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Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)最新文献

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Role of the lateral leakage current on amorphous silicon solar cells 横向漏电流在非晶硅太阳能电池中的作用
R. Martins, E. Fortunato, A. Bicho, G. Lavareda
The aim of this work is to interpret the role of the lateral leakage current on the a-Si:H solar cell performances (J-V characteristics, responsivity and the apparent device degradation behaviour), under low illumination conditions.
这项工作的目的是解释在低照度条件下,侧漏电流对a-Si:H太阳能电池性能(J-V特性、响应性和明显的器件退化行为)的作用。
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引用次数: 2
Metastable shunt paths in a-Si solar cells a-Si太阳能电池的亚稳态分流路径
T. J. McMahon, M. Bennett
The transitory and erratic nature of shunt currents, whether caused by light-soaking or electrical biasing, in amorphous Si (a-Si) single- and triple-junction solar cells has been a real puzzle and made the study of these cells difficult. The authors present a careful study of the time/voltage dependence of these current transients in several different a-Si solar cell structures and find they reveal more about the basic shunt mechanism. In single-junction cells, they see stepwise current changes that increase in size and number with reverse bias and can be removed with forward bias. This stepwise, on and off switching suggests a discrete shunt path conduction mechanism. The kinetics of these metastable shunt paths show that both the "on-state" and "off-state" possess memory. Cells without (Al)ZnO show no metastable switching. The authors associate the stepwise features with the textured substrate and the switching metastability with contact to (Al)ZnO. Switching in triple-junction cells occurs with hundreds of oscillations at each step.
在非晶硅(a-Si)单结和三结太阳能电池中,无论是由光浸透还是电偏置引起的分流电流的短暂性和不稳定性一直是一个真正的难题,使这些电池的研究变得困难。作者仔细研究了几种不同的a- si太阳能电池结构中这些电流瞬变的时间/电压依赖性,并发现它们揭示了更多关于基本分流机制的信息。在单结电池中,他们看到电流的逐步变化,随着反向偏置的增加,电流的大小和数量增加,并且可以通过正向偏置消除。这种渐进式的通断开关表明了一种离散的分流通路传导机制。这些亚稳态分流路径的动力学表明,“开状态”和“关状态”都具有记忆。没有(Al)ZnO的细胞没有亚稳态开关。作者将这种渐变特性与织构衬底联系起来,将开关亚稳态与(Al)ZnO接触联系起来。在三结细胞中,每一步发生数百次振荡。
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引用次数: 13
Extended infrared response of silicon solar cells and the impurity photovoltaic effect 硅太阳能电池的扩展红外响应和杂质光伏效应
M. Keevers, M. Green
Sub-bandgap spectral response measurements on silicon solar cells are used to characterise the infrared response of present devices, and to investigate the impurity photovoltaic (IPV) effect for improving their infrared response. The former has, aside from establishing a baseline case, led to an improved determination of the subgap absorption coefficient of crystalline silicon. Absorption coefficient values as low as 10/sup -7/ cm/sup -1/ have been determined, revealing structure due to 3- and 4-phonon assisted absorption. The influences of free carrier absorption, bandgap narrowing, and the Franz-Keldysh effect on cell infrared response are considered. Investigation of the IPV effect of indium in high efficiency bulk and thin film cells reveals that indium improves their infrared response. The cross-section for electron photoemission from the indium level, a crucial parameter for modelling indium's IPV effect, is determined.
利用硅太阳能电池的亚带隙光谱响应测量来表征器件的红外响应,并研究杂质光伏(IPV)效应以改善器件的红外响应。前者除了建立了一个基线情况外,还改进了对晶体硅的子间隙吸收系数的测定。吸收系数值低至10/sup -7/ cm/sup -1/,揭示了由于3声子和4声子辅助吸收的结构。考虑了自由载流子吸收、带隙变窄和Franz-Keldysh效应对细胞红外响应的影响。研究了铟在高效块体电池和薄膜电池中的IPV效应,发现铟改善了它们的红外响应。确定了铟能级的电子光发射截面,这是模拟铟的IPV效应的关键参数。
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引用次数: 45
Optical characterization of CuInSe/sub 2/ grown by molecular beam epitaxy 分子束外延生长CuInSe/ sub2 /的光学特性
S. Niki, Y. Makita, A. Yamada, H. Shibata, P. Fons, A. Obara, T. Kurafuji, S. Chichibu, N. Nakanishi
CuInSe/sub 2/ epitaxial films with near stoichiometric compositions have been grown on GaAs (001) by molecular beam epitaxy, and radiative recombination processes in these films have been characterized by means of low temperature photoluminescence (PL) spectroscopy. Temperature dependent PL measurements on such epitaxial films have made possible the identification of conduction band to acceptor and donor-acceptor pair transitions. Well-defined emission lines were present near the bandgap, and the emissions at 1.0386 eV and at 1.0311 eV were found to be due to the ground-state free exciton and the excitons bound to neutral acceptors, respectively. The bandgap of CuInSe/sub 2/ is also determined to be E/sub g/=1.0462 eV at 2 K.
