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Geochemical (δ13C, δ18O, 87Sr/86Sr, REEs) characterization of travertine in Tengchong, China: Insights into travertine origin and reservoir conditions 中国腾冲洞石的地球化学特征(δ13C、δ18O、87Sr/86Sr、REEs):洞察洞石起源和储层条件
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-11-01 DOI: 10.1016/j.sedgeo.2024.106759
Lianchao Luo , Huaguo Wen , Enrico Capezzuoli , Sándor Kele , Orlando Vaselli , Zhipeng Lu , Yaxin Xu , Huixuan Huang , Lei Du , Andrea Brogi
Geochemical characterization is extensively employed in travertine research, yet few studies have explored the potential of travertine geochemistry for elucidating the subterranean details of spring systems. In this study, we systematically characterized the geochemical signatures (δ13C, δ18O, 87Sr/86Sr, REEs, Zr, Th, Sr, Mn) of travertine from six spring systems in Tengchong (SW China) and compared them with those of potential reservoir rocks, aiming to understand travertine origin and assess reservoir conditions. Our results revealed substantial variations in the δ13C and δ18O of travertine among the examined systems, but the water temperature and parent CO2 assessments suggest a hot spring thermogene origin of the travertine. The 87Sr/86Sr of the studied travertine also varies significantly among the systems and overlaps with that of potential reservoir rocks. However, only the springs systems with reservoir temperatures exceeding 150 °C are likely to have precipitated travertine with 87Sr/86Sr resembling the whole-rock 87Sr/86Sr of the reservoir rocks. REE contamination by exogenous detritus and FeMn (oxyhydr)oxides was noted, emphasizing the need for careful REE contamination evaluation in travertine research. The REE comparison reveals that the studied travertine does not fully replicate the REE signature of its potential reservoir rocks, but the REE pattern, (Eu/Eu*)SN, and (Ce/Ce*)SN characteristics of the travertine reveal informative reservoir conditions. In summary, this study shows that the geochemistry of the travertine offers valuable insights into its origin and reservoir conditions. These findings could assist in the geochemical interpretation of travertine and the exaction of hypogean reservoir conditions from travertine.
地球化学特征描述在洞石研究中得到了广泛应用,但很少有研究探讨洞石地球化学在阐明泉水系统地下细节方面的潜力。在本研究中,我们系统地描述了腾冲(中国西南部)六个泉系洞石的地球化学特征(δ13C、δ18O、87Sr/86Sr、REEs、Zr、Th、Sr、Mn),并将其与潜在储层岩石的地球化学特征进行了比较,旨在了解洞石成因并评估储层条件。研究结果表明,不同泉系的洞石δ13C和δ18O存在很大差异,但水温和母体CO2评估表明洞石起源于温泉热成岩。所研究的洞石的 87Sr/86Sr 含量在不同泉系之间也有显著差异,并与潜在储层岩石的 87Sr/86Sr 含量重叠。然而,只有储层温度超过150 °C的泉系才有可能析出87Sr/86Sr与储层岩石全岩87Sr/86Sr相似的洞石。REE受到外源残积物和铁锰(氧氢)氧化物的污染,强调了在洞石研究中仔细评估REE污染的必要性。REE对比显示,所研究的洞石并没有完全复制其潜在储层岩石的REE特征,但洞石的REE模式、(Eu/Eu*)SN和(Ce/Ce*)SN特征揭示了储层的信息条件。总之,这项研究表明,洞石的地球化学特征为了解其成因和储层条件提供了宝贵的信息。这些发现有助于对石灰华进行地球化学解释,并从石灰华中推断出次生储层条件。
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引用次数: 0
Quantifying paleoecological impact of the OAE1a on shallow marine ecosystems from southeastern France 量化 OAE1a 对法国东南部浅海生态系统的古生态影响
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-10-11 DOI: 10.1016/j.sedgeo.2024.106757
Alexis Godet , Jacob Byerly , Matthew Bourdon , Marina Suarez
