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Dinoflagellate cyst and vegetational dynamics during the Early Jurassic (late Pliensbachian–early Toarcian) in Tibet
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-17 DOI: 10.1016/j.palaeo.2025.113500
Changjun Ji , Ahmed Mansour , Zhenhan Wu , James B. Riding , Yun Chen , Qian Wang
The late Pliensbachian–early Toarcian (Early Jurassic) marks a critical interval in Earth history, characterised by major palaeoclimatic, palaeoenvironmental, and palaeoceanographical perturbations. This study examines the Pliensbachian–Toarcian Quse Formation at the Qixiangcuo section in the Southern Qiangtang Basin (Tibet), using palynological analysis to investigate dinoflagellate cyst evolutionary patterns and vegetation dynamics prior to and during the Jenkyns Event. Palynological data showed a clear record of late Pliensbachian dinoflagellate cyst radiation, likely owing to cooler climatic and enhanced water mass circulation between the Arctic-Boreal and Tethyan realms. Prior to the Jenkyns Event, a dinoflagellate cyst acme is observed, possibly controlled by sea-level rise, increased seawater salinity, and well-ventilated conditions. During the Jenkyns Event, a blackout event of dinoflagellate cysts occurred in the Southern Qiangtang Basin, consistent with records from the central Tethys and Boreal regions, likely triggered by global warming and rising seawater temperatures. Pollen assemblages across the Pliensbachian-Toarcian transition are dominated by Cheirolepidiaceae conifers (Classopollis), compared to reduced cycadophytes, bennettites, and ginkgophytes, and sparse fern spores. This reflects a vegetation turnover towards xerophytic, drought-tolerant vegetation in arid lowland environments, likely linked to the initial phase of Karoo-Ferrar volcanism. During the Jenkyns Event, Cheirolepid coniferous pollen remained dominant before temporarily disappearing, indicating a demise of mixed wet mire-conifer communities and a shift towards drought-adapted flora. Similar patterns of deforestation and vegetation crisis are observed across the Tethys and Boreal realms, contemporaneous with the main phase of the Karoo-Ferrar volcanism and rising atmospheric CO2. Regional comparisons of vegetation response across the Jenkyns Event reflect different magnitudes of predominance and recovery patterns in Cheirolepid conifers.
pliensbachia - Toarcian Early侏罗世是地球历史上一个以古气候、古环境和古海洋扰动为主要特征的关键时期。孢粉学数据显示了Pliensbachian晚期鞭毛藻囊辐射的清晰记录,可能是由于北极-北方和特提斯领域之间较冷的气候和增强的水团循环。在詹金斯事件之前,观察到甲藻囊肿顶点,可能由海平面上升,海水盐度增加和通风良好的条件控制。在詹金斯事件期间,在羌塘盆地南部发生了甲藻囊肿的停电事件,与特提斯中部和北方地区的记录一致,可能是由全球变暖和海水温度上升引发的。在pliensbachia - toarcian过渡时期,花粉组合以Cheirolepidiaceae针叶树(Classopollis)为主,相比之下,减少了苏铁植物、贝尼特植物和银杏植物,以及稀疏的蕨类孢子。这反映了干旱低地环境中植被向旱生耐旱植被的转变,可能与Karoo-Ferrar火山活动的初始阶段有关。在詹金斯事件期间,Cheirolepid针叶树花粉在暂时消失之前仍然占主导地位,这表明湿泥针叶树混合群落的消亡和向适应干旱的植物群的转变。在特提斯和北方地区也观察到类似的森林砍伐和植被危机模式,与Karoo-Ferrar火山活动的主要阶段和大气中二氧化碳的上升同时发生。在詹金斯事件中植被响应的区域比较反映了不同程度的优势和恢复模式。
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引用次数: 0
Taiwan's land-vertebrate suite: An assemblage forged by tectonism and sea-level shifts 台湾陆生脊椎动物群:由构造运动和海平面变化形成的组合
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-17 DOI: 10.1016/j.palaeo.2025.113502
Jason R. Ali , Uwe Fritz
Like many islands in continental-shelf settings, Taiwan has a rich land-vertebrate suite comprising mainly nonendemic taxa. Unusually, though, it also hosts a substantial fraction of endemic species, some the result of in situ diversification. Here, we disentangle the physical processes that have shaped the island's assemblage and document the roles they played. Taiwan is a high-elevation landmass on the edge of China's continental shelf, its emergence resulting from the ongoing collision between the Eurasian and Philippine Sea Plates, which started c. 5 Mya. For the first c. 4 Myr of the island's history colonizations involved over-water dispersal, hence relatively few establishment events. Significantly, the sizeable ecospace the incomers entered hosted a variety of niches (notably, greater than those in the areas they crossed from), and this spurred anagenesis and occasionally cladogenesis. Although the Pleistocene sea-level falls (starting c. 2.6 Mya) modified greatly and frequently the regional geography, only those occurring after 900 kya were sufficiently large (i.e., below −72/−75 m) to open up a succession of landbridges across the Taiwan Strait seabed to mainland Asia. Significantly, such episodes allowed taxa to enter Taiwan unimpeded, thereby accounting for the bulk of its lineages, most of which are nonendemic.
