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Substantiation of a method for producing sugar during deep processing of beet molasses 甜菜糖蜜深加工过程中制糖方法的证实
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-58-65
N. G. Kulneva, P. Y. Surin, V. A. Fedoruk, N. A. Matvienko
When processing sugar beets, the final waste is formed - molasses containing sucrose and other compounds. Under the conditions of traditional technology, further extraction of sucrose from molasses is difficult. The technology of deep processing of molasses using chromatographic separation (desugarization) has been developed and implemented, which allows additional extraction of sucrose. The resulting extract requires further processing at sugar factories. This article is devoted to the choice of a method for processing the extract under the conditions of sugar production. Various options for processing the extract are considered: after the completion of the processing of sugar beet and during the joint processing of beet and extract. You can send molasses to a desugarization station once, work with a partial return of molasses, or carry out continuous processing of molasses obtained in the crystallization department of a sugar refinery by desugarization. Each processing option has its own advantages and disadvantages. The performed numerical analysis shows that processing the extract with a second pass stage will lead to the maximum total sugar recovery. The second most efficient is endless recycling. An improvement over endless recycling in the molasses recycling process is achieved by optimizing the separator settings due to the consistent quality of the processed feed. Endless processing leads to the accumulation of non-sugars, which destabilizes the quality of the molasses and makes it difficult to set up the separator.
当加工甜菜时,最终的废物形成-糖蜜含有蔗糖和其他化合物。在传统工艺条件下,糖蜜中蔗糖的进一步提取是困难的。开发并实现了糖蜜色谱分离(脱糖)深加工技术,该技术允许额外提取蔗糖。得到的提取物需要在糖厂进一步加工。本文研究了在制糖条件下,提取液加工方法的选择。考虑了加工提取物的各种选择:在甜菜加工完成后和在甜菜和提取物的联合加工期间。您可以将糖蜜一次性送到糖蜜站,使用部分返回的糖蜜,或者将糖蜜在糖厂的结晶部通过糖蜜进行连续加工。每种处理方法都有其优缺点。数值分析表明,采用第二道工序处理提取液可获得最大的总糖回收率。第二个最有效的方法是无限循环利用。在糖蜜回收过程中,由于加工饲料的质量一致,通过优化分离器设置,实现了对无限回收的改进。没完没了的加工会导致非糖的积累,这会破坏糖蜜的质量,使分离器的设置变得困难。
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引用次数: 0
The impact of processing on hemp seeds protein complex 加工对大麻籽蛋白复合物的影响
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-66-72
V. I. Uschapovsky, A. A. Goncharova, I. E. Minevich
Recently, commercial hemp seeds, Cannabis sativa L., have attracted considerable interest in nutritional and industrial research due to their high nutritional value and good digestibility. Hemp seeds are becoming a new source of vegetable protein and the necessary components for maintaining health due to the rich content of protein compounds, vitamins, and unsaturated fatty acids. The effect of processing on the protein complex of low THC hemp seeds was studied in the current study. Standard methods of analysis (determination of protein, fat, moisture) and special methods (determination of the ratio of protein fractions of hemp seeds and products of their processing) were applied in the work. The objects of study were hemp seeds (Surskaya variety) and products of their de-oiling by mechanical and chemical methods. The globulin fraction predominance in the original hemp seeds (69.44%) and in the product obtained by hemp seeds de-oiling with hexane (fine fraction of meal, 80.94%) was revealed. Glutelin fraction (38.98%) prevailed in hemp seed flour obtained by cold pressing. After the hemp seeds processing (pressing, extraction), the ratio of protein fractions (albumin, globulin and glutelin) in the resulting products changed: meal (1:3.2:3.2), fine fraction (0.1:4.7:1) and flour (1.1:1:1.4), in comparison with the initial raw material (1:2.5:0.1). A significant increase in the glutelin fraction: from 2.78 to 43.10 and 38.98%, by mechanical and chemical methods, respectively, and a decrease in the amount of water- and salt-soluble fractions were observed with all processing methods. Researches of the study of the ratio of oilseeds protein fractions are of practical importance for improving healthy foods quality.
