Pub Date : 2020-12-20DOI: 10.48141/sbjchem.v28.n29.2020.06_rosa_pgs_46_54.pdf
Flávia Sapper DA ROSA, A. Lhamby, Vinicyus Mourão Monteiro Guillet, M. A. Klunk, N. Caetano
The ore beneficiation process uses little technology, but mining companies have high economic performance. As an energy source, firewood plays a fundamental role due to its simple storage, low cost, great availability of forests, and lack of processing. Thus, the present work aims to analyze the consumption of firewood as fuel and possible improvements in the process for the production of lime in terms of harnessing raw materials and costs. Calcium oxide is obtained from the thermal decomposition of calcium and magnesium carbonates obtained from dolomitic deposits of limestone (CaCO3 : CaMgCO3). After CaO extraction, it is subjected to a calcination process, removing carbon dioxide (CO2) in ovens that work at temperatures between 900 and 1200°C. The source of energy applied to the calcination furnaces in the analyzed area is wood. The wood has a calorific value between 2,250 and 2,700 Kcal/Kg, but the moisture content responsible for the thermal variation must be considered. The firewood burning process was carried out in a ravine type oven where the temperature at which operators are exposed to heat was evaluated. The results indicated that the cooking time dropped by 20% as the amount of wood is fed into the oven. This increase represents a significant gain in lime production, thus leading to a higher profit for the company.
{"title":"THERMAL AND ECONOMIC ANALYSIS OF LIME PRODUCTION","authors":"Flávia Sapper DA ROSA, A. Lhamby, Vinicyus Mourão Monteiro Guillet, M. A. Klunk, N. Caetano","doi":"10.48141/sbjchem.v28.n29.2020.06_rosa_pgs_46_54.pdf","DOIUrl":"https://doi.org/10.48141/sbjchem.v28.n29.2020.06_rosa_pgs_46_54.pdf","url":null,"abstract":"The ore beneficiation process uses little technology, but mining companies have high economic performance. As an energy source, firewood plays a fundamental role due to its simple storage, low cost, great availability of forests, and lack of processing. Thus, the present work aims to analyze the consumption of firewood as fuel and possible improvements in the process for the production of lime in terms of harnessing raw materials and costs. Calcium oxide is obtained from the thermal decomposition of calcium and magnesium carbonates obtained from dolomitic deposits of limestone (CaCO3 : CaMgCO3). After CaO extraction, it is subjected to a calcination process, removing carbon dioxide (CO2) in ovens that work at temperatures between 900 and 1200°C. The source of energy applied to the calcination furnaces in the analyzed area is wood. The wood has a calorific value between 2,250 and 2,700 Kcal/Kg, but the moisture content responsible for the thermal variation must be considered. The firewood burning process was carried out in a ravine type oven where the temperature at which operators are exposed to heat was evaluated. The results indicated that the cooking time dropped by 20% as the amount of wood is fed into the oven. This increase represents a significant gain in lime production, thus leading to a higher profit for the company.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78996137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.48141/sbjchem.v28.n29.2020.03_bahrami_pgs_17_27.pdf
Saeed Bahrami
In many low-temperature areas, the environmental factor is an important limiting factor for the production and distribution of horticultural plants. This study aimed to investigate the cold tolerance of the male catkins and inoculated female flowers to screen the popular native hazelnut cultivars in Qazvin under low-temperature stress. A completely randomized factorial block design with three replications was used in this experiment with eight cultivars (Nakhnroud, Khandan, Mish-Pestan, South of Qarabagh, Asl-e-Qarabagh, Rasmi, and Gerdashkevar). After removing each of the treated samples at the end of the experiment, the samples were examined morphologically (appearance) and compared with the control. The changes were recorded as qualitative traits. To understand the influence of cold stress on reproductive organs, hydrogen peroxide and proline were measured. The results showed the onset of freezing in unopened male catkins at -7 and -9 °C and in inoculated female flowers at -3 °C. Damage to unopened male catkins' tissue occurred at -11 °C and in female flowers at -5 °C. The highest value observed among cultivars in the case for proline content of male catkins was in Mish-Pestan and Khandan cultivars with 0.816 and 0.660 µmol/ g FW, respectively. In inoculated female flowers, Mish-Pestan and Tabestaneh cultivars with 0.185 and 0.168 µmol/ g FW, respectively, showed the highest statistically significant increase in proline content. Interestingly, the cultivars with the highest proline content in male catkins indicated the most increase in H2O2; Mish-Pestan and Khnadan with 0.569 and 0.541 ug/g FW, respectively. Asl-eQarabagh was observed to have the least H2O2 content (0.042 ug/g FW) among cultivars. Again, in inoculated female flowers, those with the highest concentration of proline (Mish-Pestan and Tabestaneh) were found to have the highest H2O2 content (0.335 and 0.331 ug/g FW, respectively