像许多大陆架上的岛屿一样,台湾有丰富的陆生脊椎动物群,主要由非地方性类群组成。然而,不同寻常的是,它还拥有相当一部分地方性物种,其中一些是原位多样化的结果。在这里,我们解开了塑造岛屿组合的物理过程,并记录了它们所扮演的角色。台湾是中国大陆架边缘的一块高海拔大陆,它的出现是由欧亚海板块和菲律宾海板块持续碰撞造成的,这种碰撞始于约5000万年前。在该岛历史的第一个c. 4世纪,殖民化涉及水上分散,因此相对较少的建立事件。值得注意的是,进入者所进入的相当大的生态空间承载了各种各样的生态位(值得注意的是,比他们所穿越的区域的生态位更大),这刺激了发育,偶尔也刺激了枝发生。虽然更新世海平面下降(始于2.6 Mya)极大且频繁地改变了区域地理,但只有发生在900 kya之后的海平面下降才足够大(即低于- 72/ - 75 m),从而在台湾海峡海底与亚洲大陆之间开辟了一系列陆桥。值得注意的是,这些事件使得分类群畅通无阻地进入台湾,从而占了其大部分谱系,其中大多数是非地方性的。
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引用次数: 0
Vegetation responses to the mid-Holocene abrupt climate events in the Forest-Steppe Ecotone in northern China 中国北方森林-草原交错带植被对中全新世气候突变事件的响应
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-16 DOI: 10.1016/j.palaeo.2025.113506
Yao Zhang , Lili Niu , Qiaoyu Cui , Yi Lin , Zhiping Zhang , Jiaju Zhao , Xinwei Yan , Aifeng Zhou
Vegetation ecosystems in the East Asian monsoon margin in northern China are highly sensitive and ecologically vulnerable. Understanding long-term vegetation dynamics and their responses to abrupt climate events is critical for guiding ecological conservation and sustainable land-use planning. In this study, we reconstructed vegetation dynamics using a high-resolution pollen record from the Qixing peatland in the Saihanba region. Results indicated that climate was the primary driver of vegetation changes, while temperature and precipitation variations were asynchronous. The mid-Holocene was characterized by maximum precipitation; however, an abrupt cooling event between 7000 and 5500 cal yr BP triggered a rapid decline in deciduous broadleaf trees alongside a concurrent expansion of herbaceous vegetation, ultimately leading to steppe-dominated ecosystems. This transition was accompanied by reduced vegetation diversity and increased spatial heterogeneity. Subsequently, coniferous forests dominated by Pinus, as a major component of the secondary vegetation, became prevalent. However, a sudden shift to aridity around 5000 cal yr BP associated with the weakening of the East Asian summer monsoon prompted a rapid spread of herbs, along with a recovery in diversity and evenness. This study demonstrates that abrupt climate shifts caused forest retreat and grassland expansion once critical climatic thresholds were exceeded across the monsoon marginal zone. Given the current context of accelerated climate warming and increasingly frequent extreme climatic events, urgent protective measures are essential for these highly vulnerable ecosystems.
中国北方东亚季风边缘植被生态系统具有高度敏感性和生态脆弱性。了解植被长期动态及其对气候突变事件的响应对于指导生态保护和土地利用可持续规划具有重要意义。本文利用塞罕坝地区七星泥炭地的高分辨率花粉记录重建了植被动态。结果表明,气候是植被变化的主要驱动力,而温度和降水的变化是不同步的。中全新世以最大降水为特征;然而,在7000 - 5500 cal - yr BP之间的一次突然变冷事件引发了落叶阔叶树的迅速减少,同时草本植被的扩张,最终导致了草原为主的生态系统。这一转变伴随着植被多样性的减少和空间异质性的增加。随后,以松林为主的针叶林成为次生植被的主要组成部分。然而,在距今5000万年左右,东亚夏季风减弱导致了干旱的突然转变,促使草本植物迅速传播,多样性和均匀性也随之恢复。该研究表明,一旦超过季风边缘带的临界气候阈值,气候突变会导致森林退缩和草地扩张。在当前气候变暖加速和极端气候事件日益频繁的背景下,对这些高度脆弱的生态系统采取紧急保护措施至关重要。
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引用次数: 0
Sedimentary facies and invertebrate faunal exchange confirm humid conditions in the tropical eastern Atlantic during interglacial Marine Isotopic Stage (MIS) 11c 沉积相和无脊椎动物动物交换证实了间冰期海洋同位素阶段(MIS) 11c期间热带东大西洋的湿润条件
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-16 DOI: 10.1016/j.palaeo.2025.113505
Carlos S. Melo , José Madeira , Ricardo S. Ramalho , Ana C. Rebelo , Michael W. Rasser , Esther Martín-González , Alfred Uchman , Carlos Marques da Silva , Emílio Rolán , Luís Silva , Joseph A. Stewart , Laura F. Robinson , Deirdre D. Ryan , Alessio Rovere , Antje Voelker , Patrícia Madeira , Mário Cachão , Sérgio P. Ávila
The geological study of Marine Isotopic Stage (MIS) 11c (424–397 ka) is key to reconstructing the climatic and oceanographic conditions during one of the longest and the warmest interglacial in the last 1 million years. Moreover, interglacial MIS 11c is considered as an important analogue for our near future in times of climate change, under anthropogenic emissions scenarios, due to its similar orbital forcing configuration. Here we present the results of a comprehensive analysis of one of the most extensive Quaternary fossiliferous sedimentary successions in the Cabo Verde archipelago in the tropical northeastern Atlantic. The Nossa Senhora da Luz Bay (Santiago Island) is one of the few MIS 11 fossiliferous sites known in Macaronesia. The sedimentary succession records a set of transitions between fluvial and marine environments, and emersion and immersion events within a confined, highly protected bay environment. A thick layer of fine-branched rhodoliths in its upper part suggests ecological conditions that no longer exist in Cabo Verde. The presence of specimens of the intertidal clam Senilia senilis in life position ∼12 m above present-day mean sea level leads us to reinterpret the relative sea-level changes at Santiago Island and show that the uplift trend since MIS 11c is an order of magnitude lower (0.01 mm/yr) than previously calculated (0.10 to 0.14 mm/yr). The fossil assemblage includes representatives of five phyla, with molluscs being the most diverse and abundant. Despite the abundance of some bivalves (Saccostrea cuccullata, S. senilis, and Aequipecten opercularis), and gastropods (Thetystrombus latus and Thais nodosa), and some horizons showing the crustacean burrows Thalassinoides suevicus, the general biodiversity is low. The presence of S. cuccullata and S. senilis, both absent from present-day Cabo Verde archipelago, indicates a tropical, more humid climate in this region, during MIS 11c.
