Micrite envelopes are common early diagenetic features in marine carbonate grains. Most case studies of micrite envelopes focus on those with calcium-carbonate compositions. This paper documents a new type of lacustrine dolomicrite envelopes, coating both terrigenous grains and bioclasts, which developed in the upper Shahejia Formation of early Oligocene age in the middle of the Bohai Bay Basin. These dolomicrite envelopes on grains in a lacustrine mixed sedimentary environment are puzzling for their formation and linkage with the porosity preservation of porosity among grains. We investigate the microstructure and formation mechanism of these dolomicrite envelopes that coat grains through the study of the mineralogy, petrology and porosity characteristics. These studies show that there are two occurrences of the dolomicrite envelopes, i.e., coating on detrital grains and coating on carbonate grains, with a multi-layer microstructure. A potential two stage model to interpret the formation of dolomicrite envelopes incorporates an initial illite coating followed by dolomite encrustation. The illite coating played an important role in the precipitation of the dolomite. Post-envelope diagenetic processes include sparry cementation and destructive dissolution. The quantitative content of dolomicrite envelopes positively correlates with the preserved porosity, which suggests that their formation contributed to resisting compaction and protecting porosity among grains. Indeed, the dolomicrite envelopes appear to have aided in maintaining a kind of extremely high-quality reservoir for hydrocarbon exploration within the Shahejia Formation of the Bohai Bay Basin. In addition, the coating film seems to be conducive to the exchange of anions, thereby resulting in the dissolution of interior feldspar-, bioclast- or ooid-grains. In summary the Shahejia Formation of the Bohai Bay Basin provides a new type of dolomicrite envelope on grains in a lacustrine setting.
Siliciclastic grains, characterized by concentrated Al, Si, K and other elements, are typical components of ooids, but their distribution and contribution to ooid formation are uncertain. Coatings have played a significant role in small shelly fossil preservation in early Cambrian phosphate or phosphatic carbonates. However, the relationship between ooid construction and the preservation of small shelly fossils has not been fully elucidated. Herein, we report well-developed flaggy ooids containing siliciclastic grains from a middle Cambrian carbonate–siliciclastic depositional system in North China. We observe that ooids consist of multiple layers of dark and light laminae. The dark laminae with a high organic content and flexible appearance are interpreted as biofilms. The distribution of detrital grains is closely coupled with these dark laminae and the filamentous structures around fossil shells, which indicates that the detrital particles are bound by the biofilms or filamentous structures. The high occurrence and compacted nature of siliciclastic particles observed in these ooids reveal that detrital grains could be the main contributing factor in ooid formation in the middle Cambrian Longwanggou section. Those flaggy ooids composed of clay-size detrital grains finely mimic the shell morphology and microstructure, providing another important window for the preservation of small shelly fossils in the Cambrian.
Detrital single-mineral geochemistry and geochronology are strong tools in provenance studies and indicate great potentials in addressing issues in earth sciences. Various biases (both natural and artificial) exist objectively and may mislead provenance interpretations. Both the sedimentary sorting process and hand-picking in-laboratory processing may lead to analyzed grain textural (e.g., size and shape) variability and thus may introduce biases in single-mineral provenance analysis. Here, we take the Mesozoic–Cenozoic Qaidam basin, northeastern Tibet, as an example to investigate the relationship between single-mineral grain texture and detrital zircon geochronological and detrital tourmaline, rutile and garnet geochemical data and to explain how grain texture affects detrital single-mineral provenance interpretations. Results indicate that Precambrian zircons take less proportions in coarse (>125 μm), subrounded and high aspect ratio (>2) fractions than Phanerozoic zircons. Parent rock lithology discrimination results of detrital tourmaline and garnet in different grain size fractions show significant differences. Zr-temperature values of detrital rutile have an increasing trend with increasing grain size. The geochemistry of detrital tourmaline, rutile and garnet shows no dependence with grain aspect ratio and roundness. We suggest that inheritance of grain texture features from parent rocks is the major reason. Detrital zircons from recycled (meta)sedimentary rocks tend to be smaller and more rounded than those from igneous rocks. Detrital tourmaline, rutile and garnet grains from different parent rock types vary in size. Grain textural bias may cause the underestimated contributions of the Qilian Shan to the Cenozoic Qaidam basin if small detrital zircons were not involved in the analysis. Quantitative description of the source-to-sink system of the Cenozoic Qaidam is also influenced by grain textural bias. This study highlights the underestimated grain textural bias in single-mineral provenance studies. We suggest that a comprehensive understanding of potential sedimentary sources, depositional processes, sample petrographic features and laboratory analysis procedures is important to reliable provenance interpretations and to related implications in earth sciences.
