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Unravelling organic rich shale formation using geochemical proxies in the Doushantuo Formation, South China 利用地球化学指标揭示中国南方陡山沱组富有机质页岩地层
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-26 DOI: 10.1016/j.sedgeo.2026.107042
Junfeng Zhang , Detian Yan , Zeyu Lu
The black shale of the Doushantuo Formation provides important insights into the Ediacaran geological environment and organic carbon enrichment with shale gas potential and exploration. As a typical marine shale with high organic carbon content and considerable thickness, it also holds significant resource potential. In this study, shale samples from multiple water depths and depositional environments across the middle Yangtze block, were examined by well log analysis, field surveys, and lithological divisions. We identified four distinct systems tracts within the second member of Doushantuo Formation (DST-2). High-resolution total organic carbon (TOC) profiles recorded several discrete enrichment pulses. These pulses vary systematically across systems tracts and water depths. This pattern suggests changes in organic-matter supply and preservation and these changes are driven by shifts in water-column redox structure. They are also linked to episodic upwelling. Together, these factors control organic carbon accumulation. Enrichment occurred primarily during transgressive phases, driven by varying water column redox conditions and persistent upwelling. Notably, deeper-water shales showed stronger organic matter enrichment than shallow-water shales did, highlighting the importance of deep-water environments for shale gas exploration. By integrating a sequence-stratigraphic framework with high-resolution TOC data across a nearshore–offshore transect, we constrain the timing and controls of episodic organic carbon enrichment in DST-2. The results highlight transgressive-phase enrichment driven by redox stratification and persistent upwelling; and demonstrate that deep-water settings consistently hosted higher TOC and thicker organic-rich intervals, thereby refining most prospective facies and intervals for shale-gas exploration.
陡山沱组黑色页岩为研究埃迪卡拉系地质环境和有机碳富集提供了重要线索,具有页岩气潜力和勘探方向。作为典型的海相页岩,有机碳含量高,厚度大,资源潜力巨大。通过测井分析、野外调查和岩性划分,对中扬子区块不同水深、不同沉积环境的页岩样品进行了研究。在陡山沱组二段(DST-2)中发现了四个不同的体系域。高分辨率总有机碳(TOC)剖面记录了几个离散的富集脉冲。这些脉冲在不同的系统域和水深有系统地变化。这一模式表明水体中有机质的供应和保存发生了变化,而这些变化是由水柱氧化还原结构的变化所驱动的。它们还与间歇性上升流有关。这些因素共同控制着有机碳的积累。富集主要发生在海侵阶段,受不同水柱氧化还原条件和持续上升流的驱动。值得注意的是,深水页岩有机质富集程度高于浅水页岩,凸显了深水环境对页岩气勘探的重要性。通过将层序地层格架与近海岸-近海样带的高分辨率TOC数据相结合,我们确定了DST-2幕式有机碳富集的时间和控制。结果表明,氧化还原分层和持续上升流驱动的海侵相富集;表明深水环境始终具有较高的TOC和较厚的富有机质层段,从而改善了页岩气勘探的大多数远景相和层段。
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引用次数: 0
Polymetallic nodules offshore NE Greenland: links to Fram Strait opening and local hydrothermal activity 格陵兰岛东北部近海多金属结核:与弗拉姆海峡开放和当地热液活动的联系
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-24 DOI: 10.1016/j.sedgeo.2026.107033
Dmitrii Zastrozhnov , John M. Millett , Sverre Planke , Stéphane Polteau , Adriano Mazzini , Derek Fabel , Finlay Stuart , Ana Carracedo , Luigia Di Nicola , Valerie Olive , Nina Lebedeva-Ivanova , Iakov Gogin , Reidun Myklebust , Ebbe H. Hartz
This study presents the first documentation and analysis of polymetallic Fe–Mn seafloor nodules from offshore Northeast Greenland. Samples were collected from three sites by dredging and gravity coring along the slopes of both the outer and transform margin highs. The morphology, petrography, and whole-rock geochemistry of twenty-four nodules were determined. 10Be/9Be and (U–Th)/He dating were undertaken for representative samples to constrain the time of formation. Two nodule groups were identified in all studied sampling sites. Group 1 (n = 19) are light banded, primarily hydrogenetic nodules with notable enrichments in Mn and Fe, as well as several trace elements including rare earth elements (REE), V, Co, and Y. They have geochemical and textural similarities to Fe–Mn deposits from the Arctic Basin. 10Be/9Be age estimates suggest that growth initiated around 13,5 Ma, shortly after the opening of the Fram Strait, which influence deep-water circulation and inflow of nutrient-rich Arctic waters onto the NE Greenland shelf. Group 2 nodules (n = 5) are dense with high Fe (up to 64 wt% Fe2O3), low Mn content and little to no enrichment in trace elements and REEs. They are interpreted as hydrothermal in origin, with preliminary (U–Th)/He ages suggesting Quaternary formation under weak, diffuse fluid circulation in near-bottom environments of uncertain source. This study expands our understanding of seafloor mineralization in the Arctic–North Atlantic gateway, revealing that on the NE Greenland shelf this process reflects a long-term interplay between tectonic evolution, ocean circulation, and fluid-driven alteration.
