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An Overview of the Glucocorticoids’ Pathways in the Environment and Their Removal Using Conventional Wastewater Treatment Systems 糖皮质激素在环境中的途径及其在常规废水处理系统中的去除综述
Pub Date : 2021-07-05 DOI: 10.3390/POLLUTANTS1030012
Munshi Md. Shafwat Yazdan, Md Tanvir Ahad, Zayed Mallick, S. Mallick, I. Jahan, Mozammel Mazumder
Numerous micropollutants, especially endocrine-disrupting compounds (EDCs), can pollute natural aquatic environments causing great concern for human and ecosystem health. While most of the conversation revolves around estrogen and androgen, glucocorticoids (GCs) are also prevalent in natural waters. Despite the fact that GCs play a crucial role in both inflammatory and immunologic development activities, they are also detected in natural waters and considered as one of the EDCs. Although many researchers have mentioned the adverse effect of GCs on aquatic organisms, a complete management technology to remove these pollutants from surface and coastal waters is yet to be established. In the current study, six glucocorticoids (prednisone, prednisolone, cortisone, cortisol, dexamethasone, and 6R-methylprednisolone) have been selected according to their higher detection frequency in environmental waters. The concentration of selected GCs ranged from 0.05 ng/L to 433 ng/L and their removal efficiency ranged from 10% to 99% depending on the water source and associated removal technologies. Although advanced technologies are available for achieving successful removal of GCs, associated operational and economic considerations make implementation of these processes unsustainable. Further studies are necessary to resolve the entry routes of GCs compounds into the surface water or drinking water permanently as well as employ sustainable detection and removal technologies.
大量的微污染物,尤其是内分泌干扰化合物(EDCs)会污染自然水体环境,对人类和生态系统的健康造成极大的关注。虽然大多数话题都围绕着雌激素和雄激素展开,但天然水体中也普遍存在糖皮质激素(GCs)。尽管GCs在炎症和免疫发育活动中起着至关重要的作用,但它们也在天然水中被检测到,并被认为是EDCs的一种。虽然许多研究人员提到了gc对水生生物的不利影响,但尚未建立一套完整的管理技术来清除地表水和沿海水域的这些污染物。本研究选择了六种糖皮质激素(强的松、强的松、可的松、皮质醇、地塞米松和6r -甲基强的松龙),因为它们在环境水体中检测频率较高。所选gc的浓度范围为0.05 ng/L ~ 433 ng/L,去除率为10% ~ 99%,具体取决于水源和相关的去除技术。虽然有先进的技术可以成功地去除gc,但相关的操作和经济考虑使得这些过程的实施不可持续。需要进一步研究gc化合物永久进入地表水或饮用水的途径,并采用可持续的检测和去除技术。
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引用次数: 11
Reviewing the Crop Residual Burning and Aerosol Variations during the COVID-19 Pandemic Hit Year 2020 over North India 回顾2020年印度北部2019冠状病毒病大流行期间作物残留燃烧和气溶胶变化
Pub Date : 2021-07-01 DOI: 10.3390/pollutants1030011
Manoj Hari, R. Sahu, B. Tyagi, Ravi Kaushik
The north Indian states of Haryana and Punjab are believed to be the key sources of air pollution in the National Capital Region due to massive agricultural waste burning in crop harvesting seasons. However, with the pandemic COVID-19 hitting the country, the usual practices were disrupted. COVID-19 preventive lockdown led to restricted vehicular and industrial emissions and caused the labours to leave the agricultural business in Haryana and Punjab. With the changed scenario of 2020, the present study investigates the variations in air quality over the Haryana and Punjab, and their relative impact on the air quality of Delhi. The work attempts to understand the change in agricultural waste burning during 2020 and its implication on the local air quality over both the states and the transported pollution on the national capital Delhi. The study utilises in-situ data for the year 2019–2020 with satellite observations of MODIS aqua/terra for fire counts, aerosol optical depth (AOD) and back-trajectories run by the hybrid single-particle Lagrangian integrated trajectory model (HYSPLIT).