海洋同位素阶段(MIS) 11c (424-397 ka)的地质研究是重建近100万年来最长、最温暖的间冰期之一的气候和海洋条件的关键。此外,间冰期MIS 11c被认为是人类排放情景下不久的将来气候变化时期的重要模拟,因为它具有类似的轨道强迫配置。在这里,我们提出了对大西洋东北部热带佛得角群岛最广泛的第四纪化石沉积演替之一的综合分析结果。Nossa Senhora da Luz湾(圣地亚哥岛)是Macaronesia已知的少数MIS 11化石遗址之一。沉积演替记录了一系列河流环境与海洋环境之间的过渡,以及在一个封闭的、高度保护的海湾环境中发生的突出和浸没事件。它的上部有一层厚厚的细分枝的虹石,表明佛得角已不复存在的生态条件。在高于现今平均海平面约12米的生活位置发现了潮间带蚌Senilia senilis标本,这使我们重新解释了圣地亚哥岛的相对海平面变化,并表明自MIS 11c以来的上升趋势比先前计算的(0.10至0.14 mm/yr)低一个数量级(0.01 mm/yr)。化石组合包括五个门的代表,其中软体动物种类最多,数量最多。尽管一些双壳类(Saccostrea cuccullata、s.s senilis和Aequipecten opercularis)和腹足类(Thetystrombus latus和Thais nodosa)丰富,以及一些视野显示甲壳类动物洞穴,但总体生物多样性较低。现在佛得角群岛上都没有S. cuccullata和S. senilis的存在,这表明在MIS 11c期间,该地区属于热带,更潮湿的气候。
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引用次数: 0
Decoupled intracontinental convergence between the South Tian Shan and northern Tarim Basin since the Neogene: Constraints from stratigraphy and detrital zircon UPb geochronology of the Alparlek section 新近纪以来天山南缘与塔里木盆地北缘的陆内解耦辐合:来自Alparlek剖面地层和碎屑锆石UPb年代学的制约
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-16 DOI: 10.1016/j.palaeo.2025.113493
Kaixuan An , Jialun Huang , Xiubin Lin , Hanlin Chen , Yong Li , Xianzhang Yang , Liang Zhang , Cai Chen , Jinkai Xia , Xiaogan Cheng , Fengqi Zhang , Ziyi Wang , Lin Jiang , Zhuxin Chen , Beiwei Luo , Nan Su
The Cenozoic collision between the Indian and Eurasian plates caused widespread intracontinental deformation, which accommodated roughly half of the present-day India-Eurasia convergence rate. However, the mechanisms driving such intracontinental convergence remain debated, particularly regarding the vertically coherent pure-shear thickening model and the decoupled crustal-scale deformation model. The South Tian Shan and the Tarim Basin record substantial Cenozoic intracontinental convergence, and the Kashi foreland basin preserves abundant synorogenic strata, providing a key archive to test these competing models. Herein, we conducted sedimentological and detrital zircon UPb geochronological analyses of the Neogene–Quaternary strata in the Alparlek section. Stratigraphic observations reveal an overall upward-coarsening facies succession, reflecting a transition from the low-energy depositional environments of the early–middle Miocene Keziluoyi–Pakabulake Formations to the high-energy alluvial systems of the late Miocene–Quaternary Artux–Xiyu Formations. This sedimentary evolution indicates a progressive advance of thrust-induced flexural loading and corresponding basinward migration of the Kashi foreland basin since the mid-Miocene. Detrital zircon UPb age distributions further document episodic provenance shifts between the South Tian Shan and the northern Tarim Basin, indicating the multistage, basinward growth of foreland fold-and-thrust belts and a migrating orogen–basin boundary. Integrated with previous geophysical studies, these findings indicate that the Neogene intracontinental convergence between the South Tian Shan and the Tarim Basin occurred in a decoupled mode, characterised by southward thrusting of the upper crust of the northern Tarim Basin and the northward underthrusting of its lower crust beneath the South Tian Shan.