本研究首次记录和分析了格陵兰岛东北部近海的多金属铁锰海底结核。通过疏浚和重力取芯,沿外缘和转化缘高地的斜坡从三个地点采集了样本。测定了24个结核的形态、岩石学和全岩地球化学特征。对代表性样品进行了10Be/9Be和(U-Th)/He定年,以限定形成时间。在所有研究的取样部位均发现两组结节。第1组(n = 19)为轻带状,主要为氢成因结核,具有显著的Mn和Fe富集,以及几种微量元素,包括稀土元素(REE), V, Co和y,它们与北极盆地的Fe - Mn矿床具有地球化学和结构相似性。10Be/9Be年龄估计表明,生长始于13,5 Ma左右,在Fram海峡打开后不久。影响深水循环和营养丰富的北极水域流入格陵兰岛东北陆架。第2组结核(n = 5)致密,铁含量高(高达64 wt% Fe2O3),锰含量低,微量元素和稀土元素几乎没有富集。初步的(U-Th)/He年龄表明,它们是在来源不确定的近底环境中弱弥漫性流体循环下形成的第四纪地层。这项研究扩大了我们对北极-北大西洋门户海底矿化的认识,揭示了在格陵兰岛东北陆架,这一过程反映了构造演化、海洋环流和流体驱动蚀变之间的长期相互作用。
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引用次数: 0
Mud volcanoes and synsedimentary deformation structures in Miocene lacustrine deposits over evaporites: Evidence of seismite interpretation 中新世湖相蒸发岩上的泥火山和同沉积变形构造:震积岩解释证据
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-23 DOI: 10.1016/j.sedgeo.2026.107043
M.E. Sanz-Montero , C. Giraldo , J.P. Rodríguez-Aranda
In continental tectonic basins, evaporite paleokarst and soft sediment deformation structures can occur together. However, distinguishing between the effects of tectonism and karst-related dissolution is challenging. Highly deformed beds overlying an evaporite paleokarst in the Miocene deposits of Madrid Basin have been studied in exceptional and laterally continuous outcrops. The paleokarst overburden is mudstone-dominated and displays closely packed fluid seepage structures in the form of mud breccias, tubes, fractures and veins networks connected to surface. At fault intersections, these features dip inwards decametric bowl-shaped to funnel-like structures bounded by circular fractures. This supports that these depressions represent collapsed mud volcanoes built at the surface by the fluid seepage features. They developed in periods of high pore pressures favoured by compressional regimes. Associated fluidization structures including in situ breccia, plastic intrusions, convolute and load forms support that earthquakes are the triggering mechanism.
The network of conduits is lithified by carbonate cements, including slickenfibers of aragonite, as well as by oxides of rare earths and iron‑manganese. The calcite and aragonite cements are highly depleted in 18O in comparison with the hosts suggesting overpressured aquifers as the source of freshwater fluids.
This analogue provides clues to identifying ancient, sagged beds as evolved fluid seepage systems and help to recognizing seismic events in lacustrine environments. Interpretations of sagging structures, common in worldwide-evaporitic paleokarst as purely dissolution-driven should be revisited considering the potential tectonic controls behind their rapid and extensive formation.
