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Temperature dependence of the absorption edge of synthetic diamond 合成金刚石吸收边的温度依赖性
Pub Date : 2021-12-02 DOI: 10.1117/12.2616516
E. A. Kolesnik, V. Ripenko, S. Dzyadukh, E. Lipatov
Using optical spectroscopy in the spectral range from 200 to 300 nm, the absorption edge and transmission spectra of 7 samples of synthetic diamond of IIa type in the temperature range from 12 K to 470 K was studied. Using numerical methods, the temperature dependences of optical absorption into the free exciton state were obtained for negative and positive phonon branches.
利用200 ~ 300 nm光谱范围内的光谱学方法,研究了7种IIa型合成金刚石样品在12 ~ 470 K温度范围内的吸收边缘和透射光谱。利用数值方法,得到了负声子和正声子分支光吸收进入自由激子态的温度依赖关系。
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引用次数: 0
Study of the complexation reaction between substituted [2,2'-bipyridine]-6,6'-diyl(phosphonates) and terbium ions 取代[2,2'-联吡啶]-6,6'-二基膦酸盐与铽离子络合反应的研究
Pub Date : 2021-12-02 DOI: 10.1117/12.2613666
Tsagana B. Sumyanova, N. Borisova, A. Kirsanova
The influence of the structure of phosphonic acid esters on the stability of their terbium complexes was studied. It was shown that one complex particle was formed irrespective the nature of the side ester chain, and the metal-ligand stoichiometry of the complex was 1:1. The stability constants of the terbium complexes were determined. An increase in the size of the bulky substituent leads to an increase in the stability of the complexes.
研究了膦酸酯的结构对其铽配合物稳定性的影响。结果表明,无论侧酯链的性质如何,都能形成一个配合物颗粒,配合物的金属配体化学计量比为1:1。测定了铽配合物的稳定常数。大体积取代基尺寸的增加导致配合物稳定性的增加。
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引用次数: 0
Numerical simulation of the optical radiation absorption by dielectric microcapsules of different spatial shapes 不同空间形状介质微胶囊对光辐射吸收的数值模拟
Pub Date : 2021-12-02 DOI: 10.1117/12.2601285
Y. Geints, E. K. Panina
The heating dynamics a micron-sized two-layer capsules simulating transport microcontainers with water-containing load and light-absorbing composite shell exposed to a near-IR laser pulse (wavelength 800 nm) is theoretically studied. Both single microcapsules and the microassemblies of particles with various spatial shapes and different packing densities are considered. Using FDTD and FEM calculations, the numerical simulations of the optical field distribution inside and near the microcapsules are carried out, and the temporal dynamics of the temperature profiles of microparticles shells is obtained. Based on the simulation results, one can conclude that the particle morphology introduces specificity in the spatial profile of the optical field and the distribution of light absorption regions. Variation in the geometric shape of a capsule leads to dramatic changes in the distribution of absorbed light energy and, accordingly, particle temperature field. In order to increase the efficiency of absorption of optical radiation in capsule volume and to obtain the maximum heating of absorbing shells, the capsules of cubic, cylindrical and partly rectangular shapes are preferable. Thus, having a 100-fs laser pulse with energy of only 20 μJ it becomes possible to heat a cylindrical microcapsule to the temperature of thermal destruction of its polymeric shell (~ 410 K). Worthwhile notice, the water-filling of a capsule core remains cold. At the same conditions, the ellipsoid-shaped capsule is heated to multiple lower temperatures (~ 340 K).
