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Geochemical Characterization of Podiform Chromite Ores from the Ultramafic Massif of Bulqiza (Eastern Ophiolitic Belt, Albania) and Hints for Exploration 阿尔巴尼亚Bulqiza(东蛇绿岩带)超基性地块脚状铬铁矿的地球化学特征及找矿提示
Pub Date : 2000-04-01 DOI: 10.2113/0090149
A. Beqiraj, U. Masi, M. Violo
Four main podiform occurrences of chromite have been distinguished in the ultramafic Bulqiza massif, Albania; they are associated from the bottom to the top with: i) basal harzburgites (lower tectonite sequence), ii) dunitic lens-bearing harzbugites (middle-upper tectonite sequence), iii) layered chromitite-bearing dunites of transitional zone, and, iiii) the stratigraphically lowermost part of the magmatic section. However, only the occurrences hosted by rocks ii) and iii) are economically important. Chromite compositions similar to those of other podiform chromites are bimodal. Thus, chromites from occurrences ii) and iii) are richer in Cr than chromites from the other two occurrences. Accessory chromite disseminated throughout the massif is richer in Fe than orebody chromite, displaying similar range of the Cr/Cr+Al ratios, with accessory residue chromite matching the characteristic (Cr/Cr+Al >0.6) range of type-III Alpine peridotites. Both orebody and accessory chromites show compositional ranges correlating with host-rock compositions, i.e., the Cr-rich chromites are hosted by the most refractory ultramafic rocks. Therefore, the Cr/Cr+Al and Mg/Fe tot (Cr/Fe tot ) ratios of chromite are useful for exploration of high-grade, metallurgical chromite ore at Bulqiza and in other massifs of similar geodynamic setting.
在阿尔巴尼亚的超镁质Bulqiza地块中发现了4个主要的脚状铬铁矿产状;它们从下往上依次与:1)基底黑陶粒岩(下构造岩序列),2)含双晶透镜状黑陶粒岩(中上构造岩序列),3)过渡带层状含铬铁矿的黑陶粒岩,3)岩浆剖面地层最下部。然而,只有由岩石(ii)和(iii)承载的矿点具有经济意义。与其他足状铬铁矿相似的铬铁矿成分是双峰的。因此,产自矿床ii)和iii)的铬铁矿比产自其他两个矿床的铬铁矿含铬量更丰富。弥散在整个岩体中的副渣铬铁矿铁含量高于矿体铬铁矿,Cr/Cr+Al比值范围相近,副渣铬铁矿符合iii型高寒橄榄岩特征(Cr/Cr+Al >0.6)范围。矿体和副铬铁矿均显示出与寄主岩组成相关的成分范围,富铬铬铁矿的寄主岩为最难熔的超镁铁质岩。因此,铬铁矿的Cr/Cr+Al和Mg/Fe tot (Cr/Fe tot)比值对布尔奇扎及其他具有类似地球动力背景的地块的高品位冶金铬铁矿具有指导意义。
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引用次数: 11
Investigation of Electrical Properties of Radioactive Phosphatic Layers in the Al-Sharquieh Mine, Syria 叙利亚Al-Sharquieh矿放射性磷化层电学性质研究
Pub Date : 2000-04-01 DOI: 10.2113/0090141
J. Asfahani, R. Mohamad
Radioactive characteristics of pits drilled in the Al-Sharquieh mine while prospecting for recent phosphatic resources have been investigated. The results indicate that phosphatic layers are characterized generally by high radioactive intensities (more than 800 c.p.s). The lithological section in the study area is very complex sedimentologically, and characterized by high faciological variation in all directions. The Schlumberger geo-electrical configuration with fine separation of AB/2 was successfully applied to determine lithological boundaries, and the resistivities of the layers of the lithological section, especially for thin layers. It was shown that the phosphatic layer resistivities increase or decrease as a function of associated material. As a result, two types of phosphatic layers have been geo-electrically distinguished. The first is characterized by high resistivity and relatively low radioactivity, which could be related to the rock phosphatic layers. The second is characterized by low resistivities and high radioactivity, which could be related to the sandy phosphatic layers.