在陆相构造盆地中,蒸发岩古岩溶和软沉积变形构造可以同时发生。然而,区分构造作用和与岩溶有关的溶蚀作用是具有挑战性的。在马德里盆地中新世沉积中,对蒸发岩古岩溶上覆的高度变形层进行了特殊的横向连续露头研究。古岩溶上覆层以泥岩为主,呈现出以泥角砾岩、管道、裂缝、脉网等形式与地表连通的致密流体渗流构造。在断层交叉处,这些特征向内倾斜,呈十度碗状到漏斗状结构,由圆形裂缝包围。这支持了这些洼地是由流体渗流特征在地表形成的塌陷泥火山。它们在高孔隙压力时期发育,有利于挤压作用。伴生流化构造包括原地角砾岩、塑性侵入体、涡旋和荷载形式,支持地震是触发机制。管道网络被碳酸盐胶结物(包括文石的光滑纤维)以及稀土和铁锰的氧化物所石化。方解石和文石胶结物在18O年与宿主相比高度枯竭,表明超压含水层是淡水流体的来源。这种类似物为识别古代凹陷地层为演化的流体渗流系统提供了线索,并有助于识别湖泊环境中的地震事件。考虑到其快速而广泛的形成背后潜在的构造控制因素,应重新审视在全球蒸发古岩溶中常见的纯粹溶蚀驱动的下垂构造的解释。
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引用次数: 0
Sedimentary evolution under high-frequency sea-level oscillations of the lower Triassic carbonate-evaporite system in Xuanhan area, Sichuan Basin: Implications for the genesis of polyhalite minerals 四川盆地宣汉地区下三叠统碳酸盐岩-蒸发岩体系在海平面高频振荡下的沉积演化:对多盐岩矿物成因的启示
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-19 DOI: 10.1016/j.sedgeo.2026.107032
Fanfan Zuo , Yongsheng Zhang , Baoling Gui , Kui Su , Enyuan Xing , Xinsheng Niu , Yuan Peng , Yan Xue
Polyhalite is a common potassium-bearing mineral of many ancient evaporitic systems, which can provide important ore resources for agricultural development. However, the genesis of polyhalite is still debated, especially for the origin of primary type. In order to provide novel perspectives and evidence for the genesis of polyhalite minerals, detailed sedimentological and sequence stratigraphic analyses, combined with sulfur isotope stratigraphy, were carried out using Lower Triassic core data in the Xuanhan area, northeastern Sichuan Basin. Fifteen microfacies grouped into six microfacies associations were identified. Furthermore, facies cycle types were recognized and the target intervals were subdivided into six fourth-order sequences and multiple parasequences within them. The result of fourth-order sequences was further validated by sulfur isotope chemostratigraphy. Sedimentary models in the study area and a formation model for primary polyhalite were established consequently. The coupled effects of paleoenvironmental conditions, tectonic activities, and provenance supply caused by sea-level fluctuations collectively led to the precipitation of primary polyhalite in the Sichuan Basin during the Early Triassic. Specifically, primary polyhalite occurs when K+- and Mg2+-enriched concentrated brine within halite saltern mixes with external influxes carrying Ca2+ and SO42− ions, a process regulated by the dynamic fluctuations of multi-order sea-levels, especially the high-frequency ones. Moreover, the margins of the halite saltern and the gypsum saltern, as well as the spatial transition zone between them, created an ideal setting that can meet the above-mentioned geochemical conditions for the precipitation of polyhalite. These results contribute to the supplementation and refinement of the formation mechanisms of polyhalite minerals, especially for the primary ones.
多卤石是许多古代蒸发系统中常见的含钾矿物,可为农业发展提供重要的矿石资源。然而,多盐岩的成因仍有争议,特别是原生型的成因。利用川东北宣汉地区下三叠统岩心资料,结合硫同位素地层学和沉积层序地层学分析,为多盐岩矿物的成因提供新的视角和证据。确定了15个微相,分为6个微相组合。识别了相旋回类型,将目标层段划分为6个4级层序及其内的多个准层序。硫同位素化学地层学进一步验证了四阶层序的结果。建立了研究区沉积模式和原生多岩石的形成模式。早三叠世四川盆地原生多岩石的沉积是由古环境条件、构造活动和海平面波动引起的物源供应等因素共同作用的结果。当盐酸盐岩浆岩中富含K+-和Mg2+的浓盐水与携带Ca2+和SO42 -离子的外部流入混合时,原生多盐岩形成,这一过程受多级海平面尤其是高频海平面动态波动的调节。岩盐盐田和石膏盐田的边缘以及两者之间的空间过渡带,为多盐岩的降水创造了满足上述地球化学条件的理想环境。这些结果有助于补充和完善多盐岩矿物,特别是原生多盐岩矿物的形成机制。
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引用次数: 0
Sedimentology and sequence architecture of the inner shelf siliciclastic‑carbonate succession of the Lower to Middle Jurassic Shusha Formation, Gebel El-Maghara, North Sinai, Egypt 埃及北西奈Gebel El-Maghara地区下—中侏罗统Shusha组内陆架硅屑-碳酸盐序列沉积学及层序结构
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-15 DOI: 10.1016/j.sedgeo.2026.107031
Mounir H. El-Azabi