印度北部的哈里亚纳邦和旁遮普邦被认为是国家首都地区空气污染的主要来源,因为在农作物收获季节大量焚烧农业废弃物。然而,随着COVID-19大流行袭击该国,通常的做法被打乱了。新冠肺炎预防性封锁导致车辆和工业排放受到限制,并导致工人离开哈里亚纳邦和旁遮普邦的农业企业。随着2020年情景的变化,本研究调查了哈里亚纳邦和旁遮普邦空气质量的变化,以及它们对德里空气质量的相对影响。这项工作试图了解2020年农业废弃物燃烧的变化,以及它对各邦当地空气质量和首都德里的运输污染的影响。该研究利用了2019-2020年的现场数据,以及MODIS aqua/terra的卫星观测数据,包括火灾计数、气溶胶光学深度(AOD)和混合单粒子拉格朗日综合轨迹模型(HYSPLIT)运行的反轨迹。
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引用次数: 7
Trace Metal Levels and Nutrient Characteristics of Crude Oil-Contaminated Soil Amended with Biochar–Humus Sediment Slurry 生物炭-腐殖质底泥对原油污染土壤微量金属含量及养分特性的影响
Pub Date : 2021-06-23 DOI: 10.3390/pollutants1030010
Nnanake-Abasi O. Offiong, E. Inam, H. Etuk, G. Ebong, Akwaowo I. Inyangudoh, Francis Addison
Biochar utilization for environmental remediation applications has become very popular. We investigated the trace metal levels and soil nutrient characteristics of a biochar–humus sediment slurry treatment of a simulated crude oil-contaminated soil in the present work. The results revealed that biochar prepared at moderate pyrolysis temperature (500 °C) could still retain a significantly higher nutrient content than those prepared at high temperatures (700 and 900 °C). Despite the suitability for soil treatment, one-pot treatment studies seem not to be very effective for monitoring trace metal sorption to biochar because trace metals do not biodegrade and remain in the system.
生物炭在环境修复中的应用已经非常普遍。研究了生物炭-腐殖质污泥处理模拟原油污染土壤的微量金属含量和土壤养分特征。结果表明,在中等热解温度(500℃)下制备的生物炭仍能保持显著高于高温(700℃和900℃)下制备的生物炭的营养成分。尽管适用于土壤处理,但单锅处理研究似乎不是很有效地监测痕量金属对生物炭的吸附,因为痕量金属不能生物降解并留在系统中。
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引用次数: 5
Microplastics in the Aquatic Environment—The Occurrence, Sources, Ecological Impacts, Fate, and Remediation Challenges 水生环境中的微塑料——发生、来源、生态影响、命运和修复挑战
Pub Date : 2021-06-18 DOI: 10.3390/pollutants1020009
N. Chaukura, K. Kefeni, I. Chikurunhe, I. Nyambiya, W. Gwenzi, Welldone Moyo, T. Nkambule, B. Mamba, F. Abulude
Microplastics are discharged into the environment through human activities and are persistent in the environment. With the prevalent use of plastic-based personal protective equipment in the prevention of the spread of the COVID-19 virus, the concentration of microplastics in the environment is envisaged to increase. Potential ecological and health risks emanate from their potential to adsorb and transport toxic chemicals, and ease of absorption into the cells of living organisms and interfering with physiological processes. This review (1) discusses sources and pathways through which microplastics enter the environment, (2) evaluates the fate and behavior of microplastics, (3) discusses microplastics in African aquatic systems, and (4) identifies research gaps and recommends remediation strategies. Importantly, while there is significant microplastics pollution in the aquatic environment, pollution in terrestrial systems are not widely studied. Besides, there is a dearth of information on microplastics in African aquatic systems. The paper recommends that the governments and non-governmental organizations should fund research to address knowledge gaps, which include: (1) the environmental fate of microplastics, (2) conducting toxicological studies under environmentally relevant conditions, (3) investigating toxicity mechanisms to biota, and developing mitigation measures to safeguard human health, and (4) investigating pollutants transported by microplastics. Moreover, regulatory measures, along with the circular economy strategies, may help reduce microplastic pollution.
