消费者和增加购买意愿的替代方案;然而,对消费者认知的影响,并没有广泛的研究。通过这种方式,目前的研究旨在了解巴西人经常食用的食物(谷物棒、三明治饼干、酸奶、面包、番茄酱和番茄酱)中使用CL的影响及其对消费者认知的影响。研究人员对392名志愿者进行了研究,通过在线表格获取数据,并使用电子表格进行分析。每个志愿者都将类似的食品包装与传统标签或CL进行比较,考虑到相同的价格和有效期。从消费者的看法得出的数据进行了分析使用词联想(WA)方法。志愿者的结果表明,人们会核实食品中是否含有天然成分,并更喜欢含有CL的加工产品。此外,志愿者还提到了产品质量、营养价值和成分等影响购买意愿的几个变量。最后,WA的结果证实了志愿者对含CL的食品包装的偏好;因此,含CL的食品与感官和营养方面相关。本研究证实了CL在加工食品包装中的重要性,以及它对消费者产生积极感受的重要性。
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引用次数: 1
Space food packaging: A review of its past, present and future materials and technologies 空间食品包装:回顾其过去、现在和未来的材料和技术
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-25 DOI: 10.1002/pts.2752
R. Evans
20 July 1969: approximately 240 000 mi away from Earth, two astronauts named Neil Armstrong and Edwin E. Aldrin Jr. landed on the moon. 20 October 2020: approximately 200 million miles away from Earth, the National Aeronautics and Space Administration (NASA) managed to land a spacecraft on an asteroid named Bennu and collect a sample from its surface. Sometime 2030s: approximately 34 million miles away from Earth, NASA is looking to successfully send humans to Mars. So, why is all this important? The effects of climate change are apparent on Earth today—temperatures around the world higher than normal, a rising sea level, natural disasters increasing in frequency and strength—and these effects continue to become ever more apparent as time goes on; thus, there is a need for solutions, which outer space has become one that is simultaneously grown in seriousness over the years. Colonizing space, traveling to distant planets and inhabiting them, these are definite possibilities for humans, as evidenced above by the remarkable progress NASA has made; however, one of the biggest obstacles NASA is dealing with in bringing those possibilities into fruition is their food system—all the actors and interactions within a food chain, meaning those who grow the food, those who process the food, those who transport the food, those who sell the food and finally, those who consume and dispose of the food. The shelf life of NASA's current food system will not last past 18 months in the unique environment of space, where there are the hazards of galactic cosmic rays, solar radiation and microgravity. Recognizing this—essentially recognizing that achieving such aforementioned feats would require a food system that can last much longer—NASA and others have constantly been researching and experimenting with their food system, ranging from how its food is grown, processed and preserved to the focus of this literature review: how it is packaged. Henceforth, the purpose of this literature review is to chronologically look at and discuss the major materials and technologies used in NASA's space food packaging of the past—the 1960s–1970s—look at and discuss those of the present—the 1980s–2000s—and finally, look ahead and discuss those of the future, entailing materials and technologies currently being worked on or considered for future use in NASA space missions. At that, here's to 60 years of activity in space.
1969年7月20日:在距离地球约24万英里的地方,两名宇航员尼尔·阿姆斯特朗和小埃德温·e·奥尔德林登上了月球。2020年10月20日:距离地球约2亿英里的地方,美国国家航空航天局(NASA)成功地将一艘宇宙飞船降落在一颗名为Bennu的小行星上,并从其表面收集了样本。21世纪30年代的某个时候:距离地球大约3400万英里,美国宇航局正在寻求成功地将人类送上火星。那么,为什么这一切都很重要呢?气候变化对当今地球的影响是显而易见的——全球气温高于正常水平,海平面上升,自然灾害的频率和强度都在增加——而且随着时间的推移,这些影响将变得越来越明显;因此,有必要寻求解决办法,多年来,外层空间已成为一个同时日益严重的解决办法。殖民太空,旅行到遥远的星球并在那里居住,这些都是人类明确的可能性,正如美国宇航局所取得的显著进展所证明的那样;然而,在将这些可能性付诸实践的过程中,NASA面临的最大障碍之一是他们的食品系统——食物链中的所有参与者和相互作用,包括种植食物的人、加工食物的人、运输食物的人、销售食物的人,以及最终消费和处理食物的人。在独特的太空环境中,由于银河宇宙射线、太阳辐射和微重力的危害,美国宇航局目前的食品系统的保质期不会超过18个月。认识到这一点——本质上是认识到实现上述壮举需要一个可以持续更长时间的食品系统——nasa和其他机构一直在不断地研究和试验他们的食品系统,从食品如何种植、加工和保存到本文文献综述的重点:如何包装。今后,本文献综述的目的是按时间顺序回顾和讨论过去(20世纪60年代至70年代)NASA太空食品包装中使用的主要材料和技术,回顾和讨论现在(20世纪80年代至2000年)的材料和技术,最后展望和讨论未来的材料和技术,包括目前正在研究或考虑在NASA太空任务中未来使用的材料和技术。这是60年的太空活动。
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引用次数: 0
Investigating the effects of packaging design factors on customer purchasing decisions for goat manure fertilizer 调查包装设计因素对顾客购买羊粪肥决策的影响
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-24 DOI: 10.1002/pts.2755
