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Geological and hypogene mineralization characteristics of the hematite‐rich Pelusa IOCG prospect, Antofagasta Region, Northern Chile 智利北部Antofagasta地区富赤铁矿Pelusa IOCG远景区地质及深部成矿特征
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12310
Nicolás Carvajal, S. Kojima, A. Vallejo, Freddy Ildefonso
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引用次数: 0
Geology, mineralization and calcite‐rich potassic alteration at the Humpa Leu East ( HLE ) porphyry Cu‐Au prospect, Hu'u district, Sumbawa Island, Indonesia 印度尼西亚松巴哇岛胡乌地区Humpa Leu East (HLE)斑岩铜金远景区地质、成矿作用及富方解石钾蚀变
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12309
Fadlin, R. Takahashi, A. Agangi, Hinako Sato, A. Idrus, B. Sutopo, Rachmat Pratiwinda
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引用次数: 1
Chemical changes during endoskarn and porphyry‐style alteration and Cu—Fe exoskarn mineralization in the Tonglushan system, eastern China 铜绿山体系内矽卡岩和斑岩型蚀变及Cu-Fe外矽卡岩成矿过程中的化学变化
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12319
Fei Zhang, Ben J. Williamson, Clemens V. Ullmann, Hannah S. R. Hughes
Element mobility and chemical mass transfer are evaluated in the formation of Cu—Fe exoskarn deposits and endoskarn and minor porphyry‐style alteration in the Tonglushan quartz monzodiorite (QMD) system, eastern China. Endoskarn formation involved the migration of Ca into the QMD from the exoskarnification of carbonates (now marble) xenoliths and wall rocks, addition of Fe and Mn by magmatic‐hydrothermal fluids emanating from the interior of the QMD, and removal of alkali elements due to the replacement of feldspars and mica by prograde skarn minerals. Zirconium, Hf, U, and rare earth elements (REE) were added by hydrothermal fluids which were able to carry these often poorly mobile high field strength elements (HFSE) due to elevated F activity. Additions of Al were likely from Na‐rich fluids that also caused sodic alteration. Several factors favored mineralization within the exoskarns rather than endoskarns and QMD. The endoskarns were relatively oxidizing, as evidenced by a significant addition of Fe3+, which caused Cu to remain in magmatic‐hydrothermal fluids until they entered and precipitated sulphides in the more reducing environment of the exoskarns. Fluid migration from the QMD through the endoskarns and into the exoskarns was favored due to decarbonation of wall rock carbonates and related upwards migration of CO2 to produce a self‐sustaining chimney effect, which drew further fluids towards the carbonates to form, alter and mineralize the exoskarns. The higher porosity and permeability of the endoskarns compared with the QMD further promoted the lateral flow of Cu‐bearing fluids towards the exoskarns and limited porphyry‐style alteration and mineralization within the QMD. This proposed mechanism is only likely to be relevant for porphyry‐type systems developed predominantly within carbonate host rocks. Its significance for exploration models is that relatively poorly mineralized porphyry stocks in this setting may be associated with more substantive exoskarn deposits on their margins.
