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Preparation and Characterization of PVA/ZrO2 Composite Membranes PVA/ZrO2复合膜的制备与表征
Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300164
Akanksha Mehto, V. R. Mehto, J. Chauhan
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引用次数: 0
Nitride Semiconductors 氮化硅半导体
Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300286
M. Kneissl, J. Christen, A. Hoffmann, B. Monemar, T. Wernicke, Ulrich T. Schwarz, Å. Haglund, M. Meneghini
{"title":"Nitride Semiconductors","authors":"M. Kneissl, J. Christen, A. Hoffmann, B. Monemar, T. Wernicke, Ulrich T. Schwarz, Å. Haglund, M. Meneghini","doi":"10.1002/pssb.202300286","DOIUrl":"https://doi.org/10.1002/pssb.202300286","url":null,"abstract":"","PeriodicalId":20107,"journal":{"name":"physica status solidi (b)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85372965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Demonstration of enhanced saturable absorption in upconverter integrated MoS2 heterostructure thin film using nanopulsed green laser 纳米脉冲绿色激光增强上转换器集成二硫化钼异质结构薄膜的饱和吸收
Pub Date : 2023-08-01 DOI: 10.1002/pssb.202300216
M. Durairaj, T. Girisun
Upconverter/MoS2 heterostructure thin films fabricated by hydrothermal technique are confirmed by X‐ray diffraction and Raman studies. Field‐emission scanning electron microscopy (FESEM) and high‐resolution transmission electron microscopy (HRTEM) reveal the nanobelt structured MoS2 mingled with trapezoid structure fluoride upconverters and sphere‐shaped oxide upconverters. The films exhibit green ( H 11 / 2 2   to   I 15 / 2 4 ) and red ( F 9 / 2 4   to   I 15 / 2 4 ) emission. The influence of upconverters on the nonlinear absorption of MoS2 is exploited by Z‐scan technique using nanopulsed laser. Estimated ground‐state absorption cross section is higher than the excited‐state absorption cross section of the samples and it confirms the occurrence of saturable absorption. CeO2:Yb,Er@MoS2 exhibits stronger saturable absorption due to synergetic effects like higher linear absorption coefficient at 532 nm, stronger green emission, and reduced size. Results pave way for the design of optical switches, Q‐switches, and mode lockers using upconverter integrated MoS2 thin films.
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引用次数: 1
Hydrogen Incorporation in Semiconductors 半导体中氢的掺入
Pub Date : 2023-07-30 DOI: 10.1002/pssb.202300309
Norbert H. Nickel
In many materials, the presence of hydrogen influences the structural and electronic properties. An equilibrium model based on statistical mechanics is presented that describes the unintentional incorporation of hydrogen. As an example, the H concentration in four different semiconductors, namely, c‐Si, c‐Ge, ZnO, and β‐Ga2O3, is measured using H effusion. The measured H concentration ranges from 5.2×1016 to 1.1×1018  cm −3 . From the effusion data, the position of the H chemical potential and the H binding energies are derived.