The sedimentological characteristics of Lower to Middle Jurassic deposits are poorly defined in the southern Tethys. These deposits represent shallow marine siliciclastic‑carbonate facies in Gebel El-Maghara, North Sinai, marked by vertically stacked meter-scale cycles; their origin remains unclear. They include a well-preserved example of Aalenian sediments, which are not so ubiquitous around the Tethys. An integrative sedimentological and sequence stratigraphic study provides new insights into the sedimentation patterns and stratal architecture of the siliciclastic‑carbonate cycles, representing the first cyclostratigraphic research on Uppermost Toarcian–Lower Bajocian deposits in the southern Tethys. The siliciclastic facies include shale and sandstone of barrier-island/lagoon, estuary, and beach-ridge strandplain, developed along a northwestward-dipping coast on an inner shelf during transgressive and early regressive events. The carbonate facies comprise limestone and dolostone, which formed during falling sea levels, marking late regressive events. Facies characteristics indicate the development of a passive-margin shelf in North Sinai during the latest Early Jurassic, earlier than previously assumed. The transgressive-regressive cycles reflect reciprocal sedimentation of alternating siliciclastic and carbonate systems, a relatively uncommon pattern in the geologic record. At intervals, deep incisions, along with dolomitization and ferribands, interrupt these cycles, leading to the formation of incised valleys filled with fluvial sandstones and estuarine sands deposited during sea-level rise. The incised valleys and other discontinuities divide the transgressive-regressive cycles into five distinct depositional sequences, each separated by boundaries linked to short-term eustatic sea-level falls. These falls, combined with a humid climate, largely controlled the initiation of incised valleys, resulting in sequence incompleteness, variations in cycle numbers and durations within equivalent sequences, and the preservation of lowstand deposits along the inner shelf. The clear record of global eustatic sea-level changes preserved on the passive-margin shelf enables more accurate dating of these sequences, revealing that the enclosed low-amplitude, high-frequency cycles have average durations of 54–400 kyr. These fourth- to fifth-order cycles were likely driven by climatic variations within the Milankovitch frequency band and are probably linked to global cooling intervals during the Aalenian and Bajocian.
特提斯南部下侏罗统至中侏罗统沉积学特征尚不明确。这些沉积代表了北西奈Gebel El-Maghara地区浅海相的硅屑-碳酸盐沉积,具有垂直堆积的米级旋回特征;它们的起源尚不清楚。其中包括一个保存完好的阿勒尼亚沉积物的例子,这种沉积物在特提斯周围并不普遍。综合沉积学和层序地层学研究,对特提斯南部上托阿西统—下巴约修统沉积模式和地层构型提供了新的认识,首次对特提斯南部上托阿西统—下巴约修统沉积进行旋回地层学研究。在海侵和早退时期沿内陆架西北倾海岸发育的堰洲岛/泻湖、河口和滩脊滨滩平原的页岩和砂岩等硅质碎屑相。碳酸盐岩相包括灰岩和白云岩,形成于海平面下降时期,标志着晚退期。相特征表明,北西奈早侏罗世晚期形成被动边缘陆架,早于前人的假设。海侵—海退旋回反映了交替的硅屑与碳酸盐体系的相互沉积作用,这在地质记录中是一种相对少见的模式。每隔一段时间,随着白云化作用和铁带作用,深切口会中断这些循环,导致形成了充满河流砂岩和海平面上升期间沉积的河口砂的切割山谷。切割的山谷和其他不连续面将海侵-退回旋回划分为五个不同的沉积层序,每个层序都由与短期海平面上升下降有关的边界隔开。这些瀑布与潮湿的气候相结合,在很大程度上控制了切谷的形成,导致层序不完整,循环次数和等效层序持续时间的变化,以及内陆架低洼沉积物的保存。在被动边缘陆架上保存的全球海平面上升变化的清晰记录使这些序列的定年更加准确,揭示了封闭的低振幅、高频旋回的平均持续时间为54 - 400kyr。这些四阶至五阶周期可能是由米兰科维奇频带内的气候变化驱动的,并且可能与阿勒期和巴约西亚期的全球降温间隔有关。
{"title":"Sedimentology and sequence architecture of the inner shelf siliciclastic‑carbonate succession of the Lower to Middle Jurassic Shusha Formation, Gebel El-Maghara, North Sinai, Egypt","authors":"Mounir H. El-Azabi","doi":"10.1016/j.sedgeo.2026.107031","DOIUrl":"10.1016/j.sedgeo.2026.107031","url":null,"abstract":"<div><div>The sedimentological characteristics of Lower to Middle Jurassic deposits are poorly defined in the southern Tethys. These deposits represent shallow marine siliciclastic‑carbonate facies in Gebel El-Maghara, North Sinai, marked by vertically stacked meter-scale cycles; their origin remains unclear. They include a well-preserved example of Aalenian sediments, which are not so ubiquitous around the Tethys. An integrative sedimentological and sequence stratigraphic study provides new insights into the sedimentation patterns and stratal architecture of the siliciclastic‑carbonate cycles, representing the first cyclostratigraphic research on Uppermost Toarcian–Lower Bajocian deposits in the southern Tethys. The siliciclastic facies include shale and sandstone of barrier-island/lagoon, estuary, and beach-ridge strandplain, developed along a northwestward-dipping coast on an inner shelf during transgressive and early regressive events. The carbonate facies comprise limestone and dolostone, which formed during falling sea levels, marking late regressive events. Facies characteristics indicate the development of a passive-margin shelf in North Sinai during the latest Early Jurassic, earlier than previously assumed. The