在许多低温地区，环境因素是制约园艺植物生产和分布的重要因素。本研究旨在研究雄性榛子絮和接种雌花在低温胁迫下的耐寒性，以筛选甘孜温地区常见的乡土榛子品种。8个品种(Nakhnroud、Khandan、mishish - pestan、South of Qarabagh、Asl-e-Qarabagh、Rasmi和Gerdashkevar)采用完全随机因子区组设计，共3个重复。在实验结束时去除每个处理过的样品后，对样品进行形态学(外观)检查，并与对照进行比较。这些变化被记录为质量性状。为了解低温胁迫对生殖器官的影响，测定了过氧化氢和脯氨酸含量。结果表明，未开放雄絮在-7℃和-9℃开始冻结，接种后雌花在-3℃开始冻结。在-11°C和-5°C时，未开放的雄花柳絮组织发生损伤。雄絮脯氨酸含量最高的品种为米什-佩斯坦和坎丹，分别为0.816和0.660µmol/ g FW。在接种雌花中，Mish-Pestan和Tabestaneh分别添加0.185和0.168µmol/ g FW的品种脯氨酸含量的增加具有显著的统计学意义。有趣的是，雄絮脯氨酸含量最高的品种H2O2含量增加最多;米什-巴基斯坦和卡纳丹分别为0.569和0.541 ug/g FW。其中，阿斯勒-伊卡拉巴的H2O2含量最低(0.042 ug/g FW)。同样，在接种雌花中，脯氨酸浓度最高的雌花(Mish-Pestan和Tabestaneh) H2O2含量最高，分别为0.335和0.331 ug/g FW
{"title":"INVESTIGATING THE EFFECT OF COLD TEMPERATURE STRESS ON UNOPENED MALE CATKINS AND INOCULATED FEMALE FLOWERS OF IRANIAN NATIVE HAZELNUT CULTIVARS","authors":"Saeed Bahrami","doi":"10.48141/sbjchem.v28.n29.2020.03_bahrami_pgs_17_27.pdf","DOIUrl":"https://doi.org/10.48141/sbjchem.v28.n29.2020.03_bahrami_pgs_17_27.pdf","url":null,"abstract":"In many low-temperature areas, the environmental factor is an important limiting factor for the production and distribution of horticultural plants. This study aimed to investigate the cold tolerance of the male catkins and inoculated female flowers to screen the popular native hazelnut cultivars in Qazvin under low-temperature stress. A completely randomized factorial block design with three replications was used in this experiment with eight cultivars (Nakhnroud, Khandan, Mish-Pestan, South of Qarabagh, Asl-e-Qarabagh, Rasmi, and Gerdashkevar). After removing each of the treated samples at the end of the experiment, the samples were examined morphologically (appearance) and compared with the control. The changes were recorded as qualitative traits. To understand the influence of cold stress on reproductive organs, hydrogen peroxide and proline were measured. The results showed the onset of freezing in unopened male catkins at -7 and -9 °C and in inoculated female flowers at -3 °C. Damage to unopened male catkins' tissue occurred at -11 °C and in female flowers at -5 °C. The highest value observed among cultivars in the case for proline content of male catkins was in Mish-Pestan and Khandan cultivars with 0.816 and 0.660 µmol/ g FW, respectively. In inoculated female flowers, Mish-Pestan and Tabestaneh cultivars with 0.185 and 0.168 µmol/ g FW, respectively, showed the highest statistically significant increase in proline content. Interestingly, the cultivars with the highest proline content in male catkins indicated the most increase in H2O2; Mish-Pestan and Khnadan with 0.569 and 0.541 ug/g FW, respectively. Asl-eQarabagh was observed to have the least H2O2 content (0.042 ug/g FW) among cultivars. Again, in inoculated female flowers, those with the highest concentration of proline (Mish-Pestan and Tabestaneh) were found to have the highest H2O2 content (0.335 and 0.331 ug/g FW, respectively","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"47 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80795181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.48141/sbjchem.v28.n29.2020.01_delgado_pgs_01_06.pdf
P. Grima-Gallardo, S. Durán, M. Muñoz, D. P. Rai, Gerzon E. DELGADO
A new phase of the (CuAlSe2)1-x(TaSe)x alloy system was synthesized by the melt and annealing technique and studied by SEM, DTA, and XRPD techniques. Its structure has been refined by the Rietveld method using X-ray powder diffraction data. The new alloy corresponds with the stoichiometry Cu0.4Al0.3TaSe2. This compound crystallizes in the hexagonal space group 𝑃6ത𝑚2 (Nº 187) with a MoS2-type structure, and unit cell parameters a = 3.455(2) Å, c = 13.423(4) Å, V = 138.7(1) Å3, Z =2. The crystal structure is based on the MoS2- type of stacking of TaSe2 layers with a partial ordering of Cu and Al cations over the tetrahedral sites. The powder pattern was composed of 63.1% of the principal phase Cu0.4Al0.3TaSe2 and 29.9% of CuAlSe2, 7.0% of TaSe3, as the secondary phases.
