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Electron, phonon, and superconducting properties of Mg2CuH6 under pressure 压力下 Mg2CuH6 的电子、声子和超导特性
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-07-15 DOI: 10.1016/j.physc.2024.1354571

Recent theoretical prediction of Mg2IrH6 is a significant advance in achieving high-temperature superconductivity under atmospheric pressure, Mg2IrH6 is the hydride superconductor with the highest superconducting transition temperature (Tc ∼ 160 K) under ambient pressure so far. In general, Tc is usually related to the degree of hydrogen enrichment. As a representative of the hydrogen-poor structures, MgHCu3 was also predicted to have a Tc of 43 K under atmospheric pressure. In this work, we try to replace the Ir atom in Mg2IrH6 with the Cu atom to improve the superconductivity of the system. The phonon dispersion curves and the ab initio molecular dynamics (AIMD) simulation indicate that the novel ternary Mg2CuH6 hydride is dynamically and thermodynamically stable. But, regrettably, the Tc and electron-phonon coupling (EPC) parameters λ of Mg2CuH6 are calculated to be 12.5 K and 0.55 at 25 GPa, which is far inferior to the superconductivity of Mg2IrH6. Compared with Fm3¯m Mg2CuH6, Fm3¯m Mg2IrH6 produces obvious phonon softening in the G point near 30 meV, which significantly enhances the EPC and increases the Tc of the system. Moreover, Cu substitution for Ir results in a sharp decrease in the contribution of the electronic states for Mg and H to the total density of states at the Fermi level. The huge difference in predicted Tc between Mg2CuH6 and Mg2IrH6 and their causes may provide insights into the design of high-temperature atmospheric superconductors and help to understand the superconducting mechanisms of related systems.

最近对 Mg2IrH6 的理论预测是实现常压下高温超导的重大进展,Mg2IrH6 是迄今为止常压下超导转变温度(Tc ∼ 160 K)最高的氢化物超导体。一般来说,Tc 通常与氢的富集程度有关。作为贫氢结构的代表,MgHCu3 在常压下的 Tc 也被预测为 43 K。在这项工作中,我们尝试用铜原子取代 Mg2IrH6 中的 Ir 原子,以提高系统的超导性。声子频散曲线和 ab initio 分子动力学(AIMD)模拟表明,新型三元 Mg2CuH6 氢化物在动力学和热力学上是稳定的。但遗憾的是,Mg2CuH6 的 Tc 和电子-声子耦合(EPC)参数 λ 在 25 GPa 条件下分别为 12.5 K 和 0.55,远低于 Mg2IrH6 的超导性。与 Fm3¯m Mg2CuH6 相比,Fm3¯m Mg2IrH6 在 30 meV 附近的 G 点产生了明显的声子软化,这显著增强了系统的 EPC 并提高了 Tc。此外,用 Cu 替代 Ir 会导致 Mg 和 H 的电子状态对费米级总状态密度的贡献急剧下降。Mg2CuH6 和 Mg2IrH6 预测 Tc 的巨大差异及其原因可能为高温大气超导体的设计提供启示,并有助于理解相关系统的超导机制。
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引用次数: 0
The influence of Sm2O3 nanoparticles adding on some superconducting properties of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ceramics 添加 Sm2O3 纳米粒子对 Bi1.6Pb0.4Sr2Ca2Cu3O10+δ 陶瓷某些超导特性的影响
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-07-10 DOI: 10.1016/j.physc.2024.1354566

