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Heat Dissipation at Cement Hardening 水泥硬化时的散热
Pub Date : 2020-06-20 DOI: 10.48141/SBJCHEM.V28.N28.2020.01_ZHUMADILOVA1_PGS_01_09.PDF
Z. Zhumadilova, K. Akmalaiuly
During the construction of concrete structures of small cross-sections, the release of heat during cement hardening has no harmful effects. With the increasing temperature of the hardening cement mass, the rate of cement hydration increases. This increases the rate of release of its heat of hydration of cement. The consequence of the accelerated process of hydration of the binder is a more intensive increase in the strength of cement stone than in the case of hardening under normal conditions. This fact is widely used in practice for the intensification of the hardening of concrete. When structures with small cross-sections are being built, the heat released during hardening is relatively quickly transferred to the surrounding space and does not cause a significant increase in temperature. In structures made of massive concrete (with a large cross-section), this heat is stored in the interior of the array for a long time, which causes a rather large rise in temperature and its slow drop. This is due to the fact that heat transfer to the external environment is hampered here by the considerable thickness of the massif and the rapid rate of concreting, mechanized laying of large masses of concrete. As a result, a temperature difference is created between the internal and external parts of the structure and harmful internal stresses arise that can cause cracking in the hardened concrete. This leads to a violation of its solidity. The faster cement hydrates, the sooner and more heat is released. The types of cements with a high content of tricalcium silicate and aluminate emit more heat and rather than types of cement with a high content of dicalcium silicate and tetra-calcium aluminoferrite. However, the latter has a lower strength. The increase in strength resulting from the hydration process is inevitably associated with the release of heat into the environment
在小截面混凝土结构施工中,水泥硬化过程中热量的释放没有有害影响。随着水泥体硬化温度的升高,水泥水化速率增大。这增加了水泥水化热的释放速度。胶结剂水化过程加速的结果是水泥石的强度比在正常条件下硬化的情况下更强烈的增加。这一事实在实践中被广泛用于混凝土硬化的强化。当建造小截面结构时,硬化过程中释放的热量相对较快地传递到周围空间,不会引起温度的显著升高。在由大块混凝土(具有大截面)制成的结构中,这些热量在阵列内部储存了很长时间,这导致了相当大的温度上升和缓慢下降。这是由于向外部环境的热量传递在这里受到相当厚的块体和混凝土的快速混凝土速度的阻碍,机械化铺设大块混凝土。结果,在结构的内部和外部部分之间产生温差,并且产生有害的内应力,可能导致硬化混凝土开裂。这就破坏了它的坚固性。水泥水化得越快,释放的热量也就越快。硅酸三钙和铝酸盐含量高的水泥比硅酸二钙和四钙铁铝酸盐含量高的水泥释放更多的热量。而后者的强度较低。由水化过程引起的强度的增加不可避免地与向环境中释放热量有关
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引用次数: 1
STUDY ON THE DPPH FREE RADICAL-SCAVENGING ACTIVITY OF SALVIA NEMOROSA L. AT TWO GROWTH STAGES 鼠尾草两个生长阶段对DPPH自由基清除能力的研究
Pub Date : 2020-06-20 DOI: 10.48141/SBJCHEM.V28.N28.2020.05_GHAFIYEHSANJ_PGS_34_39.PDF
Elham Ghafiyehsanj, Kamaladdin Dilmaghani, Nader Chaparzade, S. Saadatmand
This study was designed to examine the DPPH free radical-scavenging activity, in different concentrations (0.025, 0.05, 0.07, 0.1, 0.2, 0.04 and 0.6) of methanolic extracts of Salvia nemorosa L. collected from the northwest of Iran (Zonouz and Ardabil regions) at two-stage of growth (vegetative stage leaves, flowering stage leaves, and flowers). The result showed that the mean of inhibition percentage in the Zonouz region increased in various concentrations and between flowers, vegetative stage leaves, and flowering stage leaves, compared with the plants of the Ardabil region. In each of the regions of Zonouz and Ardabil, the highest amount of DPPH inhibition was observed in the vegetative stage leaves in comparison with flowering stage leaves and flowers. In addition, in the effect of DPPH radical trapping in different concentrations of methanolic extracts of Salvia nemorosa L. was observed that from each of the collected region, methanolic extracts from sage plants were dose-dependent and acted very effective and useful and the best antioxidant activity was in the high concentration of extracts, So in Zonouz and Ardabil regions, the content of inhibition of DPPH increased significantly, by increasing the concentration of 0.025 mg/ml to 0.6 mg/ml and in Zonouz region the content of inhibition of DPPH similarly increased in 0.2, 0.4 and 0.6 mg/ml concentrations. In the Ardabil region, the most content of inhibition of DPPH was seen in 0.4 mg/ml and 0.6 mg/ml concentrations, but in this region, the content of inhibition of DPPH in 0.2 mg/ml concentration there was only in vegetative stage leaves and flowering stage leaves.