最近,商业大麻种子(Cannabis sativa L.)因其高营养价值和良好的消化性而引起了人们对营养和工业研究的极大兴趣。大麻籽因其丰富的蛋白质化合物、维生素和不饱和脂肪酸,正成为植物蛋白的新来源和维持健康的必要成分。本研究研究了加工对低THC大麻种子蛋白质复合物的影响。采用标准分析方法(测定蛋白质、脂肪和水分)和特殊方法(测定大麻种子及其加工产品的蛋白质组分的比例)。以麻籽(Surskaya)及其机械和化学脱油产品为研究对象。结果表明,原麻籽中球蛋白含量最高(69.44%),经正己烷脱油后的麻籽中球蛋白含量最高(粗粉细分,80.94%)。冷榨麻籽粉中谷蛋白含量最高,为38.98%。麻籽加工(压榨、提取)后,所得产品中蛋白质组分(白蛋白、球蛋白、谷蛋白)的比例为:粗粉(1:32 .2 .2 .2)、细粉(0.1:47 .7 .1)、面粉(1.1:1:1.4 .4),与初始原料(1:25 .5 .1)相比发生了变化。机械法和化学法处理后的谷蛋白含量分别从2.78%提高到43.10%和38.98%,水溶性和盐溶性含量均有所下降。油籽蛋白质组分比例的研究对提高健康食品质量具有重要的现实意义。
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引用次数: 0
Functionalized styrene-butadiene copolymers based on improved metal-alcoholate systems 基于改进金属-醇体系的功能化丁苯共聚物
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2021-4-302-307
A. Firsova, A. Kharitonov, O. Karmanova, A. S. Lynova
A method for preparing functionalized styrene-butadiene copolymers on a new initiating system, which is a modifier consisting of a mixed sodium-calcium alkoxide of oxypropylated aniline dissolved in ?-methylstyrene and n-butyllithium has been developed. It was revealed that the lowered content of calcium ions makes it possible to obtain a modifier without colloidal fine-dispersed sludge, which negatively affects the operation of equipment in the industrial production of rubbers. The high initiation activity on lithium amides promoted a high conversion of monomers and a good stereoregulating ability of the 1.2-unit content of the butadiene part of the copolymer macromolecule, amounting to 66-68 wt%. The addition of a reactive compound to the end of the "living" polymer chain, stannous tetrachloride, improves the technological properties estimated by the Mooney viscosity, which increased by 5 units. It was shown on the example of prototypes of rubber mixtures, the polymer base of which was functionalized styrene-butadiene rubbers, that they are characterized by a sufficiently high rate of vulcanization, and in terms of technological, elastic and strength properties, the samples are identical with the foreign analogue NS-616, in terms of abrasion resistance they surpass the imported analogue by 20%, in resistance to crack growth by 36% was shown. The rubber mixture based on functionalized rubber was characterized by better adhesion on ice. The use of functionalized rubbers instead of serial rubber has little effect on tire rolling losses. A slight decrease in tan ? values at 0 °C for rubbers based on functionalized rubbers was noted, which can be compensated for by adjusting their microstructure and requires additional research.
