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Investigation on Characterization and Pyrolysis of Some Coals from Mongolia 蒙古部分煤的表征及热解研究
P. Barnasan, Batkhishig Damdin, B. Sanjaa, Battsetseg Munkhtaivan, Ankhtuya Ariunbold, Jargalmaa Soninkhuu, Avid Budeebazar, A. Aleksandr, P. Kuznetsov
This study reports the technical characteristics, the organic elemental composition of coal, and the inorganic elemental composition of coal ashes from four selected coals including Tavan tolgoi, Nariin sukhait, Baganuur and Shivee-Ovoo deposits in Mongolia. The thermal stability analyses of the organic mass in coal samples were also conducted with thermogravimetric analysis and discussed with the detailed mechanisms of the thermal decomposition of the coal organic mass. Furthermore, the coal samples were processed by pyrolysis at different heating temperatures and determined the yields of pyrolysis products such as hard residue, condensed liquid (tar and pyrolysis water), and uncondensed gas products. The coal ashes from the selected coals were also studied in detail and report that the ashes of high-rank coals of Tavan tolgoi and Nariin sukhait deposits have acidic character and ashes of low-rank coals of Baganuur and Shivee-Ovoo deposits have alkaline character. In addition, the coals samples from Tavan tolgoi, Nariin sukhait, Shivee-Ovoo, and Baganuur deposits were processed by pyrolysis at different heating temperatures and determined with the yields of pyrolysis products such as hard residue, condensed liquid (tar and pyrolysis water), and uncondensed gas products. The yields of hard residue from high-rank coals of Tavan tolgoi and Nariin sukhait were higher than that of low-rank coals of Baganuur and Shivee-Ovoo coal. The dewatered tar products of pyrolysis were investigated for chemical composition analysis.
本文报道了蒙古Tavan tolgoi、narin sukhait、Baganuur和Shivee-Ovoo 4个矿床煤的技术特征、煤的有机元素组成和煤灰的无机元素组成。采用热重分析方法对煤样中有机质进行了热稳定性分析,并详细探讨了煤样有机质的热分解机理。在不同加热温度下对煤样进行热解处理,测定热解产物如硬渣、冷凝液(焦油和热解水)和未冷凝气产物的产率。对所选煤的煤灰进行了详细的研究,并报道了塔班陶勒盖和纳林苏哈伊特矿床的高阶煤灰分具有酸性,巴格努尔和Shivee-Ovoo矿床的低阶煤灰分具有碱性。此外,对Tavan tolgoi、Nariin sukhait、Shivee-Ovoo和Baganuur矿床的煤样进行了不同加热温度下的热解处理,并测定了热解产物如硬渣、冷凝液(焦油和热解水)和非冷凝气产物的产率。塔班陶勒盖和纳林苏哈伊特高阶煤的硬渣产率高于巴格努尔煤和Shivee-Ovoo煤的低阶煤。对热解后的脱水焦油进行了化学成分分析。
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引用次数: 0
Experimental Study on the Effect of Oil Recovery and Transportability Through the Rock Core Using SiO2 Nanoparticles Fluid for Sandstone SiO2纳米流体对砂岩岩心采收率和可输运性影响的实验研究
K. Abe, Taisuke Inomata, S. Naganawa, Hikari Fujii
In oil recovery technique using SiO2 nanoparticles, evaluating the transportability of the nanoparticles in various sandstones contributes to controls of fluid behaviour in petroleum reservoirs and improvement of oil recovery factor. In the core flooding test with high-content kaolinite sandstones, the maximum oil recovery of about 4.5% was obtained by injecting negatively surface charged nanoparticles without adsorption of a large amount of the SiO2 nanoparticles on the rocks and the pore channels plugging effect. The main mechanisms of the oil recovery were suggested wettability alteration changing to more water-wet on the rock surface and increase of disjoining
在SiO2纳米颗粒采油技术中,评价纳米颗粒在不同砂岩中的可输运性,有助于控制储层流体行为,提高采收率。在高含量高岭石砂岩岩心驱油试验中,注入表面带负电荷的纳米颗粒可获得4.5%左右的最大采收率,且没有大量SiO2纳米颗粒吸附在岩石上,也没有孔隙通道堵塞效应。提出了采油的主要机理:润湿性改变,岩石表面更湿化,分离程度增加
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引用次数: 0
Vertical Profile of Water and Sediment in Lake Oigon 奥贡湖水沙垂直剖面
Byambadulam Enkhee, B. Chuluun, Bayanmunkh Baatar, S. Nyamdorj, Sen-Lin Tang, B. Oyuntsetseg
Determining vertical variation of water quality parameters is contributed to a better understanding of the true nature of lakes. Lakes are classified into holomictic and meromictic lakes by their mixing mode; the former occurs physicochemical mixing between the surface and deep waters, while the latter layers of lake water occur unmixed for years, decades, or centuries. Lake Oigon is the only Meromictic Lake identified in Mongolia. Few Mongolian lakes have been studied in different seasons but not in the vertical directions. Therefore, we studied the vertical profile of water and sediment parameters in Lake Oigon for two years. Physico-chemical parameters in water were measured on-site, while sediment parameters were determined off-site. Salinity in lake water ranged from 21.3 to 65.9 g/L which represented mesosaline to hypersaline. In oxic, sub-oxic, and anoxic zones, the physico-chemical parameters of Lake Oigon were varied a lot in longitudinal ways lake and seasonal variation observed as well. However, most parameters were stable in the anoxic zone, regardless of seasons, indicating that no water movement was at the bottom of the lake. Layered sediments with salt indicating hardly exchange with lake water at the anoxic zone. The statistical correlation and principal component analysis between the various physico-chemical parameters of lake water and lake sediment were computed. This study provides the basic information for future research on the characteristic of the vertical profile, impact on the ecosystem, and environmental assessment for Lake Oigon.