High-Temperature Superconductors Bi1.6Pb0.4Sr2Ca2Cu3O10+δ samples doped with Sm2O3 nanoparticles in different quantities (0.00, 0.02, 0.04 and 0.06), were synthesised. Solid state feedback technique was used to prepare the samples and then characterised. The morphology and structure of the specimens were deployed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) examination. The spectroscopy of the energy dispersive X-ray (EDX) experiment was utilised to obtain the elemental composition of the samples. Resistivity versus temperature measurement in DC mode was employed to estimate the critical transition temperature of each sample. XRD with the Rietveld refinement process revealed that Bi2223 and Bi2212 stages exist mutually in specimens with orthorhombic crystal systems. The lowest percentage of volume fraction associated with the Bi2223 phase belonged to the sample with x=0.06 nanoparticle samarium doped. It was detected that with rising samarium content the volume division of the Bi2223 phase decreases but the Bi2212 stage increases compared with the pristine specimen. SEM showed that the shrinkage of grain size occurs when the amount of nano-sized Sm was added to x=0.02 sample with lower inter-coupling among superconducting granules. This effect might be verified by SEM and TEM images. EDX exhibited some peaks related to Sm and other elements of the Bi2223 structure. These patterns confirm that all elements associated with the compounds were introduced into the Bi2223 matrix. The critical temperatures such as Tconset, TcPeak and Tczero decreased for Sm doped samples compared with the pure sample. Adding Sm2O

合成了掺杂不同数量(0.00、0.02、0.04 和 0.06)Sm2O3 纳米粒子的高温超导体 Bi1.6Pb0.4Sr2Ca2Cu3O10+δ 样品。采用固态反馈技术制备样品,然后进行表征。通过扫描电子显微镜(SEM)和 X 射线衍射(XRD)检查了试样的形态和结构。利用能量色散 X 射线(EDX)光谱实验获得了样品的元素组成。采用直流模式测量电阻率与温度的关系,以估算每个样品的临界转变温度。利用里特维尔德细化过程进行的 XRD 显示,Bi2223 和 Bi2212 在正方晶系试样中相互存在。掺杂 x=0.06 纳米钐的样品中,Bi2223 相的体积分数百分比最低。与原始试样相比,随着钐含量的增加,Bi2223 相的体积分数减少,但 Bi2212 相的体积分数增加。扫描电子显微镜显示,在 x=0.02 的样品中添加纳米级的 Sm 时,晶粒尺寸会缩小,超导颗粒之间的相互耦合降低。扫描电镜和电子显微镜图像可以验证这种效应。电离辐射 X 显示了一些与 Sm 和 Bi2223 结构中其他元素有关的峰值。这些图形证实,所有与化合物相关的元素都被引入到了 Bi2223 基体中。与纯样品相比,掺入 Sm 的样品的临界温度(如 Tconset、TcPeak 和 Tczero)有所降低。加入 Sm2O3 纳米粒子会导致计算密度和空穴载流子浓度上升。这些结果可以解释为额外的正电荷被分配到了 CuO2 平面上。值得一提的是,Bi2223 具有高 Tc、高 Jc、强磁通钉销和良好的热稳定性等优异特性,而 Sm2O3 具有高击穿电场、高介电常数和大带隙等特性,这些都是促使作者在 Bi2223 中掺入 Sm2O3 NP 的原因。简而言之,掺杂 Sm2O3 NPs 的 Bi2223 的电气、机械和结构特性在应用中起着主要作用,这促使研究人员重视超导样品的合成。
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引用次数: 0
Investigating the impact of magnetic air gap variations on short circuit characteristics of partially high temperature superconducting generator 研究磁气隙变化对部分高温超导发电机短路特性的影响
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-07-03 DOI: 10.1016/j.physc.2024.1354550
Mohamed Elhindi , Modawy Adam Ali Abdalla , Dong Liu

Partially high-temperature superconducting generators (PHTSGs) feature large magnetic air gaps imposed by using cryostats for HTS field windings. This increased air gap significantly affects end winding inductance and can lead to elevated fault torque levels. This study investigates the influence of magnetic air gap variation on generator design and end winding inductance and its implications for short-circuit faults in PHTSGs. Through a combination of numerical simulations and analytical analysis, the study explores how changes in the magnetic air gap affect end winding inductance and subsequently influence short-circuit fault behavior. The results reveal a direct correlation between magnetic air gap length, end winding inductance, and key short-circuit parameters such as stator current, field currents, and electromagnetic torque. Notably, an increase in the magnetic air gap is observed to elevate stator and field currents and electromagnetic torque during short-circuit events. These insights underscore the importance of considering magnetic air gap variation and its impact on end winding inductance and its relationship with short circuit characteristics in the design and operation of PHTSGs, providing valuable insights for enhancing the resilience and performance of high-temperature superconductor-based generator systems.