采用熔体和退火技术合成了一种新的(CuAlSe2)1-x(TaSe)x合金体系，并用SEM、DTA和XRPD技术对其进行了研究。利用x射线粉末衍射数据，用Rietveld方法对其结构进行了细化。新合金的化学计量量为Cu0.4Al0.3TaSe2。该化合物在六角形空间群𝑃6𝑚2 (Nº187)中结晶，具有二硫化钼型结构，晶胞参数a = 3.455(2) Å， c = 13.423(4) Å， V = 138.7(1) Å3, Z =2。晶体结构是基于MoS2-型的TaSe2层的堆叠，在四面体位点上有Cu和Al阳离子的部分排序。粉末形貌中，主相Cu0.4Al0.3TaSe2占63.1%，次相CuAlSe2占29.9%，TaSe3占7.0%。
{"title":"(Cu0.4Al0.3)TaSe2: PREPARATION AND CRYSTAL STRUCTURE ANALYSIS FROM X-RAY POWDER DIFFRACTION","authors":"P. Grima-Gallardo, S. Durán, M. Muñoz, D. P. Rai, Gerzon E. DELGADO","doi":"10.48141/sbjchem.v28.n29.2020.01_delgado_pgs_01_06.pdf","DOIUrl":"https://doi.org/10.48141/sbjchem.v28.n29.2020.01_delgado_pgs_01_06.pdf","url":null,"abstract":"A new phase of the (CuAlSe2)1-x(TaSe)x alloy system was synthesized by the melt and annealing technique and studied by SEM, DTA, and XRPD techniques. Its structure has been refined by the Rietveld method using X-ray powder diffraction data. The new alloy corresponds with the stoichiometry Cu0.4Al0.3TaSe2. This compound crystallizes in the hexagonal space group 𝑃6ത𝑚2 (Nº 187) with a MoS2-type structure, and unit cell parameters a = 3.455(2) Å, c = 13.423(4) Å, V = 138.7(1) Å3, Z =2. The crystal structure is based on the MoS2- type of stacking of TaSe2 layers with a partial ordering of Cu and Al cations over the tetrahedral sites. The powder pattern was composed of 63.1% of the principal phase Cu0.4Al0.3TaSe2 and 29.9% of CuAlSe2, 7.0% of TaSe3, as the secondary phases.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79761337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-20DOI: 10.48141/sbjchem.v28.n29.2020.05_ramirez_pgs_37_45.pdf
Jeans W. Ramírez, M. Guillén, G. Delgado
The extraction of naturally occurring compounds is one of the fastest-growing industries because of its benefits against its synthetic analogs. Environmental protection must require the use of natural products instead of chemicals to minimize pollution. Thus, this investigation studies the use of some natural product, as curcumin, as naturally occurring acid‐base indicators. Curcumin can be used as acid-base indicators since it was found that it possesses pH-dependent solubility. Curcumin, the major active component of turmeric, Curcuma longa (Zingiberaceae), is used as a spice in curry and as a coloring agent in yellow mustards, cosmetics, pharmaceuticals, and hair dyes. In this research, the main compound colored rhizome of turmeric (Curcuma longa) cultivated in Mérida, Venezuela, is extracted: Curcumin (C21H20O6) (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione, in a yield of 3.42% after 8 hours of extraction using soxhlet extractor system with organic solvents (hexane and ethanol). The thin-layer chromatography and column performed separation and purification using a mobile phase, a mixture of chloroform-hexane 3:2. The dye was characterized by spectroscopic analysis of visible ultraviolet (UV-Vis) and infrared (IR), in addition to his studio in steering sensitivity as an acid-base indicator. This dye is useful as an acid-base indicator in strong acid-strong base volumes and did not require large amounts of it as it has high sensitivity. The results indicate that curcumin as an acid-base indicator allows the development of new standards in different chemistry fields that require this type of analysis.