在许多材料中,氢的存在会影响其结构和电子性能。提出了一个基于统计力学的平衡模型来描述氢的非故意掺入。作为一个例子,用H -渗出法测量了四种不同半导体(即c‐Si, c‐Ge, ZnO和β‐Ga2O3)中的H浓度。测得的H浓度范围为5.2×1016 ~ 1.1×1018 cm−3。从渗液数据推导出了氢化学势和氢结合能的位置。
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引用次数: 0
Crystal Structure, Magnetic, and Dielectric Properties of (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 Multiferroics (x)CoFe2O4 -(1−x)Ba0.8Sr0.2TiO3多铁质材料的晶体结构、磁性和介电性能
Pub Date : 2023-07-29 DOI: 10.1002/pssb.202300215
Anant Shukla, Jyotirekha Mallick, Suman Kumari, Murli Kumar Manglam, P. Biswas, M. Kar
The composites (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 are prepared by solid‐state reaction method using microwave double‐step sintering. Ba0.8Sr0.2TiO3 crystallizes to tetragonal crystal symmetry with P4mm space group and CoFe2O4 crystallizes to cubic crystal symmetry with Fd3¯m space group. Electron microscopy techniques are used to understand the microstructure, elemental composition, and morphology of the composites. The dielectric properties are measured in the 1 Hz–1 MHz frequency range and 40–400 °C temperature range. Composite with x = 0.1 (ε′ ≈ 170, tan δ = 0.08 at 1 kHz) and 0.2 (ε′ ≈ 390, tan δ = 0.07 at 1 kHz) has better dielectric properties than the parent Ba0.8Sr0.2TiO3 ferroelectric (ε′ ≈ 125, tan δ = 0.16 at 1 kHz) and CoFe2O4 ferrimagnetic phases (ε′ ≈ 375, tan δ = 0.72 at 1 kHz), respectively. Composite with 10% cobalt ferrite has the highest saturation polarization (2.1 μC cm−2), the highest remanent polarization (0.9 μC cm−2), and coercive field (23.9 kV cm−1) compared to ferroelectric phase followed by x = 0.2 composite (PS = 1.6 μC cm−2, Pr = 0.8 μC cm−2, and EC = 19.2 kV cm−1). Composite with x = 0.2 shows the highest magnetic coercive field of 1.96 kOe. Hence, this article advocates that 20% ferrite in the composites is the optimized composition for multiferroic applications. The present study will help to explore piezoelectric, magnetostrictive, and magnetoelectric properties of (x)CoFe2O4–(1−x)Ba0.8Sr0.2TiO3 for the technological application.
采用微波双步烧结固相反应法制备了CoFe2O4 -(1−x)Ba0.8Sr0.2TiO3复合材料。Ba0.8Sr0.2TiO3结晶为P4mm空间群的四方对称晶体,CoFe2O4结晶为Fd3¯m空间群的立方对称晶体。利用电子显微镜技术了解复合材料的微观结构、元素组成和形貌。在1 Hz-1 MHz频率范围和40-400℃温度范围内测量介电性能。x = 0.1 (ε′≈170,tan δ = 0.08, 1 kHz)和0.2 (ε′≈390,tan δ = 0.07, 1 kHz)的复合材料的介电性能分别优于母材Ba0.8Sr0.2TiO3铁电相(ε′≈125,tan δ = 0.16, 1 kHz)和CoFe2O4铁磁相(ε′≈375,tan δ = 0.72, 1 kHz)。与铁电相(PS = 1.6 μC cm−2,Pr = 0.8 μC cm−2,EC = 19.2 kV cm−1)相比,含10%钴铁氧体的复合材料具有最高的饱和极化(2.1 μC cm−2)、最高的剩余极化(0.9 μC cm−2)和最高的矫顽力场(23.9 kV cm−1)。当x = 0.2时,复合材料的矫顽力最强,为1.96 kOe。因此,本文主张复合材料中20%的铁氧体是多铁性应用的最佳成分。本研究将有助于探索(x)CoFe2O4 -(1−x)Ba0.8Sr0.2TiO3的压电、磁致伸缩和磁电性能,为技术应用提供参考。
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引用次数: 0
First‐Principles Study of the Effects of La2+/3+ Doping and Oxygen Vacancies on TiO2 Magnetism, Carrier Lifetime, Activity, and Absorption Spectra La2+/3+掺杂和氧空位对TiO2磁性、载流子寿命、活性和吸收光谱影响的第一线原理研究
Pub Date : 2023-07-28 DOI: 10.1002/pssb.202300276
Q. Hou, Mude Qi, Fang Wang, Riguleng Si
The effects of photocatalytic performance and magnetism between La doping and oxygen vacancy on rutile and anatase TiO2 systems are rarely compared. Oxygen vacancies in rutile and anatase TiO2 are also experimentally challenging to control accurately. Herein, the first‐principles generalized gradient approximation (GGA + U) method is used to investigate the effects of La2+/La3+doping and oxygen vacancy on TiO2 magnetism and photocatalytic performance. Results of magnetic calculation show that La2+ doping and oxygen vacancies are magnetic to TiO2, whether rutile or anatase, and that the bound magnetic polaron is the source of ferromagnetism in the anatase Ti15La2+O31 system. The anatase Ti30La22+O62 system can achieve room‐temperature ferromagnetism at Curie temperature. The calculation results of photocatalytic performance show that the anatase‐type Ti15La3+O31 system has minimum formation energy, the highest stability, maximum electric dipole moment, the strongest carrier activity, the strongest polarization ability, the slowest electron–hole recombination, the longest lifetime, and remarkable absorption spectrum redshift among the tested systems.