部分高温超导发电机(PHTSG)的磁气隙较大,这是由于 HTS 场绕组使用了低温恒温器。这种增大的气隙会严重影响末端绕组电感,并可能导致故障转矩水平升高。本研究探讨了磁气隙变化对发电机设计和末端绕组电感的影响,以及其对 PHTSG 短路故障的影响。研究结合数值模拟和分析,探讨了磁气隙的变化如何影响端部绕组电感,进而影响短路故障行为。研究结果表明,磁气隙长度、端部绕组电感与定子电流、磁场电流和电磁转矩等关键短路参数之间存在直接关联。值得注意的是,在短路事件中,磁气隙的增加会提高定子电流、磁场电流和电磁转矩。这些见解强调了在 PHTSG 的设计和运行中考虑磁气隙变化及其对末端绕组电感的影响及其与短路特性的关系的重要性,为提高基于高温超导体的发电机系统的恢复能力和性能提供了宝贵的见解。
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引用次数: 0
Thermal analysis of the HTS transformer in the fault current condition considering the tape roughness effect 考虑磁带粗糙度效应的故障电流条件下 HTS 变压器的热分析
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-07-03 DOI: 10.1016/j.physc.2024.1354548
Mahdi Mahamed, Seyyedmeysam Seyyedbarzegar

High temperature superconducting (HTS) transformers have many advantages over conventional transformers in terms of volume, weight, and total efficiency. However, fault conditions limit the electro-thermal performance of an HTS transformer. Based on this, we investigate the thermal modeling of the HTS transformer in the fault-current state. For thermal modeling, heat transfer and parameters affecting it such as surface roughness and bubble behavior have been considered. At first, an accurate thermal model for a 10 kVA HTS transformer has been prepared. Experimental results show that the penalty of this model is about 2.5 K in the hot-spot point (HSP) temperature in fault-current conditions. In a second step, the impact of a roughness on the heat transfer and mass transfer rate in nucleated boiling mode is investigated. Results show that surface roughness decreases the HSP temperature by more than 10 K in fault-current conditions. These results have significant impacts on protecting HTS windings against quenching.

与传统变压器相比,高温超导(HTS)变压器在体积、重量和总效率方面具有许多优势。然而,故障条件限制了 HTS 变压器的电热性能。基于此,我们研究了故障电流状态下 HTS 变压器的热建模。在热建模中,我们考虑了热传导以及影响热传导的参数,如表面粗糙度和气泡行为。首先,为 10 kVA HTS 变压器建立了精确的热模型。实验结果表明,在故障电流条件下,该模型对热点(HSP)温度的影响约为 2.5 K。第二步,研究了粗糙度对成核沸腾模式下传热和传质速率的影响。结果表明,在故障电流条件下,表面粗糙度可将热斑点温度降低 10 K 以上。这些结果对保护 HTS 绕组免受淬火影响具有重大意义。
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引用次数: 0
Evidences for d-wave symmetry of c-axis superconducting gap in atomically thin twisted flakes of bismuth-based HTS cuprates 铋基 HTS 铜氧化物原子薄扭曲片中 c 轴超导间隙 d 波对称性的证据
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-06-24 DOI: 10.1016/j.physc.2024.1354549
Evgeny F. Talantsev