采用分子束外延的方法在GaAs(001)上生长了具有接近化学计量组成的CuInSe/sub 2/外延薄膜,并利用低温光致发光(PL)光谱对薄膜中的辐射复合过程进行了表征。在这种外延薄膜上的温度相关PL测量使得识别传导带到受体和供体-受体对的转变成为可能。在带隙附近有清晰的发射线,1.0386 eV和1.0311 eV的发射分别是由基态自由激子和中性受体结合的激子引起的。CuInSe/sub 2/的带隙也确定为E/sub g/=1.0462 eV。
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引用次数: 0
Real time characterization of the preparation of amorphous silicon-based solar cells 非晶硅基太阳能电池制备的实时表征
Yiwei Lu, Sangbo Kim, I. Chen, Yeeheng Lee, C. Fortmann, C. Wronski, R. Collins
Real time spectroscopic ellipsometry (RTSE) has been applied to characterize the p and i layers that compose amorphous silicon-based solar cells prepared in the superstrate configuration using a single-chamber reactor system. In this study, 106-point spectra (1.5-4.5 eV) in the ellipsometry angles (/spl Psi/, /spl Delta/) are obtained during solar cell preparation with acquisition and repetition times as short as 160 ms and 1 s, respectively. With the spectroscopic capability, the evolution of the microstructure can be determined, including void densities, and surface roughness and bulk layer thicknesses, the latter with submonolayer sensitivity. In addition, the complex dielectric function and optical gap of the individual layers can be determined. An ultrathin (mass thickness /spl sim/4 /spl Aring/) narrow gap interface layer is observed to form during an Ar flushing period between the growth of the p and i layers, which may reduce the open-circuit voltage and short-circuit current of the solar cell.
采用实时椭偏光谱(RTSE)技术对非晶硅基太阳能电池的p层和i层进行了表征。本研究在太阳能电池制备过程中获得了椭圆偏振角(/spl Psi/, /spl Delta/)下的106点(1.5-4.5 eV)光谱,采集时间和重复时间分别短至160 ms和1 s。利用光谱能力,可以确定微观结构的演变,包括空洞密度,表面粗糙度和体层厚度,后者具有亚单层灵敏度。此外,还可以确定各层的复介电函数和光隙。在p层和i层生长之间的Ar冲刷期形成超薄(质量厚度/spl sim/4 /spl Aring/)窄间隙界面层,可以降低太阳能电池的开路电压和短路电流。
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引用次数: 0
Efficient ZnO/CdS/InP heterojunction solar cell 高效ZnO/CdS/InP异质结太阳能电池
Shotaro Saito, Yoshio Hashimoto, Kentara Ito
Heterojunction solar cells consisting of an atom beam sputtered transparent conductive window layer/chemical bath deposited CdS buffer layer/p-type InP single crystal structure were studied. A total area cell efficiency up to 17.8% was obtained at AM 1.5 and was expected to reach as high as 23% based on this structure. The buffer layer 45 to 240 nm thick plays a key role to reduce sputter damages which would be formed at the surface of InP without this layer. It was found that the the choice of window materials has an important effect on the aging properties of the cell. When ZnO is used as a window material, the fill factor of the cell was particularly degraded by aging. Using an atom beam sputtered In/sub 2/O/sub 3/ window layer, the authors have been able to obtain more reliable solar cells.
研究了由原子束溅射透明导电窗层/化学浴沉积CdS缓冲层/p型InP单晶结构组成的异质结太阳能电池。在am1.5下获得了高达17.8%的总面积电池效率,并且基于该结构有望达到高达23%的效率。45 ~ 240 nm厚的缓冲层对减少表面溅射损伤起关键作用。研究发现,窗口材料的选择对细胞的老化性能有重要影响。当ZnO作为窗口材料时,电池的填充因子随着老化而降低。利用原子束溅射的In/sub 2/O/sub 3/窗口层,作者已经能够获得更可靠的太阳能电池。
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引用次数: 6
Investigation on SnS film by RF sputtering for photovoltaic application 用于光伏应用的射频溅射SnS薄膜的研究
Wei Guang-pu, Zhang Zhi-lin, Zhao Wei-ming, Gao Xiang-Hong, Chen Wei-Qun, H. Tanamura, M. Yamaguchi, H. Noguchi, T. Nagatomo, O. Omoto
Tin sulfide (SnS) solar cell semiconductor thin films were prepared by an RF sputtering method. The component, crystal structure, optical properties and electrical properties of SnS films were measured. The relationship between the SnS films properties and the sputtering condition was discussed. Using Sb as a dopant and combining thermal annealing at elevated temperatures (about 400/spl deg/C), n-type SnS homojunction solar cell thin films were obtained.