确定水质参数的垂直变化有助于更好地了解湖泊的真实性质。根据湖泊的混合方式,将湖泊分为完整湖泊和分生湖泊;前者发生在表层水和深层水之间的物理化学混合,而后者发生在数年、数十年或数百年的未混合状态。Oigon湖是蒙古唯一被确认的Meromictic湖泊。蒙古湖泊在不同季节的研究较少,但在垂直方向上的研究较少。为此,我们对奥贡湖水沙参数的垂直剖面进行了为期两年的研究。现场测量水体理化参数,非现场测定沉积物参数。湖水盐度在21.3 ~ 65.9 g/L之间,为中盐~高盐。在缺氧区、亚缺氧区和无氧区,奥贡湖的理化参数在湖泊纵向和季节上都有较大的变化。然而,大多数参数在缺氧区是稳定的,无论季节如何,这表明湖底没有水的运动。含盐层状沉积物表明在缺氧区与湖水几乎没有交换。计算了湖泊水与沉积物各理化参数之间的统计相关关系和主成分分析。本研究为今后进一步研究奥贡湖垂直剖面特征、对生态系统的影响及环境评价提供了基础资料。
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引用次数: 1
First-Principles Study of Adsorption of Hazardous Atoms on the Silica Surface 二氧化硅表面吸附有害原子的第一性原理研究
Ankhzaya Ganbaatar, Namsrai Tsogbadrakh, Ochirkhuyag Baynjargal, T. Ganbold
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引用次数: 0
Chemical Composition of Peloid from Lake Khyargas 喀尔加斯湖泥球的化学成分
Bayaraa Batnasan, Ganzaya Gankhurel, Dolmaa Gania
The purpose of the study was to determine chemical and organic matter compositions of peloid from Lake Khyargas in Uvs province by chemical and instrumental methods, including X-ray, ICP–OES, and GS/MS. Based on our results, it was identified that the peloid from Lake Khyargas belongs to hydrogen sulfide mud. The content of microelements ranged from 0.5–480 ppm. The peloid contains humic substance 18.08%, lipid 6.56%, and carbohydrate 15.95% in total organic matter (TOM). In addition, organic matter extracted by non-polar and polar solvents counts for 1.83% of TOM. The organic extracts were analyzed by gas chromatography-mass spectrometry (GC/MS) and identified 110 organic compounds in peloid from Lake Khyargas. There were compounds hydrocarbons and their derivatives (16.27%), carboxylic acid (12.94%), dialkyl phthalate (6.52%), element sulfur (4.53%), alcohol (17.65%), halogen bearing hydrocarbons (2.26%), nitrogen-containing compound (12.19%), cyclic hydrocarbons (0.41%), steroids (0.49%), and ketone (14.52%).
