Pub Date : 2022-01-04DOI: 10.3390/pollutants2010002
Tomoya Takada, R. Tanaka, Ryoto Ono
Carbon adsorbents for use in the removal of gaseous toluene from the air were prepared from buckwheat (Fagopyrum esculentum Moench) hull. A chemically-activated adsorbent was prepared via the impregnation of raw hull powder with potassium carbonate, followed by thermal decomposition. The chemically-activated adsorbent exhibited improved adsorption capacity for toluene compared to the adsorbent prepared without chemical activation. Toluene concentration in the air decreased from 220 ppm to 160 ppm during 24 h of adsorption using unactivated adsorbent. Only a trace amount of toluene remained after the adsorption under the same conditions using K2CO3-activated adsorbent. This improvement was explained based on experimental results, specifically, iodine adsorption tests, methylene blue adsorption tests, and microscopic observations. Chemical activation dramatically increased the specific surface area of the adsorbent and created mesopores capable of adsorbing toluene. This study revealed that a mesoporous adsorbent for use in volatile toluene removal can be prepared from waste biomass (buckwheat hull) by chemical activation using potassium carbonate.
{"title":"Removal of Volatile Toluene Using K2CO3-Activated Carbon Adsorbents Prepared from Buckwheat Hull","authors":"Tomoya Takada, R. Tanaka, Ryoto Ono","doi":"10.3390/pollutants2010002","DOIUrl":"https://doi.org/10.3390/pollutants2010002","url":null,"abstract":"Carbon adsorbents for use in the removal of gaseous toluene from the air were prepared from buckwheat (Fagopyrum esculentum Moench) hull. A chemically-activated adsorbent was prepared via the impregnation of raw hull powder with potassium carbonate, followed by thermal decomposition. The chemically-activated adsorbent exhibited improved adsorption capacity for toluene compared to the adsorbent prepared without chemical activation. Toluene concentration in the air decreased from 220 ppm to 160 ppm during 24 h of adsorption using unactivated adsorbent. Only a trace amount of toluene remained after the adsorption under the same conditions using K2CO3-activated adsorbent. This improvement was explained based on experimental results, specifically, iodine adsorption tests, methylene blue adsorption tests, and microscopic observations. Chemical activation dramatically increased the specific surface area of the adsorbent and created mesopores capable of adsorbing toluene. This study revealed that a mesoporous adsorbent for use in volatile toluene removal can be prepared from waste biomass (buckwheat hull) by chemical activation using potassium carbonate.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"33 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88901507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-20DOI: 10.3390/pollutants1040021
Diana Amorello, S. Orecchio
Edible mushrooms are a food source with interesting nutritional values. The chief objective of this research was to develop a consistent method for the quantitative ultra-trace analysis of Pt in mushrooms, which is complex because it cannot be readily quantified by common analytical procedures. This research is one of the first analytical methods to establish Pt amount in these vegetables. In this research, 28 different edible mushroom samples from Italy were investigated. Determination of Pt in mushrooms was completed using Differential Pulse Voltammetry (DPV). In this study, we applied the standard addition method because there are no certified reference mushrooms containing platinum group elements on the market. The platinum quantification limit was 0.03 µg kg−1 d.w. In the analyzed samples, platinum amount was in the range of 0.03–73 µg kg−1. Our mushroom samples had a Pt content lower than the concentrations recommended by international establishments for other foodstuffs. In the future, the optimized method could be used for the analysis of plant and animal matrices intended for food supply.