提出了一种以氧丙基苯胺与甲基苯乙烯和正丁基锂混合钠钙醇氧盐为引发剂的新引发体系制备功能化丁苯共聚物的方法。研究表明,钙离子含量的降低使改性剂不存在胶体细分散污泥成为可能,这对橡胶工业生产中设备的运行产生了不利影响。在锂酰胺上的高引发活性促进了单体的高转化率和共聚物大分子中1.2单位含量的丁二烯部分的良好立体调节能力,达到66-68 wt%。在“活的”聚合物链的末端添加活性化合物四氯化亚锡,提高了根据穆尼粘度估计的工艺性能,提高了5个单位。以官能化丁苯橡胶为基体的混联橡胶样品具有足够高的硫化率,在工艺性能、弹性性能和强度性能上均与国外类似物NS-616相同,耐磨性比进口类似物NS-616高20%,抗裂纹扩展性能比进口类似物NS-616高36%。基于功能化橡胶的混炼胶具有较好的冰上粘附性。用功能化橡胶代替系列橡胶对轮胎滚动损失影响不大。肤色略有下降?基于功能化橡胶的橡胶在0°C时的值被注意到,这可以通过调整其微观结构来补偿,需要进一步的研究。
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引用次数: 0
Assessment of the influence of alimentary biocorrectors on the energy efficiency of the nutritional status of adolescent children 评价消化道生物矫正剂对青少年儿童营养状况能量利用效率的影响
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2021-4-57-62
L. A. Albycheva
An assessment of the increase in the efficiency of gas exchange was carried out on the example of students of an engineering university with the daily use of an additive containing food components with known bio-correcting properties: flour of wheat germ cake Ц 45%, sprouted chickpea seeds Ц 15%, dried leaves of japanese kelp Ц 5%, a component of animal origin in the form of whey protein concentrate Ц 35%. The change in the energy efficiency of the nutritional status was assessed based on the analysis of the concentration of carbon dioxide (CO2) and oxygen (O2) in the exhaled gas mixture and the level of hemoglobin oxygenation (SpO2), the values ??of which were recorded before and after daily consumption of the test products for 30 days. The study group of patients consisted of volunteers among first-year students of the Voronezh State University of Engineering Technologies - boys and girls aged 17-18 years. In the course of experimental studies, the subjects showed an increase in the SpO2 level by 0,83% and CO2 by 4,06%, as well as a decrease in the O2 concentration by 2,62% in the exhaled gas mixture. The data obtained indicate an increase in the level of oxygenated hemoglobin in the subjects' blood, accompanied by a shift in the active blood reaction (pH) towards an alkaline medium, which occurs between the alveolar air and the blood of the pulmonary veins and capillaries due to the diffusion of CO2 through the alveolar membrane. An increase in the concentration of CO2 in exhaled air is accompanied by an increase in the efficiency of O2 transport, and also prevents the formation of erythrocyte complexes as a result of changes in the physicochemical properties of the membrane. The data obtained make it possible to state the possibility of an active alimentary effect on the efficiency of gas exchange, and prove the antihypoxant properties of the enrichment additive. The reliability of the experimental data was assessed using the Mann-Whitney test, which confirmed the presence of a positive effect of the components of the enrichment supplement on the human body. The results of the work convincingly prove the role of alimentary factors in increasing the efficiency of the most important functions of the body of adolescents of the older age group, regardless of gender, which naturally leads to an increase in the body's resistance to changes in external and internal influences. The data obtained in the course of research indicate the possibility of classifying the components of the supplement as alimentary biocorrectors that ensure the effectiveness of the process of energy metabolism of the body in adolescents.
以一所工程大学的学生为例,对气体交换效率的提高进行了评估,每天使用一种含有已知生物校正特性的食品成分的添加剂:小麦胚芽蛋糕面粉Ц 45%,鹰嘴豆发芽Ц 15%,日本海带干叶Ц 5%,乳清蛋白浓缩物形式的动物成分Ц 35%。通过对呼出混合气中二氧化碳(CO2)和氧气(O2)浓度及血红蛋白氧合(SpO2)水平的分析,评价营养状态能量效率的变化情况。其中记录每日食用试验产品前后30天。患者研究组由沃罗涅日国立工程技术大学的一年级学生志愿者组成——年龄在17-18岁的男孩和女孩。在实验研究过程中,受试者的SpO2浓度增加了0.83%,CO2浓度增加了4,06%,呼出气体混合物中的O2浓度下降了2,62%。所获得的数据表明,受试者血液中的含氧血红蛋白水平增加,同时由于二氧化碳通过肺泡膜扩散,肺静脉和毛细血管的血液与肺泡空气之间的活性血液反应(pH)向碱性介质转移。呼出空气中CO2浓度的增加伴随着O2运输效率的提高,并且由于膜的物理化学性质的变化,也阻止了红细胞复合物的形成。所获得的数据可以说明食物对气体交换效率的积极影响的可能性,并证明了富集添加剂的抗缺氧性能。使用曼-惠特尼试验对实验数据的可靠性进行了评估,证实了浓缩补充剂的成分对人体的积极作用。这项工作的结果令人信服地证明,无论性别如何,饮食因素在提高老年群体青少年身体最重要功能效率方面的作用,自然导致身体对外部和内部影响变化的抵抗力增强。在研究过程中获得的数据表明,有可能将补充剂的成分分类为营养生物矫正剂,以确保青少年身体能量代谢过程的有效性。
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引用次数: 0
Use of object-oriented simulation in solving issues of optimal enterprise management 利用面向对象的仿真方法解决企业最优管理问题
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-288-294
