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Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)最新文献

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Voltage performance of quantum well solar cells in the Al/sub x/Ga/sub 1-x/As/GaAs and the GaAs/In/sub y/Ga/sub 1-y/As material systems Al/sub x/Ga/sub 1-x/As/GaAs和GaAs/ in /sub y/Ga/sub 1-y/As材料体系中量子阱太阳能电池的电压性能
G. Haarpaintner, J. Barnes, K. Barnham, J. P. Connolly, S. S. Dosarajh, J. Nelson, C. Roberts, C. Button, G. Hili, M. Pate, J. Roberts
The open circuit voltage V/sub oc/ and reference voltage V/sub ref/ defined as a measure of the dark current quality, have been studied for a large number of quantum well (QW) solar cells and homogenous control cells. Samples were grown in the Al/sub x/Ga/sub 1-x/As/GaAs and GaAs/In/sub y/Ga/sub 1-y/As material systems. For both combinations, QW solar cells show a better voltage performance in V/sub oc/ and V/sub ref/ than one would expect from a single bandgap solar cell with the same effective absorption bandgap E/sub a/. For the AlGaAs/GaAs cells, V/sub oc/ is related to structural parameters of the QW cells such as the well width L/sub W/ and the Al fraction x. For the strained GaAs/InGaAs cells a relationship is found between V/sub ref/ and the barrier width L/sub B/, which is a dominant parameter in determining strain relaxation and defect formation at a fixed In fraction.
开路电压V/sub /和基准电压V/sub /作为暗电流质量的度量,已经在大量量子阱(QW)太阳能电池和均质控制电池中进行了研究。样品在Al/sub x/Ga/sub 1-x/As/GaAs和GaAs/ in /sub y/Ga/sub 1-y/As材料体系中生长。对于这两种组合,QW太阳能电池在V/sub oc/和V/sub ref/下表现出比具有相同有效吸收带隙E/sub a/的单个带隙太阳能电池更好的电压性能。对于AlGaAs/GaAs细胞,V/sub oc/与QW细胞的结构参数有关,如井宽L/sub W/和Al分数x。对于应变GaAs/InGaAs细胞,V/sub ref/与势垒宽度L/sub B/之间存在关系,这是决定固定in分数下应变松弛和缺陷形成的主要参数。
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引用次数: 5
Optimal surface and bulk passivation of high efficiency multicrystalline silicon solar cells 高效多晶硅太阳电池的最佳表面和本体钝化
H.E. Elgamel, A. Rohatgi, Z. Chen, C. Vinckier, J. Nijs, R. Mertens
Conventional (CC) and electromagnetically cast (EMC) multicrystalline silicon solar cells are fabricated following different passivation schemes. Thin layers (/spl sim/100 /spl Aring/) of thermal dry and PECVD SiO/sub 2/ are implemented for providing oxide surface passivation for multicrystalline silicon solar cells. It is found that growing thin layers of thermal dry oxide results in efficient surface passivation. However, for thin PECVD SiO/sub 2/ layers it is necessary to perform, post deposition, low temperature (/spl sim/350/spl deg/C) forming gas anneal in order to observe the surface passivation effect. In addition, hydrogen plasma passivation has been optimized for achieving very deep penetration of atomic hydrogen in the material (>30 /spl mu/m) and as a consequence very effective bulk passivation of multicrystalline silicon solar cells. By combining the thermal dry surface oxide passivation with the hydrogen plasma treatment from the front and the back sides, efficiency of 17% on 4 cm/sup 2/ (independently confirmed by NREL as 16.93%) is realized without any Al gettering. On the other hand, the solar cell efficiencies obtained using thin layers of PECVD SiO/sub 2/ are found to be very comparable to the efficiency of the cells fabricated with thermal dry SiO/sub 2/ layers.