transgressive-regressive cycles reflect reciprocal sedimentation of alternating siliciclastic and carbonate systems, a relatively uncommon pattern in the geologic record. At intervals, deep incisions, along with dolomitization and ferribands, interrupt these cycles, leading to the formation of incised valleys filled with fluvial sandstones and estuarine sands deposited during sea-level rise. The incised valleys and other discontinuities divide the transgressive-regressive cycles into five distinct depositional sequences, each separated by boundaries linked to short-term eustatic sea-level falls. These falls, combined with a humid climate, largely controlled the initiation of incised valleys, resulting in sequence incompleteness, variations in cycle numbers and durations within equivalent sequences, and the preservation of lowstand deposits along the inner shelf. The clear record of global eustatic sea-level changes preserved on the passive-margin shelf enables more accurate dating of these sequences, revealing that the enclosed low-amplitude, high-frequency cycles have average durations of 54–400 kyr. These fourth- to fifth-order cycles were likely driven by climatic variations within the Milankovitch frequency band and are probably linked to global cooling intervals during the Aalenian and Bajocian.</div></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"494 ","pages":"Article 107031"},"PeriodicalIF":2.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146079587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-phase tectonic evolution regulating multi-source provenance and spatio-temporal sedimentary migration in the Middle-Upper Ordovician, Tarim Basin (NW China) 塔里木盆地中上奥陶统多期构造演化调控多物源及时空沉积迁移
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-12 DOI: 10.1016/j.sedgeo.2026.107030
Qian Liu , Jun Wu , Tailiang Fan , Pengfei Wu , Weiguo Zhang , Suju Yang , Qinqi Xu , Yongtao Xia , Mingjie Lan
The Middle-Upper Ordovician succession in the Tarim Basin documents the evolution of a “reactivated cratonic basin” during the transition from a passive to a collisional continental margin. Deep exploration is hindered by extreme burial depths, limited seismic resolution, and unclear tectonic-sedimentary coupling mechanisms. This study integrates outcrops, cores, well logs, seismic data, and geochemical analyses to establish a high-resolution sequence stratigraphic framework, reconstruct the provenance evolution history, and decipher the spatio-temporal migration of sedimentary systems. Five third-order sequences (SQ1–SQ5) were identified: SQ1—upper Yijianfang and Qiaerbake Formations; SQ2—Lianglitage and lower Sangtamu Formations; SQ3–SQ5—middle–upper Sangtamu Formation. Provenance evolution exhibits a clear tectonically controlled three-stage pattern: during SQ1–SQ2, extra-basinal sources dominated, primarily from the Altyn Orogenic Belt, driven by its east-west “scissor-like” oblique collision; SQ3 was a mixed-source stage with contributions from both the Altyn Orogenic Belt and the Tazhong and Tabei paleo-uplifts, responding to intensified arc-continent collision and intra-basinal tectonic activation; SQ4–SQ5 transitioned to intra-basinal source dominance. The evolution of sedimentary systems was jointly controlled by the coupling of extra-basinal and intra-basinal tectonic dynamics, tectonically driven provenance migration, and relative sea-level fluctuations, overall showing a transition from deep-water gravity flow systems to shallow-water deltaic systems: (1) SQ1–SQ2 featured eastern submarine fans and western carbonate platforms; (2) SQ3 saw expanded eastern submarine fans and newly developed western slope turbidite fans; (3) SQ4–SQ5 were dominated by a basin-center “shelf to shelf-edge delta” system, with gradual shrinkage of the eastern deep-water fans. This study clarifies the core coupling mechanism of “tectonic activation driving provenance transformation, which in turn controls sequence distribution and sedimentary migration,” and establishes a “reactivated cratonic basin” sedimentary evolution model applicable to the Tarim type. The research results provide an important reference for the tectonic-sedimentary analysis of intracratonic collisional basins globally.