M. Lapshina, O. Lukina, D. D. Lapshin
Modern scientific research in economics cannot be imagined without the use of economic and mathematical models and their subsequent analysis. Foreign economic literature contains a significant proportion of articles of both theoretical and applied nature, dominated by mathematical models used to substantiate the assumptions made and the most accurate calculation of economic efficiency. A number of economists very convincingly confirm that the recognition of any theoretical study of an economic nature is determined by the measure of the mathematical formalization of the problem, the adequacy of the mathematical apparatus used and the effectiveness of the final results obtained as a result of the study. In this regard, the article discusses the urgent problem of developing a mathematical model of optimal enterprise management. The authors propose an approach to the selection of the most appropriate modeling, taking into account the restrictions imposed on the boundary states of the system that describes the economic component of the enterprise. The use of classical mathematical approaches with their subsequent adaptation to modern conditions is given and substantiated..
现代经济学的科学研究离不开经济和数学模型及其后续分析的使用。国外经济文献包含了相当大比例的理论和应用性质的文章,主要是用于证实所作假设和最准确的经济效率计算的数学模型。许多经济学家非常令人信服地证实,任何具有经济性质的理论研究的认可都是由问题的数学形式化程度、所使用的数学工具的充分性以及作为研究结果获得的最终结果的有效性来决定的。为此,本文讨论了建立企业最优管理数学模型的迫切问题。作者提出了一种选择最合适模型的方法,考虑到对描述企业经济组成部分的系统的边界状态施加的限制。经典数学方法的使用及其随后对现代条件的适应是给出和证实的。
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引用次数: 2
Investigation of the properties of synthetic and biodegradable polymers, with a view to the possibility of their use in the food industry 研究合成和可生物降解聚合物的性能,着眼于它们在食品工业中应用的可能性
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-245-251
O. Ershova, E. Mullina, J. A. Bessonova, K. V. Bagreeva
The article deals with the actual problem of environmental friendliness of packaging materials used in the food industry. The aim of the work was to study the physical and mechanical characteristics of biodegradable and synthetic polymers, with the aim of updating the replacement of synthetic packaging materials with more environmentally friendly materials. The article discusses the main characteristics of innovative biodegradable materials based on polylactides (PLA). A comparative analysis of the strength and sorption properties of both biodegradable and synthetic polymeric materials is presented. A comparative analysis of the materials under study was carried out according to the following parameters: water absorption, puncture resistance, deformation-strength and thermophysical characteristics. The paper also presents the results of a study of the water-absorbing capacity of the analyzed polymeric materials. The results of tests are presented, which make it possible to establish the temperature-time parameters of the processing of polylactide by the melt method. The data obtained by the DSC method on the establishment of relaxation and phase transitions that occur in the polymer during thermolysis are analyzed. During the experiment, experimental studies of the chemical properties of biodegradable materials based on polylactides (PLA), made in China were carried out. The main advantages and disadvantages of synthetic and natural polymeric materials are considered. In addition, the paper analyzes the environmental aspects of the practical application of the studied polymeric materials. Conclusions are formulated about the possibility and safety of using the presented materials in various branches of the food industry. Based on the results of the experiment, it was found that synthetic polymer materials slightly exceed biopolymer materials in terms of the investigated physical and mechanical parameters, however, given the environmental friendliness and the possibility of complete utilization in natural conditions, this fact does not reduce the relevance of using biopolymers in the food industry. In addition, the analysis of data on the chemical composition of the studied biopolymers based on polylactides (PLA) showed that the decrease in the strength parameters of the presented samples can be neutralized by introducing modifying strengthening and hydrophobizing additives.