采用不同的钝化方案制备了传统(CC)和电磁铸造(EMC)多晶硅太阳电池。热干燥和PECVD SiO/sub 2/的薄层(/spl sim/100 /spl Aring/)用于为多晶硅太阳能电池提供氧化物表面钝化。发现生长薄层的热干氧化物可以有效地实现表面钝化。然而,对于薄的PECVD SiO/ sub2 /层,为了观察表面钝化效果,必须在沉积后进行低温(/spl sim/350/spl℃)形成气体退火。此外,氢等离子体钝化已经过优化,可实现原子氢在材料中的极深渗透(>30 /spl mu/m),从而非常有效地实现多晶硅太阳能电池的体钝化。通过将热干表面氧化钝化与前后氢等离子体处理相结合,在4 cm/sup 2/下实现了17%的效率(NREL独立证实为16.93%),而没有任何Al的吸入性。另一方面,使用PECVD SiO/sub 2/薄层获得的太阳能电池效率与使用热干SiO/sub 2/层制造的电池效率非常相似。
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引用次数: 4
New upper efficiency limits for semiconductor solar cells 半导体太阳能电池的新效率上限
J. H. Werner, R. Brendel, H. J. Oueisser
Quantum efficiency measurements showed that more than one electron/hole pair per absorbed photon can be created in a solar cell. Theoretical consideration of this effect leads to new upper radiative efficiency limits for photovoltaic energy conversion. More than 43% efficiency are theoretically possible for cells which are illuminated by the Sun's unconcentrated black body radiation. For sunlight of full concentration, the new limit is above 85%. These values are theoretically possible with a single semiconductor which makes efficient use of carrier multiplication. The theoretical description of radiative recombination in a cell with carrier multiplication leads us also to a novel mathematical description of the saturation current density.
量子效率测量表明,在太阳能电池中,每个吸收光子可以产生一个以上的电子/空穴对。对这一效应的理论考虑导致了光伏能量转换的新的辐射效率上限。从理论上讲,被太阳不集中的黑体辐射照射的电池的效率可能超过43%。对于完全集中的阳光,新的限制在85%以上。这些值在理论上可以用单个半导体实现,从而有效地利用载流子乘法。对载流子倍增的细胞中辐射复合的理论描述也使我们得到了饱和电流密度的一种新的数学描述。
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引用次数: 28
Characterization of amorphous silicon pin solar cells by transient measurement techniques 用瞬态测量技术表征非晶硅引脚太阳能电池
G. Schmid, M. Schubert, H. Brummack, N. Bernhard
In order to provide more specific access to solar cell limitations (and to faults during line production as well) the authors report on space-charge limited time-of-flight (SCL-TOF) studies in the voltage mode, and on forward bias transient switching experiments in 500 nm thick pin structures. Complementing I-V characteristics and quantum yield, both techniques are easy to use and give a clear and reproducible measure of the degradation state of a-Si:H based solar cells. An effective carrier lifetime can be deduced from the extraction time of SCL-TOF. Time and temperature dependent forward current transients show a distinct voltage threshold in the onset of double-injection recombination currents which is related to the built-in voltage of the devices. Enhanced bulk recombination due to light or current induced degradation reduces saturated forward currents and increases the time initially needed for building up space charge in the pin-diodes. Differences upon light-soaking by front or back side illumination have also been investigated.
为了更具体地了解太阳能电池的局限性(以及生产线生产过程中的故障),作者报告了电压模式下空间电荷限制飞行时间(SCL-TOF)的研究,以及500 nm厚引脚结构的正偏置瞬态开关实验。补充了I-V特性和量子产率,这两种技术都易于使用,并提供了a- si:H基太阳能电池降解状态的清晰和可重复的测量。利用SCL-TOF的萃取时间可以推导出有效载流子寿命。与时间和温度相关的正向电流瞬态在双注入复合电流开始时显示出明显的电压阈值,这与器件的内置电压有关。由于光或电流诱导降解而增强的体复合减少了饱和正向电流,并增加了在针脚二极管中建立空间电荷最初所需的时间。还研究了前后侧光照对光吸收的影响。
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引用次数: 0
Present status and future prospects of electromagnetic casting for silicon solar cells 硅太阳能电池电磁铸造技术的现状与展望
K. Kaneko, R. Kawamura, T. Misawa
The development research of electromagnetic casting (EMC) for silicon crystal manufacturing technology has been carried out for years with the purpose of providing low cost multicrystalline silicon substrate for solar cells. The EMC technology is a new concept, in which electromagnetic force is utilized to suspend molten metal without contact to crucible wall for melting and solidification of silicon material. The first fundamental research for casting was begun in 1987 with a small round cross-sectioned ingot of 5 cm diameter, and the ingot size was gradually expanded with a square cross-sectioned ingot shape. The research has been carried out for the development of casting technique with an ingot size of 22/spl times/22 cm/sup 2/ cross section, and the furnace construction for producing a 35/spl times/35 cm/sup 2/ cross sectioned ingot has begun. Solar cell conversion efficiencies using EMC ingot crystals are in the range of 13-14%, and the quality of EMC material reaches within that of conventional mold casting material. By the improvements of higher casting speed, higher material quality and larger ingot size of EMC technology, it is expected that a new casting technique for lower cost ingot production will be realized.