Narucha Tanaiutchawoot, Warangkana Saengtawan, Jiraporn Sinlapasiriwat, Nadthanicha Sukkeaw
Most of the packaging in agriculture products usually focuses on keeping and containing products rather than appealing to customers. However, because today's competition is fierce both online and onsite, it's critical to improve competitiveness through package development and design. Goat manure, one of the best animal manures for fertilizer to help provide the ideal growth conditions for plants, is selected for the pilot study to investigate the influence of packaging design in agriculture products. The goal of this article is to look at (1) consumer behaviour while making a fertilizer purchase and (2) the impact of packaging design on customer purchasing decisions by comparing the old and new designs. Answers from these questions will be a guideline for the new packaging design. To create the packaging for the community's product, researchers collaborated with one community enterprise at Petchburi in Thailand. According to the 110 participants who took part in the pre‐survey, 64.5% of them are more concerned with packaging design than with pricing, market channels, or marketing. The packaging, originality, product feature representation, cleanliness, safety and the ability to pack and unpack the goods are all important considerations when buying goat dung fertilizer. These elements are used to create a new packaging design. Furthermore, the NUDGES idea is included in the packaging design to support the customer's behaviour while using the product. After designing and production, the old and new packages are tested in the market via online and onsite channels. Although the quality and quantity of products remain the same, 87.5% of the 32 consumers who purchased fertilizer chose the new packaging design for 60 baht and the rest chose the other option for 50 baht. As a result, packaging design raises the perceived value of a product and promotes customer acceptability.
大多数农产品的包装通常侧重于保存和容纳产品,而不是吸引顾客。然而,由于今天的竞争无论是在线还是现场都很激烈,因此通过包装开发和设计来提高竞争力至关重要。山羊粪便是最好的动物粪便之一,有助于为植物提供理想的生长条件,被选为试点研究,以调查包装设计对农产品的影响。本文的目标是看看(1)消费者行为,而使化肥购买和(2)包装设计对客户购买决策的影响,通过比较新旧设计。这些问题的答案将成为新包装设计的指导方针。为了为社区产品制作包装,研究人员与泰国佩奇布里的一家社区企业合作。根据参与预调查的110名参与者,64.5%的人更关心包装设计,而不是价格、市场渠道或营销。在购买羊粪肥料时,包装、创意、产品特征表现、清洁度、安全性以及包装和开箱能力都是重要的考虑因素。这些元素被用来创造一个新的包装设计。此外,NUDGES理念包含在包装设计中,以支持客户在使用产品时的行为。设计制作完成后,通过网络和现场渠道对新旧包装进行市场测试。虽然产品的质量和数量保持不变,但32名购买肥料的消费者中有87.5%的人选择了60泰铢的新包装设计,其余的人选择了50泰铢的其他包装设计。因此,包装设计提高了产品的感知价值,促进了客户的接受度。
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引用次数: 0
Ethylene modelling in package headspace of fresh produce: A review 新鲜农产品包装顶空乙烯造型研究进展
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-21 DOI: 10.1002/pts.2753
A. D. Sonawane, N. Pathak, Cornelia Weltzien, P. Mahajan
Ethylene accumulation is one of the main causes of rapid deterioration of climacteric fruit and vegetables in a package as ethylene accelerates the ripening process. Modelling the ethylene gas in a package headspace is a promising way to control the ripening process as it provides and optimises the methods to remove ethylene. In this review, the transmission of ethylene through a package, ethylene removal by a scavenger and ethylene accumulation inside the package are discussed with their models. The permeability of packaging material allows ethylene to escape from the package to a little extent. The perforation in packaging material also helps ethylene to depart rapidly from the fruit package which is explained and modelled using Fick's first law of diffusion. The pseudo‐first‐ and second‐order kinetics based on the adsorption phenomena have been used to model the removal of ethylene by a scavenger. The mass balance between the ethylene transmission rate through the package, ethylene production rate by fruit and ethylene removal by scavenger provides the ethylene accumulation which can be helpful for predicting the quality of the fruit inside a package. This study could lead to the development of an active fruit packaging system with the inclusion of ethylene along with oxygen and carbon dioxide for extending the shelf life of fresh commodities in postharvest storage.