食用菌是一种具有有趣营养价值的食物来源。本研究的主要目的是为蘑菇中铂的定量超痕量分析开发一种一致的方法，这是复杂的，因为它不容易被普通的分析方法定量。本研究是首次建立这些蔬菜中铂含量的分析方法之一。在这项研究中，研究人员调查了来自意大利的28种不同的食用菌样本。采用差分脉冲伏安法(DPV)测定蘑菇中铂的含量。在本研究中，我们采用标准添加法，因为市场上没有认证的含铂族元素的参考蘑菇。铂的定量限为0.03µg kg - 1 d.w.，分析样品中铂的含量在0.03 ~ 73µg kg - 1之间。我们的蘑菇样品的铂含量低于国际机构对其他食品的建议浓度。在未来，优化的方法可用于食品供应的植物和动物基质的分析。
{"title":"Quantification of Platinum in Edible Mushrooms Using Voltammetric Techniques","authors":"Diana Amorello, S. Orecchio","doi":"10.3390/pollutants1040021","DOIUrl":"https://doi.org/10.3390/pollutants1040021","url":null,"abstract":"Edible mushrooms are a food source with interesting nutritional values. The chief objective of this research was to develop a consistent method for the quantitative ultra-trace analysis of Pt in mushrooms, which is complex because it cannot be readily quantified by common analytical procedures. This research is one of the first analytical methods to establish Pt amount in these vegetables. In this research, 28 different edible mushroom samples from Italy were investigated. Determination of Pt in mushrooms was completed using Differential Pulse Voltammetry (DPV). In this study, we applied the standard addition method because there are no certified reference mushrooms containing platinum group elements on the market. The platinum quantification limit was 0.03 µg kg−1 d.w. In the analyzed samples, platinum amount was in the range of 0.03–73 µg kg−1. Our mushroom samples had a Pt content lower than the concentrations recommended by international establishments for other foodstuffs. In the future, the optimized method could be used for the analysis of plant and animal matrices intended for food supply.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90594028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-12-03DOI: 10.3390/pollutants1040020
Naoharu Murasawa, T. Hatta
Radioactive cesium (r-Cs) released from the 2011 Fukushima Daiichi Nuclear Power Plant attaches to vegetation/soil and is collected as municipal solid waste (MSW) for incineration, being concentrated in incineration ash (bottom ash [BA], fly ash [FA], and chelate-treated FA [TFA]). r-Cs in FA and TFA can easily leach upon contact with moisture. It is important to prevent further contamination, as r-Cs has negative effects on ecosystems and the human body. Naturally available clay minerals, considered effective for capturing r-Cs, are a good alternative. Here, we sampled ash from MSW incineration facilities in Fukushima in August 2016 and February 2017. We used energy dispersive X-ray fluorescence spectroscopy and Ge semiconductor detector to determine elemental composition and r-Cs concentration in the samples and conducted leaching tests. We also determined the extent of leaching suppression by zeolite, acidic clay, and vermiculite. Chloride contents and r-Cs leaching rates were higher in FA and TFA than in BA, regardless of the season. Prior direct addition and mixing of clay minerals (5 to 20 wt.%) effectively prevented r-Cs leaching. This study is the first to examine r-Cs leaching inhibition by clay mineral direct addition and mixing to MSW incineration ash.
{"title":"Use of Clay Minerals to Control Radioactive Cesium Leaching from Municipal Solid Waste Incineration Ash in Fukushima Prefecture in Summer and Winter","authors":"Naoharu Murasawa, T. Hatta","doi":"10.3390/pollutants1040020","DOIUrl":"https://doi.org/10.3390/pollutants1040020","url":null,"abstract":"Radioactive cesium (r-Cs) released from the 2011 Fukushima Daiichi Nuclear Power Plant attaches to vegetation/soil and is collected as municipal solid waste (MSW) for incineration, being concentrated in incineration ash (bottom ash [BA], fly ash [FA], and chelate-treated FA [TFA]). r-Cs in FA and TFA can easily leach upon contact with moisture. It is important to prevent further contamination, as r-Cs has negative effects on ecosystems and the human body. Naturally available clay minerals, considered effective for capturing r-Cs, are a good alternative. Here, we sampled ash from MSW incineration facilities in Fukushima in August 2016 and February 2017. We used energy dispersive X-ray fluorescence spectroscopy and Ge semiconductor detector to determine elemental composition and r-Cs concentration in the samples and conducted leaching tests. We also determined the extent of leaching suppression by zeolite, acidic clay, and vermiculite. Chloride contents and r-Cs leaching rates were higher in FA and TFA than in BA, regardless of the season. Prior direct addition and mixing of clay minerals (5 to 20 wt.%) effectively prevented r-Cs leaching. This study is the first to examine r-Cs leaching inhibition by clay mineral direct addition and mixing to MSW incineration ash.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"238 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76873571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-28DOI: 10.3390/pollutants1040018
G. Cillis, B. Tucci, V. Santarsiero, G. Nolè, A. Lanorte
Sustainable land management is one of the key actions for the achievement of objectives set by the 2030 Agenda for Sustainable Development. In particular, land represents a fundamental resource to address issues of climate change, biodiversity preservation, maintaining ecosystem services, and at the same time ensuring shared prosperity and well-being. Therefore, it is necessary to activate strategies to monitor changes in land use and land cover in order to evaluate strategies for proper management. To do this, the new open source geospatial analysis tools and the increasing availability of remote sensed open data can allow the activation of methodologies for monitoring changes in land use and land cover in order to provide data usable in other research areas or, for example, to implement a decision support system for environmental sustainability. In this study, a GIS approach based on open remote sensing data has been used to perform a spatial analysis of land cover changes within the Basilicata region (Southern Italy) that is spatially expeditious yet accurate. The results showed a very evident land transformation with important repercussions on the environmental components. The ease of use of techniques makes this methodology replicable in other territory and can be used as a preliminary approach to sustainable development model.