本研究研究了采自伊朗西北部(Zonouz和Ardabil地区)不同浓度(0.025、0.05、0.07、0.1、0.2、0.04和0.6)的鼠尾草(Salvia nemorosa L.)甲醇提取物在营养期叶、花期叶和花的两个生长阶段对DPPH自由基的清除能力。结果表明,与阿达比尔地区相比,Zonouz地区在不同浓度下以及在花、营养期叶和开花期叶之间的平均抑制率都有所增加。在Zonouz和Ardabil的每个区域,与开花期叶片和花相比,营养期叶片中DPPH的抑制量最高。此外,在不同浓度鼠尾草甲醇提取物对DPPH自由基的诱捕效果中,我们观察到,在不同的采集区,鼠尾草甲醇提取物具有剂量依赖性,并且具有非常有效和有用的作用,并且在高浓度的提取物中具有最好的抗氧化活性,因此在Zonouz和Ardabil地区,DPPH的抑制含量显著增加。当浓度为0.025 mg/ml至0.6 mg/ml时,Zonouz区对DPPH的抑制作用在0.2、0.4和0.6 mg/ml浓度下均明显增加。在阿达比尔地区,0.4 mg/ml和0.6 mg/ml浓度对DPPH的抑制含量最高,但在该地区,0.2 mg/ml浓度对DPPH的抑制含量仅在营养期和开花期叶片中存在。
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引用次数: 0
Clinical and Laboratory Testing of a New Modification of Two-Layer "Silep" Dentures Used in Prosthetic Dentistry 一种新型改良的双层“睡眠”义齿在口腔修复中的临床和实验室检测
A. Timoshin, N. Mitin, Alexander Oleynikov, M. Timoshina, E. Mitina
Dentistry is a part of medicine, where various polymer materials were used for the first time. Many factors forced researchers to find more stable, versatile, and hygienic materials for the manufacture of dental products. It is important to note that the search for the ideal polymer dental material is still ongoing. This is because modern polymers, in some cases, do not meet the specified requirements for chemical, physical, strength, and elastic properties. Based on the data on the method of creating and using silicone material for the base of the removable prosthesis "Gossil", an improved silicone material for two-layer dentures "Silep" was developed, as well as a special primer for better connection of the lining with the rigid acrylic base of the prosthesis. To evaluate the most suitable compound, materials were tested for several parameters, such as tensile strength, elongation, and shore hardness. In addition to selecting a suitable material for modification, the selection and testing of an adhesive that allows the chemical bonding of the acrylate surface to the siloxane surface were carried out
牙科是医学的一部分,首次使用了各种高分子材料。许多因素迫使研究人员寻找更稳定、通用和卫生的材料来制造牙科产品。值得注意的是,寻找理想的聚合物牙科材料仍在进行中。这是因为在某些情况下,现代聚合物不符合化学、物理、强度和弹性性能的规定要求。根据“gossip”活动义齿基托硅胶材料的制作和使用方法的数据,开发了一种改进的双层义齿基托硅胶材料“Silep”,以及一种特殊的底漆,使内衬与义齿刚性丙烯酸基托更好地连接。为了评估最合适的化合物,测试了材料的几个参数,如抗拉强度、伸长率和邵氏硬度。除了选择合适的改性材料外,还进行了丙烯酸酯表面与硅氧烷表面化学键合的粘合剂的选择和测试
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引用次数: 0
INDICATORS OF TRYPSIN-LIKE ACTIVITY OF MIXED SALIVAAFTER INSTALLING THE ENDOSSEOUS IMPLANTS IN THE PRESENCE OF GASTRIC ULCER AND DUODENAL ULCER 胃溃疡和十二指肠溃疡患者植入假体后混合唾液胰蛋白酶样活性指标
Pub Date : 2019-12-20 DOI: 10.48141/sbjchem.v27.n27.2019.19_2019.pdf
M. Kuznetsova, A. Nikonova, Ivan Kuznetsov, Mariya Sevbitova, M. Timoshina
The trypsin-like activity of mixed saliva in orthopedic patients after implant placement was monitored. Proved negative impact on the processes of repair of background somatic pathology (peptic ulcers and 12 duodenal ulcers), justify the application of immunomodulator "Erbisol" as a drug that speeds up the repair processes during implantation. At present, the relevant issues are those related to the development of inflammatory complications at the stage of rehabilitation of patients, especially in the presence of somatic pathology and the study of the tissue complex of the implantation zone. Peptic ulcer disease occupies one of the main places in the structure of lesions of the digestive system. The close interdependence between the pathology of internal organs and the oral cavity is confirmed by numerous observations and studies.Implant