新生代印度板块和欧亚板块之间的碰撞造成了广泛的大陆内变形,这一变形约占当今印度-欧亚大陆辐合速率的一半。然而,推动这种陆内辐合的机制仍然存在争议,特别是关于垂直相干的纯剪切增厚模型和解耦的地壳尺度变形模型。南天山和塔里木盆地记录了大量的新生代陆内辐合,喀什前陆盆地保存了丰富的同造陆地层,为验证这些相互竞争的模式提供了重要的资料。为此,我们对Alparlek剖面新近系—第四纪地层进行了沉积学和碎屑锆石UPb年代学分析。地层观测显示,整体上呈上向粗化的沉积相序列,反映了中新世早期-中中新世克子洛依-帕布拉克组低能沉积环境向晚中新世-第四纪阿图什-西余组高能冲积体系的过渡。这一沉积演化标志着中中新世以来喀什前陆盆地逆冲弯曲作用的递进和相应的向盆迁移。碎屑锆石UPb年龄分布进一步证明了天山南缘与塔里木盆地北缘物源的幕式转移,表明了前陆褶皱冲断带的多期向盆内生长和造山盆地边界的迁移。综合前人的地球物理研究结果,表明塔里木盆地与南天山的新近纪陆内辐合是以塔北上地壳向南逆冲和南天山下地壳向北逆冲的解耦模式发生的。
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引用次数: 0
Component-specific carbon and oxygen isotope variability in marine limestones of the Mid-Ludfordian (late Silurian) carbon isotope excursion of the Baltic Basin 波罗的海盆地中卢德福尔(晚志留世)海相灰岩碳氧同位素变化特征
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-15 DOI: 10.1016/j.palaeo.2025.113504
Imre Andreas Martin , Leho Ainsaar , Aivo Lepland , Alicja Wudarska , Maria Rosa Scicchitano , Tony Prave
The Vidukle-61 core, located in the Baltic Basin of central Lithuania, contains an excellent record of the Mid-Ludfordian Carbon Isotope Excursion (MLCIE; c. 1 Myr duration) identified by carbonate δ13C values rising steadily from c. 0 ‰ to 8 ‰, followed by a return to c. 0 ‰ through a 40-m thick interval of marine limestone. Here, we report carbon and oxygen (CO) isotope data obtained by secondary ion mass spectrometry (SIMS) on two samples (VID-1 and VID-3) of bioclastic packstone from the zenith of the MLCIE. As reported in a previous study, the two samples have bulk-rock values of 7.37 ‰ and 8.17 ‰ for δ13C and − 5.27 ‰ and − 4.68 ‰ for δ18O (values relative to VPDB and repeatability ±0.1 ‰). In contrast, high-spatial-resolution SIMS analyses of the same samples show δ13C values for the calcitic matrix and spar cement ranging between c. 5 ‰ and 11 ‰, and for fossil fragments between c. 6 ‰ and 13 ‰. δ18O SIMS values of individual components vary by up to ±2 ‰ relative to the bulk-rock baseline values. Based on SIMS results and observed isotopic variations between individual components, we attribute the bulk-rock values as an admixture of original seawater CO isotope compositions that are best preserved in the bioclasts and the isotopic compositions of later-stage fluids from which spar and matrix-bound microspar precipitated. Our findings emphasize the significant differences between component-specific and bulk-rock CO isotope values. While δ13Cbulk curves may capture broad temporal trends in the carbon cycle, high-spatial-resolution and component-specific data reveal microscale isotopic heterogeneity, which can deviate considerably from bulk-rock values. Differentiating and identifying the values that best record original carbonate CO isotopic compositions, even in well-preserved carbonate rocks, requires micro-scale studies to resolve C-isotope heterogeneity in carbonate rocks.