{"title":"Understanding Land Changes for Sustainable Environmental Management: The Case of Basilicata Region (Southern Italy)","authors":"G. Cillis, B. Tucci, V. Santarsiero, G. Nolè, A. Lanorte","doi":"10.3390/pollutants1040018","DOIUrl":"https://doi.org/10.3390/pollutants1040018","url":null,"abstract":"Sustainable land management is one of the key actions for the achievement of objectives set by the 2030 Agenda for Sustainable Development. In particular, land represents a fundamental resource to address issues of climate change, biodiversity preservation, maintaining ecosystem services, and at the same time ensuring shared prosperity and well-being. Therefore, it is necessary to activate strategies to monitor changes in land use and land cover in order to evaluate strategies for proper management. To do this, the new open source geospatial analysis tools and the increasing availability of remote sensed open data can allow the activation of methodologies for monitoring changes in land use and land cover in order to provide data usable in other research areas or, for example, to implement a decision support system for environmental sustainability. In this study, a GIS approach based on open remote sensing data has been used to perform a spatial analysis of land cover changes within the Basilicata region (Southern Italy) that is spatially expeditious yet accurate. The results showed a very evident land transformation with important repercussions on the environmental components. The ease of use of techniques makes this methodology replicable in other territory and can be used as a preliminary approach to sustainable development model.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"26 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85855814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-28DOI: 10.3390/pollutants1040019
Karina García-Villacís, L. Ramos-Guerrero, José Luis Canga, Daniel Hidalgo-Lasso, Paul Vargas-Jentzsch
Past petroleum-extraction activities in Ecuador have contaminated its Amazon region. To assess the environmental impact attributed to remediation activities regarding the cleanup of these oil spills, two scenarios were studied according to Life Cycle Analysis methodology: (1) No-action, which means to leave the contamination in place without any further action and (2) Environmental remediation, where the environmental-load attributed to the remediation of the representative oil spill was studied. Results indicated that the no-action scenario presented a higher environmental impact for 12 out of the 16 environmental categories evaluated (climate change, ozone depletion, human toxicity non-cancer effects, particulate matter, ionizing radiation human health, ionizing radiation ecosystem, photochemical ozone formation, acidification, terrestrial eutrophication, marine eutrophication, freshwater ecotoxicity, mineral, fossil and renewable resource depletion). Moreover, the no-action scenario presented a global weighted score of contamination of 5.45 points, while the remediation scenario got a score of 3.3 points, which means that the remediation decreased by 39% of the global environmental impact due to the remediation activity applied, showing the positive influence of environmental remediation to mitigate the effects attributed to the presence of pollution sources associated to the petroleum industry in the Ecuadorian Amazon region.