placement is accompanied by changes in the enzymatic activity of mixed saliva. The presence of somatic pathology (ulcerative disease of the stomach and 12 duodenal ulcers) often leads to more long-term violations of the enzymatic activity of saliva. The use of the drug "Erbisol" in orthopedic dentistry accelerates the repair process, as evidenced by the earlier periods of normalization of the enzymatic activity of mixed saliva, after the installation of implants.Regular and timely monitoring of the condition of the periarticular tissues, as well as objective diagnosis of early inflammatory complications, are necessary to ensure the reliability and long-term functioning of prosthetic structures installed on implants in the oral cavity.It can be concluded that the purpose of our study was to study the trypsin-like activity (TPA) of mixed saliva after implant placement on the background of somatic pathology.
对骨科患者植体后混合唾液胰蛋白酶样活性进行监测。证实对背景体病理(消化性溃疡和十二指肠溃疡)修复过程的负面影响,证明了免疫调节剂“Erbisol”作为一种药物在植入过程中加速修复过程的应用是正确的。目前,相关的问题是患者康复阶段炎症并发症的发展,特别是在存在躯体病理和植入区组织复合体的研究中。消化性溃疡是消化系统结构病变的主要部位之一。许多观察和研究证实了内部器官和口腔病理之间的密切相互依存关系。种植体植入伴随着混合唾液酶活性的变化。躯体病理(胃溃疡性疾病和12个十二指肠溃疡)的存在经常导致更长期的唾液酶活性的破坏。在矫形牙科中使用药物“Erbisol”加速修复过程,正如在安装植入物后混合唾液酶活性正常化的早期阶段所证明的那样。定期及时监测关节周围组织的状况,客观诊断早期炎症并发症,是保证口腔种植体上安装的假体结构的可靠性和长期功能的必要条件。由此可见,本研究的目的是在躯体病理背景下研究植入后混合唾液的胰蛋白酶样活性(TPA)。
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引用次数: 0
Indicators of trypsin-like activity of mixed saliva after installing the endosseous implants in the presence of gastric ulcer and duodenal ulcer 胃溃疡和十二指肠溃疡患者植入假体后混合唾液胰蛋白酶样活性指标
Mariya Mkuznetsova, A. Nikonova, I. Kuznetsov, Mariya Sevbitova, M. Timoshina
The trypsin-like activity of mixed saliva in orthopedic patients after implant placement was monitored. Proved negative impact on the processes of repair of background somatic pathology (peptic ulcers and 12 duodenal ulcers), justify the application of immunomodulator "Erbisol" as a drug that speeds up the repair processes during implantation. At present, the relevant issues are those related to the development of inflammatory complications at the stage of rehabilitation of patients, especially in the presence of somatic pathology and the study of the tissue complex of the implantation zone. Peptic ulcer disease occupies one of the main places in the structure of lesions of the digestive system. The close interdependence between the pathology of internal organs and the oral cavity is confirmed by numerous observations and studies.Implant placement is accompanied by changes in the enzymatic activity of mixed saliva. The presence of somatic pathology (ulcerative disease of the stomach and 12 duodenal ulcers) often leads to more long-term violations of the enzymatic activity of saliva. The use of the drug "Erbisol" in orthopedic dentistry accelerates the repair process, as evidenced by the earlier periods of normalization of the enzymatic activity of mixed saliva, after the installation of implants.Regular and timely monitoring of the condition of the periarticular tissues, as well as objective diagnosis of early inflammatory complications, are necessary to ensure the reliability and long-term functioning of prosthetic structures installed on implants in the oral cavity.It can be concluded that the purpose of our study was to study the trypsin-like activity (TPA) of mixed saliva after implant placement on the background of somatic pathology.
