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Control of the catalytic, acid and structural properties of zeolites by changing the framework composition 通过改变分子筛的骨架组成来控制分子筛的催化、酸性和结构性质
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90048-K
A.L. Klyachko, I.V. Mishin
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引用次数: 0
Activity, selectivity and stability of high-silica faujasites in the cracking of neohexane 高硅faujasites在新己烷裂解中的活性、选择性和稳定性
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90028-E
T.M. Gairbekov, S.N. Khadzhiyev, R.A.-V. Turluyev, A.V. Mel'nichenko, A.K. Manovyan, S.M. Gairbekova
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引用次数: 0
List of contents and author index vol. 30, 1990 目录和作者索引第30卷,1990年
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90047-J
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引用次数: 0
Catalytic breakdown of paraffinic hydrocarbons in the presence of adamantanes 金刚烷存在下石蜡烃的催化分解
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90050-P
Ye.I. Bagrii, Ye.K. Dragalova, N.Ya. Supryadkina
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引用次数: 0
Dearomatization of petroleum fractions on a composite catalyst containing hydride ZrNiHx and talum 含氢化物ZrNiHx和talum的复合催化剂上石油馏分的脱芳化
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90041-D
K.A. Manovyan, V.V. Lunin, G.V. Tarakanov, A.K. Manovyan, V.V. Stolyarov

Processes of dearomatization of reforming benzine, kerosine fraction and liquid paraffins on a composite ZrNiHx (40%)-talum catalyst have been investigated. The influence of process conditions (pressure, temperature and volume feedrate of feedstock) on the degree of dearomatization has been shown. Investigation of the physicochemical properties of the catalyst before and after experiments has made it possible to conclude that the catalyst is deactivated by organic sulphur compounds contained in kerosine fraction owing to the formation of surface nickel sulphides. The strength of the catalyst did not change during tests and amounted to ∼-35 kg/cm2. It was shown that the catalyst exhibits high activity in the dearomatization of liquid paraffins, and there the time of stable operation is at least 45 hr.

研究了在ZrNiHx (40%)-talum复合催化剂上重整汽油、煤油馏分和液态石蜡的脱芳过程。研究了工艺条件(压力、温度和进料体积进料速度)对脱芳程度的影响。对实验前后催化剂的物理化学性质进行了研究,可以得出这样的结论:由于表面硫化物镍的形成,煤油馏分中含有的有机硫化合物使催化剂失活。在测试过程中,催化剂的强度没有变化,达到~ -35 kg/cm2。结果表明,该催化剂在液体石蜡脱芳反应中表现出较高的活性,稳定运行时间至少为45小时。
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引用次数: 0
Influence of the composition of polymeric petroleum resins on their oxidation by oxygen 聚合石油树脂的组成对其氧氧化的影响
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90054-J
V.V. Voronenkov, V.D. Sukhov, V.S. Krasnobayeva, T.A. Yermilova
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引用次数: 0
Asphaltenes of Dzhafarly crude oil 扎法利原油的沥青质
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90027-D
V.F. Kam'yanov , V.D. Ogorodnikov , M.F. Mir-Babayev , F.I. Samedova , L.A. Gorbunova
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引用次数: 1
Synthesis, stereochemistry and mass spectra of epimeric 9,10-seco-24-methylcholestanes 9,10-seco-24-甲基胆甾烷的合成、立体化学及质谱分析
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90015-8
N.S. Vorob'yeva, Z.K. Zemskova, A.A. Petrov
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引用次数: 0
Dehydrogenation of isobutane in the presence of a Zr2Fe hydrogen acceptor 异丁烷在Zr2Fe氢受体存在下的脱氢反应
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90037-G
V.V. Lunin , O.V. Chetina
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引用次数: 1
Higher unsaturated hydrocarbons in crude oils 原油中不饱和烃含量较高
Pub Date : 1990-01-01 DOI: 10.1016/0031-6458(90)90032-B
Ye.B. Frolov, M.B. Smirnov
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引用次数: 8
期刊
Petroleum Chemistry U.s.s.r.
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