本文论述了食品工业中包装材料环境友好的实际问题。这项工作的目的是研究生物可降解和合成聚合物的物理和机械特性,目的是更新用更环保的材料替代合成包装材料。本文讨论了新型聚乳酸基生物降解材料的主要特点。对生物可降解材料和合成高分子材料的强度和吸附性能进行了比较分析。根据吸水率、抗穿刺性、变形强度和热物理特性等参数对所研究材料进行了对比分析。本文还介绍了所分析的高分子材料吸水性能的研究结果。给出了试验结果,为建立熔体法制备聚乳酸的温度-时间参数提供了可能。用DSC法对聚合物在热裂解过程中发生的弛豫和相变进行了分析。在实验过程中,对国产聚乳酸(PLA)可生物降解材料的化学性能进行了实验研究。分析了合成高分子材料和天然高分子材料的主要优缺点。此外,本文还对所研究的高分子材料在实际应用中的环境问题进行了分析。结论是关于在食品工业的各个分支中使用所提出的材料的可能性和安全性。根据实验结果,合成高分子材料在所研究的物理和机械参数方面略高于生物高分子材料,然而,考虑到环境友好性和在自然条件下完全利用的可能性,这一事实并不会降低生物高分子材料在食品工业中使用的相关性。此外,对聚乳酸(PLA)生物聚合物的化学成分分析表明,通过引入改性增强剂和疏水性添加剂,可以抵消样品强度参数的下降。
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引用次数: 0
The analysis and research of the composition a protein-vitamins product from plant materials 植物性维生素蛋白制品的成分分析与研究
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-49-57
V. A. Khanturgaeva, I. V. Hamaganova
According to a new report from the Food and Agriculture Organization of the United Nations (FAO), there is a problem of a shortage of protein-rich foods in the world due to the influence of COVID-19 and other factors. Lack of protein in the body leads to disturbances in the processes in which protein is involved and a decrease in immunity. Since the main protein deficiency is associated with a drop in the rate of manufacturing of products containing animal protein, it is relevant to use modern technologies to create alternatives in the form of plant protein sources. To solve this problem, we have developed a product obtained from cedar oilcake by grinding and then processing it with ethyl alcohol in a microwave installation under vacuum for 5-10 minutes. The article presents results of the study of the chemical composition and substantiates the biological value of the protein-vitamins product. Research of the chemical composition of the developed product showed a high content of essential substances, protein 47%. The analysis of the amino acid composition established the presence of 18 amino acids, nonessential and conditionally essential amino acids were found in an amount of 43%. The indicators of the biological value of the protein of the developed product indicate the completeness and balance of the amino acid composition. This proves the high biological value of the protein contained in the protein-vitamin product. The mineral composition of the developed product is capable of meeting the daily requirement for minerals necessary for the human body by 50%. In the product identified water-soluble vitamins group B and vitamin C. The obtained data indicate the possibility of using a protein-vitamin product as an independent product for the prevention of protein-energy malnutrition, and as a functional additive in food production, to increase their nutritional value.