Vidukle-61岩心位于立陶宛中部的波罗的海盆地,具有中卢德福尔碳同位素偏移(MLCIE; c. 1 Myr)的良好记录,碳酸盐δ13C值从c. 0‰稳定上升到8‰,然后通过40 m厚的海相灰岩层段返回到c. 0‰。本文报道了利用次级离子质谱法(SIMS)对来自MLCIE天顶的两个生物碎屑岩样品(VID-1和VID-3)的碳氧(CO)同位素数据。前人研究结果表明,这两个样品的δ13C值分别为7.37‰和8.17‰,δ18O值分别为- 5.27‰和- 4.68‰(相对于VPDB和重复性±0.1‰)。相反,相同样品的高空间分辨率SIMS分析显示,钙质基质和晶石胶结物的δ13C值在c. 5‰~ 11‰之间,化石碎片的δ13C值在c. 6‰~ 13‰之间。各组分的δ18O SIMS值相对于整体岩石基线值变化可达±2‰。基于SIMS结果和观测到的单个组分之间的同位素变化,我们将大块岩石值归因于生物碎屑中保存最完好的原始海水CO同位素组成和沉淀晶石和基质结合微晶石的后期流体同位素组成的混合。我们的发现强调了组分特异性和大块岩石CO同位素值之间的显著差异。虽然δ13Cbulk曲线可以捕捉碳循环的广泛时间趋势,但高空间分辨率和组分特异性数据揭示了微尺度同位素非均质性,这可能与大块岩石值有很大偏差。即使在保存完好的碳酸盐岩中,区分和识别最能记录原始碳酸盐岩CO同位素组成的值,也需要微观尺度的研究来解决碳酸盐岩中c同位素的非均质性。
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引用次数: 0
How volcanoes affect boreal mires: Climate-driven regional vegetation changes and stage-dependent responses to tephra fallout in Kamchatka during the Late Holocene 火山如何影响北方沼泽:晚全新世期间堪察加半岛气候驱动的区域植被变化和对火山灰沉降的阶段依赖反应
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-15 DOI: 10.1016/j.palaeo.2025.113501
Valerii E. Pimenov , Maria M. Pevzner , Natalia G. Mazei , Andrey N. Tsyganov , Ekaterina G. Ershova , Yuri A. Mazei
Studying vegetation dynamics in the regions with high volcanic activity is crucial for understanding ecosystem responses to environmental disturbances and predicting future ecological changes. However, the impacts of tephra deposition on vegetation at local and regional scales remain poorly quantified, limiting understanding of ecosystem resilience to volcanic disturbances. This study presents a high-resolution, multiproxy palaeobotanical record from the Kumroch peatland (Kamchatka, Eurasian Far East), integrating detailed tephrostratigraphy, radiocarbon ages, pollen, plant macrofossil, and loss on ignition data. The peat sequence spans the last ∼5 kyr, anchored by 28 recorded tephra layers. Birch forests (Betula ermanii) and alder shrublands (Alnus alnobetula subsp. fruticosa) dominated during the Middle and Late Holocene, with their proportions shifting in response to climate variations. These changes align in timing with the Late Holocene climate oscillations, primarily reflecting temperature fluctuations. Tephra fallout events had no persistent impact on regional vegetation and limited effects on the local vegetation. These findings demonstrate the resilience of boreal ecosystems to tephra deposition across volcanically active areas and underscore the importance of large-scale studies for understanding ashfall-related disturbances.
研究高火山活动区植被动态对于了解生态系统对环境扰动的响应和预测未来生态变化具有重要意义。然而,在局部和区域尺度上,火山沉积对植被的影响仍然缺乏量化,限制了对生态系统对火山扰动的恢复能力的理解。本文介绍了欧亚远东堪察加半岛Kumroch泥炭地的高分辨率、多代理古植物学记录,综合了详细的地层、放射性碳年龄、花粉、植物宏观化石和燃烧损失数据。泥炭层序列跨越最后~ 5 kyr,由28个记录的tephra层固定。白桦林(桦)和桤木灌丛(Alnus alnobetula subsp。在全新世中晚期占主导地位,其比例随气候变化而变化。这些变化在时间上与晚全新世气候振荡一致,主要反映温度波动。辐射尘事件对区域植被无持续性影响,对局地植被影响有限。这些发现证明了北方生态系统对火山活跃地区火山灰沉积的恢复能力,并强调了大规模研究对理解火山灰相关干扰的重要性。
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引用次数: 0
Carbonate-associated sulfate isotope signatures in marine mollusk shells 海洋软体动物壳中碳酸盐伴生硫酸盐同位素特征
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-15 DOI: 10.1016/j.palaeo.2025.113503
Shanggui Gong , Yongbo Peng , Laurie C. Anderson , Annette Summers Engel , Huiming Bao
The oxygen and sulfur isotope compositions of carbonate-associated sulfate (CAS) in biogenic materials, such as mollusk shells, are valuable for inferring paleo-seawater sulfate isotope signatures. However, infaunal species may incorporate sulfate from sediment porewater or, in chemosymbiotic taxa, sulfate metabolized by endosymbiotic sulfur-oxidizing bacteria. To evaluate whether shell CAS primarily records seawater or an ecological niche signature, we measured the δ34S and δ18O of CAS from 24 modern and Holocene mollusk species spanning epifaunal, shallow infaunal, deep infaunal, and lucinid (chemosymbiotic) habitats across the northeastern Gulf of Mexico, Bahamas and Mexico. Results show substantial isotopic variability (δ34SCAS: 15.1–22.6 ‰; δ18OCAS: 8.5–14.3 ‰): 1) Epifaunal and lucinid δ34SCAS values cluster near seawater values, while shallow infauna exhibits the greatest variability (up to 7.5 ‰ range), and deep infauna consistently show lower δ34SCAS (17.1–19.9 ‰) than seawater. 2) All taxa exhibit δ18OCAS enrichment above seawater. The absence of 34S-enrichment in infauna suggests limited porewater sulfate incorporation. Epifaunal δ34SCAS values span a 2.6 ‰ range, with a minimum of 19.5 ‰, implying contributions from non-seawater sulfate, likely dietary sulfur or intracrystalline organic sulfate. Reduced δ34SCAS in deep infauna also supports these additional sulfate sources incorporation, as deep infauna increased reliance on deposit-feeding of deeper sediment organic matter characterized by decreasing δ34S value. For shallow infauna, their larger variability in δ34SCAS stems from diverse feeding strategies (filter- and deposit-feeding) and niche adaptations. Bulk CAS of shallow-water lucinid species archive limited 34S-depeted signal of endosymbiont-derived sulfate. CAS oxygen isotope is consistently enriched due to vital effects, with highly variable δ18OCAS value across all niches supporting multiple sulfate sources in shells. These findings demonstrate that mollusk shell CAS does not purely record seawater sulfate but incorporates ecological signatures, underscoring the importance of species-specific biology in CAS-based paleoenvironmental or symbiosis studies.