微塑料通过人类活动排放到环境中,并在环境中持久存在。随着在预防COVID-19病毒传播中普遍使用塑料个人防护装备,预计环境中微塑料的浓度将会增加。潜在的生态和健康风险源于它们吸附和运输有毒化学品的潜力,以及它们容易被生物体的细胞吸收和干扰生理过程。本综述(1)讨论了微塑料进入环境的来源和途径,(2)评估了微塑料的命运和行为,(3)讨论了非洲水生系统中的微塑料,(4)确定了研究空白并建议了补救策略。重要的是,虽然水生环境中存在显著的微塑料污染,但陆地系统中的污染尚未得到广泛研究。此外,关于非洲水生系统中微塑料的信息缺乏。该报告建议,各国政府和非政府组织应为解决知识差距的研究提供资金,其中包括:(1)微塑料的环境命运;(2)在环境相关条件下开展毒理学研究;(3)调查对生物群的毒性机制,并制定缓解措施以保障人类健康;(4)调查微塑料输送的污染物。此外,监管措施以及循环经济战略可能有助于减少微塑料污染。
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引用次数: 19
Investigating the 2017 Erratic Fishkill Episode in the Jhelum River, Kashmir Himalaya 调查2017年克什米尔喜马拉雅地区Jhelum河不稳定的鱼杀事件
Pub Date : 2021-05-12 DOI: 10.3390/POLLUTANTS1020008
I. Rashid, M. I. Rather, S. Khanday
Globally, the frequency of fishkill episodes is increasing, owing to natural and human-induced modification of aquatic ecosystems. A massive fishkill took place on 22 October 2017 along an approximately 1.5 km stretch of the Jhelum River in Srinagar City, India. Thousands of fish died during this specific event, not lasting more than three hours, creating chaos and panic among the local population and government circles. In this context, affected fish were assessed for three morphological parameters, which include skin color, eye appearance, and skin texture. To back our findings, three critical water-quality parameters, including pH, water temperature, and dissolved oxygen essential for the survival of fishes were assessed in the affected river stretch. This study assumes importance given that water-quality observation stations for monitoring the health of the Jhelum River are lacking in the highly urbanized Srinagar City. The morphological examination of fish samples revealed discoloration, bulging eyes, and rough skin texture, indicating chemical contamination of waters in the affected river stretch. The water quality analysis revealed neutral pH (7.2), normal temperature (15.6 °C), and mildly depleted dissolved oxygen (6 mg L−1) levels. While the morphological examination of the affected fish indicated chemical contamination, the physicochemical parameters exhibited a typical scenario of river water. For avoiding any such further incident and to precisely ascertain the cause of such fishkill episodes in future, it is suggested that a few continuous water-quality monitoring sites along Jhelum River should be set up, supplemented with robust ecological modeling simulations.
在全球范围内,由于自然和人为引起的水生生态系统的改变,杀鱼事件的频率正在增加。2017年10月22日,印度斯利那加市约1.5公里长的杰勒姆河沿岸发生了一起大规模的鱼类捕杀事件。在这一特殊事件中,数千条鱼死亡,持续时间不超过三个小时,在当地居民和政府部门中造成了混乱和恐慌。在这种情况下,受影响的鱼被评估为三个形态学参数,包括皮肤颜色,眼睛外观和皮肤纹理。为了支持我们的发现,在受影响的河流段评估了三个关键的水质参数,包括pH值、水温和鱼类生存所必需的溶解氧。考虑到高度城市化的斯利那加市缺乏监测Jhelum河水质的水质观测站,这项研究具有重要意义。鱼类样本的形态学检查显示变色,眼睛突出,皮肤粗糙,表明受影响河段的水受到化学污染。水质分析显示pH值为中性(7.2),温度为正常(15.6°C),溶解氧(6 mg L−1)水平轻度耗尽。受影响鱼类的形态学检查显示化学污染,理化参数显示典型的河水情景。为了避免此类事件的再次发生,并准确地确定未来此类杀鱼事件的原因,建议在Jhelum河沿岸建立几个连续的水质监测点,并辅以可靠的生态模拟。
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引用次数: 2
Model-Based Analysis of the Link between Groundwater Table Rising and the Formation of Solute Plumes in a Shallow Stratified Aquifer 浅层状含水层地下水位上升与溶质羽流形成关系的模型分析
Pub Date : 2021-04-23 DOI: 10.3390/POLLUTANTS1020007
Simone Varisco, G. Beretta, L. Raffaelli, Paola Raimondi, D. Pedretti