研究了铜绿山石英二黄斑长岩(QMD)体系中Cu-Fe外矽卡岩、内矽卡岩和小斑岩型蚀变形成过程中的元素迁移和化学传质。内矽卡岩的形成过程包括:碳酸盐岩(现为大理岩)包体和围岩的外矽卡岩化作用使Ca迁移到QMD, QMD内部岩浆热液对Fe和Mn的补充作用,以及由前矽卡岩矿物取代长石和云母导致的碱元素的去除。热液流体添加了锆、铪、铀和稀土元素(REE),热液流体由于F活性升高而能够携带这些通常流动性差的高场强元素(HFSE)。添加的Al可能来自富钠液体,这也导致了钠的改变。有几个因素有利于外矽卡岩内的矿化,而不是内矽卡岩和QMD。内矽卡岩是相对氧化的,Fe3+的大量加入证明了这一点,这使得Cu留在岩浆热液中,直到它们进入并在更还原的外矽卡岩环境中沉淀硫化物。由于围岩碳酸盐的脱碳作用和二氧化碳的向上运移,形成了一个自我维持的烟囱效应,使得流体进一步流向碳酸盐,形成、改变和矿化了外矽卡岩,流体从QMD通过内矽卡岩进入外矽卡岩。与QMD相比,内矽卡岩的孔隙度和渗透率更高,进一步促进了含铜流体向外矽卡岩的侧向流动,限制了QMD内斑岩型蚀变和成矿作用。这种提出的机制只可能与主要发育于碳酸盐岩寄主岩中的斑岩型系统有关。它对勘探模式的意义在于,在这一背景下,相对较差的矿化斑岩储量可能与其边缘更实质性的外矽卡岩矿床有关。
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引用次数: 0
Geology, geochemistry, and genesis of gold mineralization in the Chifumbazi deposit of the Tete Province, Irumide Belt, Mozambique 莫桑比克伊鲁米德带太特省Chifumbazi金矿成矿地质、地球化学及成因
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12308
Euclesia P. F. Cossa, A. Agangi, R. Takahashi, Pearlyn C. Manalo, A. Imai, V. Manjate
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引用次数: 1
In search for primary sources of placer diamonds of northeast Siberian craton: Evidence from the U–Pb ages and geochemistry of alluvial zircons 寻找东北西伯利亚克拉通砂石钻石的原始来源:来自冲积锆石的U-Pb年龄和地球化学证据
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12317
E. Nikolenko, A. Agashev, Nikolay S. Tychkov, Anna M. Nikolenko, R. Zhelonkin, A. Ragozin, V. Afanasiev, N. Pokhilenko
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引用次数: 0
Provenance discrimination and geodynamics analysis of open and island coasts, South East coast of India: Inference on heavy minerals and hydrodynamics 印度东南海岸开放海岸和岛屿海岸物源判别和地球动力学分析:重矿物和水动力学的推论
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12311
Sathasivam Sathish, R. S. Kankara, P. Thanabalan, R. Arthur James
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引用次数: 0
An integrated approach for rapid exploration of carbonatites and related mineral resources 快速勘探碳酸盐岩及相关矿产资源的综合方法
4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12321
Asad Khan, Muhammad Ali, Saad Khan, Zaheen Ullah, Shah Faisal, Laeiq Ahmad
Abstract Carbonatites are proven significant repositories of several critical and strategic elements such as rare earth elements, niobium, thorium, and uranium. Owing to their economic significance, mapping of carbonatites and associated mineral deposits has occupied prominent place in mineral resource exploration programs. In this study an integrated approach was developed to map carbonatite and related mineral deposits in the Loe‐Shilman, Northwest Himalaya of Pakistan, using remotely sensed advance space‐borne thermal emission and reflection radiometer (ASTER) multispectral data and visible near infrared and short‐wave infrared (VNIR‐SWIR) spectral characteristics of minerals in these deposits. Several image enhancement techniques, including band ratio (i.e., B4/B3), principal component and minimum noise fraction transformation (PC6 and MNF5, respectively) helped in highlighting the targeted rocks. The results demonstrate the suitability of ASTER data for discriminating carbonatite related mineral deposits from other surrounding lithologies. Results obtained from these methods were validated through field observations in the area and further confirmed through petrographic and chemical analyses of collected specimens. Field data have also served as training data to perform a supervised classification, allowing further improvement of the mapping results. Moreover, the obtained results from the techniques used for exploring carbonatites and related mineral deposits were stacked together for comparison with each other, to check their sensitivities, and assess their efficiency and accuracy. Generally, all these methods successfully highlighted carbonatites and related mineral deposits; however, when used integratively they exhibit higher degree of accuracy, and has proven to be relatively rapid and cost‐effective.