{"title":"EXTRACTION AND CHARACTERIZATION OF CURCUMIN FROM TURMERIC RHIZOMES GROWN IN MÉRIDA, VENEZUELA","authors":"Jeans W. Ramírez, M. Guillén, G. Delgado","doi":"10.48141/sbjchem.v28.n29.2020.05_ramirez_pgs_37_45.pdf","DOIUrl":"https://doi.org/10.48141/sbjchem.v28.n29.2020.05_ramirez_pgs_37_45.pdf","url":null,"abstract":"The extraction of naturally occurring compounds is one of the fastest-growing industries because of its benefits against its synthetic analogs. Environmental protection must require the use of natural products instead of chemicals to minimize pollution. Thus, this investigation studies the use of some natural product, as curcumin, as naturally occurring acid‐base indicators. Curcumin can be used as acid-base indicators since it was found that it possesses pH-dependent solubility. Curcumin, the major active component of turmeric, Curcuma longa (Zingiberaceae), is used as a spice in curry and as a coloring agent in yellow mustards, cosmetics, pharmaceuticals, and hair dyes. In this research, the main compound colored rhizome of turmeric (Curcuma longa) cultivated in Mérida, Venezuela, is extracted: Curcumin (C21H20O6) (1E,6E)-1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione, in a yield of 3.42% after 8 hours of extraction using soxhlet extractor system with organic solvents (hexane and ethanol). The thin-layer chromatography and column performed separation and purification using a mobile phase, a mixture of chloroform-hexane 3:2. The dye was characterized by spectroscopic analysis of visible ultraviolet (UV-Vis) and infrared (IR), in addition to his studio in steering sensitivity as an acid-base indicator. This dye is useful as an acid-base indicator in strong acid-strong base volumes and did not require large amounts of it as it has high sensitivity. The results indicate that curcumin as an acid-base indicator allows the development of new standards in different chemistry fields that require this type of analysis.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89283288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.48141/SBJCHEM.V28.N28.2020.02_VOSTRIKOVA_PGS_10_16.PDF
T. Vostrikova, V. Kalaev, S. Medvedeva, I. Ledeneva, K. Shikhaliev
It is investigated the effect of synthesized organic compounds of 6-hydroxy-2,2,4-trimethyl-1,2- dihydroquinoline, its derivatives, and hydrogenated analogs. These compounds affected the height of seedlings when they were used for pre-sowing seed treatment of the following ornamental plants: annual ornamental grass – scarlet sage (Salvia splendens) and woody plant – yellow rhododendron (Rhododendron luteum). Prior to the sprouting process, the seeds of Rh. luteum and S. splendens were soaked in water solutions of compounds with concentrations of 0.01%, 0.05%, and 0.1% for 18 hours. Dihydro- and tetrahydroquinolines with a concentration of 0.05% proved to be the most effective for both plants. For Rhododendron luteum, the compounds of 6-hydroxy-2,2,4-trimethyl-1,2-dihydroquinoline, its derivatives, and hydrogenated analogs with a concentration of 0.1% proved to be the most effective. Dihydroquinolines at concentrations of 0.05 and 0.1% proved to have the strongest effect when applied to the studied perennial woody plant (Rhododendron luteum). Dihydroquinoline at the concentration of 0.05% also proved to be effective when applied to the annual grass (Salvia splendens). For annual S. splendens, tetrahydroquinoline at concentrations of 0.01 and 0.05% appeared to be the most effective. The pre-sowing seed treatment of grass Salvia splendens and woody plant Rhododendron luteum with the studied compounds demonstrated that their effect on the height of the seedlings is species-specific. The pre-sowing seed treatment of Rh. luteum and S. splendens allows increasing the height of the seedlings by 3-61 % and 17-25 %, respectively. It is suggested using the compounds of 6-hydroxy-2,2,4- trimethyl-1,2-dihydroquinoline, its derivatives, and hydrogenated analogs as effective growth stimulators for ornamental grasses and woody plants.