本文研究了Al-Sharquieh矿在近期磷矿资源勘探过程中所钻深坑的放射性特征。结果表明,磷化层普遍具有高放射性强度(超过800 c.p.s)。研究区岩性剖面沉积复杂,各方向岩性变化大。斯伦贝谢AB/2精细分离的地电配置成功地应用于确定岩性边界和岩性剖面层的电阻率,特别是薄层。结果表明,磷化层的电阻率随材料的变化而增大或减小。结果,两种类型的磷化层已被地电区分。第一种特征是高电阻率和相对低的放射性,这可能与岩石磷化层有关。二是低电阻率、高放射性,可能与砂质磷化层有关。
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引用次数: 6
The Horne Mine: Geology, History, Influence on Genetic Models, and a Comparison to the Kidd Creek Mine 霍恩矿:地质、历史、对成因模型的影响,以及与基德溪矿的比较
Pub Date : 2000-04-01 DOI: 10.2113/0090091
H. Gibson, D. Kerr, S. Cattalani
The Horne mine was truly a world class Cu and Au deposit. Between 1927 and 1989, it produced some 260 t of Au and 1.13 Mt of Cu from 53.7 Mt of ore that averaged 2.22% Cu, 6.1 g/t Au and 13 g/t Ag. The total value of Au and Cu production from the Horne deposit at metal prices of US$300/oz Au and US$1.00/lb Cu is an outstanding US$5.2 billion. The Horne mine was also a company builder. After optioning the property from Ed Horne (Tremoy Syndicate) in 1922, the Thomson-Chadbourne Syndicate discovered the deposit in 1923 and quickly grew to become Noranda, one of the world’s premier mining companies. This discovery fuelled exploration and, along with subsequent discoveries in the Val d’Or-Cadillac camps, led to the “economic development” of northwestern Quebec. The Horne deposit influenced and continues to influence genetic models for volcanogenic massive sulfide (VMS) deposits. Early observations at Horne contributed to an epigenetic replacement theory for VMS deposits. The most recent genetic model for the Horne, invoking sub-seafloor sulfide replacement of silicified and sericitized volcaniclastic host rocks within a graben, has subsequently been proposed for another giant VMS deposit, the Kidd Creek mine. The Horne and Kidd Creek deposits show many similarities, such as localization within synvolcanic grabens, long-lived hydrothermal activity uninterrupted by volcanism, sub-seafloor replacement sulfides, stacked sulfide lenses, zone refining, silicified footwall rocks characterized by high positive δ18O values, and association with FIII rhyolites. Notable differences between the two deposits include the lack of andesitic, basaltic or komatiitic flows at Horne, different inferred water depths, high Au content at Horne versus negligible Au, but sub-economic to economic concentrations of Sn, In and Cd at Kidd Creek.