根据联合国粮食及农业组织(粮农组织)的一份新报告,由于COVID-19和其他因素的影响,全球存在富含蛋白质的食物短缺的问题。体内缺乏蛋白质会导致与蛋白质有关的过程紊乱,免疫力下降。由于主要蛋白质缺乏与含有动物蛋白的产品的生产速度下降有关,因此使用现代技术以植物蛋白来源的形式创造替代品是相关的。为了解决这一问题,我们开发了一种以雪松油饼为原料,经研磨后用乙醇在真空微波装置中加工5-10分钟的产品。本文介绍了蛋白质-维生素产品的化学成分研究结果,并证实了其生物学价值。对所研制产品的化学成分进行了研究,发现其必需物质含量高,蛋白质含量达47%。氨基酸组成分析确定了18种氨基酸,其中非必需氨基酸和条件必需氨基酸占43%。所开发产品的蛋白质生物学价值指标表明其氨基酸组成的完整性和平衡性。这证明了蛋白质-维生素产品中所含蛋白质的高生物学价值。所开发产品的矿物质成分能够满足人体每日所需矿物质的50%。在产品中确定了水溶性维生素B族和维生素c。获得的数据表明,蛋白质-维生素产品可以作为预防蛋白质-能量营养不良的独立产品,也可以作为食品生产中的功能性添加剂,增加其营养价值。
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引用次数: 1
Specificity of separate dispersed phase particles from flue gas flows by perfo-rated filter barrier 通过穿孔过滤器屏障从烟气流中分离分散相颗粒的特异性
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2021-4-295-301
D. S. Protsko, S. Panov, E. Shipilova, O. M. Belykh, A. Khvostov
The vector of industrial development at the present stage is associated with a further increase in energy needs, which is associated with the modernization of existing and the development of new energy-efficient generating equipment. A significant share in the energy balance is still occupied by power plants that use fuel combustion and have significant environmental costs. The results of a theoretical and experimental study of the mechanisms of trapping flue gas particles of power plants by perforated filter baffles in order to reduce the load of emissions on the atmosphere are presented. Formulas for calculating the trapping coefficient under the action of various particle trapping mechanisms are systematized and proposed. The dominant role of the inertial trapping mechanism (?Stk) at the beginning of the filtration process and the gearing effect (?R) in the subsequent stage is determined. The issues of formation of the sediment layer require taking into account the adhesive properties of materials (parameter T) and the introduction of an effective Stokes coefficient (Stkeff). A special role is noted for increasing the efficiency of deposition of flue gas particles under the action of an electrostatic field (?E). In the future, the obtained research results can be used in the development and design of combined gas cleaning devices using the combined action of filtration and the action of an electrostatic field.
现阶段工业发展的方向与能源需求的进一步增加有关,而能源需求又与现有的现代化和发展新的节能发电设备有关。在能源平衡中,相当大的份额仍然由使用燃料燃烧的发电厂占据,这些发电厂的环境成本很高。本文介绍了利用多孔过滤挡板捕集电厂烟气颗粒以减少大气排放负荷的机理的理论和实验研究结果。系统地提出了在各种粒子捕获机制作用下的捕获系数计算公式。确定了惯性捕集机制(Stk)在过滤初期的主导作用和后续阶段的传动效应(R)。沉积层的形成问题需要考虑材料的粘接特性(参数T)和引入有效的Stokes系数(Stkeff)。注意到在静电场(?E)作用下提高烟气颗粒沉积效率的特殊作用。在未来,所获得的研究成果可用于利用过滤和静电场联合作用的联合气体净化装置的开发和设计。
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引用次数: 0
Institutional development of circular economy in Russia and St. Petersburg 俄罗斯和圣彼得堡循环经济的制度发展
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-275-281
O. Kalchenko, Y. Nurulin, I. Skvortsova
The term "circular economy" appeared relatively recently in Russia. Interest to the circular economy and the number of publications is growing. The concept of circular economy is very closely related to the green economy, bioeconomics, and low-carbon economy, which are based on moving away from fossil fuels and the development of new technologies. However, in Russia, most often circular economy means recycling system. The principles of circular economy are aimed at the economic, social, and environmental well-being of people. Experts identify factors that promote and hinder the development of circular economy in Russia. Issues of sustainable development, circular economy and energy transition are actively discussed by representatives of government, business and science at international and all-Russian forums. The principles of circular economy will allow achieving several Sustainable Development Goals. The circular economy is one of the key factors in achieving carbon-free energy goals. In St. Petersburg, profile committees, centers and associations are actively working in this direction. Consortia of international projects of most programs are formed from partners based on a triple helix approach- representatives of government, business and universities. The international projects of cross–border cooperation programmes "South-East Finland - Russia", "Estonia - Russia" and the INTERREG Baltic Sea region are considered. Pilot sites are being implemented within the framework of many international projects, with the possibility of further replication of successful experience. The legislative base of Russia and St. Petersburg in the field of circular economy is considered in detail.