{"title":"QUINOLINE DERIVATIVES AS GROWTH REGULATORS FOR ORNAMENTAL PLANTS","authors":"T. Vostrikova, V. Kalaev, S. Medvedeva, I. Ledeneva, K. Shikhaliev","doi":"10.48141/SBJCHEM.V28.N28.2020.02_VOSTRIKOVA_PGS_10_16.PDF","DOIUrl":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.02_VOSTRIKOVA_PGS_10_16.PDF","url":null,"abstract":"It is investigated the effect of synthesized organic compounds of 6-hydroxy-2,2,4-trimethyl-1,2- dihydroquinoline, its derivatives, and hydrogenated analogs. These compounds affected the height of seedlings when they were used for pre-sowing seed treatment of the following ornamental plants: annual ornamental grass – scarlet sage (Salvia splendens) and woody plant – yellow rhododendron (Rhododendron luteum). Prior to the sprouting process, the seeds of Rh. luteum and S. splendens were soaked in water solutions of compounds with concentrations of 0.01%, 0.05%, and 0.1% for 18 hours. Dihydro- and tetrahydroquinolines with a concentration of 0.05% proved to be the most effective for both plants. For Rhododendron luteum, the compounds of 6-hydroxy-2,2,4-trimethyl-1,2-dihydroquinoline, its derivatives, and hydrogenated analogs with a concentration of 0.1% proved to be the most effective. Dihydroquinolines at concentrations of 0.05 and 0.1% proved to have the strongest effect when applied to the studied perennial woody plant (Rhododendron luteum). Dihydroquinoline at the concentration of 0.05% also proved to be effective when applied to the annual grass (Salvia splendens). For annual S. splendens, tetrahydroquinoline at concentrations of 0.01 and 0.05% appeared to be the most effective. The pre-sowing seed treatment of grass Salvia splendens and woody plant Rhododendron luteum with the studied compounds demonstrated that their effect on the height of the seedlings is species-specific. The pre-sowing seed treatment of Rh. luteum and S. splendens allows increasing the height of the seedlings by 3-61 % and 17-25 %, respectively. It is suggested using the compounds of 6-hydroxy-2,2,4- trimethyl-1,2-dihydroquinoline, its derivatives, and hydrogenated analogs as effective growth stimulators for ornamental grasses and woody plants.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"99 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80731487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.48141/SBJCHEM.V28.N28.2020.04_OKAB_PGS_22_33.PDF
Alaa Abood Yasir Okab, M. Salih
Escherichia coli (E. coli) is the most common type of pathogen that causes Urinary tract infection disease. It can be presented as a pathogenic or non-pathogenic strain and found not only in the animal but also in the human intestine. This bacterium can cause opportunistic infection when the human host comprised of thalassemia patients or changes the healthy hemostatic flora. This study aimed to analyze the presence of bacteria in thalassemia patients with urinary tract infection. A total of 303 samples were collected during the period from August 2019 to January 2020 from thalassemia patients who suffered from urinary tract infection. The results showed that there were 6.9% of patients infected with E. coli, 2.6% of patients were infected with S. aureus, 0.7% with both Proteus and Klebsiella, while 89.1% of patients had a negative sample for bacteria. Also, the incidence of urinary tract infections in females is higher than in males. Besides, its occurrence in rural areas is higher than in city residents. Moreover, among 16 antibiotics tested to sensitize bacteria to antibiotics, Imipenem showed 100% efficacy on all isolated bacteria. In contrast, Netilmicin showed 80.1% efficacy, Gentamycin 80.1%, and Amikacin 76.2%. Ampicillin, Aztreonam, Amoxicillin-Clavulanic Acid, Tetracycline, and Ticarcillin-Clavulanic Acid, did not show any effectiveness toward the bacteria while other antibiotics showed different activities. Furthermore, the isolated microbes from thalassemia patients were the highest resistance to antibiotics in comparison with other studies, and this antibiotic-resistant may be due to the weakening of the patient's immune status and frequent blood taking and the antibodies it contains.