塔里木盆地中上奥陶统序列记录了被动大陆边缘向碰撞大陆边缘过渡过程中“活化的克拉通盆地”的演化过程。埋藏深度极深、地震分辨率有限、构造-沉积耦合机制不明确等因素阻碍了深部勘探。综合露头、岩心、测井、地震、地球化学等资料,建立高分辨率层序地层格架,重建物源演化史,破译沉积体系时空迁移。识别出5个3级层序(SQ1-SQ5): sq1 -上一间房组和恰尔贝克组;sq2 -良里塔格组及下桑塔木组;上塔木组中上部。物源演化表现出明显的构造控制的三阶段模式:SQ1-SQ2期,受阿尔金造山带东西向“剪刀状”斜碰撞的驱动,以盆外物源为主,主要来自阿尔金造山带;SQ3是阿尔金造山带和塔中、塔北古隆起共同贡献的混合源阶段,反映了弧陆碰撞和盆内构造活动的加剧;SQ4-SQ5过渡到基底内源优势。沉积体系的演化受盆外和盆内构造动力学、构造驱动物源迁移和相对海平面波动的耦合共同控制,总体上呈现由深水重力流体系向浅水三角洲体系过渡的特征:①SQ1-SQ2以东部海底扇和西部碳酸盐岩台地为主;(2) SQ3区东部海底扇扩大,西部斜坡浊积扇新发育;(3)东部深水扇逐渐萎缩,以盆地为中心的“陆架-陆架边缘三角洲”体系为主。阐明了“构造活化驱动物源转换,物源转换控制层序分布和沉积迁移”的岩心耦合机制,建立了适用于塔里木盆地的“活化克拉通盆地”沉积演化模型。研究结果为全球克拉通内碰撞盆地的构造-沉积分析提供了重要参考。
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引用次数: 0
Influence of geomorphological dynamics and associated mineralogical structures on carbon mineralization processes within different surfaces of sand ramps 地貌动力学及相关矿物学结构对砂坡不同表面碳矿化过程的影响
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-08 DOI: 10.1016/j.sedgeo.2026.107029
Mohsen Kargarian, Neda Mohseni, Reza Hosseinzadeh
Sand ramps are recognized as critical archives for reconstructing Late Quaternary environmental changes, including sediment supply, paleoclimate, and soil carbon dynamics. We investigated the influence of geomorphic processes, weathering, and mineralogical dynamics on the mechanisms controlling the sequestration and mineralization of soil organic carbon (SOC) within falling and climbing sand ramps. Analyses including XRD, XRF, SEM, granulometry, physicochemical attributes, and weathering indices were conducted on sand ramps in central Iran. The abundance of carbonate minerals, sand-sized sediments, well-sorted clastic aggregates, and symmetrical grain distribution, combined with high roundness and minimal quartz corrosion, suggests that falling surfaces remain relatively intact with limited evidence of weathering. Despite the presence of carbonate minerals on falling sand ramps, the lower proportion of clay minerals and fine particles resulted in weaker organic matter binding compared to climbing surfaces. Conversely, the higher frequency of secondary clay minerals, poor sediment sorting, high angularity, and the formation of micro-scale features on granites indicate long-term exposure of climbing surfaces to chemical weathering. The elevated presence of illite, kaolinite, montmorillonite, as well as Fe2O3 and Al2O3 oxides, supported pedogenic processes and promoted microaggregate-associated carbon, rendering SOC less accessible to microbial mineralization. The findings indicate that climbing sand ramps represent a stabilized, pedogenically altered colluvial-aeolian apron overlying the granite, where primary sedimentary structures have been obscured by chemical weathering and clay illuviation. This contrasts with the structurally intact, gravity-dominated falling ramps. These results suggest that localized variations in geomorphic and weathering processes, alongside mineralogical composition, significantly influence the biogeochemical mechanisms controlling SOC mineralization throughout the evolution of sand ramps, offering valuable insights into carbon dynamics in arid and semi-arid regions.
砂坡被认为是重建晚第四纪环境变化的重要档案,包括沉积物供应、古气候和土壤碳动态。研究了地貌过程、风化和矿物学动态对落沙坡道和爬沙坡道土壤有机碳(SOC)封存和矿化机制的影响。对伊朗中部沙坡道进行了XRD、XRF、SEM、粒度测定、理化性质和风化指标分析。丰富的碳酸盐矿物、沙粒大小的沉积物、分选良好的碎屑聚集体和对称的颗粒分布,加上高圆度和最小的石英腐蚀,表明下降表面相对完整,风化证据有限。尽管落砂坡道上存在碳酸盐矿物,但较低的粘土矿物和细颗粒比例导致有机质结合较弱。相反,次生粘土矿物频率高、沉积物分选差、棱角度高、花岗岩微尺度特征的形成表明攀缘面长期暴露于化学风化作用之下。伊利石、高岭石、蒙脱石以及Fe2O3和Al2O3氧化物的增加支持了成土过程,促进了微团聚体相关碳的形成,使得有机碳不易被微生物矿化。研究结果表明,攀爬的沙坡道代表了花岗岩上一个稳定的、成土蚀变的沉积-风成围裙,在那里,原始沉积构造被化学风化和粘土遮蔽。这与结构完整、重力主导的下降坡道形成鲜明对比。这些结果表明,在整个砂坡演化过程中,地貌和风化过程的局部变化以及矿物组成显著影响着控制有机碳矿化的生物地球化学机制,为研究干旱和半干旱地区的碳动态提供了有价值的见解。
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引用次数: 0
A novel mechanism of uranium mineralization: The role of zircon adsorption at the Qigequan deposit, Qaidam Basin, NW China 柴达木盆地奇格泉铀矿化新机制:锆石吸附作用
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-07 DOI: 10.1016/j.sedgeo.2026.107027
Yi-Han Lin , Ming-Sen Fan , Pei Ni , Jun-Yi Pan , Zhe Chi , Zhi-Lin Cheng , Wen-Yi Wu , Chen Zhang , Bing-De Qi , Xue-Bin Wei