本文从理论上研究了近红外激光脉冲(波长800 nm)作用下微米级含水负载和吸光复合壳双层模拟输运微容器胶囊的加热动力学。考虑了不同空间形状和不同堆积密度的单个微胶囊和颗粒微组合体。采用时域有限差分法和有限元法对微胶囊内部和附近的光场分布进行了数值模拟,得到了微胶囊壳体温度分布的时间动态特征。根据模拟结果可以得出结论,粒子形态在光场的空间分布和光吸收区域的分布中引入了特异性。胶囊几何形状的变化会导致吸收光能分布的剧烈变化,从而导致粒子温度场的剧烈变化。为了提高胶囊体积对光辐射的吸收效率和获得最大的吸收壳的热量,可以采用立方、圆柱形和部分矩形形状的胶囊。因此,使用能量仅为20 μJ的100 fs激光脉冲,就可以将圆柱形微胶囊加热到其聚合物外壳的热破坏温度(~ 410 K),值得注意的是,胶囊芯的充水仍然是冷的。在相同条件下,将椭球形胶囊加热到多个较低温度(~ 340 K)。
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引用次数: 0
Comparison of visible spectra of the accelerating gap of a pulsed electron accelerator in a vacuum diode with cathodes made of different materials 阴极材料不同的真空二极管中脉冲电子加速器加速间隙可见光谱的比较
Pub Date : 2021-12-02 DOI: 10.1117/12.2616673
I. Egorov, A. Klimkin, A. Poloskov, D. Pomazkin, M. Serebrennikov, M. Trigub
A possibility of monitoring of the operating mode of the plasma emitter of electrons of a pulsed accelerator (300 keV, 0.5 μs) is considered on the basis of the analysis of the visible radiation spectrum in the region of the accelerating gap. The spectrum was recorded using the optical system of a complex diagnostic device for controlling the parameters of the vacuum diode of the accelerator and spectrometer, the optical probe of which is mounted opposite the accelerating gap and is protected from the direct action of an electron beam. Characteristic visible spectra were recorded in the region of the accelerating gap for cathodes made of common structural materials (copper, graphite, and stainless steel), which makes it possible to distinguish between the electron beam generation mode and vacuum gap short-circuiting mode.
通过对脉冲加速器(300 keV, 0.5 μs)加速间隙区域可见辐射光谱的分析,探讨了监测等离子体发射电子工作模式的可能性。利用复杂诊断装置的光学系统记录光谱,以控制加速器和光谱仪的真空二极管的参数,其光学探头安装在加速间隙的对面,并保护其不受电子束的直接作用。在常用结构材料(铜、石墨和不锈钢)阴极的加速间隙区域记录了特征可见光谱,从而可以区分电子束产生模式和真空间隙短路模式。
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引用次数: 0
Femtosecond filamentation dynamics of synthesized coronary profile laser beam in air: numerical simulations 合成冠状激光束在空气中的飞秒成丝动力学:数值模拟
Pub Date : 2021-12-02 DOI: 10.1117/12.2601461
Y. Geints, A. Zemlyanov
Multiple filamentation in air of high-power ultrashort laser radiation with transverse intensity profile resembling a “corona-beam” (CB) composed by incoherent combining of several annularly distributed independent top-hat sub-beams is theoretically considered. Through the numerical solution of time-averaged nonlinear Schrodinger equation, we study the spatio-angular dynamics of synthesized near infrared CB along the optical path by varying the number and peak power of the beamlets. The evident advances in the multiple-filamentation region manipulating of synthesized CB are demonstrated. Particularly, by adjusting the number and aperture of the constituting sub-beams it makes possible to significantly delay the filamentation onset distance and increase the filamentation length in air.
从理论上考虑了高功率超短激光辐射在空气中的多重细丝现象,其横向强度分布类似于由几个环形分布的独立顶帽子光束非相干组合而成的“日冕束”。通过时间平均非线性薛定谔方程的数值解,通过改变光束的数量和峰值功率,研究了合成近红外CB沿光程的空间-角动力学。介绍了合成黑炭黑在多丝区调控方面取得的显著进展。特别是,通过调整构成子波束的数量和孔径,可以显著延迟成丝的起始距离并增加空气中的成丝长度。
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引用次数: 0
The calculation of the characteristics of the air refractive index fluctuations along line of sight for multiconjugated adaptive optics 多共轭自适应光学系统空气折射率沿视线波动特性的计算
Pub Date : 2019-12-11 DOI: 10.1117/12.2554697
A. Shikhovtsev, A. Kiselev, D. Kolobov, P. Kovadlo, I. Russkih, E. Kopylov
One of the approach to calculate the characteristics of the air refractive index fluctuations along line of sight for multiconjugated adaptive optics is based on the triangulating the wavefront distortions or/and scintillation amplitudes analysis. The description of the experiments aimed to measurements of the wavefront distortions and scintillation fluctuations is given. The scheme for recovering the optical distortions (wavefront) at the different heights is discussed. The results of changes of the wavefront distortions measured by Shack-Hartmann sensor in the spaced regions of images are discussed. The results obtained may be used for estimation of the real amplitudes of the wavefront distortions in crossed optical beams at the different heights using such method as SDimm+[ 5].