为了为太阳能电池提供低成本的多晶硅衬底,硅晶体制造技术的电磁铸造(EMC)开发研究已经进行了多年。电磁兼容技术是利用电磁力使熔融金属在不接触坩埚壁的情况下悬浮起来,实现硅材料熔融凝固的新概念。1987年开始了铸造的第一个基础研究,用直径5厘米的小圆截面铸锭,铸锭尺寸逐渐扩大为方形截面铸锭形状。开展了22/spl倍/22 cm/sup 2/横截面铸锭工艺开发研究,并开始了35/spl倍/35 cm/sup 2/横截面铸锭的炉体建设工作。使用电磁兼容铸锭晶体的太阳能电池转换效率在13-14%之间,电磁兼容材料的质量达到了常规模具铸造材料的质量水平。通过电磁兼容技术在提高铸造速度、提高材料质量、扩大铸锭尺寸等方面的改进,有望实现一种低成本铸锭生产的铸造新技术。
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引用次数: 5
Actual optical and thermal performance of PV-modules 光伏模块的实际光学和热学性能
S. Krauter, R. Hanitsch
The actual efficiency of photovoltaic generators is often lower than predicted by standard test conditions (STC) or standard operating conditions (SOC). This is caused mainly by an underestimation of reflection losses and solar cell temperature in the module. The authors describe how, in order to obtain more accurate results in predicting the performance of PV-modules, the parameters influencing incoming (optical parameters) and outgoing power flow (electrical and thermal parameters) were investigated by simulation and some verifying experiments at the University of New South Wales and the Australian desert.
光伏发电机组的实际效率往往低于标准测试条件(STC)或标准运行条件(SOC)所预测的效率。这主要是由于组件中反射损耗和太阳能电池温度的低估造成的。作者描述了如何在新南威尔士大学和澳大利亚沙漠通过模拟和一些验证实验研究了影响入射(光学参数)和输出功率流(电学和热学参数)的参数,以获得更准确的预测光伏模块性能的结果。
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引用次数: 99
A study on the microscopical and macroscopical effects of hydrogenation on the performance of multicrystalline solar cells 氢化对多晶太阳能电池微观和宏观性能影响的研究
M. Rosmeulen, H.E. Elgamel, J. Poortmans, M.-A. Trauwaert, J. Vanhellemont, J. Nijs
The grains in the multicrystalline materials used nowadays are typically in the order of a mm or more. In the present study the improvement of different materials (Eurosolare material and EMC material from Sumitomo Sitix) is studied. The method of hydrogenation used consists of a hydrogenation in an RF-plasma. The treatment is from the front or back side of the substrate. The beneficial effect of hydrogenation is illustrated by I-V-measurements under AM1.5 illumination, dark I-V measurements and extraction of minority carrier lifetime by the microwave-detected photoconductive decay method. The measurement on the full solar cell reveals only macroscopic and hence lumped consequences of the hydrogenation. Additional insight was gained from measurements on small mesa-type diodes. In this way we can discriminate between diodes with a grain boundary running through the active device and devices fully contained within one grain. This allows one to split the effects of the hydrogenation on the grain boundaries and the intra-grain defects. Dark I-V-measurements and deep-level transient spectroscopy (DLTS) were used to characterize the diodes in the Eurosolare material. The DLTS-spectra revealed a broad band for the diodes with a grain boundary running through them. This peak completely disappeared on samples which received a direct H-plasma treatment from the front side.
目前使用的多晶材料的晶粒通常在一毫米或更多的数量级。本文研究了不同材料(Eurosolare材料和Sumitomo six的EMC材料)的改进。所使用的氢化方法包括在rf等离子体中进行氢化。从基材的正面或背面进行处理。通过AM1.5照明下的I-V测量、暗I-V测量和微波探测光导衰减法提取少数载流子寿命来说明加氢的有益作用。对整个太阳能电池的测量只显示了氢化的宏观结果,因此也就集中了结果。从对小型台面型二极管的测量中获得了更多的见解。通过这种方法,我们可以区分晶界贯穿有源器件的二极管和完全包含在一个晶界内的器件。这允许人们分离氢化对晶界和晶内缺陷的影响。采用暗i - v测量和深能级瞬态光谱(DLTS)来表征Eurosolare材料中的二极管。dlt -光谱显示二极管有一个宽的晶界带穿过它们。在正面直接接受h等离子体处理的样品上,这个峰完全消失。
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引用次数: 0
Deployment of a dispatchable photovoltaic system: technical and economic results 可调度光伏系统的部署:技术和经济效果
J. Byrne, Young-Doo Wang, S. Letendre, C. Govindarajalu, R. Nigro, W. Bottenberg
This paper discusses the incorporation of PV as a demand-side management (DSM) tool. The valuation of the benefits provided by PV in a DSM role indicates that it is much closer to commercial viability than was thought from economic analyses focusing exclusively on this technology as a supply-side option. However, in order to realize PV's potential, this technology must be deployed in high-value DSM applications; in particular, applications that promise dispatchable peak-shaving capability. Our analysis of the performance of a prototype system installed by Delmarva Power, indicates that small-scale, commercial customer-sited DSM systems incorporating this technology are approaching competitive cost levels.