生物源材料(如软体动物壳)中碳酸盐伴生硫酸盐(CAS)的氧、硫同位素组成对推断古海水硫酸盐同位素特征具有重要价值。然而,动物物种可能从沉积物孔隙水中吸收硫酸盐,或者在化学共生分类群中,由内共生硫氧化细菌代谢的硫酸盐。为了评估贝壳CAS主要记录的是海水还是生态位特征,我们测量了墨西哥湾东北部、巴哈马和墨西哥的24种现代和全新世软体动物的CAS δ34S和δ18O,这些软体动物跨越了地表层、浅层、深层和lucinid(化学共生)栖息地。结果表明:1)浅层和lucinid的δ34SCAS值集中在海水附近,浅层动物δ34SCAS值变化最大(可达7.5‰),深层动物δ34SCAS值始终低于海水(17.1 ~ 19.9‰)。2)所有类群在海水以上均表现出δ18OCAS富集。动物体内不富集34s,说明孔隙水中硫酸盐的掺入有限。浅层δ34SCAS值在2.6‰范围内,最小值为19.5‰,表明非海水硫酸盐,可能是膳食硫或结晶内有机硫酸盐的贡献。深层动物δ34SCAS的减少也支持了这些额外的硫酸盐来源的结合,因为深层动物增加了对沉积物喂养的依赖,其特征是δ34S值降低。对于浅层动物,其δ34SCAS的较大变化源于不同的摄食策略(过滤器和沉积物摄食)和生态位适应。浅水lucinids物种档案的大量CAS限制了内共生衍生硫酸盐的34s信号。由于重要影响,CAS氧同位素持续富集,在所有生态位中δ18OCAS值变化很大,支持壳中多种硫酸盐来源。这些发现表明,软体动物壳CAS不仅记录了海水硫酸盐,而且包含了生态特征,强调了物种特异性生物学在基于CAS的古环境或共生研究中的重要性。
{"title":"Carbonate-associated sulfate isotope signatures in marine mollusk shells","authors":"Shanggui Gong ,&nbsp;Yongbo Peng ,&nbsp;Laurie C. Anderson ,&nbsp;Annette Summers Engel ,&nbsp;Huiming Bao","doi":"10.1016/j.palaeo.2025.113503","DOIUrl":"10.1016/j.palaeo.2025.113503","url":null,"abstract":"<div><div>The oxygen and sulfur isotope compositions of carbonate-associated sulfate (CAS) in biogenic materials, such as mollusk shells, are valuable for inferring paleo-seawater sulfate isotope signatures. However, infaunal species may incorporate sulfate from sediment porewater or, in chemosymbiotic taxa, sulfate metabolized by endosymbiotic sulfur-oxidizing bacteria. To evaluate whether shell CAS primarily records seawater or an ecological niche signature, we measured the δ<sup>34</sup>S and δ<sup>18</sup>O of CAS from 24 modern and Holocene mollusk species spanning epifaunal, shallow infaunal, deep infaunal, and lucinid (chemosymbiotic) habitats across the northeastern Gulf of Mexico, Bahamas and Mexico. Results show substantial isotopic variability (δ<sup>34</sup>S<sub>CAS</sub>: 15.1–22.6 ‰; δ<sup>18</sup>O<sub>CAS</sub>: 8.5–14.3 ‰): 1) Epifaunal and lucinid δ<sup>34</sup>S<sub>CAS</sub> values cluster near seawater values, while shallow infauna exhibits the greatest variability (up to 7.5 ‰ range), and deep infauna consistently show lower δ<sup>34</sup>S<sub>CAS</sub> (17.1–19.9 ‰) than seawater. 2) All taxa exhibit δ<sup>18</sup>O<sub>CAS</sub> enrichment above seawater. The absence of <sup>34</sup>S-enrichment in infauna suggests limited porewater sulfate incorporation. Epifaunal δ<sup>34</sup>S<sub>CAS</sub> values span a 2.6 ‰ range, with a minimum of 19.5 ‰, implying contributions from non-seawater sulfate, likely dietary sulfur or intracrystalline organic sulfate. Reduced δ<sup>34</sup>S<sub>CAS</sub> in deep infauna also supports these additional sulfate sources incorporation, as deep infauna increased reliance on deposit-feeding of deeper sediment organic matter characterized by decreasing δ<sup>34</sup>S value. For shallow infauna, their larger variability in δ<sup>34</sup>S<sub>CAS</sub> stems from diverse feeding strategies (filter- and deposit-feeding) and niche adaptations. Bulk CAS of shallow-water lucinid species archive limited <sup>34</sup>S-depeted signal of endosymbiont-derived sulfate. CAS oxygen isotope is consistently enriched due to vital effects, with highly variable δ<sup>18</sup>O<sub>CAS</sub> value across all niches supporting multiple sulfate sources in shells. These findings demonstrate that mollusk shell CAS does not purely record seawater sulfate but incorporates ecological signatures, underscoring the importance of species-specific biology in CAS-based paleoenvironmental or symbiosis studies.</div></div>","PeriodicalId":19928,"journal":{"name":"Palaeogeography, Palaeoclimatology, Palaeoecology","volume":"684 ","pages":"Article 113503"},"PeriodicalIF":2.7,"publicationDate":"2025-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-system geochronometer constraints on thermo-tectonic evolution of the Qiangtang Terrane, central Tibetan Plateau
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-13 DOI: 10.1016/j.palaeo.2025.113494
Qingqing Lei , Xiaofan Wan , Xiang Ge , Xiaowei Zeng , Chuanbo Shen