{"title":"ANTIBIOTIC SUSCEPTIBILITY OF ESCHERICHIA COLI ISOLATE FROM URINARY TRACT INFECTION OF THALASSEMIC PATIENTS IN THI-QAR PROVINCE","authors":"Alaa Abood Yasir Okab, M. Salih","doi":"10.48141/SBJCHEM.V28.N28.2020.04_OKAB_PGS_22_33.PDF","DOIUrl":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.04_OKAB_PGS_22_33.PDF","url":null,"abstract":"Escherichia coli (E. coli) is the most common type of pathogen that causes Urinary tract infection disease. It can be presented as a pathogenic or non-pathogenic strain and found not only in the animal but also in the human intestine. This bacterium can cause opportunistic infection when the human host comprised of thalassemia patients or changes the healthy hemostatic flora. This study aimed to analyze the presence of bacteria in thalassemia patients with urinary tract infection. A total of 303 samples were collected during the period from August 2019 to January 2020 from thalassemia patients who suffered from urinary tract infection. The results showed that there were 6.9% of patients infected with E. coli, 2.6% of patients were infected with S. aureus, 0.7% with both Proteus and Klebsiella, while 89.1% of patients had a negative sample for bacteria. Also, the incidence of urinary tract infections in females is higher than in males. Besides, its occurrence in rural areas is higher than in city residents. Moreover, among 16 antibiotics tested to sensitize bacteria to antibiotics, Imipenem showed 100% efficacy on all isolated bacteria. In contrast, Netilmicin showed 80.1% efficacy, Gentamycin 80.1%, and Amikacin 76.2%. Ampicillin, Aztreonam, Amoxicillin-Clavulanic Acid, Tetracycline, and Ticarcillin-Clavulanic Acid, did not show any effectiveness toward the bacteria while other antibiotics showed different activities. Furthermore, the isolated microbes from thalassemia patients were the highest resistance to antibiotics in comparison with other studies, and this antibiotic-resistant may be due to the weakening of the patient's immune status and frequent blood taking and the antibodies it contains.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"94 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78252690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.37633/sbjc.28(28)2020
{"title":"Southern Brazilian Journal of Chemistry, Volume 28, No. 28, 2020","authors":"","doi":"10.37633/sbjc.28(28)2020","DOIUrl":"https://doi.org/10.37633/sbjc.28(28)2020","url":null,"abstract":"","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"39 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82547137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.48141/SBJCHEM.V28.N28.2020.06_VOSTRIKOVA_PGS_40_44.PDF
T. Vostrikova, V. Kalaev, A. Potapov, Dmitry Yu Vandyshev, K. Shikhaliev
The pre-sowing treatment of scarlet sage (Salvia splendens Ker Gawl.) seeds with 4-methyl-2-piperidin1-yl-pyrimidine-5-carboxylic acid at concentrations of 0.01, 0.05, and 0.1% proved to have an obvious inhibiting effect. Prior to sowing, the seeds of Salvia splendens were soaked in a water suspension of 4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid and 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid with concentrations of 0.01%, 0.05%, and 0.1% for 18 hours. On the 42nd day of the experiment, the seedlings, having been preliminarily hardened for 12 days, were removed from the greenhouse and planted on the field. The pre-sowing treatment of Salvia splendens seeds with 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid proved to have the inhibiting effect at concentrations of 0.01 and 0.05%. The height of the seedlings decreased by 13.3-43.7%. It was revealed that 4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid at concentrations of 0.01, 0.05, and 0.1% decreased the growth of the seedlings by 30.4-43.7%, and 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid at concentrations of 0.01 and 0.05% decreased the growth of the seedlings by 13.3-22.2%. By contrast, the effect of pyrimidinecarboxylic acids on seed germination and plant height of another annual flower – spreading marigold (Tagetes patula L.) was stimulating. It was investigated some different concentrations from 0.01 to 0.05 %. The same concentrations of identical compounds were tested, but effects from them were opposite for Tagetes patula, and Salvia splendens seedlings. Сonsequently, the species-specific effect of pyrimidinecarboxylic acids on seed germination and plant height for ornamental grasses takes place. Therefore,4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid and 4-methyl-2-morpholin4-pyrimidine-5-carboxylic acid are recommended as growth retardants for Salvia splendens.