乙烯积累是包装中更年期水果和蔬菜迅速变质的主要原因之一,因为乙烯加速了成熟过程。模拟乙烯气体在包装顶空是一个有前途的方式来控制成熟过程,因为它提供和优化的方法,以消除乙烯。本文讨论了乙烯在包装中的传递、清除剂对乙烯的去除以及乙烯在包装内的积累。包装材料的透气性使乙烯能在一定程度上从包装中逸出。包装材料中的穿孔也有助于乙烯迅速离开水果包装,这是用菲克第一扩散定律解释和建模的。基于吸附现象的准一级动力学和准二级动力学被用来模拟清除剂对乙烯的去除。乙烯通过包装的传输速率、水果的乙烯产生速率和清除剂的乙烯去除速率之间的质量平衡提供了乙烯积累,有助于预测包装内水果的质量。该研究可用于开发含有乙烯、氧气和二氧化碳的活性水果包装系统,以延长新鲜商品在采后储存中的保质期。
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引用次数: 1
Development and characterization of defatted pumpkin seed meal and halloysite nanoclay composite films for food packaging 食品包装用脱脂南瓜籽粕和高岭土纳米粘土复合薄膜的研制与表征
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-16 DOI: 10.1002/pts.2751
Yaghuvendra Kumar, R. Santhosh, M. Hoque, Debarshi Nath, Rahul Thakur, D. Madhubabu, Vedsagar Rajesh Suryavanshi, Harshi Singhi, J. Ahmed, P. Sarkar
The valorization of agricultural by‐products into sustainable packaging materials is one of the best strategies to utilize industrial waste efficiently. In this study, defatted pumpkin seed meal (DPSM) has been converted into films by impregnating selected concentrations of halloysite (HS) nanoclay (1%, 2% and 3% w/w). Various analytical techniques, including scanning electron microscopy (SEM), X‐ray diffraction (XRD), differential scanning calorimetry (DSC) and barrier property measurements, were employed to characterize the developed films. The appearance of the roughness on the surface of the films was evident from SEM micrographs upon the addition of HS. No change in the crystallinity of DPSM occurred when HS was incorporated; however, the Tg showed a variation with the loading concentration of the clay. Fourier transform infrared spectroscopy (FTIR) spectroscopy indicated that the decrease in hydrogen bonding was associated with increasing the HS concentrations. The addition of HS improved the tensile strength, stress relaxation percentage and Young's modulus, while the elongation at break was reduced at a similar condition. The biodegradability of the film was excellent within 20 days of the burying period. Overall, the developed films could be a potential candidate for sustainable food packaging.
将农业副产品转化为可持续包装材料是有效利用工业废物的最佳策略之一。在这项研究中,通过浸渍选定浓度的高岭土(HS)纳米粘土(1%,2%和3% w/w),将脱脂南瓜籽粕(DPSM)转化为薄膜。各种分析技术,包括扫描电子显微镜(SEM), X射线衍射(XRD),差示扫描量热法(DSC)和势垒性能测量,被用来表征显影膜。在加入HS后,薄膜表面的粗糙度在SEM显微照片上很明显。加入HS后,DPSM的结晶度没有变化;而Tg随黏土的加载浓度而变化。傅里叶红外光谱(FTIR)分析表明,氢键的减少与HS浓度的增加有关。HS的加入提高了拉伸强度、应力松弛率和杨氏模量,而在相同条件下,断裂伸长率降低。在掩埋期20 d内,膜的生物降解性良好。总的来说,开发的薄膜可能是可持续食品包装的潜在候选人。
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引用次数: 1
Sorption of flavour compounds by polyethylene terephthalate and copolyester films for food packaging 食品包装用聚对苯二甲酸乙二醇酯和共聚酯薄膜对风味化合物的吸附
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-10 DOI: 10.1002/pts.2738
H. Hosono, N. Hirakawa, N. Zhang, Yuuki Kinoshita
The sorption of flavour compounds by PET and 15 copolyesters (PET copolymerized with isophthalic acid, adipic acid, sebacic acid, tetramethylene glycol, diethylene glycol, triethylene glycol and neopentyl glycol in the range of 5 to 18 mol%) was studied. Biaxially oriented films of each resin were immersed in aqueous solutions containing 37 types of flavour compounds for 4 weeks at 37°C. The amount of flavour compounds sorbed by the films was highly dependent on the copolymer composition. Among the tested films, the copolyester film containing 11 mol% sebacic acid exhibited the highest sorption of the 37 compounds, which was approximately 40 times that of PET. The copolyester film containing 11 mol% isophthalic acid exhibited the lowest sorption, approximately half that of PET. The relationship between sorption and the characteristic values of the polyester films was studied. Sorption was negatively correlated with the solubility parameter and density of the amorphous area and strongly negatively correlated with the glass transition temperature. It was concluded that the dynamic free volume involved in diffusion dominates the sorption of flavour compounds by copolyesters. The log P value and molecular size of the compounds had a strong effect on the sorption of individual flavour compounds by the films in aqueous solutions.