碳酸盐岩被证明是几种关键和战略元素的重要储存库,如稀土元素、铌、钍和铀。由于其经济意义,碳酸盐岩及其伴生矿床的测绘在矿产资源勘查中占有重要地位。在这项研究中,利用遥感先进的星载热发射和反射辐射计(ASTER)多光谱数据以及这些矿床中矿物的可见近红外和短波红外(VNIR - SWIR)光谱特征,开发了一种综合方法来绘制巴基斯坦喜马拉雅西北部Loe - Shilman的碳酸盐岩和相关矿床。几种图像增强技术,包括波段比(即B4/B3)、主成分和最小噪声分数变换(分别为PC6和MNF5),有助于突出目标岩石。结果表明,ASTER数据可用于碳酸盐岩相关矿床与周围其他岩性的鉴别。这些方法得到的结果通过该地区的实地观察得到验证,并通过收集标本的岩石学和化学分析得到进一步证实。现场数据也用作训练数据,以执行监督分类,从而进一步改进制图结果。此外,将碳酸盐岩和相关矿床勘探技术所得结果叠加在一起进行比较,以检查其灵敏度,并评估其效率和准确性。总的来说,所有这些方法都成功地突出了碳酸盐岩及其相关矿床;然而,当集成使用时,它们表现出更高的准确性,并且已被证明相对快速且具有成本效益。
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引用次数: 0
Lateral variations in the Hosen 8‐2 vein in the Hishikari deposit, Japan: Implications for high Au‐grade zone 日本石kari矿床Hosen 8‐2脉的横向变化:对高金品位带的启示
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12318
Jonathan Macuroy, R. Takahashi, Akira Hara, Yoshinori Okaue, A. Imai, Pearlyn C. Manalo, Hinako Sato, A. Agangi
Lateral sampling of each blasting interval (~ 2.6 m) along a 79 m strike length was conducted for the Hosen 8‐2 vein on the −5 ML (mining level, meters relative to sea level) of the Main ore zone in the Hishikari epithermal Au deposit, Kagoshima, Japan. The horizontal variation of mineral textures, bulk chemical compositions, and fluid inclusion temperatures and apparent salinity of ore fluids were determined. The major gangue minerals of the quartz veins studied include quartz and adularia with minor amounts of calcite and smectite. The major ore minerals include electrum, galena, and sphalerite with minor pyrite, petzite, and hessite. Electrum commonly occurs in a discrete band with microcrystalline quartz, granular adularia, and smectite. The electrum‐bearing band is followed by tabular adularia, and finally by granular or comb quartz. Mineral textures that indicate high degrees of supersaturation with respect to amorphous silica (presently quartz with microcrystalline/mosaic and feathery textures) and adularia (with tabular, rhombic, and granular textures) were common throughout the vein strike. Bulk chemical analyses indicate that Au grade is positively correlated with Ag, Bi, Pb, and Te contents. A bonanza zone with Au grades up to 10,800 ppm occurs in the central part of the Hosen 8‐2 vein on the −5 ML, and is associated with high adularia content, calculated as adularia / (quartz + adularia). The wide lateral variation in the geochemical composition contrasts with the consistent association of electrum with microcrystalline quartz, granular adularia, and smectite throughout the Hosen 8‐2 vein on the −5 ML. Fluid inclusion microthermometry of primary and pseudosecondary inclusions in quartz and adularia yielded histogram modes of homogenization temperature between 160 and 240°C; the most frequent mode is 200–210°C, with most data within ±10°C from this value. The maximum ice‐melting temperature of most samples excluding late comb quartz is −1.5°C, which is equivalent to an apparent salinity of 2.6 wt% NaCl eq. The wide variation in ice‐melting temperatures and apparent salinities (up to 5.2 wt% NaCl eq.) may be due to dissolved CO2 in the fluids, while the sharp decrease in apparent salinity with temperature decrease indicates CO2 loss due to fluid boiling during vein formation. The intimate association of electrum with microcrystalline quartz that recrystallized from amorphous silica indicate sharp boiling and vapor loss as the primary mechanism of Au deposition in the Hosen 8‐2 vein.