镧掺杂和氧空位对金红石型和锐钛矿型TiO2体系光催化性能和磁性的影响很少进行比较。金红石型和锐钛型TiO2中的氧空位在实验上也难以精确控制。本文采用第一性原理广义梯度近似(GGA + U)方法研究了La2+/La3+掺杂和氧空位对TiO2磁性和光催化性能的影响。磁性计算结果表明,无论是金红石还是锐钛矿,La2+掺杂和氧空位都对TiO2具有磁性,并且在锐钛矿Ti15La2+O31体系中,束缚的磁性极化子是铁磁性的来源。锐钛矿Ti30La22+O62体系可以在居里温度下实现室温铁磁性。光催化性能计算结果表明,锐钛矿型Ti15La3+O31体系具有最小的形成能、最高的稳定性、最大的电偶极矩、最强的载流子活性、最强的极化能力、最慢的电子-空穴复合、最长的寿命和显著的吸收光谱红移。
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引用次数: 0
Crystal Growth and Physical Properties Evolution in Co‐Doped NiTe2 System Co掺杂NiTe2体系的晶体生长和物理性质演变
Pub Date : 2023-07-26 DOI: 10.1002/pssb.202300272
Wei-Bin Wu, Yuan-Qiao Chen, Li-Xin Gao, Luo-Zhao Zhang, Qiling Xiao, Junyi Ge
Transition metal tellurides have been widely studied for their diverse crystal structures and exotic physical properties such as large magnetoresistance, charge density waves, superconductivity, ferromagnetic and topological properties. NiTe2 has recently been found to be a Dirac semimetal, allowing it to achieve exotic properties by pressure and doping. A series of Ni1−xCoxTe2−δ single crystals are synthesized by the standard solid‐state reaction method. The energy‐dispersive X‐ray spectroscopy and X‐ray diffraction tests confirm Co is successfully doped into the crystal structure. The electrical transport measurements show typical metallic behaviors for all the samples. Magnetization measurements reveal that, in the doping range of x = 0.12–0.62, the samples exhibit a coexistence of antiferromagnetic and paramagnetic phases above the characteristic temperature Tt. By using the combined Curie–Weiss and spin‐wave model, the antiferromagnetic to ferromagnetic transition is found to occur as the temperature drops below Tt. The magnetic transition is attributed to the Te vacancies, which can be explained using the bound magnetic polaritons model. A magnetic phase diagram for Ni1−xCoxTe2−δ system is constructed.
过渡金属碲化物因其多样的晶体结构和特殊的物理性质,如大磁阻、电荷密度波、超导性、铁磁性和拓扑性质而受到广泛的研究。NiTe2最近被发现是一种狄拉克半金属,允许它通过压力和掺杂获得奇异的性能。采用标准固相反应法制备了一系列Ni1−xCoxTe2−δ单晶。能量色散X射线光谱和X射线衍射测试证实Co被成功地掺杂到晶体结构中。电输运测量显示了所有样品的典型金属行为。磁化测量表明,在x = 0.12-0.62的掺杂范围内,样品在特征温度Tt以上呈现反铁磁相和顺磁相共存。通过使用居里-魏斯和自旋波模型,发现当温度降至低于Tt时,会发生反铁磁到铁磁的转变。磁跃迁归因于Te空位,这可以用束缚磁极化子模型来解释。构造了Ni1−xCoxTe2−δ体系的磁相图。
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引用次数: 0
Optoelectronic characterization of 2D graphene based heterostructures. Gr/MoS2 and Gr/WS2 二维石墨烯异质结构的光电特性。Gr/MoS2和Gr/WS2
Pub Date : 2023-07-26 DOI: 10.1002/pssb.202300202
D. Arcos, Daniel Nuño, Muhammad Farooq Khan, J. Eom, L. Ametller, N. Ferrer‐Anglada
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引用次数: 0
Enhancement of Optical, Electrical, Magnetic, and Thermopower Properties of LaMnO3 by Potassium‐Doping 钾掺杂增强LaMnO3的光、电、磁和热电性能
Pub Date : 2023-07-25 DOI: 10.1002/pssb.202300175
Hany F. Mohamed, Ahmed M. Ahmed, M. R. Ahmed, J A Paixão, S. A. Mohamed