Climate and environmental instability during the early Aptian culminated with the unfolding of the Oceanic Anoxic Event (OAE) 1a, which resulted in the deposition of black shales in deep marine settings and a typical negative spike followed by a positive excursion in δ13C values. In Vercors (southern France) the Urgonian platform developed prior to and coeval to the OAE1a, but the impact of this paleoenvironmental crisis on the ecology of benthic ecosystems is yet to be quantified. We gathered field and petrographic data to identify sequence boundaries and maximum flooding surfaces that are biostratigraphically dated and correlated between four localities within the study area. A composite δ13C curve is built where the C3 to C7 isotope segments from the literature are identified, pinpointing the onset of the OAE1a above the last episode of deposition of Urgonian facies rich in rudist bivalves. Furthermore, thin section point counting data are used to quantify the proportion of allochems in samples and to trace changes in the ecology of ecosystems. The principal component analysis of point counting data helps define ecological tiers: a diversified, photozoan association with rudists, green algae, and benthic foraminifera dominated ecosystems before the OAE1a and up to the C7 segment, while a less diversified heterozoan association with bryozoans and crinoids developed after the OAE1a. To explore the triggers for this change, the principal component analysis of elemental geochemical data highlights an increased nutrient and detrital input as major triggering mechanisms for ecological adjustments and changes in the biodiversity of ecosystems. In particular after the OAE1a, an increase in detrital and nutrient input leads to the replacement of photozoan by heterozoan assemblages more adapted to these stressful conditions. This research directly links paleoenvironmental deterioration to paleoecological changes and quantifies the amount of adaptation of ecosystems.
始新世早期气候和环境的不稳定性随着大洋缺氧事件(OAE)1a的发生而达到顶峰,该事件导致了深海环境中黑色页岩的沉积,以及δ13C值典型的先负后正的偏移。在 Vercors(法国南部),在 OAE1a 之前和同时,Urgonian 平台也得到了发展,但这一古环境危机对底栖生态系统生态学的影响尚有待量化。我们收集了实地数据和岩相数据,以确定序列边界和最大洪水面,并对研究区域内的四个地点进行了生物地层年代测定和关联。我们绘制了一条综合 δ13C 曲线,确定了文献中的 C3 至 C7 同位素段,将 OAE1a 的起始时间精确定位在富含芦管双壳类动物的乌尔贡面最后一次沉积的上方。此外,还利用薄片点计数数据来量化样本中的分配体比例,并追踪生态系统的生态变化。对点计数数据的主成分分析有助于确定生态层:在 OAE1a 之前直至 C7 段,生态系统中占主导地位的是多样化的光生动物群,包括有孔虫、绿藻和底栖有孔虫;而在 OAE1a 之后,生态系统中形成了多样性较低的异生动物群,包括双壳类和有孔虫。为了探索这种变化的诱因,对元素地球化学数据进行了主成分分析,结果表明,营养物质和碎屑输入的增加是生态调整和生态系统生物多样性变化的主要诱因。特别是在 OAE1a 之后,碎屑和营养物质输入的增加导致光生动物被更适应这些压力条件的异生动物群所取代。这项研究将古环境恶化与古生态变化直接联系起来,并量化了生态系统的适应程度。
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引用次数: 0
Facies architecture, pedogenesis and palynology of the Olenekian dryland setting – A sedimentary record of Early Triassic climate oscillations in the SE Germanic Basin 奥利尼克干地环境的地貌结构、植被形成和古植物学--日耳曼东南盆地早三叠世气候震荡的沉积记录
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-10-01 DOI: 10.1016/j.sedgeo.2024.106754
Karol Jewuła , Wiesław Trela , Artur Kędzior , Anna Fijałkowska-Mader , Natalia Wasielka