在日本鹿儿岛Hishikari浅成热液金矿主矿带- 5 ML(采矿水平,相对海平面米)上,沿79 m走向长度对Hosen 8‐2矿脉进行了每个爆破间隔(~ 2.6 m)的横向采样。测定了矿体结构、总体化学成分、流体包裹体温度和矿液表观盐度的水平变化。所研究的石英脉脉石矿物主要为石英和黄铁矿,少量方解石和蒙脱石。矿石矿物主要有银、方铅矿和闪锌矿,次要有黄铁矿、泥铁矿和海锰矿。金缕石通常与微晶石英、粒状灰岩和蒙脱石呈离散带状。含钾石英带之后是板状石英,最后是粒状或梳状石英。在整个脉状走向中,无定形二氧化硅(目前为石英,具有微晶/马赛克和羽毛状结构)和adularia(具有板状,菱形和颗粒状结构)的矿物结构表明高度过饱和。大量化学分析表明,Au品位与Ag、Bi、Pb、Te含量呈正相关。在- 5 ML上的Hosen 8‐2矿脉的中部出现了一个金品位高达10800 ppm的富矿带,并且与高的阿胶含量有关,计算为阿胶/(石英+阿胶)。地球化学组成的广泛横向变化与- 5 ML上整个Hosen 8‐2脉中钾离子与微晶石英、粒状adularia和蒙脱石的一致关联形成对比。石英和adularia中原生和伪次生包裹体的流体包裹体显微测温得出了均一温度在160 - 240°C之间的直方图模式;最常见的模式是200-210°C,大多数数据在±10°C范围内。除晚梳子石英外,大多数样品的最高融冰温度为- 1.5°C,相当于2.6 wt% NaCl当量的表观盐度。融冰温度和表观盐度的巨大变化(高达5.2 wt% NaCl当量)可能是由于流体中溶解的CO2造成的,而表观盐度随着温度的降低而急剧下降,表明在静脉形成过程中由于流体沸腾而损失了CO2。由无定形二氧化硅再结晶而成的微晶石英表明,剧烈沸腾和蒸汽损失是Hosen 8‐2矿脉中金沉积的主要机制。
{"title":"Lateral variations in the Hosen 8‐2 vein in the Hishikari deposit, Japan: Implications for high Au‐grade zone","authors":"Jonathan Macuroy, R. Takahashi, Akira Hara, Yoshinori Okaue, A. Imai, Pearlyn C. Manalo, Hinako Sato, A. Agangi","doi":"10.1111/rge.12318","DOIUrl":"https://doi.org/10.1111/rge.12318","url":null,"abstract":"Lateral sampling of each blasting interval (~ 2.6 m) along a 79 m strike length was conducted for the Hosen 8‐2 vein on the −5 ML (mining level, meters relative to sea level) of the Main ore zone in the Hishikari epithermal Au deposit, Kagoshima, Japan. The horizontal variation of mineral textures, bulk chemical compositions, and fluid inclusion temperatures and apparent salinity of ore fluids were determined. The major gangue minerals of the quartz veins studied include quartz and adularia with minor amounts of calcite and smectite. The major ore minerals include electrum, galena, and sphalerite with minor pyrite, petzite, and hessite. Electrum commonly occurs in a discrete band with microcrystalline quartz, granular adularia, and smectite. The electrum‐bearing band is followed by tabular adularia, and finally by granular or comb quartz. Mineral textures that indicate high degrees of supersaturation with respect to amorphous silica (presently quartz with microcrystalline/mosaic and feathery textures) and adularia (with tabular, rhombic, and granular textures) were common throughout the vein strike. Bulk chemical analyses indicate that Au grade is positively correlated with Ag, Bi, Pb, and Te contents. A bonanza zone with Au grades up to 10,800 ppm occurs in the central part of the Hosen 8‐2 vein on the −5 ML, and is associated with high adularia content, calculated as adularia / (quartz + adularia). The wide lateral variation in the geochemical composition contrasts with the consistent association of electrum with microcrystalline quartz, granular adularia, and smectite throughout the Hosen 8‐2 vein on the −5 ML. Fluid inclusion microthermometry of primary and pseudosecondary inclusions in quartz and adularia yielded histogram modes of homogenization temperature between 160 and 240°C; the most frequent mode is 200–210°C, with most data within ±10°C from this value. The maximum ice‐melting temperature of most samples excluding late comb quartz is −1.5°C, which is equivalent to an apparent salinity of 2.6 wt% NaCl eq. The wide variation in ice‐melting temperatures and apparent salinities (up to 5.2 wt% NaCl eq.) may be due to dissolved CO2 in the fluids, while the sharp decrease in apparent salinity with temperature decrease indicates CO2 loss due to fluid boiling during vein formation. The intimate association of electrum with microcrystalline quartz that recrystallized from amorphous silica indicate sharp boiling and vapor loss as the primary mechanism of Au deposition in the Hosen 8‐2 vein.","PeriodicalId":21089,"journal":{"name":"Resource Geology","volume":"20 1","pages":""},"PeriodicalIF":1.4,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82034371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochronology, geochemistry, and genesis of the Shamai tungsten deposit, Inner Mongolia , NE China 内蒙古沙脉钨矿年代学、地球化学及成因