对骨科患者植体后混合唾液胰蛋白酶样活性进行监测。证实对背景体病理(消化性溃疡和十二指肠溃疡)修复过程的负面影响,证明了免疫调节剂“Erbisol”作为一种药物在植入过程中加速修复过程的应用是正确的。目前,相关的问题是患者康复阶段炎症并发症的发展,特别是在存在躯体病理和植入区组织复合体的研究中。消化性溃疡是消化系统结构病变的主要部位之一。许多观察和研究证实了内部器官和口腔病理之间的密切相互依存关系。种植体植入伴随着混合唾液酶活性的变化。躯体病理(胃溃疡性疾病和12个十二指肠溃疡)的存在经常导致更长期的唾液酶活性的破坏。在矫形牙科中使用药物“Erbisol”加速修复过程,正如在安装植入物后混合唾液酶活性正常化的早期阶段所证明的那样。定期及时监测关节周围组织的状况,客观诊断早期炎症并发症,是保证口腔种植体上安装的假体结构的可靠性和长期功能的必要条件。由此可见,本研究的目的是在躯体病理背景下研究植入后混合唾液的胰蛋白酶样活性(TPA)。
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引用次数: 0
PRODUCTION OF BIOPLASTIC FROM POTATO STARCH 用马铃薯淀粉生产生物塑料
Paula Novais Cordeiro, S. T. Caetano, R. Carvalho
Due to their diverse properties, plastic materials are used in numerous sectors. It is possible to produce different articles and plastic objects with reduced costs, being more accessible to the population. Conventional plastics are obtained from petroleum-derived raw materials, a non-renewable resource in which their extraction and refining process cause major environmental impacts. The production of plastic reaches a level of approximately one hundred and forty million tons per year, and the disposal of these materials is increasing, generating a high rate of waste and leading to an increase of pollution since the decomposition of these materials lasts about five hundred years old. Conventional plastics can be replaced by bioplastics, a material obtained from renewable raw materials such as potatoes, cassava, maize, and which, when disposed of under favorable conditions, decomposes faster, as during its degradation process at least one step occurs. Through the metabolism of organisms present in the environment. Starch has been widely used in the production of biodegradable packaging, so the objective of this work was to produce a biodegradable bioplastic from the potato starch. Potato starch, glycerin, hydrogen peroxide, distilled water, and commercial agar were used to produce the bioplastic. Bench-scale bioplastics had good organoleptic characteristics, similar in appearance to a conventional plastic obtained from petroleum. The thickness, moisture content, and solubility of the bioplastics were analyzed, as well as their fruit preservation capacity. The samples produced were rigid and with good resistance.