c-axis Josephson tunnelling in atomically thin twisted flakes of quasi-two-dimensional cuprate superconductors is one of the experimental techniques which can be used to reveal the pairing symmetry in HTS cuprates. Until very recent experiments reported by Zhao et al. (Science 382, 1422 (2023)), there was a widely accepted consensus that the c-axis Josephson currents, Ic(T), in twisted cuprate junctions manifest the s-wave gap symmetry for c-axis gap component. Here, I highlighted that this consensus was based on the analysis of the Ic(T) data by using the Ambegaokar-Baratoff equation, where the weak-coupling s-wave gap equation was utilized. In this study, I introduced a more accurate gap equation in the AB model and reanalyzed the Ic(T) data in atomically thin twisted Bi2Sr2-xLaxCuO6+y (Bi-2201) and Bi2Sr2CaCu2O8+x (Bi-2212) flakes. In the result, the analysis revealed evidences for d-wave pairing symmetry. Beside this, the analysis of the RnIc(T) data reported by Zhao et al. (Science 382, 1422 (2023)) by a piecewise AB model, where a linear low-T dependence of the Ic(T) is used, and where the threshold temperature TM is a free-fitting parameter, confirmed the d-wave symmetry in these twisted Bi-2212 junctions.

准二维铜氧化物超导体原子薄扭曲片中的 c 轴约瑟夫森隧穿是揭示 HTS 铜氧化物配对对称性的实验技术之一。在赵等人最近的实验报告(Science 382, 1422 (2023))之前,人们普遍认为扭曲杯状石结中的c轴约瑟夫森电流Ic(T)表现出c轴间隙分量的s波间隙对称性。在这里,我强调了这一共识是基于使用弱耦合 s 波间隙方程的 Ambegaokar-Baratoff 方程分析 Ic(T) 数据得出的。在本研究中,我在 AB 模型中引入了更精确的间隙方程,并重新分析了原子薄扭曲 Bi2Sr2-xLaxCuO6+y (Bi-2201) 和 Bi2Sr2CaCu2O8+x (Bi-2212) 薄片的 Ic(T) 数据。分析结果显示了 d 波配对对称性的证据。此外,Zhao 等人(Science 382, 1422 (2023))用片式 AB 模型分析了 RnIc(T)数据,其中使用了 Ic(T) 的线性低 T 依赖性,阈值温度 TM 是自由拟合参数。
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引用次数: 0
Magnetic and mechanical analyses of superconducting coil for the magnetic Czochralsky technique 用于磁性 Czochralsky 技术的超导线圈的磁性和机械分析
IF 1.3 3区 物理与天体物理 Q4 PHYSICS, APPLIED Pub Date : 2024-06-20 DOI: 10.1016/j.physc.2024.1354545
Mohmmed Mun ELseed Hassaan , Wanjiang Pan , Yinfeng Zhu , Mo Shen , Cheng Wu

Solar cells, electronics, and the semiconductor industry all need high-quality silicon crystals. The Czochralsky technique has been widely used to make a high-quality single silicon crystal from the silicon melt. However, this technique needs a strong magnetic field to stabilize the melt and control the temperature. In this paper, two coils with a curved shape have been optimized and simulated to produce a transverse magnetic field for the Czochralsky technique grower. The coils face each other and have an opening angle of 150°, and a NbTi superconducting wire was used to wind the coils with 5110 turns. The current was 106 A and flowing in the same direction. The finding results indicated that the magnetic field at the silicon melt center is 0.4 T, and the peak field in coils is 2.95 T. The optimized curve shape coils were compared with conventional coils (circle shape coils). The comparison indicated that the curve shape coils produced a highly uniform magnetic field, required less current, and significantly reduced the outer diameter of the superconducting magnet. In addition, heat generation by the current leads was calculated. In the case of the curve-shaped coils, less heat leakage has been achieved; as a result, the cooling capacity, magnet size, weight, and cost will be reduced. Furthermore, mechanical analysis was performed, and the results showed that the stress in the coils is within the permissible range for NbTi at 4.2 K.