采用x射线、ICP-OES、GS/MS等化学和仪器方法对新疆省喀尔加斯湖的球状体进行化学和有机质组成测定。结果表明,喀尔加斯湖的似球体属于硫化氢泥。微量元素含量在0.5 ~ 480ppm之间。总有机质(TOM)中腐殖质占18.08%,脂质占6.56%,碳水化合物占15.95%。此外,非极性溶剂和极性溶剂提取的有机质占总有机质的1.83%。采用气相色谱-质谱联用技术(GC/MS)对有机提取物进行分析,鉴定出110种有机化合物。主要化合物有烃类及其衍生物(16.27%)、羧酸(12.94%)、邻苯二甲酸二烷基酯(6.52%)、元素硫(4.53%)、醇(17.65%)、含卤烃(2.26%)、含氮化合物(12.19%)、环烃(0.41%)、甾体(0.49%)和酮(14.52%)。
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引用次数: 0
A Technological Study of Reduced Iron from Standard Concentrate 标准精矿中还原铁的工艺研究
Unursaikhan Buyannasan, Sukhbat Sandag-Ochir, Sugir-Erdene Namsrai, Soyolmaa Tsolkhuu, Orgilbayar Batkhuyag, Baasanjav Dashtseren, Zagarzusem Tsedendamba, Khasbaatar Dashkhuu, Otgonjargal Enkhtur
The gas-based direct reduction of iron concentrate pellets was carried out by using the typical carbon monoxide. The investigation on the influences of time and temperature of the reduction were studied. The results showed that the temperature and time of the reduction were directly related to the reduced iron content. In order to perform the iron reduction experiment, the powder iron concentrate needed to be pelletized, and the binder agents have used molasses and bentonite. As the result of the reducing experiment at the 1050°C temperature and for 120 minutes, the reduced iron content was 85.6%, and hardness was 115.5 HV which meets the requirements of the reduced iron standard.
采用典型的一氧化碳对铁精矿球团进行气基直接还原。研究了还原时间和温度对还原效果的影响。结果表明,还原温度和还原时间与还原铁含量有直接关系。为了进行铁还原实验,需要将粉末铁精矿制成球团,粘结剂使用糖蜜和膨润土。在1050℃温度下,还原120 min,还原铁含量为85.6%,硬度为115.5 HV,符合还原铁标准要求。
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引用次数: 0
Chlorophyll Catabolites in Senescent Leaves of Lima Bean (Phaseolus Lunatus) and in the Frass of Spodoptera Littoralis After Defecation 青豆(Phaseolus Lunatus)衰老叶片和滨夜蛾(Spodoptera Littoralis)粪便后叶片中叶绿素分解物的研究
Amarsanaa Badgaa, Axel Mithoefer, Khureldavaa Otgonbayar, C. Paetz, W. Boland
Chlorophylls (Chls), the green pigments responsible for photosynthesis in plants, algae and bacteria, are also part of the daily diet of herbivorous feeders. Chl degradation occurs during leaf senescence and fruit ripening but is also noticed as a response to biotic and abiotic stresses. Besides the programmed degradation during senescence different factors such as high temperature, extreme pH values, enzymatic actions, molecular oxygen, and light initiate the degradation of Chl. To gain more information on Chl degradation in the gut of plant-feeding insects, regurgitate and frass of Spodoptera littoralis caterpillars were analysed for late Chl catabolites by using LC-MS, UV, Fluorescence and NMR spectroscopy. The major metabolites were determined in fresh leaves of the food plant lima bean (Phaseoluslunatus), and were compared with digestive products. The observed spectrum of metabolites can be attributed to the combined action of esterolytic gut enzymes and the strongly alkaline milieu in the digestive tract. Interestingly, linear Chl catabolites were not detected in the gut of the larvae of S. littoralis. Substantial amounts of Chl catabolites were found to be macrocyclic rings opened in the senescent food plants, but also in the aged frass. We studied two primary fluorescent chlorophyll catabolites in senescent leaves of lima bean. One of the primary fluorescent chlorophyll catabolites that have been found in the frass of S. littoralis might be generating opened tetrapyrroles of Chl, only after being exposed to the air and light.