Groundwater table rising (GTR) represents a well-known issue that affects several urban and agricultural areas of the world. This work addresses the link between GTR and the formation of solute plumes from contaminant sources that are located in the vadose zone, and that water table rising may help mobilize with time. A case study is analyzed in the stratified pyroclastic-alluvial aquifer near Naples (Italy), which is notoriously affected by GTR. A dismissed chemical factory generated a solute plume, which was hydraulically confined by a pump-and-treat (P&T) system. Since 2011, aqueous concentrations of 1,1-dichloroethene (1,1-DCE) have been found to exceed regulatory maximum concentration levels in monitoring wells. It has been hypothesized that a 1,1-DCE source may occur as buried waste that has been flushed with time under GTR. To elucidate this hypothesis and reoptimize the P&T system, flow and transport numerical modeling analysis was developed using site-specific data. The results indicated that the formulated hypothesis is indeed plausible. The model shows that water table peaks were reached in 2011 and 2017, which agree with the 1,1-DCE concentration peaks observed in the site. The model was also able to capture the simultaneous decrease in the water table levels and concentrations between 2011 and 2014. Scenario-based analysis suggests that lowering the water table below the elevation of the hypothesized source is potentially a cost-effective strategy to reschedule the pumping rates of the P&T system.
地下水位上升(GTR)是一个众所周知的问题,影响着世界上一些城市和农业地区。这项工作解决了GTR和溶质羽流的形成之间的联系,这些羽流来自位于渗透带的污染源,并且随着时间的推移,地下水位的上升可能有助于动员。以意大利那不勒斯附近的层状火山碎屑冲积含水层为例进行了分析,该含水层受GTR的影响非常严重。一家废弃的化工厂产生了溶质羽流,该羽流由泵和处理(P&T)系统进行水力限制。自2011年以来,在监测井中发现1,1-二氯乙烯(1,1- dce)的水溶液浓度超过了规定的最大浓度水平。据推测,1,1- dce源可能作为在GTR下随时间冲洗的掩埋废物出现。为了阐明这一假设并对P&T系统进行再优化,利用特定场地的数据进行了流动和输运数值模拟分析。结果表明,所提出的假设确实是合理的。模型显示,2011年和2017年达到了地下水位峰值,这与现场观测到的1,1- dce浓度峰值一致。该模型还能够捕捉到2011年至2014年间地下水位和浓度同时下降的情况。基于场景的分析表明,将地下水位降低到假设水源的海拔以下,可能是重新安排P&T系统抽水速率的一种经济有效的策略。
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引用次数: 1
Multivariable 3D Geovisualization of Historic and Contemporary Lead Sediment Contamination in Lake Erie 伊利湖历史和当代铅沉积物污染的多变量三维地理可视化
Pub Date : 2021-02-21 DOI: 10.3390/POLLUTANTS1010004
K. Forsythe, D. Ford, C. Marvin, R. Shaker, Michael W. MacDonald, R. Wilkinson
Lead sediment contamination in Lake Erie stems from a long history of natural and synthetic resource production. Sediment samples with variable sampling densities were collected by the Canada Centre for Inland Waters in 1971, 1997/1998, and 2014. The kriging interpolation method was used to create continuous sediment contamination surfaces for time/space comparisons. Change detection analyses identified an overall decreasing trend in high lead pollution levels from 1971 to 2014, while sediments with the lowest concentrations increased in surface area. Lake-wide circulation patterns and bathymetric data were added to interpolated contamination surfaces to enhance the understanding of interrelated hydrodynamic processes and geophysical features in the movement of contaminated sediments. Utilizing visualization tools in Esri’s ArcScene, bathymetric data were employed to enhance the geographic context of contamination maps. The physical barriers to sediment transportation created by bathymetric features can be visualized in three-dimensions. Elevated features between lake basins are easily recognized as impedances to lake currents when circulation directions are draped over the bathymetric model. By using illumination tools and techniques, geovisualizations of lead sediment contamination throughout Lake Erie create a scientific communication tool for a wide audience to use in multiple-criteria decision making for environmental remediation of sediment contamination.