计算多共轭自适应光学系统空气折射率沿视线波动特性的方法之一是基于波前畸变的三角测量和闪烁幅度分析。对测量波前畸变和闪烁波动的实验进行了描述。讨论了在不同高度恢复光畸变(波前)的方案。讨论了沙克-哈特曼传感器测量的波前畸变在图像间隔区域的变化结果。所得结果可用于用SDimm+等方法估计不同高度交叉光束波前畸变的真实幅度[5]。
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引用次数: 0
Super-atmospheric pressure CO2 lasers with duration of radiation pulses less than 10 nanoseconds and pulse repetition rates up to 20 Hz 超大气压CO2激光器,其辐射脉冲持续时间小于10纳秒,脉冲重复率高达20赫兹
Pub Date : 2019-12-11 DOI: 10.1117/12.2550678
Quang Manh Do, B. Kozlov, T. N. Mai, A. Y. Payurov, A. Yastrebkov
There are described some constructions and generation characteristics of small–sized sealed–off metal–ceramic CO2-lasers working at super atmospheric pressures with active discharge volumes V1 =18×0.8×0.8 cm3 and V2 =7×0.8×0.8 cm3 and resonator length 20÷46 cm. The main goal of this work was determination of main interrelations between gas discharge parameters, parameters of optical resonator and laser energy per pulse and laser pulse duration. There are achieved radiation pulses with a maximum energy per pulse up to 50÷150 mJ and with minimal durations 5÷8 nanoseconds at pulse repetition rates up to 20 Hz.
介绍了在超大气压下工作的小型密封金属陶瓷co2激光器的结构和产生特性,其主动放电体积V1 =18×0.8×0.8 cm3和V2 =7×0.8×0.8 cm3,谐振腔长度20÷46 cm。本工作的主要目的是确定气体放电参数、光腔参数与激光脉冲能量和激光脉冲持续时间之间的主要相互关系。已经实现的辐射脉冲,每脉冲的最大能量可达50÷150兆焦耳,最小持续时间5÷8纳秒,脉冲重复率可达20赫兹。
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引用次数: 0
Obtaining of micro-powder coatings from Fe-Ni and Fe-Cr alloys by pulse-periodic laser action 脉冲周期激光作用制备Fe-Ni和Fe-Cr合金微粉末涂层
Pub Date : 2019-12-11 DOI: 10.1117/12.2550426
M. Khomyakov, P. Pinaev, Aleksandr Smirnov, P. Statsenko, G. N. Grachev
This paper presents the results of experimental research concerning the laser-plasma coating of steel substrate with the following powder grades: AP-FeCr4MnSiB (Fe71.75C4.81Cr3.33Si3.54B14.10Mn1.74V0.73), AP-FeCr11Mn4SiB (Fe66.8Mn2.84C2.85Si5.3B11.42Cr10.79), AP-FeNi19Mn10SiB (Fe56.12Ni15.82C1.65Si4.92B12.82Mn8.66) and AP-G14 (Fe29.4Ni32.24C5.32Cr14.78Si4.06B10.22Mo2.8W1.16). As a focusing head was used self-made lateral nozzle for feeding powder. The nozzle was used in conjunction with scanning the laser radiation in the direction perpendicular to the movement of the focusing head. Coated tracks with various nozzle head movement speed (7-20 mm/s) was obtained. The elemental compositions of the resulting coatings were studied. Alloying elements are uniform distributed throughout the coating. During surfacing the powder particles are completely melted and partially mixed with the base material. This leads to increased iron content in the resulting coatings compared with the original powder. The hardness and thickness of the deposited layers were measured depending on the speed of the process. The hardness of the coatings is in the range of 7-12 GPa, the thickness is 0.15-0.7 mm. The wear resistance of the resulting coatings is up to 10 times higher than that of a steel substrate.