本文讨论了光伏作为需求侧管理(DSM)工具的整合。对光伏发电在电力需求侧管理中所提供的好处的评估表明,它比经济分析所认为的更接近商业可行性,而经济分析只关注该技术作为供应侧选择。然而,为了实现光伏的潜力,这项技术必须部署在高价值的DSM应用中;特别是那些承诺可调度的削峰能力的应用程序。我们对Delmarva Power安装的原型系统的性能分析表明,采用该技术的小规模商业客户现场DSM系统的成本水平接近具有竞争力的水平。
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引用次数: 1
Interference effects on room-temperature photoluminescence spectra of GaAs/Ge space solar cells 干扰对GaAs/Ge空间太阳能电池室温光致发光光谱的影响
G. Timò, C. Flores
This paper describes a new method, based on room-temperature photoluminescence (PL), for time-saving and nondestructive characterization of thin emitter GaAs/Ge solar cells used for space power applications. It has been shown that the interference phenomena produced between the PL directly escaping from the surface and the PL reflected from the GaAs/Ge interface can provide information on the doping level, thickness and uniformity of the GaAs structure deposited on Ge substrates. This method can be utilized for the quality control of mass-production of GaAs/Ge solar cells for space power applications.
本文描述了一种基于室温光致发光(PL)的新方法,用于空间电源应用的薄发射极GaAs/Ge太阳能电池的省时和无损表征。研究表明,直接从表面逸出的发光与从GaAs/Ge界面反射的发光之间产生的干涉现象可以提供沉积在Ge衬底上的GaAs结构的掺杂水平、厚度和均匀性的信息。该方法可用于空间发电用砷化镓/锗太阳能电池的批量生产质量控制。
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引用次数: 0
High-efficiency solar cells using HEM silicon 使用HEM硅的高效太阳能电池
C. Khattak, F. Schmid, W. K. Schubert
Developments in heat exchanger method (HEM) technology for production of multicrystalline silicon ingot production have led to growth of larger ingots (55 cm square cross section) with lower costs and reliability in production. A single reusable crucible has been used to produce 16 multicrystalline 33 cm square cross section 40 kg ingots, and capability to produce 44 cm ingots has been demonstrated. Large area solar cells of 16.3% (42 cm/sup 2/) and 15.3% (100 cm/sup 2/) efficiency have been produced without optimization of the material production and the solar cell processing.
用于生产多晶硅锭的热交换器方法(HEM)技术的发展导致了更大的锭(55平方厘米的横截面)的增长,在生产中具有更低的成本和可靠性。一个可重复使用的坩埚已被用于生产16个33平方厘米横截面40公斤的多晶锭,并证明了生产44厘米锭的能力。在没有优化材料生产和太阳能电池加工的情况下,已经生产出了效率为16.3% (42 cm/sup 2/)和15.3% (100 cm/sup 2/)的大面积太阳能电池。
{"title":"High-efficiency solar cells using HEM silicon","authors":"C. Khattak, F. Schmid, W. K. Schubert","doi":"10.1109/WCPEC.1994.520197","DOIUrl":"https://doi.org/10.1109/WCPEC.1994.520197","url":null,"abstract":"Developments in heat exchanger method (HEM) technology for production of multicrystalline silicon ingot production have led to growth of larger ingots (55 cm square cross section) with lower costs and reliability in production. A single reusable crucible has been used to produce 16 multicrystalline 33 cm square cross section 40 kg ingots, and capability to produce 44 cm ingots has been demonstrated. Large area solar cells of 16.3% (42 cm/sup 2/) and 15.3% (100 cm/sup 2/) efficiency have been produced without optimization of the material production and the solar cell processing.","PeriodicalId":20517,"journal":{"name":"Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1994-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86165148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
期刊
Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)
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