{"title":"USING SYNTHESISED ORGANIC COMPOUNDS AS ENVIRONMENTALLY FRIENDLY RETARDANTS FOR ORNAMENTAL PLANTS","authors":"T. Vostrikova, V. Kalaev, A. Potapov, Dmitry Yu Vandyshev, K. Shikhaliev","doi":"10.48141/SBJCHEM.V28.N28.2020.06_VOSTRIKOVA_PGS_40_44.PDF","DOIUrl":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.06_VOSTRIKOVA_PGS_40_44.PDF","url":null,"abstract":"The pre-sowing treatment of scarlet sage (Salvia splendens Ker Gawl.) seeds with 4-methyl-2-piperidin1-yl-pyrimidine-5-carboxylic acid at concentrations of 0.01, 0.05, and 0.1% proved to have an obvious inhibiting effect. Prior to sowing, the seeds of Salvia splendens were soaked in a water suspension of 4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid and 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid with concentrations of 0.01%, 0.05%, and 0.1% for 18 hours. On the 42nd day of the experiment, the seedlings, having been preliminarily hardened for 12 days, were removed from the greenhouse and planted on the field. The pre-sowing treatment of Salvia splendens seeds with 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid proved to have the inhibiting effect at concentrations of 0.01 and 0.05%. The height of the seedlings decreased by 13.3-43.7%. It was revealed that 4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid at concentrations of 0.01, 0.05, and 0.1% decreased the growth of the seedlings by 30.4-43.7%, and 4-methyl-2-morpholin-4-pyrimidine-5-carboxylic acid at concentrations of 0.01 and 0.05% decreased the growth of the seedlings by 13.3-22.2%. By contrast, the effect of pyrimidinecarboxylic acids on seed germination and plant height of another annual flower – spreading marigold (Tagetes patula L.) was stimulating. It was investigated some different concentrations from 0.01 to 0.05 %. The same concentrations of identical compounds were tested, but effects from them were opposite for Tagetes patula, and Salvia splendens seedlings. Сonsequently, the species-specific effect of pyrimidinecarboxylic acids on seed germination and plant height for ornamental grasses takes place. Therefore,4-methyl-2-piperidin-1-yl-pyrimidine-5-carboxylic acid and 4-methyl-2-morpholin4-pyrimidine-5-carboxylic acid are recommended as growth retardants for Salvia splendens.","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"37 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73412168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.48141/SBJCHEM.V28.N28.2020.07_ROYES_PGS_46_52.PDF
D. Alshayban, Royes Joseph, Jisha M. Lucca, Fatimah Aljishi, Yara Alsadiq
Prescription and non-prescription medication misuse or abuse is a global problem that has a negative impact on all human life aspects, including health, social, economic, and security status. According to the United Nations Office on Drug and Crime reports, over 5% of adult people used drugs at least once in the year 2015, and 29.5 million of them were suffered from the consequences of inappropriate use of drugs. Information on the knowledge and perception among pharmacists regarding the misuse and abuse medications in Saudi Arabia are limited, and therefore, a study was conducted among pharmacy staff to assess their knowledge and awareness on drug misuse and abuse. A cross-sectional study was carried out in Eastern Province, Saudi Arabia. Pharmacy professionals with more than three months of experience were included in the study. A structured questionnaire was used to obtain the participant’s responses. A Chi-square test was used to evaluate the association of sociodemographic factors with the participant's responses. Ninety pharmacy professionals were responded. Overall, 69 (76.7%) participants agreed that misuse and abuse are two different terms. In addition, the study showed different responses for patients who suspected to be medication abusers. In conclusion, this study provides an initial picture of pharmacy staffs’ knowledge and opinion regarding the misuse and abuse of medicines in Saudi Arabia. Participants’ reactions toward such behaviors were different and not consistent. Therefore, there should be a clear policy to define the role of the pharmacy staff toward the misuse and abuse of medication in Saudi Arabia