本文介绍了AP-FeCr4MnSiB (fe71.75 5c4.81 cr3.33 si3.54 b14.10 mn1.74 v0.73)、AP-FeCr11Mn4SiB (Fe66.8Mn2.84C2.85Si5.3B11.42Cr10.79)、AP-FeNi19Mn10SiB (fe56.12 ni15.82 2c1.65 si4.92 b12.82 mn8.66)和AP-G14 (Fe29.4Ni32.24C5.32Cr14.78Si4.06B10.22Mo2.8W1.16)粉末级激光等离子体涂层钢基体的实验研究结果。作为聚焦头,采用自制的侧向喷嘴供粉。该喷嘴与垂直于聚焦头运动方向的激光辐射扫描结合使用。获得了不同喷嘴头部运动速度(7 ~ 20 mm/s)的涂覆轨迹。研究了所得涂层的元素组成。合金元素均匀分布在整个涂层中。在堆焊过程中,粉末颗粒完全熔化并部分与基材混合。这导致与原始粉末相比,所得涂层中的铁含量增加。沉积层的硬度和厚度根据工艺的速度进行测量。涂层硬度为7- 12gpa,厚度为0.15-0.7 mm。所得涂层的耐磨性比钢基体高10倍。
{"title":"Obtaining of micro-powder coatings from Fe-Ni and Fe-Cr alloys by pulse-periodic laser action","authors":"M. Khomyakov, P. Pinaev, Aleksandr Smirnov, P. Statsenko, G. N. Grachev","doi":"10.1117/12.2550426","DOIUrl":"https://doi.org/10.1117/12.2550426","url":null,"abstract":"This paper presents the results of experimental research concerning the laser-plasma coating of steel substrate with the following powder grades: AP-FeCr4MnSiB (Fe71.75C4.81Cr3.33Si3.54B14.10Mn1.74V0.73), AP-FeCr11Mn4SiB (Fe66.8Mn2.84C2.85Si5.3B11.42Cr10.79), AP-FeNi19Mn10SiB (Fe56.12Ni15.82C1.65Si4.92B12.82Mn8.66) and AP-G14 (Fe29.4Ni32.24C5.32Cr14.78Si4.06B10.22Mo2.8W1.16). As a focusing head was used self-made lateral nozzle for feeding powder. The nozzle was used in conjunction with scanning the laser radiation in the direction perpendicular to the movement of the focusing head. Coated tracks with various nozzle head movement speed (7-20 mm/s) was obtained. The elemental compositions of the resulting coatings were studied. Alloying elements are uniform distributed throughout the coating. During surfacing the powder particles are completely melted and partially mixed with the base material. This leads to increased iron content in the resulting coatings compared with the original powder. The hardness and thickness of the deposited layers were measured depending on the speed of the process. The hardness of the coatings is in the range of 7-12 GPa, the thickness is 0.15-0.7 mm. The wear resistance of the resulting coatings is up to 10 times higher than that of a steel substrate.","PeriodicalId":205170,"journal":{"name":"Atomic and Molecular Pulsed Lasers","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116135372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Indirect action of VUV radiation on micro-organisms VUV辐射对微生物的间接作用
Pub Date : 2019-12-11 DOI: 10.1117/12.2548657
G. Zvereva, I. Y. Kirtsidely, E. Machs, E. Letova
The contribution of the indirect mechanism to the inactivation of microorganisms by long wavelength VUV radiation (λ>170 nm) was investigated in this work. For these purposes dry spores of microscopic fungi Rhodotorula colostri and Saccharomyces cerevisiae were irradiated by Xe excilamp (λ= 173 nm).To determine the contribution of indirect action to the microfungi inactivation, the survival probabilities of the samples grown on a nutrient medium containing antioxidant (I2) and without it were carried out. The results have shown, that the survival probabilities of the spores containing antioxidant increases by no less than 20-25% compared to control ones. The increase value depends on VUV irradiation dose and microorganism type. It should be emphasized, that due to the masking of microfungi survival by I2 bactericidal action, the obtained survival probability increase values should be considered as a lower estimate. Electrophoresis of microfungi DNA have shown, that VUV irradiation of spores containing antioxidants leads to less DNA destruction and heaver DNA fragments appearance. The latter may indicate a decrease of reactive oxygen species effect on DNA in the presence of antioxidants. Atomic force microscopy and IR spectroscopy haven’t shown influence of antioxidant on cell wall destruction. This can indicate, that in contrast to wet spores, in the case of VUV irradiation of dry ones, the indirect mechanism of cell wall destruction is absent or weakly expressed.