The Qiangtang Terrane preserves a complete geological record documenting the growth of the central Tibetan Plateau; however, its thermo-tectonic evolution and the timing of topographic development remains debated. This study employs multi-system thermochronology (zircon U–Pb, apatite U–Pb, apatite fission track, apatite (U–Th)/He) of sedimentary strata and magmatic rocks from the Qiangtang Terrane to reconstruct its thermal history. The new thermochronological data show that zircon and apatite U–Pb geochronology from Late Triassic and Eocene igneous rocks yield ages in close agreement at ∼220 Ma and ∼ 35 Ma, respectively. Apatite fission track ages range from 121.2 ± 2.7 Ma to 39.3 ± 2.7 Ma, while AHe ages are between 72.5 ± 1.5 Ma and 27.2 ± 0.6 Ma. Integration of these geochronological data with thermal history modeling constrains four distinct tectonic phases: (1) post-magmatic cooling following the South–North Qiangtang collision during the Late Triassic (∼220 Ma), (2) tectonic deformation and uplift related to the Lhasa–Qiangtang collision during the Late Cretaceous (∼90 Ma), (3) magmatic activity in response to intracontinental subduction during the Eocene (55–36 Ma), and (4) tectonic transition triggered by lithospheric mantle delamination since the post-Oligocene (<35 Ma). Furthermore, by synthesizing previous studies on regional exhumation, magmatic activity, fault systems, and palaeoelevation, this study supports the “Proto-Tibetan Plateau” model and provides new insights into the pulsed growth of the central Tibetan Plateau. Eocene deep-seated magmatic processes generated crustal thickness capable of isostatically sustaining a plateau, which then experienced its final uplift after the Oligocene.
采用多系统热年代学方法(锆石U-Pb、磷灰石U-Pb、磷灰石裂变径迹、磷灰石(U-Th)/He)重建羌塘地体沉积地层和岩浆岩的热历史。新的热年代学数据表明,晚三叠世和始新世火成岩的锆石和磷灰石U-Pb年代学结果分别在~ 220 Ma和~ 35 Ma接近一致。磷灰石裂变径迹年龄范围为121.2±2.7 Ma ~ 39.3±2.7 Ma, AHe年龄范围为72.5±1.5 Ma ~ 27.2±0.6 Ma。将这些地质年代学数据与热历史模拟相结合,约束了四个不同的构造阶段:(1)晚三叠世(~ 220 Ma)南-北羌塘碰撞引起的岩浆后冷却,(2)晚白垩世(~ 90 Ma)拉萨-羌塘碰撞引起的构造变形和隆升,(3)始新世(55-36 Ma)陆内俯冲引起的岩浆活动,(4)后渐新世(<35 Ma)以来岩石圈地幔剥离引起的构造转变。始新世深部岩浆作用产生的地壳厚度能够在均衡上维持一个高原,然后在渐新世之后经历了最终的隆起。
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引用次数: 0
Discerning biotic from abiotic carbonate cementations in Holocene beachrock: mineralogical and geochemical fingerprints for biosignatures 全新世滩岩中生物与非生物碳酸盐胶结的识别:生物特征的矿物学和地球化学指纹图谱
IF 2.7 2区 地球科学 Q2 GEOGRAPHY, PHYSICAL Pub Date : 2025-12-11 DOI: 10.1016/j.palaeo.2025.113454
Xi-yang Zhang , Ming-zhuang Wang , Qi Shi , Fei Tan , Guo-tao Zhang , Si-qi Chen , Hong-qiang Yang
Beachrock cementation, mediated by physicochemical and biological processes, plays a pivotal role in the rapid lithification of coastal sediments. Distinguishing between biotic and abiotic carbonate cements is critical for quantitatively reconstructing diagenetic pathways and accurately evaluating paleoenvironmental conditions. We analyzed Holocene beachrocks from Hainan and the Xisha Islands to compare their cement types. Beachrocks from Hainan are characterized by isopachous high-Mg calcite (HMC) rinds, HMC-rich peloidal fabrics, and blocky–drusy low-Mg calcite (LMC), whereas those from the Xisha Islands are dominated by acicular aragonite. HMC rinds composed of equilong fibrous crystals represent marine phreatic cements with minimal diagenetic alteration, whereas LMC forms through meteoric vadose processes, as indicated by red cathodoluminescent rings. Acicular aragonite nucleates within organic-rich micrite envelopes, with its rapid growth governed primarily by inorganic mechanisms. Peloidal fabrics exhibit distinct fluorescence patterns, dull cathodoluminescence, and elevated Mn/Fe ratios, consistent with their interpretation as microbially mediated precipitates formed during organic matter degradation under intermittently reducing conditions. Notably, peloidal fabrics and aragonite are enriched in bioactive metals (V, Fe, Zn, Pb) relative to coral Porites, consistent with active microbial metabolism. Unlike HMC rinds and acicular aragonite, peloidal fabrics display high total rare earth element (REE) contents, uniform REE distributions, LREE depletion (low LREE/HREE), negative Ce anomalies, positive La anomalies, Y/Ho ratios (∼45), and REE partitioning patterns closely matching modern seawater. These distinctive geochemical signatures establish peloidal fabrics as high-fidelity, high-resolution archives of paleo-seawater chemistry, providing a robust tool for deciphering ancient marine environments.