太阳能电池、电子产品和半导体工业都需要高质量的硅晶体。Czochralsky 技术已被广泛用于从硅熔体中制造高质量的单晶硅晶体。然而,这种技术需要强磁场来稳定熔体和控制温度。本文对两个弯曲形状的线圈进行了优化和模拟,以便为 Czochralsky 技术生长器产生横向磁场。线圈面对面,开口角为 150°,使用铌钛超导线材绕制,匝数为 5110。电流为 106 A,流向相同。研究结果表明,硅熔体中心的磁场为 0.4 T,线圈中的磁场峰值为 2.95 T。比较结果表明,曲线形状线圈产生的磁场高度均匀,所需的电流较小,并显著缩小了超导磁体的外径。此外,还计算了电流引线产生的热量。曲线线圈的漏热量较少,因此冷却能力、磁体尺寸、重量和成本都有所降低。此外,还进行了机械分析,结果表明,在 4.2 K 下,线圈中的应力在铌钛的允许范围内。
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引用次数: 0
Preparation of a/c-oriented YBa2Cu3O7−x homogeneous superconducting junctions via pulsed laser deposition 通过脉冲激光沉积制备面向 a/c 的 YBa2Cu3O7-x 均相超导结
IF 1.3 3区 物理与天体物理 Q3 Energy Pub Date : 2024-06-19 DOI: 10.1016/j.physc.2024.1354551
Xiaoqin Liu , Yeming He , Peng Li , Wei Li , Yangyang Wang , Mingyang Zhou

The growth orientation of YBa2Cu3O7−x (YBCO) is extremely sensitive to the growth atmosphere and the heat-treatment temperature. However, according to the existing literature, to obtain YBCO with preferred a-axis orientation, a buffer layer needs to be prepared on the substrate. In this work, YBCO films were grown via pulsed laser deposition, and the influence of N2 and O2 deposition atmospheres on the growth orientation of the YBCO films was studied. It was found that high-quality YBCO films with preferred c-axis orientation can be grown in O2 atmosphere, but it is difficult to grow a-axis-oriented YBCO films in O2 atmosphere without using a buffer layer; however, YBCO films with a high degree of preferred a-axis orientation can be grown in N2 atmosphere without using a buffer layer. Furthermore, an a/c-oriented homogeneous YBCO bilayer with c-axis orientation in the lower layer and a-axis orientation in the upper layer was prepared. X-ray diffraction and scanning transmission electron microscopy results show that the bilayer is epitaxial with a good a/c orientation, and the resistance–temperature curve shows the occurrence of two transitions at temperatures of 91 and 71 K. We believe that these temperatures correspond to the superconducting onset transition temperatures of YBCO in the c- and a-axis growth orientations, respectively. The superconducting current usually flows within the Cu–O plane. With its sudden change in the direction of the current at the interface, the homogeneous junction prepared in this work is expected to provide new ideas for the research of high-temperature superconducting junction devices.

YBa2Cu3O7-x(YBCO)的生长取向对生长气氛和热处理温度极为敏感。然而,根据现有文献,要获得具有优先 a 轴取向的 YBCO,需要在基底上制备缓冲层。本研究通过脉冲激光沉积法生长了 YBCO 薄膜,并研究了 N2 和 O2 沉积气氛对 YBCO 薄膜生长取向的影响。研究发现,在 O2 气氛中可以生长出高质量的具有 c 轴优先取向的 YBCO 薄膜,但在不使用缓冲层的情况下,很难在 O2 气氛中生长出 a 轴取向的 YBCO 薄膜;然而,在不使用缓冲层的情况下,可以在 N2 气氛中生长出高度优先 a 轴取向的 YBCO 薄膜。此外,还制备了一种 a/c 取向的均匀 YBCO 双层膜,其下层为 c 轴取向,上层为 a 轴取向。X 射线衍射和扫描透射电子显微镜结果表明,该双层层具有良好的 a/c 取向外延,电阻-温度曲线显示在 91 和 71 K 的温度下出现了两个转变,我们认为这些温度分别对应于 YBCO 在 c 轴和 a 轴生长方向上的超导起始转变温度。超导电流通常在 Cu-O 平面内流动。本研究制备的均匀结在界面处电流方向发生了突变,有望为高温超导结器件的研究提供新思路。
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引用次数: 0
Effect of laser energy density on microstructure and critical current of YGBCO and HGBCO films fabricated by PLD 激光能量密度对 PLD 制造的 YGBCO 和 HGBCO 薄膜微观结构和临界电流的影响
IF 1.7 3区 物理与天体物理 Q3 Energy Pub Date : 2024-06-13 DOI: 10.1016/j.physc.2024.1354547
Xiang Wu