霍恩矿确实是一个世界级的铜金矿。1927年至1989年间,该公司从5370万吨矿石中生产了约260吨金和113万吨铜,平均铜含量为2.22%,金含量为6.1克/吨,银含量为13克/吨。在金属价格为300美元/盎司金和1.00美元/磅铜的情况下,Horne矿床的金和铜生产总价值为52亿美元。霍恩矿也是一家公司的建设者。1922年,汤姆森-查德本辛迪加公司从埃德·霍恩(特雷莫伊辛迪加公司)手中买下了这块土地,1923年,汤姆森-查德本辛迪加公司发现了这块矿藏,并迅速成长为诺兰达公司,成为世界上首屈一指的矿业公司之一。这一发现推动了勘探,并与随后在Val d 'Or-Cadillac营地的发现一起,导致了魁北克西北部的“经济发展”。霍恩矿床影响并将继续影响火山成因块状硫化物矿床的成因模式。霍恩的早期观察为VMS沉积的表观遗传替代理论做出了贡献。Horne的最新成因模型,援引了地堑内硅化和绢云母化火山碎屑宿主岩的海底硫化物替代作用,随后又提出了另一个大型VMS矿床,Kidd Creek矿。Horne和Kidd Creek矿床具有同火山地堑内定位、不受火山作用影响的长寿命热液活动、海底替代硫化物、叠合硫化物透镜体、带细化、具有高正δ18O值的硅化下盘岩石以及与FIII流纹岩相关联等特点。两个矿床之间的显著差异包括Horne缺乏安山岩、玄武岩或马马岩流,推断水深不同,Horne的Au含量高,而Kidd Creek的Au含量可忽略不计,而Sn、In和Cd的浓度则低于经济水平。
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引用次数: 28
The Cobalt Mining District: Silver Sources, Transport and Deposition 钴矿区:银的来源、运输和沉积
Pub Date : 2000-04-01 DOI: 10.2113/0090081
D. Marshall, D. H. Watkinson
Cobalt, Ontario, is renowned for the 12.6 billion grams (445 million ounces) of silver produced from the area since discovery in 1903 by workers of the Timiskaming and Northern Ontario Railway. Native silver generally occurs with cobalt arsenides and sulfosalts in near-vertical carbonate veins cutting the Huronian sedimentary rocks of the Gowganda Formation, the Archean metavolcanics and/or the Nipissing diabase. All major deposits have been found within a few hundred meters of the unconformity between the Archean and Huronian rocks in general proximity to the Nipissing diabase and volcanogenic sulfide mounds within the Archean meta-volcanics. Silver has been mobilized from one or more of the local country rocks by hyper-saline brines and deposited in or near zones of mixing where the saline brines encounter paleometeoric water transported to depth along the unconformity or local structures. Previous work has shown that chloride complexes are the dominant ligands responsible for silver transport. These hypersaline brines, represented as halite-bearing fluid inclusions at room temperature, have been trapped as primary fluid inclusions within vein minerals. Pressure-temperature conditions of vein formation have been derived from mineral equilibria, maximum lithostat and fluid-inclusion studies. These data are consistent with vein formation occurring over the temperature range 300°C to 350°C, with pressures constrained between 60 Mpa and 136 Mpa (600 bars and 1360 bars).
自1903年由蒂米斯卡明和北安大略铁路的工人发现以来,安大略省的钴矿以其126亿克(4.45亿盎司)的白银产量而闻名。原生银通常与砷化钴和硫酸盐一起赋存于戈干达组休伦期沉积岩、太古宙变质火山和/或尼皮辛辉绿岩的近垂直碳酸盐岩脉中。所有主要矿床都在太古宙与休伦期岩石不整合面几百米范围内被发现,一般靠近尼皮辛辉绿岩和太古宙变质火山内的火山成因硫化物丘。银被高盐盐水从一个或多个当地的乡村岩石中动员起来,并沉积在混合带或附近,在混合带中,盐盐水遇到沿不整合面或当地构造输送到深处的古大气水。先前的研究表明,氯配合物是银转运的主要配体。这些高盐盐水在室温下表现为含岩盐流体包裹体,在脉状矿物中作为原生流体包裹体被圈闭。矿脉形成的压力-温度条件已从矿物平衡、最大岩石层和流体包裹体研究中得到。这些数据与温度范围为300°C至350°C,压力限制在60 Mpa至136 Mpa (600 bar至1360 bar)之间的脉状地层相一致。
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引用次数: 19
The NICO and Sue-Dianne Proterozoic, Iron Oxide-hosted, Polymetallic Deposits, Northwest Territories: Application of the Olympic Dam Model in Exploration 西北地区NICO和Sue-Dianne元古代氧化铁多金属矿床:奥林匹克坝模型在勘探中的应用
Pub Date : 2000-04-01 DOI: 10.2113/0090123
R. Goad, A. Mumin, N. Duke, K. Neale, D. L. Mulligan, W. J. Camier