滩岩胶结作用是由物理化学和生物过程介导的,在海岸沉积物的快速岩化过程中起着关键作用。区分生物和非生物碳酸盐胶结物对于定量重建成岩路径和准确评价古环境条件至关重要。我们分析了海南和西沙群岛的全新世滩岩,比较了它们的胶结类型。海南滩岩以等径高镁方解石(HMC)表层、富HMC的似球粒状组构和块状低镁方解石(LMC)为主,西沙滩岩以针状文石为主。HMC环由等长纤维晶体组成,代表海洋潜水胶结物,成岩蚀变最小,而LMC则通过大气渗透过程形成,如红色阴极发光环所示。针状文石在富有机质泥晶包壳内成核,其快速生长主要受无机机制支配。Peloidal织物表现出明显的荧光模式、暗淡的阴极发光和升高的Mn/Fe比率,这与它们的解释一致,即在间歇性还原条件下有机物降解过程中形成的微生物介导的沉淀。值得注意的是,相对于珊瑚孔隙岩,peloidal fabric和文石富含生物活性金属(V, Fe, Zn, Pb),与活跃的微生物代谢一致。与HMC和针状文石不同,peloidal织物显示出高总稀土元素(REE)含量,均匀的REE分布,LREE枯竭(低LREE/HREE),负Ce异常,正La异常,Y/Ho比(~ 45),以及与现代海水密切匹配的REE分配模式。这些独特的地球化学特征使peloidal织物成为高保真度,高分辨率的古海水化学档案,为破译古代海洋环境提供了强大的工具。
{"title":"Discerning biotic from abiotic carbonate cementations in Holocene beachrock: mineralogical and geochemical fingerprints for biosignatures","authors":"Xi-yang Zhang ,&nbsp;Ming-zhuang Wang ,&nbsp;Qi Shi ,&nbsp;Fei Tan ,&nbsp;Guo-tao Zhang ,&nbsp;Si-qi Chen ,&nbsp;Hong-qiang Yang","doi":"10.1016/j.palaeo.2025.113454","DOIUrl":"10.1016/j.palaeo.2025.113454","url":null,"abstract":"<div><div>Beachrock cementation, mediated by physicochemical and biological processes, plays a pivotal role in the rapid lithification of coastal sediments. Distinguishing between biotic and abiotic carbonate cements is critical for quantitatively reconstructing diagenetic pathways and accurately evaluating paleoenvironmental conditions. We analyzed Holocene beachrocks from Hainan and the Xisha Islands to compare their cement types. Beachrocks from Hainan are characterized by isopachous high-Mg calcite (HMC) rinds, HMC-rich peloidal fabrics, and blocky–drusy low-Mg calcite (LMC), whereas those from the Xisha Islands are dominated by acicular aragonite. HMC rinds composed of equilong fibrous crystals represent marine phreatic cements with minimal diagenetic alteration, whereas LMC forms through meteoric vadose processes, as indicated by red cathodoluminescent rings. Acicular aragonite nucleates within organic-rich micrite envelopes, with its rapid growth governed primarily by inorganic mechanisms. Peloidal fabrics exhibit distinct fluorescence patterns, dull cathodoluminescence, and elevated Mn/Fe ratios, consistent with their interpretation as microbially mediated precipitates formed during organic matter degradation under intermittently reducing conditions. Notably, peloidal fabrics and aragonite are enriched in bioactive metals (V, Fe, Zn, Pb) relative to coral <em>Porites</em>, consistent with active microbial metabolism. Unlike HMC rinds and acicular aragonite, peloidal fabrics display high total rare earth element (REE) contents, uniform REE distributions, LREE depletion (low LREE/HREE), negative Ce anomalies, positive La anomalies, Y/Ho ratios (∼45), and REE partitioning patterns closely matching modern seawater. These distinctive geochemical signatures establish peloidal fabrics as high-fidelity, high-resolution archives of paleo-seawater chemistry, providing a robust tool for deciphering ancient marine environments.</div></div>","PeriodicalId":19928,"journal":{"name":"Palaeogeography, Palaeoclimatology, Palaeoecology","volume":"684 ","pages":"Article 113454"},"PeriodicalIF":2.7,"publicationDate":"2025-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145753755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Palaeogeography, Palaeoclimatology, Palaeoecology
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