{"title":"Environmental Impact Assessment of Remediation Strategy in an Oil Spill in the Ecuadorian Amazon Region","authors":"Karina García-Villacís, L. Ramos-Guerrero, José Luis Canga, Daniel Hidalgo-Lasso, Paul Vargas-Jentzsch","doi":"10.3390/pollutants1040019","DOIUrl":"https://doi.org/10.3390/pollutants1040019","url":null,"abstract":"Past petroleum-extraction activities in Ecuador have contaminated its Amazon region. To assess the environmental impact attributed to remediation activities regarding the cleanup of these oil spills, two scenarios were studied according to Life Cycle Analysis methodology: (1) No-action, which means to leave the contamination in place without any further action and (2) Environmental remediation, where the environmental-load attributed to the remediation of the representative oil spill was studied. Results indicated that the no-action scenario presented a higher environmental impact for 12 out of the 16 environmental categories evaluated (climate change, ozone depletion, human toxicity non-cancer effects, particulate matter, ionizing radiation human health, ionizing radiation ecosystem, photochemical ozone formation, acidification, terrestrial eutrophication, marine eutrophication, freshwater ecotoxicity, mineral, fossil and renewable resource depletion). Moreover, the no-action scenario presented a global weighted score of contamination of 5.45 points, while the remediation scenario got a score of 3.3 points, which means that the remediation decreased by 39% of the global environmental impact due to the remediation activity applied, showing the positive influence of environmental remediation to mitigate the effects attributed to the presence of pollution sources associated to the petroleum industry in the Ecuadorian Amazon region.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74531107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-10-25DOI: 10.3390/pollutants1040017
S. Barreca, M. Busetto, Carola Forni, Luisa Colzani, Laura Clerici, Daniela Daverio, S. Balzamo, E. Calabretta, M. Peleggi, P. Dellavedova
In recent years, the quality of aquatic ecosystems has received increasing attention from European institutions. The Commission Implementing Decision (EU) 2018/840 drafted a Watch List (WL) of compounds to be monitored in Europe. In this study, we report a method based on solid phase extraction with ultra-high-performance liquid chromatography, coupled with a triple-quadrupole mass spectrometer (UHPLC-MS/MS) to analyze the whole water sample. The method was developed and validated for the determination of 12 listed compounds. The employment of solid-phase extraction by a horizon system ensures the analysis of the entire body of samples and minimizes sample manipulation. Different ng L−1 detection limits (from 2 to 50 ng L−1), linearities (from 2 to 500 ng L−1), accuracy (from 70 to 130%) and levels of precision (RSD less 20% at LOQs levels) were assessed to be satisfactory for quantification and confirmation at the levels of interest. The developed method was applied for quantitative analysis for Watch List compounds (with the exception of hormones) in surface water samples from different Italian sites during monitoring activities by the Regional Environmental Protection Agencies in the years 2019 and 2020.
近年来，水生生态系统的质量越来越受到欧洲机构的关注。欧盟委员会实施决定(EU) 2018/840起草了一份在欧洲监测的化合物观察清单(WL)。在本研究中，我们报告了一种基于超高效液相色谱固相萃取，结合三重四极杆质谱仪(UHPLC-MS/MS)对整个水样进行分析的方法。建立并验证了该方法对12个所列化合物的测定。采用水平系统的固相萃取确保了对整个样品的分析，并最大限度地减少了样品操作。不同的ng L−1检测限(从2到50 ng L−1)、线性(从2到500 ng L−1)、准确度(从70到130%)和精密度水平(在loq水平上RSD小于20%)被评估为在感兴趣的水平上令人满意的定量和确认。在2019年和2020年区域环境保护机构的监测活动中，开发的方法用于定量分析意大利不同地点地表水样品中的观察名单化合物(激素除外)。
{"title":"Determination of Antibiotics, Pesticides, Herbicides, Fungicides and Hormones in Water Bodies in Italy in Occurrence with European Watch List Mechanism by Using an UHPLC-MS/MS System: Method Validation, Quantification and Evaluations","authors":"S. Barreca, M. Busetto, Carola Forni, Luisa Colzani, Laura Clerici, Daniela Daverio, S. Balzamo, E. Calabretta, M. Peleggi, P. Dellavedova","doi":"10.3390/pollutants1040017","DOIUrl":"https://doi.org/10.3390/pollutants1040017","url":null,"abstract":"In recent years, the quality of aquatic ecosystems has received increasing attention from European institutions. The Commission Implementing Decision (EU) 2018/840 drafted a Watch List (WL) of compounds to be monitored in Europe. In this study, we report a method based on solid phase extraction with ultra-high-performance liquid chromatography, coupled with a