Y0.5Gd0.5Ba2Cu3O7-σ (YGBCO) and Ho0.5Gd0.5Ba2Cu3O7-σ (HGBCO) targets with similar densities were prepared by solid-phase reaction. Pulsed laser deposition (PLD) technology was used to fabricate superconducting films with these targets. During the experiments in this paper, we varied the laser energy by adjusting the optical lens. The structure and texture of RE0.5Gd0.5Ba2Cu3O7-σ (REGBCO, where RE = Y, Ho) thin films were analyzed by X-ray diffraction (XRD). The surface morphology was observed by atomic force microscopy (AFM) and scanning electron microscopy (SEM), and the superconducting critical current was measured at 77 K using the standard four-probe method. The laser energy density and different doping elements can affect the properties of REGBCO films. This may be related to the ejection process of target particles and the size of rare earth atoms. Additionally, we prepared a 510-meter long second-generation high-temperature superconducting tape with the optimized parameters. The critical current of the tape is 350 A, and the current density is 3.9 × 106 A/cm2.

通过固相反应制备了密度相似的 Y0.5Gd0.5Ba2Cu3O7-σ (YGBCO) 和 Ho0.5Gd0.5Ba2Cu3O7-σ (HGBCO) 靶件。利用脉冲激光沉积(PLD)技术用这些靶材制造了超导薄膜。在本文的实验中,我们通过调节光学透镜来改变激光能量。通过 X 射线衍射 (XRD) 分析了 RE0.5Gd0.5Ba2Cu3O7-σ (REGBCO,其中 RE = Y、Ho)薄膜的结构和纹理。用原子力显微镜(AFM)和扫描电子显微镜(SEM)观察了表面形貌,并用标准四探针法测量了 77 K 时的超导临界电流。激光能量密度和不同的掺杂元素会影响 REGBCO 薄膜的特性。这可能与靶粒子的喷射过程和稀土原子的大小有关。此外,我们还利用优化后的参数制备了一条 510 米长的第二代高温超导带。该磁带的临界电流为 350 A,电流密度为 3.9 × 106 A/cm2。
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引用次数: 0
Gradient magnetic field measurement using first-order gradiometers equipped with 50 mm diameter pickup coils made out of a 2G high-Tc superconducting tape 使用一阶梯度仪测量梯度磁场,梯度仪配备直径 50 毫米的拾取线圈,线圈由 2G 高锝超导带制成
IF 1.7 3区 物理与天体物理 Q3 Energy Pub Date : 2024-06-02 DOI: 10.1016/j.physc.2024.1354519
Kazunori Komori , Shunichi Arisawa , Minoru Tachiki , Shuuichi Ooi , Tadayuki Hayashi , Kazuhiro Endo

Two types of first-order gradiometers equipped with 50 mm diameter pickup coils were made out of an REBaCuO High-Tc superconducting (HTS) flexible tape. The HTS tapes were formed into the HTS gradiometers by ``cut-and-wind'' method without cable jointing.

The HTS gradiometers were examined at 77 K for magnetic sensitivity to a gradient field applied by an external coil. The axial-type HTS gradiometer eliminated the magnetic field output of the device induced by a uniform field, and enhanced the magnetic field output induced by a gradient field on the axis of the pickup coil. The planar-type HTS gradiometer made it possible to detect a 20 mm diameter steel cylinder placed beside the pickup coil in a uniform field of 100 µT by detecting the spatial field gradient in the vicinity of a ferromagnetic object.