伊利湖的铅沉积物污染源于长期的自然和人工资源生产。加拿大内陆水域中心于1971年、1997/1998年和2014年收集了不同采样密度的沉积物样本。采用克里格插值法建立连续的沉积物污染面进行时间/空间比较。变化检测分析发现,从1971年到2014年,高铅污染水平总体呈下降趋势,而最低浓度的沉积物表面积增加。将全湖环流模式和水深数据添加到插值的污染面中,以增强对污染沉积物运动中相互关联的水动力过程和地球物理特征的理解。利用Esri的ArcScene可视化工具,水深数据被用来增强污染地图的地理背景。由水深特征造成的泥沙运输的物理障碍可以在三维中可视化。当环流方向覆盖在水深模型上时,湖盆之间的高架特征很容易被识别为湖流的阻抗。通过使用照明工具和技术,整个伊利湖铅沉积物污染的地理可视化为广大受众提供了一种科学交流工具,用于沉积物污染环境修复的多标准决策。
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引用次数: 0
The Appropriateness of Using Aquatic Snails as Bioindicators of Toxicity for Oil Sands Process-Affected Water 水生蜗牛作为油砂工艺影响水体毒性生物指标的适宜性
Pub Date : 2021-01-06 DOI: 10.3390/POLLUTANTS1010002
Zhongzhi Chen, B. Eaton, J. Davies
Canada’s oil sands mining activity produces large volumes of oil sands process-affected water (OSPW), and there have been increasing concerns regarding the potential environmental impacts associated with this material. Developing an understanding of the toxicity of OSPW is critical to anticipating and mitigating the potential risks and effects of the oil sands industry on surrounding ecosystems. The composition of OSPW is highly variable and is influenced by a range of factors. While numerous research projects have been conducted on the toxicity of OSPW, much remains unknown about its impact on various biota. Freshwater gastropods (snails and slugs) are an ecologically crucial aquatic group, and members of this taxa have been used as bioindicators in a range of ecological settings. The literature suggests freshwater snails could be used as an indicator of toxicity in monitoring programs associated with oil sands development. This mini-review explores the use of snails as bioindicators in aquatic systems affected by oil sands development, focusing on how snails may respond to potential constituents of concern in systems exposed to OSPW.
加拿大的油砂开采活动产生了大量的油砂过程影响水(OSPW),人们越来越关注与这种材料相关的潜在环境影响。了解OSPW的毒性对于预测和减轻油砂行业对周围生态系统的潜在风险和影响至关重要。OSPW的组成变化很大,受到一系列因素的影响。虽然对OSPW的毒性进行了许多研究项目,但对其对各种生物群的影响仍知之甚少。淡水腹足动物(蜗牛和蛞蝓)是一个生态上至关重要的水生类群,该类群的成员已被用作一系列生态环境中的生物指标。文献表明,淡水蜗牛可以作为与油砂开发相关的监测项目的毒性指标。这篇小型综述探讨了蜗牛在受油砂开发影响的水生系统中作为生物指标的应用,重点是蜗牛如何对暴露于OSPW的系统中可能关注的成分做出反应。
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引用次数: 3
Influence of Moderate Cd and Pb Soil Pollution on Seed Development, Photosynthetic Performance and Foliar Accumulation in the Medicinal Plant Hypericum perforatum 中度镉、铅土壤污染对药用植物贯叶连翘种子发育、光合性能和叶片积累的影响
Pub Date : 2020-12-24 DOI: 10.3390/pollutants1010001
M. Jafarova, A. Vannini, F. Monaci, S. Loppi
This study investigated whether moderate soil contamination by Cd and Pb may negatively affect seed germination, photosynthesis and foliar accumulation in the medicinal plant Hypericum perforatum. Seeds were incubated with Cd and Pb solutions of 10 and 100 µM, and two-month-old plants were watered weekly for three weeks with the same solutions. Control samples were treated with deionized water. The percentage of seed germination and seedling length, as well as chlorophyll content, chlorophyll fluorescence and foliar reflectance, were measured, along with the foliar Cd and Pb concentrations. The results indicated that seed germination is not affected, while seedling length is decreased by approximately 81% by high Cd levels. Cadmium was subjected to foliar translocation from the soil depending on the supplied concentration, thus causing reductions in the chlorophyll content (−24%). It is of interest that foliar Cd levels in Cd-treated plants were close to or above the limit for the European Pharmacopoeia. Negative effects of Pb were not detected, but accumulation and blockage of this metal at the root level, although not approached experimentally, cannot be ruled out.