叶绿素(Chls)是植物、藻类和细菌中负责光合作用的绿色色素,也是食草动物日常饮食的一部分。Chl降解发生在叶片衰老和果实成熟过程中,但也被认为是对生物和非生物胁迫的反应。除了衰老过程中的程序性降解外,高温、极端pH值、酶促作用、分子氧和光等因素也会引发Chl的降解。为了进一步了解Chl在植物食性昆虫肠道中的降解情况,采用LC-MS、UV、荧光和NMR等方法分析了沿海Spodoptera littoralis毛虫的反刍物和碎屑中Chl的晚期分解产物。测定了食用植物利马豆(Phaseoluslunatus)鲜叶中的主要代谢物,并与消化产物进行了比较。所观察到的代谢物光谱可归因于肠道溶酯酶和消化道强碱性环境的共同作用。有趣的是,在滨海棘海棠幼虫的肠道中没有检测到线性Chl分解产物。在衰老的食用植物中发现了大量的Chl分解代谢物是开放的大环,在衰老的杂草中也发现了大量Chl分解代谢物。研究了青豆衰老叶片中两种主要荧光叶绿素分解产物。在滨草中发现的一种主要荧光叶绿素分解产物可能是在暴露于空气和光照后才产生开放的Chl四吡啶。
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引用次数: 0
Screening for Superoxide Dismutase Activity in Certain Food and Medicinal Plants of Mongolia 蒙古某些食用和药用植物超氧化物歧化酶活性的筛选
Bayarmaa Jambalsuren, Purev Dondog
The purpose of the present work was to perform a screening for SOD activity in plants traditionally used as food and medicine in Mongolia. The SOD activity was measured by their effects on pyrogallol autoxidation. In the studied plants, the SOD activity varied from 0.42±0.01 to 10.47±0.1 U/mg protein. Plants with high SOD activity can serve as a potential source of antioxidant supplements in the human diet. Research is currently ongoing.
本研究的目的是筛选蒙古传统食用和药用植物中SOD的活性。通过对邻苯三酚的自氧化作用测定SOD活性。在所研究的植物中,SOD的活性变化范围为0.42±0.01 ~ 10.47±0.1 U/mg蛋白。具有高SOD活性的植物可以作为人类饮食中抗氧化剂补充剂的潜在来源。研究目前正在进行中。
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引用次数: 0
Biochemical Composition, Amino Acid and Fatty Acid Contents of Muskrat (Ondatra zibethicus) Meat 麝鼠肉的生化组成、氨基酸和脂肪酸含量
Sukhdolgor Jigmed, Enkhsukh Lkhamkhuu, Oyunjargal Tumurbaatar, S. Shar, Suvdmaa Tuvaanjav
We have defined the biochemical composition of the carcass meat of muskrat, including the content of the amino acids, lipids, and saturated and unsaturated fatty acids. The moisture, crude proteins, fatty acid, and ash were 74.6, 23.2, 1.2, and 0.92%, respectively. The average amount of calories was 478 kJ per 100 g meat. We separated 17 amino acids using reversed-phase high-performance liquid chromatography (RP-HPLC) analysis. The fat content was low in both male and female invasive muskrats. The aliphatic tails of the fatty acids range from 16 to 18 carbons. The saturated palmitic (C16:0) and stearic acids (C18:0), and unsaturated oleic (C18:1) and linoleic (C18:2), and linolenic acids (C18:3) were extracted. Even though some of the western provinces in Mongolia applied the carcass meat of the muskrats for treatment against kidney disease in traditional medicine, the scientific proof is still unclear.
我们确定了麝鼠胴体肉的生化组成,包括氨基酸、脂类、饱和和不饱和脂肪酸的含量。水分、粗蛋白质、脂肪酸和灰分分别为74.6%、23.2%、1.2%和0.92%。每100克肉的平均热量为478千焦。采用反相高效液相色谱法(RP-HPLC)分离了17种氨基酸。雄性和雌性入侵麝鼠的脂肪含量都很低。脂肪酸的脂肪尾部有16到18个碳。提取饱和棕榈酸(C16:0)和硬脂酸(C18:0),不饱和油酸(C18:1)和亚油酸(C18:2)和亚麻酸(C18:3)。尽管蒙古西部的一些省份在传统医学中使用麝鼠的胴体肉来治疗肾脏疾病,但科学证据仍不清楚。
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引用次数: 0
Corrigendum to “Waterflooding Technique to the Kashkari Oilfield in the North Part of Afghanistan” “阿富汗北部Kashkari油田注水技术”勘误表
Zabihullah Mahdi, Kazunori Abe, Khwaja Naweed Seddiqi, Hikari Fujii
{"title":"Corrigendum to “Waterflooding Technique to the Kashkari Oilfield in the North Part of Afghanistan”","authors":"Zabihullah Mahdi, Kazunori Abe, Khwaja Naweed Seddiqi, Hikari Fujii","doi":"10.2991/ahcps.k.211004.025","DOIUrl":"https://doi.org/10.2991/ahcps.k.211004.025","url":null,"abstract":"","PeriodicalId":20562,"journal":{"name":"Proceedings of the 5th International Conference on Chemical Investigation and Utilization of Natural Resource (ICCIUNR-2021)","volume":"238 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77059311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings of the 5th International Conference on Chemical Investigation and Utilization of Natural Resource (ICCIUNR-2021)
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