Early micritic cementation is important to reconstruct paleoenvironments of sedimentary gaps. However, due to their scarcity in ancient records, their initial mineralogy (low-magnesium calcite (LMC), high-magnesium calcite (HMC), aragonite), as well as their origin (biotic or abiotic) and paleoenvironments are still controversial. Herein, based on fluorescence microscopy (FL), cathodoluminescence microscopy (CL), and microdrilling carbon and oxygen isotope analyses, we investigate well developed micritic cements in lower Pliensbachian limestones from the Traras Mountains, northwestern Algeria. Evidence for a microbiological influence in the formation of these cements is given by their irregular morphology, the presence of clotted micropeloidal structures, as well as their bright fluorescence under FL. Together, they reflect precipitation of the micritic cements under microbial control via active and/or passive mechanisms, in the presence of organic matter. Their orange luminescence and low δ18O signals suggest their initial precipitation by sea-water as HMC before being recrystallized into LMC within the meteoric and/or burial realm. These micritic cements, including anisopachous and meniscus-like cements are thought to be precipitated within the marine phreatic zone, as they are associated mainly with isopachous fibrous cements, which is in contrast to their widespread attribution as typical and indicative fabrics of the marine vadose zone. In addition, it has been shown that crystalline cements are developed always upon the early micritic envelopes and micritic cements. These observations which are in line with recent studies conducted on modern deposits confirm that preservation of marine microbial cements in deep time is crucial not only for early grain stabilization, but also serving as a foundation for the subsequent crystal growth.
The present study focuses on the morphosedimentary organization and sediment infilling stratigraphy of one of the largest estuaries of southern Patagonia in Argentina. With a tidal range up to 12 m, the area is subject to extreme tidal conditions, combined with moderate offshore wave climate, strong and constant westerly winds, and contrasted water and sediment discharges from the two tributaries of the estuary, the Santa Cruz and Chico rivers. The estuarine valley is entrenched in the Patagonian coastal plateau due to significant uplift. On the basis of sediment facies (sedimentary structures, grain size, geochemistry, mineralogy), meiofauna (foraminifera and testate amoebae), morphological changes and shallow geophysics (high-resolution seismic reflection, ground-penetrating radar) data, the Santa Cruz–Chico River system is defined as a hybrid system comprising a tide-influenced fluvial mouth (the Santa Cruz River) and a tide-dominated estuary (the Chico River estuary), both converging toward an elongated subtidal ria-type estuarine basin. River-supplied sands and muds by-pass the estuarine basin and are exported offshore where they settle and form an ebb-tidal delta. Sediments in the Santa Cruz–Chico River valley mainly consist of Pleistocene lowstand fluvial gravels resting on the regional Miocene substrate, and thin early Holocene transgressive deposits, deeply incised by a tidal ravinement surface that developed during the highest Holocene sea-level at ca 7500 y. BP. After the maximum stillstand, relative sea level fell and a competition occurred between erosion, promoted by water depth decrease, and deposition, favored by tidal prism reduction. At present, sediment by-passing and offshore sediment export are the dominant processes. The very large size of the ebb-tidal delta, which expands on the continental shelf, suggests that this situation has prevailed for a very long time.
Dolomite is widely present in geological history, but its origin has always been a prominent problem that troubles sedimentologists. For lacustrine dolomite, current research has not yet provided a reliable explanation for its complex genesis mechanism. The Early Cretaceous lakes in Northwest China host various morphological dolomites, providing valuable materials for exploring the origin of dolomites. According to their petrological and mineralogical characteristics, it can be divided into thick laminated dolomite, thin laminated dolomite, dolomitic mudstone, and vein dolomite. The ratios of trace elements and rare earth elements show that these dolomites precipitated in a brackish–suboxic environment. The high δ13C values (>8 ‰VPDB) of thick laminated dolomite and some thin laminated dolomite suggest the involvement of methane-producing microorganisms in the precipitation of dolomite, and the appearance of microscale/nanoscale spherical dolomite aggregates and the dispersed organic matter around dolomite particles jointly confirm that microbial-mediated biological activity promotes dolomite precipitation. The dolomite stoichiometry (mole % MgCO3) confirms that thick laminated dolomite was deposited in a restricted shallow water environment, while dolomitic mudstone is mainly deposited in relatively open water areas. The thin laminated dolomite in the shale laminae represents short-term or seasonal climatic and environmental fluctuations. In addition, some carbonate minerals of dolomitic mudstone in shallow water environment recrystallized by post-depositional hydrothermal effect, resulting in δ18O value decreased (<−10 ‰VPDB). The vein dolomite is characterized by high rare earth content and low δ13C and δ18O values, and its Sr isotope (0.712894 ± 0.000374) values reflect that the hydrothermal fluid may have been formed by the mixing of infiltrating lake water and crustal magmatic water. According to the characteristics of fluid inclusions, it is inferred that the hydrothermal fluid has the characteristics of low temperature (108.3 °C–159.8 °C), medium salinity (3.5 wt%–14.3 wt% NaCl) and high density (0.95–1.00 g/cm3). The microbial mediation and tectonic hydrothermal fluids play an important role in the formation of the Early Cretaceous lacustrine dolomite.