triple-quadrupole mass spectrometer (UHPLC-MS/MS) to analyze the whole water sample. The method was developed and validated for the determination of 12 listed compounds. The employment of solid-phase extraction by a horizon system ensures the analysis of the entire body of samples and minimizes sample manipulation. Different ng L−1 detection limits (from 2 to 50 ng L−1), linearities (from 2 to 500 ng L−1), accuracy (from 70 to 130%) and levels of precision (RSD less 20% at LOQs levels) were assessed to be satisfactory for quantification and confirmation at the levels of interest. The developed method was applied for quantitative analysis for Watch List compounds (with the exception of hormones) in surface water samples from different Italian sites during monitoring activities by the Regional Environmental Protection Agencies in the years 2019 and 2020.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"38 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82252984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-10-14DOI: 10.3390/pollutants1040016
Justus Hardegen, Patrick Braeutigam, C. Abendroth, Thomas Wichard
The endocrine disruptor bisphenol A (BPA) is one of the most commonly found micropollutants in the environment. However, the biodegradation of BPA under anaerobic (methanogenic) conditions is still an understudied process in wastewater treatment systems. The current study thus addresses the need for a simple and user-friendly analytical method for the rapid and accurate quantification of BPA in complex matrices such as digested and co-digester sludges. We established a microwave-assisted extraction method, followed by derivatization and gas chromatography–mass spectrometry to quantify BPA by comparing it with a deuterated internal standard. The BPA removal capabilities of three digester sludges and three co-digester sludges were examined under mesophilic methanogenic conditions in biogas plants. The endogenous BPA concentration (dry weight) ranged from 1596 to 10,973 µg kg−1 in digested sewage sludges, and from below the limit of quantification to 9069 µg kg−1 in co-digester sludges. When BPA was added to the sludges, the removal capabilities ranged from not significant to 50% after 21 days of incubation. Biogas production was unaffected by the addition of BPA (228 µg kg−1) to the aqueous sludge. The study demonstrated that BPA could be removed under anaerobic conditions in accustomed inoculates. The findings have far-reaching implications for understanding BPA persistence and detoxification under anaerobic conditions.
内分泌干扰物双酚A (BPA)是环境中最常见的微污染物之一。然而，在厌氧(产甲烷)条件下双酚a的生物降解在废水处理系统中仍然是一个未充分研究的过程。因此，目前的研究需要一种简单易用的分析方法来快速准确地定量复杂基质(如消化污泥和共消化污泥)中的BPA。我们建立了微波辅助提取双酚a的方法，然后进行衍生化和气相色谱-质谱联用，通过与氘化内标进行比较来定量双酚a。在沼气厂中温产甲烷条件下，研究了3种沼气池污泥和3种共沼气池污泥对BPA的去除能力。消化污泥的内源BPA浓度(干重)为1596 ~ 10973µg kg - 1，共消化污泥的内源BPA浓度为9069µg kg - 1。当BPA添加到污泥中，经过21天的孵育，去除能力从不显著到50%不等。在含水污泥中添加BPA(228µg kg−1)不影响沼气的产生。研究表明，在厌氧条件下，习惯的接种物可以去除BPA。这一发现对了解双酚a在厌氧条件下的持久性和解毒具有深远的意义。
{"title":"Bisphenol A: Quantification in Complex Matrices and Removal by Anaerobic Sludges","authors":"Justus Hardegen, Patrick Braeutigam, C. Abendroth, Thomas Wichard","doi":"10.3390/pollutants1040016","DOIUrl":"https://doi.org/10.3390/pollutants1040016","url":null,"abstract":"The endocrine disruptor bisphenol A (BPA) is one of the most commonly found micropollutants in the environment. However, the biodegradation of BPA under anaerobic (methanogenic) conditions is still an understudied process in wastewater treatment systems. The current study thus addresses the need for a simple and user-friendly analytical method for the rapid and accurate quantification of BPA in complex matrices such as digested and co-digester sludges. We established a microwave-assisted extraction method, followed by derivatization and gas chromatography–mass spectrometry to quantify BPA by comparing it with a deuterated internal standard. The BPA removal capabilities of three digester sludges and three co-digester sludges were examined under mesophilic methanogenic conditions in biogas plants. The endogenous BPA concentration (dry weight) ranged from 1596 to 10,973 µg kg−1 in digested sewage sludges, and from below the limit of quantification to 9069 µg kg−1 in co-digester sludges. When BPA was added to the sludges, the removal capabilities ranged from not significant to 50% after 21 days of incubation. Biogas production was unaffected by the addition of BPA (228 µg kg−1) to the aqueous sludge. The study demonstrated that BPA could be removed under anaerobic conditions in accustomed inoculates. The findings have far-reaching implications for understanding BPA persistence and detoxification under anaerobic conditions.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"96 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78733533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-01DOI: 10.3390/pollutants1030015