The Early Triassic period was characterised by significant climatic perturbations driven by generally high global temperatures. Several significant shifts in the stable carbon and oxygen isotopes were recognised in the marine settings in the Olenekian age deposits that were linked to short-lasting but relatively high-amplitude climatic events. The record of these events in the continental strata is far less understood due to the stratigraphic incompleteness of such deposits. However, in the Holy Cross Mountains (Poland), the Olenekian continental deposits are well preserved, and sedimentation was relatively continuous, making them an ideal candidate for studying the effects of climate changes and their preservation in continental settings. As such, sedimentological analysis of five wells and one outcrop (over 530 m logged in total), integrated with new and legacy palynological data, allowed the reconstruction and dating of major steps in the palaeoenvironmental evolution of the SE part of the Central European (Germanic Basin), and its comparison with the marine-based climatic models for the Early Triassic. The lower and middle Olenekian stage is represented by fine-grained deposits of dry floodplain interbedded with sandstones deposited within fluvial distributary channels and terminal splays. The palaeosols are mainly represented by aridisols (calcisols), indicating a relatively dry, though not extreme, climate as some water was necessary to support relict plant cover. Towards the mid-Spathian times, the climate became more humid - lacustrine deposits appeared, and palaeosols displayed features of an elevated water table (gleyed vertisols and inceptisols). Frequent storms and floods also affected the lacustrine sedimentation, reflecting volatile climatic conditions. In the late Spathian time, continental sedimentation continued, and the dominance of vertisols and more stacked fluvial channels in the sequence is linked with an increased seasonality, with more pronounced humid seasons. The continental setting lasted until the latest Spathian time, when a marine transgression occurred, marking a new phase in the basin development.
早三叠世时期的特点是全球气温普遍偏高,造成了严重的气候扰动。在海洋环境中的奥利尼克纪沉积物中,稳定碳和氧同位素发生了几次重大变化,这些变化与持续时间短但振幅相对较高的气候事件有关。由于地层不完整,人们对大陆地层中这些事件的记录了解甚少。然而,在圣十字山脉(波兰),奥利尼克大陆沉积物保存完好,沉积作用相对连续,是研究气候变化影响及其在大陆环境中保存情况的理想对象。因此,通过对 5 口井和 1 个露头(共记录 530 多米)进行沉积学分析,并结合新的和遗留的古生物学数据,可以重建中欧东南部(日耳曼盆地)古环境演变的主要步骤并确定其年代,并将其与基于海洋的早三叠世气候模型进行比较。中下奥利尼克期的代表是干洪积层的细粒沉积物,与沉积在河道和末端裂隙中的砂岩互层。古土壤主要以干旱土壤(钙质土壤)为代表,这表明当时的气候虽然不是极端气候,但也相对干燥,因为需要一定的水量来支持孑遗植物的生长。到了中喀尔巴阡山时期,气候变得更加潮湿--出现了湖泊沉积,古土壤显示出地下水位升高的特征(砾石vertisols和inceptisols)。频繁的风暴和洪水也影响了湖泊沉积,反映了多变的气候条件。在斯帕提亚晚期,大陆沉积仍在继续,序列中的vertisols和更多的堆积河道占主导地位,这与季节性的增强有关,湿润季节更加明显。大陆环境一直持续到斯帕提安晚期,当时发生了一次海相侵蚀,标志着盆地发展进入了一个新阶段。
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引用次数: 0
Shaking table simulation of soft sediment deformation structures in lacustrine sediments 振动台模拟湖沼沉积物中的软沉积物变形结构
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-10-01 DOI: 10.1016/j.sedgeo.2024.106756
Lianji Liang , Zhihao Lu , Qitao Zhang , Hongshui Tian , Fuchu Dai , Hanchao Jiang , Ning Zhong