The Ross Embayment is a key region to study the dynamics of the ice sheets during colder and warmer than present climatic conditions, because both the East and West Antarctic Ice sheets shed into the Ross Sea. Numerical modeling and reconstructions of the paleo ice flows during the Last Glacial Maximum show variable contribution of East and West Antarctic Ice sheets based on a variety of proxies. In this study, we present the first petrographic and minero-chemical investigation of the gravel-sized fraction of Last Glacial Maximum subglacial-glacimarine sediments collected with piston cores in a W–E transect across the Ross Sea. The clast petrographic features are compared with outcropping geology to individuate the sediment source regions. The gravel content of the glacigenic diamictite was classified on the basis of petrographic and minero-chemical features, and three main petrofacies were identified. They reflect changes in the basement geology of the source regions, allowing the reconstruction of the paleo ice flow pattern and their comparison with scenarios built up with other datasets. Moreover, the comparison with the Oligocene to Pleistocene glacigenic sediments provided information about the changes of the gravel signature across the Ross Sea and the erosion history of the source regions during Cenozoic.
This paper analyses the lower to middle Eocene carbonate succession exposed at the Island of Pag (Croatia), in the External Dinarides, providing its palaeoenvironmental, palaeobathymetric, and stratigraphic reconstruction. A total of 125 samples have been collected within the Foraminiferal Limestone and the overlying Transitional Beds units cropping out in the sites of Vrčići and Pag for the quantitative analysis of the skeletal assemblage (point counting) and the foraminiferal association (area counting), including both large benthic and small benthic foraminifera. Further samples were collected from the overlying Dalmatian Flysch, to constrain the age of the top of the succession using calcareous nannofossil biostratigraphy. On these bases, the Foraminiferal Limestone has been dated from the Ypresian to the middle Eocene (late Lutetian/early Bartonian). Thanks to the analysis of the skeletal and foraminiferal assemblages, and the use of multivariate statistics, seven main biofacies were identified within the Foraminiferal Limestone and one biofacies within the Transitional Beds. The porcelaneous and agglutinated benthic foraminifera biofacies (BF1) indicates a well-illuminated, oligotrophic to mesotrophic, shallow water, lagoonal environment. The hyaline SBF and encrusting benthic foraminifera biofacies (BF2) developed in a shallow water, inner-ramp environment, and is related to a vegetated seafloor. The nummulitid biofacies (BF3) indicates a moderately high energy, shallow water environment, whereas the comminuted bioclasts and nummulitid biofacies (BF4) corresponds to a low-energy, shallow water environment, and both deposited in inner-to-middle ramp settings. The nummulitid and orthophragminid biofacies (BF5) indicates a moderate energy environment, deposited in middle ramp settings. The nummulitid and serpulid biofacies (BF6) consists of transported material from the inner ramp deposited in middle ramp settings. The orthophragminid and nummulitid biofacies (BF7) indicates a below-wave base, outer shelf setting and the planktic foraminifera biofacies (BF8), recorded in the Transitional Beds, indicates a hemipelagic environment. Based on the foraminiferal counting, quantitative parameters such as the orthophragminids/nummulitids ratio, the planktic/benthic foraminifera ratio, and the hyaline/porcelaneous foraminifera ratio were calculated. These parameters indicate that the succession formed along a distally steepened ramp profile, showing a progressively tectonically-controlled deepening of the depositional environment, culminating with the final drowning of the carbonate ramp. Quantification serves as a crucial instrument for a precise and reliable palaeoenvironmental reconstruction, allowing the comparison amongst different successions.