{"title":"Misuse and Abuse of Drugs: a Cross-Sectional Survey Among Pharmacy Professionals in Saudi Arabia","authors":"D. Alshayban, Royes Joseph, Jisha M. Lucca, Fatimah Aljishi, Yara Alsadiq","doi":"10.48141/SBJCHEM.V28.N28.2020.07_ROYES_PGS_46_52.PDF","DOIUrl":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.07_ROYES_PGS_46_52.PDF","url":null,"abstract":"Prescription and non-prescription medication misuse or abuse is a global problem that has a negative impact on all human life aspects, including health, social, economic, and security status. According to the United Nations Office on Drug and Crime reports, over 5% of adult people used drugs at least once in the year 2015, and 29.5 million of them were suffered from the consequences of inappropriate use of drugs. Information on the knowledge and perception among pharmacists regarding the misuse and abuse medications in Saudi Arabia are limited, and therefore, a study was conducted among pharmacy staff to assess their knowledge and awareness on drug misuse and abuse. A cross-sectional study was carried out in Eastern Province, Saudi Arabia. Pharmacy professionals with more than three months of experience were included in the study. A structured questionnaire was used to obtain the participant’s responses. A Chi-square test was used to evaluate the association of sociodemographic factors with the participant's responses. Ninety pharmacy professionals were responded. Overall, 69 (76.7%) participants agreed that misuse and abuse are two different terms. In addition, the study showed different responses for patients who suspected to be medication abusers. In conclusion, this study provides an initial picture of pharmacy staffs’ knowledge and opinion regarding the misuse and abuse of medicines in Saudi Arabia. Participants’ reactions toward such behaviors were different and not consistent. Therefore, there should be a clear policy to define the role of the pharmacy staff toward the misuse and abuse of medication in Saudi Arabia","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90377298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-20DOI: 10.48141/SBJCHEM.V28.N28.2020.03_GHAFIYEHSANJ_PGS_17_21.PDF
Elham Ghafiyehsanj, Kamaladdin Dilmaghani, Nader Chaparzade, S. Saadatmand
In order to investigate the antioxidant activity of Salvia nemorosa L. collected from Ahar and Urmia regions in Iran at different growth stages, aerial parts of sage after collecting were dried, and for measurement, the ability of scavenge DPPH (2,2-diphenyl-1-picryl-hydrazyl-hydrate) radical in different concentrations (0.025, 0.05, 0.07, 0.1, 0.2, 0.04 and 0.6) of methanolic extracts were prepared. The result showed that the ability to scavenge DPPH radical and amount of inhibition percent of vegetative stage leaves, flowering stage leaves, and flowers increased with increasing concentrations of methanolic extracts from 0.25 to 0.6 mg/ml. In the region of Urmia, the highest amount of DPPH inhibition there was in vegetative stage leaves, and the lowest amount of DPPH inhibition was seen in flowers. In Ahar regions, unlike the Urmia region, the highest amount of DPPH inhibition there was in flowers, but the lowest of DPPH inhibition was seen in flowering stage leaves. Also, the content of inhibition of DPPH in Ahar and Urmia regions similarly increased between two phenological stages (vegetative stage leaves, flowering stage leaves, and flowers) in 0.4 mg/ml and 0.6 mg/ml concentrations
{"title":"Comparative Study on Antioxidant Activity of Salvia Nemorosa L. From Two Different Locations","authors":"Elham Ghafiyehsanj, Kamaladdin Dilmaghani, Nader Chaparzade, S. Saadatmand","doi":"10.48141/SBJCHEM.V28.N28.2020.03_GHAFIYEHSANJ_PGS_17_21.PDF","DOIUrl":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.03_GHAFIYEHSANJ_PGS_17_21.PDF","url":null,"abstract":"In order to investigate the antioxidant activity of Salvia nemorosa L. collected from Ahar and Urmia regions in Iran at different growth stages, aerial parts of sage after collecting were dried, and for measurement, the ability of scavenge DPPH (2,2-diphenyl-1-picryl-hydrazyl-hydrate) radical in different concentrations (0.025, 0.05, 0.07, 0.1, 0.2, 0.04 and 0.6) of methanolic extracts were prepared. The result showed that the ability to scavenge DPPH radical and amount of inhibition percent of vegetative stage leaves, flowering stage leaves, and flowers increased with increasing concentrations of methanolic extracts from 0.25 to 0.6 mg/ml. In the region of Urmia, the highest amount of DPPH inhibition there was in vegetative stage leaves, and the lowest amount of DPPH inhibition was seen in flowers. In Ahar regions, unlike the Urmia region, the highest amount of DPPH inhibition there was in flowers, but the lowest of DPPH inhibition was seen in flowering stage leaves. Also, the content of inhibition of DPPH in Ahar and Urmia regions similarly increased between two phenological stages (vegetative stage leaves, flowering stage leaves, and flowers) in 0.4 mg/ml and 0.6 mg/ml concentrations","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":"103 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80646506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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