Soft sediment deformation structures (SSDSs) in lacustrine sediments could record paleoearthquakes in tectonically active areas. However, their interpretations of deformation and triggering mechanisms still exist disagreement due to the lack of understanding of natural formation processes of SSDSs. In this study, two large shaking table experiments of saturated lacustrine sedimentary sequences, including Model 1 (simple stratigraphic system of thick silty-clay and sand layer) and Model 2 (stratigraphic systems of thin silty-clay and sand alternating layers) were carried out at the different peak ground accelerations (PGA) in order to simulate the earthquake-triggered SSDSs on the basis of field investigation in Tashkorgan of western China. The results showed that there were no SSDSs formed at the PGA 0.125g, and the excess pore-water pressure ratio (γμ) measured in the sand layer was lower than 0.1; sand volcanos, pipes and sand veins were formed at the PGA 0.25g, and the γμ value of the sand layer reached about 0.2 with the maximum liquefied depths of nearly 30 cm, indicating that weak liquefaction occurred in the sand layer; sand volcanos, pipes, sand veins, diapirs, load and flame structures, ball-and-pillow structures, silty-clay deformation structures were formed at the PGA 0.5g and 0.8g, and the γμ value of sand layer reached about 0.91 and 0.94 with the maximum liquefied depths of nearly 60 cm and 100 cm, respectively. The γμ value of silty-clay layers measured in all the tests was lower than 0.1, indicating that little liquefaction but thixotropy happened in the silty-clay layers. The tests showed that liquefied SSDSs could form at the PGA 0.25g, while thixotropic and gravity-driven SSDSs could form until the PGA reached 0.5g. This study also provided insights for single or closely spaced shaking events being responsible of superposed deformed beds. The simulated SSDSs have striking resemblance to that of ones identified in the field, supporting the earthquake triggering of SSDSs in the Tashkorgan area.
湖沼沉积物中的软沉积物变形结构(SSDSs)可以记录构造活跃地区的古地震。然而,由于对 SSDSs 的自然形成过程缺乏了解,他们对其变形和触发机制的解释仍存在分歧。本研究在中国西部塔什库尔干野外调查的基础上,对饱和湖相沉积序列进行了两次大型振动台实验,包括模型 1(厚淤泥质粘土和砂层的简单地层系统)和模型 2(薄淤泥质粘土和砂层交替的地层系统),在不同的峰值地面加速度(PGA)下模拟地震触发的 SSDS。结果表明,PGA 0.125g 时未形成 SSDS,测得砂层过剩孔隙水压力比(γμ)小于 0.1;PGA 0.25g 时形成了砂火山、砂管和砂脉,砂层γμ值达到 0.2 左右,最大液化深度为 0.2m。2,最大液化深度近 30 cm,表明砂层发生了弱液化;在 PGA 0.5g 和 0.8g 时,砂层形成了砂火山、管道、砂脉、斜管、荷载和火焰结构、球枕结构、淤泥质变形结构,砂层的 γμ 值分别达到约 0.91 和 0.94,最大液化深度近 60 cm 和 100 cm。所有试验中测得的淤泥质粘土层的γμ值均小于 0.1,表明淤泥质粘土层液化程度很小,但发生了触变。试验表明,液化 SSDS 可在 PGA 值为 0.25g 时形成,而触变性 SSDS 和重力驱动 SSDS 可在 PGA 值达到 0.5g 时形成。这项研究还为单次或间隔较近的振动事件造成叠加变形床提供了启示。模拟的 SSDS 与实地发现的 SSDS 非常相似,这支持了地震引发塔什干地区 SSDS 的观点。
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引用次数: 0
Ichnological indicators of physico-chemical stresses in wave- to tide-dominated Miocene shallow marine environments (Argentine Patagonia) 波浪到潮汐主导的中新世浅海环境(阿根廷巴塔哥尼亚)中物理化学压力的技术指标
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-10-01 DOI: 10.1016/j.sedgeo.2024.106755
Sergio A. Celis , Damián Moyano-Paz , Sebastián Richiano , José I. Cuitiño , Francisco J. Rodríguez-Tovar