The NICO and Sue-Dianne deposits are being explored and delineated by Fortune Minerals Limited in the Mazenod Lake District of the Northwest Territories, using an Olympic Dam model. The deposits were discovered in the south part of the Great Bear magmatic zone (GBMZ) within the Proterozoic, Bear Structural Province of the Canadian Shield. They are the only known significant Canadian examples of Proterozoic iron oxide-hosted polymetallic deposits. Worldwide, this class includes such deposits as Olympic Dam and Ernest Henry in Australia, Kiruna-Aitik in Sweden, and Salobo in Brazil. Their considerable size, up to 2 billion tonnes, and polymetallic ore assemblages make them highly attractive targets for exploration. Common characteristics of this class include their Early to Middle Proterozoic cratonic settings with extensional rifting evolving from collisional tectonics. Deposits typically occur along major structural lineaments within the aureoles of a distinctive suite of anorogenic potassium-rich “A-type” granite intrusions. Although hosted by diverse lithologies, deposits of this class are characterized by a number of other diagnostic regional- and deposit-scale features, which may be recognized in reconnaissance- and property-scale geological and geophysical surveys.The southern GBMZ in Canada has several characteristics (age, tectonic setting, geology and geophysical attributes) similar to those of the Olympic Dam deposit and its other significant global analogues. Airborne and ground geophysical surveys carried out in the GBMZ identified coincident potassium, uranium, magnetic, resistivity, chargeability, and gravity anomalies centered over the NICO deposit. The nearby Sue-Dianne deposit is characterized by coincident uranium, potassium, magnetic, resistivity and chargeability anomalies. Both deposits occur within a regional, northwest-striking, arcuate trend of volcanic and sedimentary rocks characterized by significant positive Bouguer-gravity and magnetic responses and are believed to represent a major basement discontinuity. The NICO anomalies are at the intersection of this regional trend with a major transverse fault through Lou Lake. Regional and local geophysical data indicate the presence of significant concentrations of iron oxide within a broad area of intense potassium metasomatism. Geological mapping identified cobalt, gold, bismuth, and copper mineralization in biotite-magnetite-amphibole-sulfide-rich ironstone and schist. This mineralization is localized within altered wackes of the Snare Group, which are unconformably overlain by potassium feldspar- (±hematite ±magnetite) altered rhyolite of the Faber Group. The Sue-Dianne deposit is a hematite-magnetite-Fe-silicate-cemented diatreme complex enriched in copper, silver, gold, and uranium within a broad zone of potassium, iron, quartz, and epidote metasomatism. The diatreme is located at the intersection of two major faults at the north end of the basement discontinuity and i