研究了中度土壤镉和铅污染是否会对药用植物贯叶连翘种子萌发、光合作用和叶片积累产生负面影响。种子分别用10µM和100µM的Cd和Pb溶液孵育,2个月大的植株每周用相同的溶液浇水3周。对照样品用去离子水处理。测定种子发芽率、幼苗长、叶绿素含量、叶绿素荧光和叶片反射率,以及叶片Cd、Pb浓度。结果表明,高镉水平对种子萌发无影响,但幼苗长度减少约81%。镉在叶片上的转运取决于土壤中镉的供应浓度,从而导致叶绿素含量降低(- 24%)。令人感兴趣的是,Cd处理植物的叶片Cd水平接近或高于欧洲药典的限制。虽然没有检测到铅的负面影响,但不能排除这种金属在根水平的积累和堵塞,尽管没有实验研究,但不能排除。
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引用次数: 2
Effectiveness of the national pollutant release inventory as a policy tool to curb atmospheric industrial emissions in Canada 加拿大全国污染物排放清单作为抑制大气工业排放的政策工具的有效性
Pub Date : 2018-11-21 DOI: 10.7287/PEERJ.PREPRINTS.27372V1
T. Walker
To curb greenhouse gas emissions and reduce concentrations of toxic substances in Canada’s atmosphere, many pieces of environment legislation are targeted at reducing industrial emissions. Traditional regulation prescribes penalties through fines to discourage industries from polluting, but in the past two decades, alternative forms of environmental regulation like the National Pollutant Release Inventory (NPRI) have been introduced. NPRI is an information management tool which requires industries to self-report emissions data based on a set of guidelines determined by Environment and Climate Change Canada, a federal agency. The tool works to inform the public regarding industry emissions and provides a large database that can be analyzed by researchers and regulators to inform emissions trends in Canada. These tools have seen some success in other jurisdictions (e.g., United States and Australia). However, some research assessing the U.S Toxic Release Inventory suggests there are fundamental weaknesses in the self-reported nature of the data, and incidences of under-reporting. This preliminary study aimed to explore NPRI in Canada and test its effectiveness against the National Air Pollutant Surveillance Network (NAPS), an air quality monitoring program administered by the federal government. While instances of under-reporting were undetected, their study identified areas of weakness in the NPRI tool and instances of increasing emissions across various industrial sectors in Canada.
为了遏制温室气体排放和降低加拿大大气中有毒物质的浓度,许多环境立法都以减少工业排放为目标。传统的监管规定通过罚款来阻止工业污染,但在过去二十年中,引入了其他形式的环境监管,如国家污染物排放清单(NPRI)。NPRI是一种信息管理工具,它要求各行业根据联邦机构加拿大环境与气候变化局(Environment and Climate Change Canada)制定的一套指导方针自行报告排放数据。该工具旨在向公众提供有关工业排放的信息,并提供一个大型数据库,供研究人员和监管机构分析,以了解加拿大的排放趋势。这些工具在其他司法管辖区(例如美国和澳大利亚)取得了一些成功。然而,一些评估美国有毒物质释放清单的研究表明,在数据的自我报告性质和低报发生率方面存在根本性的弱点。这项初步研究旨在探索加拿大的NPRI,并测试其对国家空气污染物监测网(nap)的有效性,nap是由联邦政府管理的空气质量监测计划。虽然未发现漏报的情况,但他们的研究发现了NPRI工具的薄弱环节,以及加拿大各工业部门排放增加的情况。
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引用次数: 6
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Pollutants
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