<div><div>An integrated analysis of ichnological and sedimentological features in ancient successions provides a robust dataset of high-resolution interpretations of environmental parameters, encompassing both depositional and ecological aspects. By characterising discrete and recurring bioturbation patterns in the Puerto Madryn Formation (Late Miocene, Argentine Patagonia), we arrive at key knowledge about predominant environmental stresses within transgressive phase shallow marine and estuarine systems, shedding light on their palaeoenvironmental implications. Given the inherent complexities of coastal settings, including the challenges posed by omission/erosion surfaces, it becomes imperative to consider the intricate interplay of multiple depositional processes and environmental factors.</div><div>Through a detailed integration of sedimentological and ichnological approaches, we discern the establishment of a wave-dominated system overlain by a tide-dominated estuarine system.</div><div>The wave-dominated marine system involves tabular bodies extending laterally over tens of kilometres, with upward fining and coarsening successions from the mid- to lower-shoreface to offshore-shelf environments. The influence of waves and tides on these systems is discussed in the absence of physical sedimentary structures and the need to find elements that bring us closer to elucidating whether waves or tidal processes influence shoreface to offshore systems. The ichnological assemblages allow for the characterisation of <em>Cruziana</em> ichnofacies with proximal (<em>Taenidium</em> and <em>Thalassinoides</em>), archetypal (<em>Asterosoma</em>, <em>Chondrites</em>, <em>Cylindrichnus</em>, <em>Ophiomorpha</em>, ?<em>Rhizocorallium</em>, <em>Rosselia</em>, <em>Scolicia</em>, <em>Sinusichnus</em>, <em>Siphonichnus</em>, <em>Teichichnus</em>, and <em>Thalassinoides</em>), and distal expressions (<em>Chondrites</em>, <em>Helicodromites</em>, <em>Phycodes</em>, <em>Thalassinoides</em>, and ?<em>Zoophycos</em>) in the lower shoreface to lower offshore and transitional settings with the shelf. However, the transition from these deposits to <em>Chondrites</em>-dominated beds associated with lower offshore to shelf environments—determined by changes in oxygenation, nutrients, and energy conditions—impedes assignment of all the successions to a particular ichnofacies.</div><div>The tide-dominated estuarine system features wide, channel-shaped bodies filled with sandy to heterolithic facies, interpreted as intertidal and subtidal deposits. To differentiate between estuary mouths and other settings, the analysis involved characterisation of transgressive and regressive surfaces, ichnological assemblages, and facies distribution, determining net sediment movement—whether landwards or seawards—and its influence on system classification. The ichnological assemblages could be assigned to the <em>Skolithos</em> (<em>Arenicolites</em>, <em>Gyrolithes</em>, <em>Maiakarichnus</