由于其多种特性,塑料材料被用于许多领域。有可能以更低的成本生产不同的物品和塑料制品,使人们更容易获得。传统塑料是从石油衍生的原料中获得的,这是一种不可再生的资源,其提取和精炼过程对环境造成了重大影响。塑料的产量达到了每年大约一亿四千万吨的水平,而这些材料的处置正在增加,产生了很高的废物率,并导致污染的增加,因为这些材料的分解持续了大约五百年。传统塑料可以被生物塑料取代,生物塑料是一种从马铃薯、木薯、玉米等可再生原料中获得的材料,在有利条件下处理时,分解得更快,因为在其降解过程中至少发生了一个步骤。通过存在于环境中的生物体的新陈代谢。淀粉已广泛用于生产可生物降解包装,因此本研究的目的是利用马铃薯淀粉生产可生物降解的生物塑料。马铃薯淀粉、甘油、双氧水、蒸馏水和商用琼脂被用于生产生物塑料。实验规模的生物塑料具有良好的感官特性,其外观与从石油中获得的传统塑料相似。分析了生物塑料的厚度、含水率、溶解度及其保鲜性能。所得样品刚性好,耐蚀性好。
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引用次数: 1
Southern Brazilian Journal of Chemistry, Volume 27, No. 27, 2019 《南巴西化学杂志》,2019年第27期
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引用次数: 0
INVESTIGATION OF PHOSPHATE-ION RETENTION STRENGHT IN SOME TYPES OF KAKHETI SOILS 不同类型卡尔赫蒂土中磷离子保持强度的研究
K. Kupatadze
The presented article describes the soil types existing in east Georgia, particularly in several villages of Gurjaani Municipality-Vazisubani, Kalauri, Mukuzani, Shashiani. Meadow-brown and brown soils represent good soil types for viticulture development in Kakheti. The vineyards cultivated on these soils produce such wellknown wines as Tsinandali, Vazisubani, Mukuzani, Akhasheni, Gurjaani, Manavi. The study explores brown carbonate and meadow-brown soil lab tests to examine the absorption of phosphate ions by them. The study showed that the amount of phosphorus deposited through soils is sufficiently absorbed under various conditions, having a positive effect on the amount of crop. Was compared the rates of phosphate absorption in these soils with the efficiency of phosphorus fertilizers, which showed that the higher the absorption of phosphorus, the lower the amount of phosphorus available to the plant and the lower the yield, and the lower the strength of phosphorus retention, the higher the amount of phosphorus to be consumed by the plant and the higher the yield. But under the conditions of high cultivation degree, the strength of phosphorus absorption became weak, resulted in a large amount of exchangeable and movable phosphates already existing in the soil, which is available to the plant. So, the efficacy of phosphorus fertilizers on such soil is weak. The speed of phosphorus absorption in the soil of Gurjaani municipality villages is satisfactory. However, in case of a high degree of cultivation (or in case of excess fertilization), the degree of phosphorus retention decreases. Accordingly, phosphorus-containing fertilizers should be used within strictly controlled limits.
本文描述了格鲁吉亚东部存在的土壤类型,特别是在Gurjaani市的几个村庄- vazisubani, Kalauri, Mukuzani, Shashiani。草甸棕壤和棕壤是Kakheti地区发展葡萄栽培的良好土壤类型。在这片土地上种植的葡萄园出产著名的葡萄酒,如齐南达利、瓦齐苏巴尼、穆库扎尼、阿哈谢尼、古尔贾尼、马纳维等。该研究探索了棕色碳酸盐和草甸棕色土壤的实验室测试,以检查它们对磷酸盐离子的吸收。研究表明,在各种条件下,土壤中磷的沉积量被充分吸收,对作物产量有积极的影响。结果表明,磷吸收量越高,植株速效磷含量越低,产量越低;磷滞留强度越低,植株消耗磷含量越高,产量越高。但在高度耕作的条件下,磷的吸收强度变弱,导致土壤中已经存在大量的交换性和可动性磷酸盐,这些磷酸盐被植物利用。因此,磷肥在这类土壤上的施用效果较弱。古雅尼市村庄土壤磷的吸收速度令人满意。然而,在高度耕作(或过量施肥)的情况下,磷的保留程度降低。因此,应严格控制含磷肥料的用量。
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引用次数: 0
BUNCH NUMBER AND ANTIOXIDANT ACTIVITY IN ‘SAHEBI’ AND ‘HALAGHO’ GRAPES AFFECTED BY PRUNING INTENSITY AND CANE LENGTH ' sahebi '和' halagho '葡萄串数和抗氧化活性受修剪强度和甘蔗长度的影响
Z. Mahtab, B. Davood, Fallahi Esmaeil, A. Isa
Pruning methods can primarily affect grape production at various levels. Of the commonly affected features by pruning, the number of bunches has known to have a significant effect on the relation between the functions of assimilate sources and sinks. Further, fruitfulness can significantly be negatively influenced by shading. In this study, we aim to study the impact of 4, 6 and 8 buds per cane with pruning intensity as light, moderate and severely pruned and their interaction in the course two consecutive years, 2017 and 2018 in ‘Sahebi’ and ‘Halagho’ (both seeded red table grape cultivars). In 2018, lightly pruned ‘Halagho’ and having 8 buds per cane increased number of bunches by 54.00, which had the highest value. Results showed that there is apical buds bear more fruit by comparison to the buds with vegetative nature, 1 to 4 first buds. Based upon the outcomes of this study, it could be concluded that due to the stresses imposed by the pruning of the vines, therefore, the chemical compounds increases in order alleviate the negative aftermaths . In 2018, whole berry antioxidant activity in both cultivars was significantly lessened, and this decline was higher in ‘Saahebi’. The number of bunches was increased by increasing cane length or bud load/cane. Overall, the pruning program has an impactful role in bunch number as well as antioxidant activity and in the long-run on accumulated reserves, which makes choosing and applying a specific pruning method undeniably important. Thus, emphasize the importance of further research in this field.