研究了PET与15种共聚聚酯(PET与间苯二甲酸、己二酸、癸二酸、四亚甘醇、二甘醇、三甘醇和新戊二醇在5 ~ 18摩尔%范围内共聚)对风味化合物的吸附性能。每种树脂的双轴取向膜在含有37种风味化合物的水溶液中浸泡4周,温度为37℃。薄膜吸收的风味化合物的量高度依赖于共聚物的组成。结果表明,含11mol %癸二酸的共聚酯膜对37种化合物的吸附率最高,约为PET的40倍。含11mol %二苯二甲酸的共聚酯膜吸附量最低,约为PET的一半。研究了吸附性能与聚酯薄膜特征值的关系。吸附与溶解度参数和非晶区密度呈负相关,与玻璃化转变温度呈强负相关。结果表明,参与扩散的动态自由体积在共聚酯对风味化合物的吸附中起主导作用。化合物的logp值和分子大小对膜对单个风味化合物在水溶液中的吸附有很大影响。
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引用次数: 0
Utilising N‐glutaryl chitosan‐based film with butterfly pea flower anthocyanin as a freshness indicator of chicken breast 利用N -戊二酰壳聚糖基蝴蝶豌豆花花青素薄膜作为鸡胸肉的新鲜度指标
IF 2.6 4区 工程技术 Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-05-01 DOI: 10.1002/pts.2736
D. S. Anugrah, Graciela Delarosa, Pricylia Wangker, R. Pramitasari, D. Subali
A novel indicator film was produced with N‐glutaryl chitosan (ChGA) as a matrix and butterfly pea flower anthocyanin (BPA) as a dye. The synthesis of ChGA was achieved by the reaction of chitosan (Ch) and glutaric anhydride (GA), which resulted in the structural alteration of Ch, with carboxylic groups being present in ChGA. The ChGA–BPA film demonstrated higher sensitivity to changes in pH, a more compact structure, and more hydrophilic properties compared with Ch‐BPA film. The ChGA–BPA film demonstrated antioxidant and antimicrobial activity, as well as an enhanced biodegradable property. Further characterisation showed ChGA–BPA film possessed ultraviolet visible (UV–Vis) light barrier properties and was non‐toxic to cells. Lastly, when tested as packaging, the films underwent a visible colour changes from blue to yellowish‐green as chicken breast was stored at various temperatures, which correlated with an increase in nitrogen compounds, indicating the potential of this film as a smart packaging solution to monitor the freshness of chicken breast.
以N‐戊二酰壳聚糖(ChGA)为基质,蝴蝶豌豆花花青素(BPA)为染料制备了一种新型指示膜。壳聚糖(Ch)与戊二酸酐(GA)反应合成了ChGA,使Ch的结构发生了变化,ChGA中出现了羧基。与Ch - BPA膜相比,ChGA-BPA膜具有更高的pH敏感性、更致密的结构和更强的亲水性。ChGA-BPA薄膜显示出抗氧化和抗菌活性,以及增强的生物降解性能。进一步表征表明,ChGA-BPA膜具有紫外可见(UV-Vis)光屏障性能,对细胞无毒。最后,当作为包装进行测试时,当鸡胸肉在不同温度下储存时,薄膜经历了从蓝色到黄绿色的可见颜色变化,这与氮化合物的增加有关,表明该薄膜作为智能包装解决方案监测鸡胸肉的新鲜度的潜力。
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引用次数: 2
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Packaging Technology and Science
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