Optical, magnetoresistance, and thermoelectric properties of La1−xKxMnO3 (x = 0.05, 0.15, and 0.25) compounds have been investigated. The crystallography demonstrates that the samples x = 0.05 and 0.15 are a single‐phase rhombohedral ( R3¯C$R overset{cdot}{3} C$ ) structure, while x = 0.25 is near to a single rhombohedral phase with a minor amount of Mn3O4 (with a ratio of ≈2%). The optical properties manifest that the reflectivity decreases slightly with increasing x‐doping, where the sample of x = 0.05 has the lowest reflection value, making it a promising material for photovoltaic applications. Electrical resistivity measurements show that the samples have a metal–semiconductor transition, and the transition temperature Tms decreases with the K content. The thermoelectric data show a remarkable coincidence behavior of the ρ–T relationship, which has a peak at a transition temperature (TS). Magnetic susceptibility data show that the samples undergo ferro‐paramagnetic transition at a certain temperature (Curie temperature).
研究了La1−xKxMnO3 (x = 0.05, 0.15和0.25)化合物的光学、磁阻和热电性质。晶体学分析表明,x = 0.05和0.15的样品为单相菱形(R3¯C$R overset{cdot}{3} C$)结构,而x = 0.25的样品则接近于含有少量Mn3O4(比例约为2%)的单相菱形结构。光学性质表明,随着x掺杂量的增加,反射率略有下降,其中x = 0.05的样品具有最低的反射率值,使其成为光伏应用的有前途的材料。电阻率测量表明,样品发生金属-半导体转变,转变温度Tms随K含量的增加而减小。热电数据显示ρ-T关系具有显著的符合性,在过渡温度(TS)处有峰值。磁化率数据表明,样品在一定温度(居里温度)下发生铁-顺磁转变。
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引用次数: 0
The Visible Light Absorption Mechanism for Cubic Zirconia by Cobalt‐Ion Implantation 钴离子注入对立方氧化锆可见光吸收机理的研究
Pub Date : 2023-07-21 DOI: 10.1002/pssb.202300227
Dongyu Cao, Xiaoqing Zhao, Miao Tang, W. Lu, Jingyan Weng, Xier Yu, Jie Yu
To investigate the effect of Co ions on the visible light absorption mechanism of cubic zirconia, Co ions are doped into colorless cubic zirconia with an ion implantation method and related heat treatment is performed. The elemental content, the role of Co, and the types of O elements in cubic ZrO2 are also analyzed utilizing the data from UV–visible spectroscopy, X‐ray diffraction, X‐ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy. Based on the experimental results, the contribution of Co implantation on the visible light absorption of cubic zirconia is calculated from the electronic structure and related optical properties according to the density functional theory. The study results show that the colorless cubic ZrO2 is blue in color after ion implantation and then fades after 1400 °C heat treatment. Thus, the visible light absorption and the spectroscopic characteristics are related to the oxygen vacancy and the d‐orbital transition of Co ions.
为了研究Co离子对立方氧化锆可见光吸收机理的影响,采用离子注入法将Co离子掺杂到无色立方氧化锆中,并进行相应的热处理。利用紫外可见光谱、X射线衍射、X射线光电子能谱和电子顺磁共振谱分析了立方ZrO2的元素含量、Co的作用和O元素的类型。基于实验结果,根据密度泛函理论,从电子结构和相关光学性质出发,计算了Co注入对立方氧化锆可见光吸收的贡献。研究结果表明:离子注入后的无色立方ZrO2呈蓝色,经过1400℃热处理后逐渐褪色;因此,可见光吸收和光谱特性与氧空位和Co离子的d轨道跃迁有关。
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引用次数: 0
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physica status solidi (b)
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