用 REBaCuO 高锝超导(HTS)柔性带制作了两种配备 50 毫米直径拾波线圈的一阶梯度仪。HTS 梯度仪在 77 K 下进行了检测,以确定其对外部线圈施加的梯度场的磁灵敏度。轴向型 HTS 梯度仪消除了由均匀磁场引起的设备磁场输出,增强了由拾取线圈轴上的梯度磁场引起的磁场输出。平面型 HTS 梯度仪通过检测铁磁性物体附近的空间场梯度,可以在 100 µT 的均匀磁场中检测放置在拾取线圈旁边的直径为 20 毫米的钢筒。
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引用次数: 0
Development of high superconductor fraction (Ba, K)Fe2As2 wires with improved uniformity by two-axial rolling 通过双轴轧制技术开发出均匀度更高的高超导体分数 (Ba, K)Fe2As2 线材
IF 1.7 3区 物理与天体物理 Q3 Energy Pub Date : 2024-06-02 DOI: 10.1016/j.physc.2024.1354520
Hao Xiong , Chao Yao , Wenwen Guo , Peng Yang , Zhihong Ren , Dongliang Wang , Xianping Zhang , Yanwei Ma

Iron-based superconductors are regarded as prospective candidates for high magnetic field applications since they have very high upper critical field and low anisotropy. For practical applications, it is important to develop superconducting wires with strong current carrying capability. In this work, Cu/Ag composite sheathed (Ba, K)Fe2As2 (Ba-122) iron-based superconducting wires were fabricated by a two-axial rolling deformation process and a subsequent hot isostatic pressing (HIP) heat treatment. Compared with the previously reported Cu/Ag/Ba-122 wires prepared by groove rolling, the two-axial rolling allowed to use much thinner Cu/Ag composite sheath for wire fabrication, thus greatly increasing the filling factor of superconducting materials by about 5 times to 24 %, and lowering the volume fraction of silver down to 16 % in wires. By a comparative study on the microstructure and superconducting properties between the wires made by two-axial rolling and groove rolling processes, it is found that besides the significantly increased engineering critical current density, the former also exhibits improved homogeneity of mass distribution and uniformity of Ba-122/Ag interfaces, resulting in significantly enhanced n-values over 40 in magnetic fields up to 14 T. Our work suggests that two-axial rolling, combined with HIP processes, presents a promising approach to prepare iron-based superconducting wires with high filling factor, high uniformity and low cost for practical applications.

铁基超导体具有很高的上临界磁场和较低的各向异性,因此被视为高磁场应用的潜在候选材料。在实际应用中,开发具有强大载流能力的超导线材非常重要。在这项工作中,通过双轴轧制变形工艺和随后的热等静压(HIP)热处理,制造出了铜/银复合护套(Ba, K)Fe2As2 (Ba-122)铁基超导线材。与之前报道的通过沟槽轧制制备的 Cu/Ag/Ba-122 金属丝相比,双轴轧制工艺可以使用更薄的 Cu/Ag 复合护套来制造金属丝,从而将超导材料的填充因子提高了约 5 倍,达到 24%,并将金属丝中银的体积分数降低到 16%。通过对双轴轧制工艺和沟槽轧制工艺制作的导线的微观结构和超导性能进行比较研究,发现前者除了工程临界电流密度显著提高外,还改善了质量分布的均匀性和 Ba-122/Ag 界面的均匀性,从而在高达 14 T 的磁场中显著提高了超过 40 的 n 值。我们的工作表明,双轴轧制与 HIP 工艺相结合,为制备具有高填充因子、高均匀性和低成本的铁基超导线材提供了一种很有前途的方法,可用于实际应用。
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Physica C-superconductivity and Its Applications
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