修剪方式对葡萄产量的影响主要体现在不同的层次上。在通常受修剪影响的特征中,已知束的数量对同化源和吸收功能之间的关系有显著影响。此外,生育力会受到遮荫的显著负面影响。在本研究中,我们旨在研究2017年和2018年连续两年,在Sahebi和Halagho两种红食葡萄品种中,轻、中、重度修剪4、6和8个芽对每根甘蔗的影响及其相互作用。2018年,轻度修剪的“哈拉哥”和每根甘蔗有8个芽,使串数增加了54.00,价值最高。结果表明,与营养性芽相比,顶芽结果较多,头芽1 ~ 4个;根据本研究的结果,可以得出结论,由于葡萄藤修剪施加的压力,因此,化学成分增加以减轻负面后果。2018年,两种品种的全浆果抗氧化活性均显著降低,其中“萨赫比”下降幅度更大。通过增加茎长或芽载/茎来增加束数。综上所述,修剪方式对束数、抗氧化活性和长期累积储量都有影响,因此选择和应用特定的修剪方式至关重要。因此,强调该领域进一步研究的重要性。
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引用次数: 0
NIOBIUM ALLOY STEEL APPLIED IN COLD FORMING MANUFACTURE 铌合金钢在冷成形制造中的应用
Bruno Inácio da Maia, A. H. Futami, Marco Aurélio de Oliveira, Luiz Veriano Oliveira Dallavalentina
Niobium alloy steels are still little known and debated when applied to the metallurgy industry, including cold forming process. It is not much clear about its characteristics and your mechanical performance when compared to traditional steels, which the market already uses. The possibility of input new materials, reducing costs and generating competitiveness is the basis for researches that can generate new opportunities for industries. In this article, we showed the possibility of withdrawing the heat treatment process, which guided the execution of the tests presented here. This paper deals with the performance comparison of SAE 1312 MOD steel compared to ISO 898-1, which deals with mechanical performance for bolts. The tests were correlated with the bolts of 8.8 resistance class, which currently have heat treatment. It is possible to evaluate the positive performance of the niobium-alloyed steel (SAE 1312 MOD), despite the occasional performance limitations in some attributes addressed in ISO 898-1.
铌合金钢在冶金工业中的应用,包括冷成形工艺,仍然是鲜为人知的和争论的。与市场上已经使用的传统钢材相比,它的特性和机械性能还不太清楚。投入新材料,降低成本和产生竞争力的可能性是研究的基础,可以为工业创造新的机会。在本文中,我们展示了取消热处理工艺的可能性,这指导了本文所介绍的测试的执行。本文讨论了SAE 1312 MOD钢与ISO 898-1的性能比较,ISO 898-1涉及螺栓的机械性能。试验对象为目前已热处理的8.8级电阻级螺栓。尽管在ISO 898-1中提到的某些属性中偶尔存在性能限制,但仍可以评估铌合金钢(SAE 1312 MOD)的积极性能。
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引用次数: 0
期刊
Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE
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