本文研究了VUV长波(λ>170 nm)灭活微生物的间接机理。为此,用xexilamp (λ= 173 nm)照射显微真菌红酵母(Rhodotorula colostri)和酿酒酵母(Saccharomyces cerevisiae)的干孢子。为了确定间接作用对微真菌失活的贡献,研究了在含抗氧化剂(I2)和不含抗氧化剂的营养培养基上生长的样品的存活概率。结果表明,与对照孢子相比,含抗氧化剂孢子的存活率提高不低于20-25%。增加值与VUV辐照剂量和微生物类型有关。需要强调的是,由于I2杀菌作用掩盖了微真菌的存活,因此所得的存活概率增加值应视为较低的估计。微真菌DNA电泳结果表明,含有抗氧化剂的孢子在紫外辐射下DNA破坏较少,DNA片段出现较多。后者可能表明在抗氧化剂的存在下,活性氧对DNA的影响减少。原子力显微镜和红外光谱未见抗氧化剂对细胞壁破坏的影响。这表明,与湿孢子相比,在VUV照射干燥孢子的情况下,细胞壁破坏的间接机制不存在或表达较弱。
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引用次数: 1
Role of ozone in cryogenic plasma of carbon monoxide laser 臭氧在一氧化碳激光器低温等离子体中的作用
Pub Date : 2019-12-11 DOI: 10.1117/12.2543514
A. Ionin, I. Kinyaevskiy, Y. Klimachev, A. Kotkov, A. Kozlov, A. Kurnosov, D. Mokrousova, D. Sinitsyn
Analysis of experimental data obtained in study of cryogenic CO laser with glow discharge and cryogenic slab CO laser with RF discharge showed that oxygen concentration in laser mixture is much less than in initial gas mixture. With low oxygen content, ozone plays role of supplier of electrons in cryogenic discharge. Since ionization potential of ozone is somewhat higher than that of oxygen, and ozone quickly condenses on cold walls of cryogenic discharge, conversion of O2 to O3 is accelerated. In addition, in plasma-chemical reactions, ozone regenerates carbon monoxide after dissociation. Acceleration of ozone generation in cryogenic barrier discharge was experimentally demonstrated.
对辉光放电低温CO激光器和射频放电低温板状CO激光器的实验数据分析表明,激光混合物中的氧浓度远低于初始气体混合物中的氧浓度。臭氧含氧量低,在低温放电中起着电子供给者的作用。由于臭氧的电离电位略高于氧的电离电位,并且臭氧在低温放电的冷壁上迅速凝结,因此加速了O2向O3的转化。此外,在等离子体化学反应中,臭氧在分解后再生一氧化碳。实验证明了低温阻挡放电中臭氧的加速生成。
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引用次数: 0
期刊
Atomic and Molecular Pulsed Lasers
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