Uranium mineralization in sandstone-hosted deposits is influenced by the adsorption capacity of minerals, especially in basin fluids with sub-saturation uranium concentrations. This study investigates the Qigequan sandstone-type uranium deposit in the Qaidam Basin, focusing on uranium distribution and adsorption behavior in zircon. Samples were analyzed using TIMA, BSE, CL imaging, EDS, and EPMA. Results show zircon is abundant in both matrix and clastic components, with uranium occurring in three forms: U1 (in growth zones or inclusions), U2 (in fractures), and U3 (on grain rims). U1 is a magmatic or early hydrothermal product with low U/Th, while U2 and U3 are associated with surface adsorption by mineralizing fluids and have high U/Th. By contrast, uranium minerals unrelated to zircon (i.e., Other-U) have different Th and U characteristics. EPMA mapping reveals that absorbed uranium around rims correlates with elements like Th, Y, Mg, and Ti. Zircon demonstrates a stronger and more selective uranium adsorption capacity than other accessory minerals, despite their higher abundance. We suggest that uranium is absorbed by zircon through a physical-chemical adsorption mechanism, primarily controlled by pH changes caused by the mixing of mildly alkaline oil-gas-related fluids and supergene oxidized fluids. These findings highlight the significant role of zircon as a uranium adsorbent in sandstone-hosted uranium deposits and suggest that surface adsorption, in addition to classical precipitation due to fluid supersaturation, is an important pathway for uranium enrichment. This mechanism offers new insights into uranium mineralization and may refine genetic models of sandstone-type uranium deposits.
砂岩矿床中的铀矿化受矿物吸附能力的影响,特别是在含铀亚饱和的盆地流体中。本文对柴达木盆地奇格泉砂岩型铀矿床进行了研究,重点研究了铀在锆石中的分布和吸附行为。采用TIMA、BSE、CL成像、EDS和EPMA对样品进行分析。结果表明:锆石在基质和碎屑组分中均富集,铀以3种形式赋存:U1(生长带或包裹体)、U2(裂缝)和U3(颗粒边缘)。U1为岩浆或早期热液产物,U/Th较低,U2和U3与矿化流体表面吸附有关,U/Th较高。而与锆石无关的铀矿物(Other-U)则具有不同的Th和U特征。EPMA图显示,在轮辋周围吸收的铀与Th、Y、Mg和Ti等元素相关。尽管锆石的丰度较高,但其对铀的选择性吸附能力较其他副矿物强。认为铀被锆石吸附是一种物理-化学吸附机制,主要受温和碱性油气流体与表生氧化流体混合引起的pH变化控制。这些发现强调了锆石在砂岩型铀矿床中作为铀吸附剂的重要作用,并表明除了流体过饱和引起的经典沉淀外,表面吸附是铀富集的重要途径。这一机制为铀矿化提供了新的认识,并可能完善砂岩型铀矿床的成因模式。
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引用次数: 0
A best-practices guide to X-ray diffraction studies of sedimentary carbonates 沉积碳酸盐x射线衍射研究的最佳实践指南
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-07 DOI: 10.1016/j.sedgeo.2026.107028
Georgina Lukoczki , David L. Bish , Jay M. Gregg
The accurate identification of sedimentary dolomites and related Ca-Mg carbonates is critical for understanding their formation and, by extension, the evolution of Earth's oceans and climate. However, the literature contains numerous examples of misapplication and misinterpretation of X-ray diffraction (XRD) data. For instance, experimental studies claiming successful low-temperature dolomite synthesis have frequently misidentified very high-Mg calcite (VHMC) or other phases as dolomite due to incorrect evaluation of XRD data. Rigorous analytical standards are needed to avoid misinterpretations and to advance the understanding of sedimentary dolomite formation. This paper provides a best-practices guide for powder XRD analysis of trigonal carbonate minerals, with particular emphasis on Rietveld refinement methods for evaluating cation ordering, unit-cell parameters, crystallite size, strain, and stoichiometry. Recommendations are presented for sample preparation, data collection, and analysis, aimed at improving the reliability of carbonate mineral identification and characterization, with particular emphasis on dolomite. Additionally, the nomenclature and classification challenges in distinguishing calcite, high-Mg calcite, VHMC, protodolomite, dolomite, ferroan dolomite, and ankerite are addressed. Finally, the implications of dolomite mineralogy for interpreting past environmental conditions are critically assessed, highlighting the pervasive effects of recrystallization over geological timescales.