采用射频溅射法制备了硫化锡太阳能电池半导体薄膜。测定了SnS薄膜的组成、晶体结构、光学性能和电学性能。讨论了溅射条件与SnS薄膜性能的关系。以Sb为掺杂剂,结合高温(约400/spl℃)热退火,得到了n型SnS同质结太阳电池薄膜。
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引用次数: 14
Effects of Cd-free buffer layer for CuInSe/sub 2/ thin-film solar cells 无cd缓冲层对CuInSe/ sub2 /薄膜太阳能电池的影响
T. Nii, I. Sugiyama, T. Kase, M. Sato, Y. Kaniyama, S. Kuriyagawa, K. Kushiya, H. Takeshita
A ZnO buffer layer by a chemical-bath deposition (CBD) method is developed in this study to improve the interface quality between the n-ZnO window layer and p-CuInSe/sub 2/ (CIS) thin-film absorber in CIS thin-film solar cells as one of the approaches to the fabrication of Cd-free thin-film solar cells. The optimization of the fabrication conditions of CBD-ZnO leads to an efficiency of about 10%. These results indicate that the CBD-ZnO buffer layer has a rather high capability to fabricate high-efficiency CIS thin-film solar cells.
为了改善CIS薄膜太阳能电池中n-ZnO窗口层与p-CuInSe/sub 2/ (CIS)薄膜吸收剂之间的界面质量,本研究采用化学浴沉积(CBD)方法制备了ZnO缓冲层,作为制备无cd薄膜太阳能电池的方法之一。优化CBD-ZnO的制备条件,使其效率达到10%左右。这些结果表明,CBD-ZnO缓冲层具有较高的制备高效CIS薄膜太阳能电池的能力。
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引用次数: 3
Progress on the POWER silicon solar cell concept POWER硅太阳能电池概念的进展
G. Willeke, P. Fath, E. Bucher
Details of the design of the POWER silicon solar cell as well as process sequences are given for both a high efficiency and low cost approach. The status of the technological developments is outlined. Computer-based model calculations demonstrate the far superior performance of this design with respect to conventional structures, particularly as a starting material with small diffusion lengths. Results of a ray tracing analysis of the POWER structure with respect to optimum groove angles are also presented.
详细介绍了POWER硅太阳能电池的设计和工艺流程,以达到高效率和低成本的目的。概述了技术发展的现状。基于计算机的模型计算表明,与传统结构相比,这种设计的性能要优越得多,特别是作为具有小扩散长度的起始材料。本文还对POWER结构进行了射线追踪分析,并给出了最佳槽角的计算结果。
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引用次数: 7
Development of a TPV converter for co-generation of electricity and heat from combustion of wood powder 柴粉燃烧热电联产TPV转炉的研制
L. Broman, J. Marks
Wood fuel has a high energy density, 18.3 MJ/kg dry matter, and it is combustible also in existing oil furnaces (in the range 1-15 MW) with little alteration. In principle, wood powder would be a possible fuel for small scale combustion, and the authors are in the process of developing such a furnace. During the last few months, they have constructed and tested a feeding mechanism and a combustion chamber that seem very promising. As of November 1994, they have reached 1481 K and been able to keep the temperature around 1400 K for any length of time at the time in one of their two prototype burners. A joint thermophotovoltaic (TPV) R&D program, in which they cooperate with researchers at National Renewable Energy Laboratory, Golden, CO, USA, is in the planning, aiming at cogeneration of electricity and heat from refined wood fuel.
木材燃料具有高能量密度,18.3 MJ/kg干物质,并且它在现有的油炉(在1-15 MW范围内)中也可燃,几乎没有改变。原则上,木粉可能是小规模燃烧的燃料,作者正在开发这样的炉子。在过去的几个月里,他们已经建造并测试了一个喂食机构和一个燃烧室,看起来非常有前途。截至1994年11月,他们已经达到1481 K,并且能够在两个原型燃烧器之一的时间内保持1400 K左右的温度。他们与美国科罗拉多州戈尔登市国家可再生能源实验室的研究人员合作,正在规划一个联合热光伏(TPV)研发项目,旨在利用精制木材燃料热电联产。
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引用次数: 7
期刊
Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)
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