财富矿产有限公司正在利用奥林匹克大坝模型勘探和圈定西北地区马泽诺德湖区的NICO和Sue-Dianne矿床。这些矿床发现于加拿大地盾熊构造省元古代大熊岩浆带(GBMZ)南部。它们是加拿大唯一已知的元古代氧化铁多金属矿床的重要例子。在世界范围内,这类矿床包括澳大利亚的Olympic Dam和Ernest Henry,瑞典的Kiruna-Aitik和巴西的Salobo。它们相当大的规模,高达20亿吨,多金属矿石组合使它们成为极具吸引力的勘探目标。这一类的共同特征是早至中元古代的克拉通环境,由碰撞构造演化而来的伸展裂陷作用。矿床通常产于一套独特的造山富钾“a型”花岗岩侵入体的光晕内的主要构造线。尽管这类矿床由不同的岩性组成,但它们具有许多其他可诊断的区域和矿床尺度特征,这些特征可以在侦察和物性尺度的地质和地球物理调查中识别出来。加拿大南部的GBMZ有几个特征(年龄、构造背景、地质和地球物理属性)与奥林匹克大坝矿床和其他重要的全球类似矿床相似。在GBMZ进行的航空和地面地球物理调查确定了以NICO矿床为中心的一致的钾、铀、磁性、电阻率、电荷性和重力异常。附近的苏-黛安矿床具有铀、钾、磁、电阻率、电荷率等同步异常的特征。这两个矿床都出现在一个区域性的、西北走向的弧形火山岩和沉积岩走向中,其特征是显著的正布格重力和磁响应,被认为代表了一个主要的基底不连续。NICO异常位于这一区域走向与一条穿过娄湖的主要横向断裂的交汇处。区域和当地的地球物理数据表明,在广泛的强烈钾交代区域内存在显著浓度的氧化铁。地质填图在富含黑云母-磁铁矿-角闪石-硫化物的铁矿和片岩中发现了钴、金、铋和铜成矿作用。该成矿作用局限于Snare组蚀变纹岩内,其上覆有钾长石-(±赤铁矿±磁铁矿)Faber组蚀变流纹岩不整合。Sue-Dianne矿床是一个富含铜、银、金和铀的赤铁矿-磁铁矿-铁-硅酸盐胶结双辉石复合体,在广阔的钾、铁、石英和绿帘石交代带内。该裂谷位于基底不连续面北端两条主要断裂的交汇处,赋存于Faber湖拉帕基维花岗岩岩体边缘的流纹长岩火成岩中。在这两个矿床中,铁-氧化胶结角砾岩横跨区域变质沉积-火山不整合面,表明成矿形成于与火山活动同步的近地表环境。
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引用次数: 37
Sampling quality control 抽样质量控制
Pub Date : 1998-04-01 DOI: 10.1007/springerreference_7179
Marcel A. Vallee
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引用次数: 29
Volcanic stratigraphy and lithogeochemistry at the Seneca Zn-Cu-Pb Prospect, southwestern British Columbia 不列颠哥伦比亚省西南部Seneca Zn-Cu-Pb远景区的火山地层学和岩石地球化学
Pub Date : 1996-10-01 DOI: 10.14288/1.0052611
S. Mckinley, T. Barrett, J. F. Thompson
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引用次数: 3
Geology and lithogeochemistry at the Hidden Creek massive sulfide deposit, Anyox, west-central British Columbia 英属哥伦比亚中西部Anyox地区Hidden Creek块状硫化物矿床的地质和岩石地球化学研究
Pub Date : 1996-10-01 DOI: 10.14288/1.0052615
R. Macdonald, T. Barrett, R. Sherlock
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引用次数: 7
Geo-electrical Investigation for Sulfur Prospecting in Teshreen Structure in Northeast Syria 叙利亚东北部特什林构造找硫的地电性研究
Pub Date : 1900-01-01 DOI: 10.2113/11.1-4.49
J. Asfahani, R. Mohamad
Electrical and structural characteristics of formations favorable for sulfur occurrences in northeast Syria are described using geo-electrical prospecting methods. Simple (VES) and combined (CVES) Schlumberger vertical electrical soundings and geo-electrical profiling using a Wenner configuration were applied to the Teshreen structure. Six profiles (A, B, C, D, E, and F) at the borders of anticlines, where positive and negative structures are joined and salt formations have a tendency to disappear, were studied. Secondary structures, characterized by high apparent resistivity exceeding 3000 Ohm.m were located on each profile using a Wenner profiling configuration. These secondary structures are demonstrated to be favorable for sulfur prospecting by both drilled wells and vertical electrical soundings. Traditional interpretation of the 84 VES measurments is supported by data from 14 CVES measurments. The CVES technique is a powerful tool, due to its improved resolution of the electrical boundaries. Thicknesses and resistivities of the Lower Al-Fares, Al-Garibeh, and Al-Dibbaneh formations were determined through the interpretation of VES measurments. The same VES measurments were then interpreted using the Pichgin method, whereby all the subsurface tectonic features were determined for depth penetration corresponding to AB/2 = 1000 m. The integration of the first and second VES phases creates a clear picture of the subsurface, including tectonic, geometric, and geo-electrical information. In summary, the sulfur occurrences in the research area are controlled by tectonic paths that are well defined by geo-electrical methods. These diverse geo-electrical methods could be used successfully for sulfur prospecting in similar environments.