沉积白云岩和相关钙镁碳酸盐的准确鉴定对于了解它们的形成,进而了解地球海洋和气候的演化至关重要。然而,文献中包含了大量x射线衍射(XRD)数据误用和误读的例子。例如,声称成功合成低温白云石的实验研究,由于对XRD数据的错误评价,经常将very high-Mg方解石(VHMC)或其他相误认为白云石。需要严格的分析标准来避免误解,并促进对沉积白云岩形成的理解。本文提供了三角碳酸盐矿物粉末XRD分析的最佳实践指南,特别强调Rietveld细化方法,用于评估阳离子有序,单元参数,晶体尺寸,应变和化学计量学。提出了关于样品制备、数据收集和分析的建议,目的是提高碳酸盐矿物鉴定和特征的可靠性,特别强调白云岩。此外,还讨论了方解石、高镁方解石、VHMC、原白云石、白云石、铁白云石和铁白云石的命名和分类问题。最后,对白云岩矿物学对解释过去环境条件的影响进行了批判性评估,强调了在地质时间尺度上再结晶的普遍影响。
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引用次数: 0
Steep nested clinoforms in the mixed siliciclastic‐carbonate Eocene Sobrarbe Deltaic Complex, Aínsa Basin, Spain 西班牙Aínsa盆地始新世Sobrarbe三角洲杂岩中陡峭的嵌套斜形岩
IF 2.9 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-04 DOI: 10.1016/j.sedgeo.2025.107019
Leticia Rodriguez-Blanco , Miquel Poyatos-Moré , Ivar Midtkandal , Ingrid Anell
This study investigates and discusses the processes controlling the development of nested clinoforms in outcrops of the Eocene Sobrarbe Deltaic Complex of the Aínsa Basin, and demonstrates that early cementation in fine-grained sediments can help preserving steep deltaic foresets. Small-scale clinoforms (few 10s of m thick, few 100s of m long) record the higher-frequency cycles of delta progradation and the coetaneous development of a carbonate factory, while large-scale clinoforms (several 10s of m thick, few km long) record longer-term high-energy processes on the shelf and slope, including the reworking of previous deltaic/shelf deposits. Detailed lithological analysis across three of the high-frequency cycles reveals a downdip transition along the small-scale clinothems from subaqueous channels to distal delta front and shelf settings. The coarsest grain sizes are restricted to the proximal delta plain deposits evidencing some periods of limited coarse sediment transfer to deeper waters, enabling the development of coeval carbonate production on the delta front/shelf. Early cementation of carbonate-rich horizons preserved the relatively steep, yet fine-grained clinoform slopes and prevented their collapse. Observation of steep cemented foresets in fine-grained lithologies challenges a univocal relation between delta slope and grain size. In addition, we propose that early cementation is linked to in-situ carbonate production, which implies faunal adaptation probably favored by hiatuses in sedimentation between successive stages of delta progradation. The study also emphasizes the importance of recognizing heterogeneity in such mixed siliciclastic‑carbonate environments, and contributes to the understanding of depositional processes and sedimentary architecture in shallow-marine prograding systems.
本研究探讨了Aínsa盆地始新统Sobrarbe三角洲杂岩露头中巢状斜形发育的控制过程,并证明了细粒沉积物的早期胶结作用有助于保存陡峭的三角洲森林。小尺度的斜形(几米厚,几米长)记录了三角洲进积的高频旋回和同期碳酸盐工厂的发育,而大尺度的斜形(几米厚,几公里长)记录了陆架和斜坡上较长期的高能过程,包括以前的三角洲/陆架沉积的改造。对三个高频旋回的详细岩性分析表明,从水下河道到远端三角洲前缘和陆架环境,沿小范围的斜向构造发生了下倾转变。最粗粒度限制在三角洲平原的近端沉积,这表明在某些时期,有限的粗沉积物向较深的水域转移,使三角洲前缘/陆架的同世碳酸盐生产得以发展。富含碳酸盐的地层的早期胶结作用保存了相对陡峭但细粒的斜形斜坡,并防止了它们的崩塌。在细粒岩性中观察陡峭胶结预集,挑战了三角洲坡度与粒度之间的单一关系。此外,我们认为早期胶结作用与原位碳酸盐生产有关,这意味着动物适应可能有利于三角洲沉积过程中连续阶段之间的沉积中断。该研究还强调了识别这种混合硅酸-碳酸盐岩环境的非均质性的重要性,有助于理解浅海进积体系的沉积过程和沉积构型。
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引用次数: 0
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Sedimentary Geology
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