M. Kraft, K. Rauchfuss, H. Fromme, L. Grün, S. Sievering, B. Köllner, Y. Chovolou
Polychlorinated biphenyls (PCBs) were used in many construction products until their banning in the 1970s and 1980s. Nonetheless, exposure to PCBs from contaminated indoor air is still an important public health issue. The aim of our study was to estimate the contribution of PCB congeners in indoor air to the levels of PCBs in human blood. We analyzed all 209 PCB congeners in the blood of 35 individuals exposed to PCBs from contaminated indoor air. For each individual, we measured the six marker indicators PCB28, PCB52, PCB101, PCB138, PCB153 and PCB180 in indoor air at the workplace. Statistically significant correlations between PCB-contaminated indoor air and the existence of the sum of mono-, di-, tri-, tetra- and pentachlorinated biphenyls (∑PCB1–127) in the blood of the exposed individuals were found. We quantified the proportions of PCBs that are absorbed into the blood via inhalation of contaminated indoor air. Inhalation of PCBs from contaminated indoor air, especially in children, adolescents and younger adults, may lead to PCB blood burdens that are higher than general PCB background levels or in approximately the same range.
{"title":"Inhalation Exposure to PCB from Contaminated Indoor Air—How Much Is Absorbed into the Blood?","authors":"M. Kraft, K. Rauchfuss, H. Fromme, L. Grün, S. Sievering, B. Köllner, Y. Chovolou","doi":"10.3390/pollutants1030015","DOIUrl":"https://doi.org/10.3390/pollutants1030015","url":null,"abstract":"Polychlorinated biphenyls (PCBs) were used in many construction products until their banning in the 1970s and 1980s. Nonetheless, exposure to PCBs from contaminated indoor air is still an important public health issue. The aim of our study was to estimate the contribution of PCB congeners in indoor air to the levels of PCBs in human blood. We analyzed all 209 PCB congeners in the blood of 35 individuals exposed to PCBs from contaminated indoor air. For each individual, we measured the six marker indicators PCB28, PCB52, PCB101, PCB138, PCB153 and PCB180 in indoor air at the workplace. Statistically significant correlations between PCB-contaminated indoor air and the existence of the sum of mono-, di-, tri-, tetra- and pentachlorinated biphenyls (∑PCB1–127) in the blood of the exposed individuals were found. We quantified the proportions of PCBs that are absorbed into the blood via inhalation of contaminated indoor air. Inhalation of PCBs from contaminated indoor air, especially in children, adolescents and younger adults, may lead to PCB blood burdens that are higher than general PCB background levels or in approximately the same range.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80299887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-10DOI: 10.3390/pollutants1030013
S. Fetisov, I. Chubarenko
Observations show that after stormy events, anthropogenic litter is washed ashore for short periods of time, providing the opportunity to collect and remove it from the environment. However, water dynamics in sea coastal zones during and after storms are very complicated, and the transport properties of litter items are very diverse; thus, predicting litter wash-outs using classical numerical models is challenging. We analyze meteorological and hydrophysical conditions in the Baltic Sea coastal zone to further use the obtained data as a training sequence for an artificial neural network (ANN). Analysis of the physical processes behind large litter wash-outs links open-source meteorological (wind speed and direction) and hydrodynamic reanalysis (surface wave parameters) data to the time and location of these wash-outs. A detailed analysis of 25 cases of wash-outs observed at the shore of the Sambian Peninsula was performed. The importance of the duration of the storm and its subsiding phase was revealed. An ANN structure is proposed for forecasting marine debris wash-outs as the first step in the creation of a neural network-based tool for managers and beach cleaners, helping to plan effective measures to remove plastics and other anthropogenic contaminants from the marine environment.