“循环经济”一词在俄罗斯出现的时间相对较晚。对循环经济的兴趣和出版物的数量正在增加。循环经济的概念与绿色经济、生物经济、低碳经济密切相关,它们都是建立在摆脱化石燃料和发展新技术的基础上的。然而,在俄罗斯,循环经济通常意味着回收系统。循环经济的原则着眼于人们的经济、社会和环境福祉。专家们指出了促进和阻碍俄罗斯循环经济发展的因素。在国际和全俄论坛上,政府、企业和科学界的代表积极讨论了可持续发展、循环经济和能源转型问题。循环经济原则将有助于实现若干可持续发展目标。循环经济是实现无碳能源目标的关键因素之一。在圣彼得堡,概况委员会、中心和协会正积极朝这个方向努力。大多数项目的国际项目联盟都是由政府、企业和大学的代表组成的。审议了跨界合作方案“芬兰东南部-俄罗斯”、“爱沙尼亚-俄罗斯”和INTERREG波罗的海区域的国际项目。目前正在许多国际项目的框架内实施试验场址,有可能进一步复制成功的经验。详细论述了俄罗斯和圣彼得堡在循环经济领域的立法基础。
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引用次数: 0
Imparting ion-exchange properties to fibrous polycaproamide materials by chemically initiated graft copolymerization 通过化学引发接枝共聚赋予纤维聚酰胺材料离子交换性能
Pub Date : 2022-01-17 DOI: 10.20914/2310-1202-2022-1-232-237
V. Zhukovskiy, V. Khokhlova, T. S. Filipenko, T. U. Anuschenko
The study of the types and properties of surgical threads, as well as the experience in the production of suture surgical material and its use shows that the most promising for surgical practice are threads with antimicrobial properties. Of the methods for fixing medicinal compounds with chemical bonds for suture materials, the most expedient is their attachment by the reaction of ion-exchange interaction. Since polycaproamide (PCA) practically does not contain functional groups, a preliminary modification stage is required to impart ion-exchange properties to PCA fibrous materials. One of these stages of modification is the process of graft polymerization of methacrylic acid (MAA) in order to create active groups on the fiber, for example, peroxide or hydroperoxide. Modification of chemical fibers by graft copolymerization with inogenic monomers is one of the widespread methods of obtaining fibrous ion exchangers. Principles, new approaches and technologies for imparting ion-exchange properties to fibrous polycaproamide materials by chemically initiated graft copolymerization have been developed. Regularities in the production of fibrous PCA of sorption active materials by chemical initiation by a redox system (Fe2++H2O2) located in a modifying bath, as well as by pre-oxidation of fiber PCA in order to create peroxide and hydroperoxide groups on the fiber, are revealed.
对手术线的类型和性能的研究,以及缝合手术材料的生产和使用的经验表明,具有抗菌性能的线是最有希望用于外科实践的线。在缝合材料用化学键固定药物化合物的方法中,最方便的是离子交换相互作用。由于聚己胺(PCA)实际上不含官能团,因此需要初步的改性阶段来赋予PCA纤维材料离子交换性能。改性的其中一个阶段是甲基丙烯酸(MAA)的接枝聚合过程,以便在纤维上产生活性基团,例如过氧化物或氢过氧化物。用内生单体接枝共聚改性化学纤维是获得纤维离子交换剂的常用方法之一。研究了化学引发接枝共聚提高纤维性聚酰胺材料离子交换性能的原理、新方法和新技术。揭示了吸附活性材料纤维型PCA的生产规律,即通过修饰浴中的氧化还原体系(Fe2++H2O2)化学引发,以及通过预氧化纤维型PCA在纤维上生成过氧化物和氢过氧化物基团。
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Proceedings of the Voronezh State University of Engineering Technologies
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