利用地电法描述了叙利亚东北部有利产硫地层的电性和构造特征。简单(VES)和组合(CVES)斯伦贝谢垂直电测深和地电剖面利用Wenner配置应用于Teshreen构造。研究了背斜边缘的6条剖面(A、B、C、D、E和F),其中正、负构造连接,盐层有消失的趋势。二级结构,其特征是视电阻率高,超过3000欧姆。使用Wenner分析配置将m定位在每个配置文件上。这些次生构造经钻探和垂向电测深均证明有利于找硫。84次地震动测量的传统解释得到了14次地震动测量数据的支持。cve技术是一种强大的工具,因为它提高了电边界的分辨率。下部Al-Fares、Al-Garibeh和Al-Dibbaneh地层的厚度和电阻率是通过对电成像测量结果的解释确定的。然后使用Pichgin方法解释相同的VES测量结果,根据AB/2 = 1000 m的深度,确定所有地下构造特征。第一阶段和第二阶段的整合创建了一个清晰的地下图像,包括构造,几何和地电信息。综上所述,研究区硫赋存受构造路径控制,这些构造路径由地电方法确定。这些不同的地电方法可以成功地用于类似环境下的找硫。
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引用次数: 10
Phosphate Prospecting Using Natural Gamma Ray Well Logging in the Khneifiss Mine, Syria 利用自然伽马测井在叙利亚Khneifiss矿进行磷酸盐勘探
Pub Date : 1900-01-01 DOI: 10.2113/11.1-4.61
J. Asfahani
Natural gamma ray well logging, an effective tool in geophysical prospecting, is used to investigate the radioactive and phosphatic layers in the Khneifiss mine in Syria. The interpretation of the gamma ray measurements, using numerical methods of analysis developed previously and applied successfully in some phosphatic areas in Syria, make it possible to define precisely the phosphate thickness from place to place in the study area. This technique has been successfully applied while studying seven boreholes in the area. Sixty-three core samples from phosphatic layers in the boreholes have been analyzed, using gamma ray spectrometry for the determination of P2O5 , U, Th, and K. Good correlation between P2O5 content and U concentration has been found. The total count gamma logs correlate reasonably well with the U core analysis, suggesting that radioactive equilibrium exists in the U decay series. These gamma logs can be therefore used effectively to quantitatively map the distribution of P2O5 and U. The characteristics of both subsurface phosphatic sand and phosphatic rocks have been investigated and outlined using a statistical approach. The affinity of uranium to some trace elements such as V, Sr, Cu, and Ni has been verified using correlation matrices of these elements.
自然伽马测井是物探中的一种有效手段,在叙利亚Khneifiss矿中对放射性和磷化层进行了勘探。伽马射线测量的解释使用了以前开发的数值分析方法,并成功地应用于叙利亚的一些磷酸盐地区,从而可以精确地确定研究地区各地的磷酸盐厚度。该技术已成功应用于该地区7个井眼的研究。利用伽马能谱法对钻孔中磷层的63个岩心样品进行了P2O5、U、Th、k的测定,发现P2O5含量与U浓度具有良好的相关性。总计数伽马测井曲线与铀核分析有较好的相关性,表明在铀衰变序列中存在放射性平衡。因此,这些伽马测井曲线可以有效地用于定量绘制P2O5和u的分布。利用统计方法研究并概述了地下磷砂和磷岩的特征。利用相关矩阵验证了铀对V、Sr、Cu、Ni等微量元素的亲和力。
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引用次数: 23
期刊
Exploration and Mining Geology
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