{"title":"Marine Litter Stormy Wash-Outs: Developing the Neural Network to Predict Them","authors":"S. Fetisov, I. Chubarenko","doi":"10.3390/pollutants1030013","DOIUrl":"https://doi.org/10.3390/pollutants1030013","url":null,"abstract":"Observations show that after stormy events, anthropogenic litter is washed ashore for short periods of time, providing the opportunity to collect and remove it from the environment. However, water dynamics in sea coastal zones during and after storms are very complicated, and the transport properties of litter items are very diverse; thus, predicting litter wash-outs using classical numerical models is challenging. We analyze meteorological and hydrophysical conditions in the Baltic Sea coastal zone to further use the obtained data as a training sequence for an artificial neural network (ANN). Analysis of the physical processes behind large litter wash-outs links open-source meteorological (wind speed and direction) and hydrodynamic reanalysis (surface wave parameters) data to the time and location of these wash-outs. A detailed analysis of 25 cases of wash-outs observed at the shore of the Sambian Peninsula was performed. The importance of the duration of the storm and its subsiding phase was revealed. An ANN structure is proposed for forecasting marine debris wash-outs as the first step in the creation of a neural network-based tool for managers and beach cleaners, helping to plan effective measures to remove plastics and other anthropogenic contaminants from the marine environment.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"88 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83312231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-10DOI: 10.3390/pollutants1030014
A. Satriani, A. Loperte, S. Pascucci
Industrial hemp cultivation has the potential to be an environmentally friendly and highly sustainable crop and it can fit well in crop rotation practices to increase soil fertility. For this study, two commercial varieties of industrial hemp with low tetrahydrocannabinol (THC) content were used to test its reintroduction chance in the study area and to evaluate its response in terms of yield with respect to the soil and drought conditions of the area. During the vegetative period, non-invasive measures of the soil’s water status were performed using Watermark probes and ground penetrating radar. In addition, hemp crops vigour monitoring was performed by means of Sentinel 2 multispectral optical remote sensing data. In the absence of precipitation and/or irrigation, and with high consumption of soil water by the hemp crop due to evapotranspiration, the crop has completed its cycle thanks to its resistance to water stress conditions. From the soil water and satellite monitoring results, there is a good agreement with the field results in terms of water stress and its effects on crop vigour. This study contributes to a better understanding of the possibility of hemp crop reintroduction in areas where water deficit occurs, which could open up the opportunity for selecting hemp crop cultivars that can be grown under different agro-ecological conditions and are also of great commercial interest for decision makers involved in sustainable crop management and in the reduction of fertilizers and pollutants released into the environment.
{"title":"The Cultivation of Industrial Hemp as Alternative Crop in a Less-Favoured Agricultural Area in Southern Italy: The Pignola Case Study","authors":"A. Satriani, A. Loperte, S. Pascucci","doi":"10.3390/pollutants1030014","DOIUrl":"https://doi.org/10.3390/pollutants1030014","url":null,"abstract":"Industrial hemp cultivation has the potential to be an environmentally friendly and highly sustainable crop and it can fit well in crop rotation practices to increase soil fertility. For this study, two commercial varieties of industrial hemp with low tetrahydrocannabinol (THC) content were used to test its reintroduction chance in the study area and to evaluate its response in terms of yield with respect to the soil and drought conditions of the area. During the vegetative period, non-invasive measures of the soil’s water status were performed using Watermark probes and ground penetrating radar. In addition, hemp crops vigour monitoring was performed by means of Sentinel 2 multispectral optical remote sensing data. In the absence of precipitation and/or irrigation, and with high consumption of soil water by the hemp crop due to evapotranspiration, the crop has completed its cycle thanks to its resistance to water stress conditions. From the soil water and satellite monitoring results, there is a good agreement with the field results in terms of water stress and its effects on crop vigour. This study contributes to a better understanding of the possibility of hemp crop reintroduction in areas where water deficit occurs, which could open up the opportunity for selecting hemp crop cultivars that can be grown under different agro-ecological conditions and are also of great commercial interest for decision makers involved in sustainable crop management and in the reduction of fertilizers and pollutants released into the environment.","PeriodicalId":20301,"journal":{"name":"Pollutants","volume":"64 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73252396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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