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2023-01-01 DOI: 10.1111/rge.12307
Qingsong Dong, Shaoshan Shi, Cong Wang, Gang Xue, Kai Hu, Zhili Sun
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引用次数: 0
Ore‐forming process of the Haigou gold deposit in the eastern Central Asian Orogenic Belt, NE China: Constrains from EPMA and LA‐ICP‐MS analysis of Au‐bearing pyrite 中亚造山带东部海沟金矿床的成矿过程:EPMA和LA - ICP - MS对含金黄铁矿的制约
IF 1.4 4区 地球科学 Q3 GEOLOGY Pub Date : 2022-01-01 DOI: 10.1111/rge.12304
Yuan-Wei Chen, Huan Li, Chaoyang Zheng, S. M. Elatikpo, Shanlin Cheng, Wenting Jiang
The Haigou lode deposit, containing 40 t of gold at an average grade of 3.5 g/t, is one of the largest deposits in the Jiapigou gold belt located along the eastern segment of the northern margin of the North China Craton. The deposit comprises 15 gold‐bearing quartz veins hosted in a Carboniferous monzonite–monzogranite stock. Although many studies relating the genesis of this deposit have been carried previously, the understanding of ore‐forming process remains controversial. In this study, we combined field geological mapping with petrography, Electron Probe Micro Analysis (EPMA) and in situ LA‐ICP‐MS analysis of gold‐bearing pyrite to provide new insight into the genesis of the gold deposit. Our results show that Au in the Haigou gold deposit mainly exists in the form of native gold. LA‐ICP‐MS in situ multi‐element mapping shows that Au has a significant positive correlation with Ag, Te, Bi and Pb in Au‐bearing pyrite, indicating that these elements co‐precipitated with Au in pyrite lattice. The ore‐forming fluid existed under medium to low temperature, aiding complexing of the gold with sulfur, chlorine, and tellurium. Decoupling of sulfide and telluride complexes facilitated gold precipitation in the Haigou area. The abundance of lead and nickel tellurides in the Haigou gold deposits with general absence of tellurium in native gold is indicative of expulsion of tellurium through boiling during the process of fluid migration and evolution. Also, coexistence of Bi in native gold indicates that they were at Au–Bi eutectic. The gold‐bearing pyrite is characterized by dispersed magnetite in and around the fractures. The Au–Te–Bi–Pb element anomalies indicate that fluid oxygen fugacity increases while sulfur fugacity decreases with time, resulting in Au precipitation. Our results provide a new theoretical basis for the establishment of metallogenic model and deep prospecting of the Haigou gold deposit.
海沟金矿床是华北克拉通北缘东段夹皮沟金矿带中规模最大的金矿床之一,含金40 t,平均品位3.5 g/t。该矿床包括15条含金石英脉,赋存于石炭系二长花岗岩-二长花岗岩中。尽管前人对该矿床的成因进行了许多研究,但对成矿过程的认识仍存在争议。在这项研究中,我们将野外地质填图与岩石学、电子探针显微分析(EPMA)和含金黄铁矿的原位LA - ICP - MS分析相结合,为金矿床的成因提供了新的认识。结果表明,金在海沟金矿床中主要以自然金的形式存在。LA - ICP - MS原位多元素图谱显示,Au与含金黄铁矿中Ag、Te、Bi和Pb元素呈显著正相关,表明这些元素与Au在黄铁矿晶格中共析出。成矿流体存在于中低温条件下,有利于金与硫、氯、碲的络合。硫化物与碲化物配合物的解耦作用促进了海沟地区金的沉淀。海沟金矿床中碲含量高,而原生金中普遍不含碲,说明在流体运移演化过程中,碲是通过沸腾排出的。同时,原生金中铋的共存表明它们是金铋共晶。含金黄铁矿以裂隙内及裂隙周围的分散磁铁矿为特征。Au - te - bi - pb元素异常表明,随着时间的推移,流氧逸度增大,硫逸度减小,导致Au析出。研究结果为建立海沟金矿成矿模式及深部找矿提供了新的理论依据。
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引用次数: 5
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Resource Geology
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