对古生代演替中的生态学和沉积学特征进行综合分析,可为环境参数的高分辨率解释提供强大的数据集,其中包括沉积和生态两个方面。通过描述马德林港地层(阿根廷巴塔哥尼亚中新世晚期)中离散和重复出现的生物扰动模式,我们获得了有关横断相浅海和河口系统中主要环境压力的关键知识,揭示了其对古环境的影响。鉴于沿岸环境固有的复杂性,包括遗漏/侵蚀地表带来的挑战,考虑多种沉积过程和环境因素错综复杂的相互作用变得势在必行。通过对沉积学和生态学方法的详细整合,我们发现在以潮汐为主的河口系统之上建立了以波浪为主的系统。以波浪为主的海洋系统包括横向延伸数十公里的表层岩体,从中下游海面到近海陆架环境有向上细化和粗化的演替。在没有物理沉积结构的情况下,我们讨论了海浪和潮汐对这些系统的影响,并需要找到一些要素,使我们更接近于阐明海浪或潮汐过程是否影响了海岸表层到近海系统。通过水生态组合,可以确定 Cruziana 水生态的特征,包括近端(Taenidium 和 Thalassinoides)、原型(Asterosoma、Chondrites、Cylindrichnus、Ophiomorpha、?在下海岸表层到下近海以及与陆架的过渡环境中,这些沉积物的原型(Asterosoma、Chondrites、Cylindrichnus、Ophiomorpha、Rhizocorallium、Rosselia、Scolicia、Sinusichnus、Siphonichnus、Teichichnus 和 Thalassinoides)和远端表现(Chondrites、Helicodromites、Phycodes、Thalassinoides 和 Zoophycos)。潮汐主导的河口系统具有宽阔的河槽形水体,水体中充满了沙质至异质岩层,可解释为潮间带和潮下带沉积。为了区分河口和其他环境,分析涉及到横向和纵向表面特征、生物组合和面层分布,以确定沉积物的净移动--是向陆地移动还是向海移动--及其对系统分类的影响。生物组合可归入 Skolithos(Arenicolites、Gyrolithes、Maiakarichnus、Ophiomorpha、Schaubcylindrichnus、Skolithos 和 Thalassinoides)和 Cruziana 生物群(Ophiomorpha、Rosselia、Scolicia 和 Siphonichnus)。多样性和丰度的变化往往有助于确定某些应激条件,但讨论了向更开阔地区的过渡,探讨了如何改变丰度/多样性与物理化学应激直接相关的典型模式。
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引用次数: 0
Sediment bypass in a marl-dominated margin of a turbidite system in a narrow basin setting 狭窄盆地环境中以泥灰岩为主的浊积岩系统边缘的沉积物旁路
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-10-01 DOI: 10.1016/j.sedgeo.2024.106753
Piotr Łapcik
Submarine sediment density flows play a pivotal role in transporting clastic material to the deep sea. The volume of sediment they transport, which bypasses a specific point or geographical location, shapes the stratigraphic record of the entire turbidite systems. Hence, recognition of bypass-dominated zones is crucial in facies prediction and understanding the architecture of turbidite systems. This understanding is linked to the economic aspects of exploring hydrocarbon deposits, the occurrence of geohazards that impact submarine infrastructure, the distribution of pollutants, and carbon sequestration.
In the western part of the Ropianka Fm (Skole Nappe, Polish Outer Carpathians), three bed types showing evidence of sediment bypass were identified in the channel-mouth setting of marl-dominated slope and base-of-slope successions. The varying proportions of these bed types in studied successions and relationship with adjacent facies associations led to the identification of two channel-mouth zones. This study provides insights into deposits with characteristics differing from the previously described channel-mouth setting, evidenced by a significantly lower sand-to-mud ratio and smaller scale of erosional and depositional structures. The reported channel-mouth zones are interpreted as the marginal parts of a channel mouth, formed by subcritical flows. This study broadens the understanding of the channel-mouth setting by introducing dynamic and mud-dominated zones that experience sediment bypass and weak erosion. The identified bed types and typical characteristics of Marginal channel-mouth zones 1 and 2 can serve as a reference for interpreting marginal areas of channel-mouth settings in mud-dominated successions with scattered thin-bedded and coarse-grained deposits in other deep-water basins.
海底沉积密度流在向深海运送碎屑物质方面发挥着关键作用。它们绕过特定地点或地理位置的沉积物运移量决定了整个浊积岩系统的地层记录。因此,识别绕流主导区对于预测地层面貌和了解浊积岩系统的结构至关重要。这种认识与勘探碳氢化合物矿藏的经济方面、影响海底基础设施的地质灾害的发生、污染物的分布和碳封存有关。在 Ropianka Fm(波兰外喀尔巴阡山脉 Skole Nappe)西部,在以泥灰岩为主的斜坡和斜坡基底演替的槽口环境中,发现了三种显示沉积物旁路证据的岩床类型。根据这些岩床类型在所研究的岩层中的不同比例以及与相邻岩层的关系,确定了两个河道-河口带。这项研究深入探讨了与之前描述的河槽口环境不同的沉积特征,砂泥比明显降低,侵蚀和沉积结构规模较小。所报告的河道口区被解释为由亚临界流形成的河道口边缘部分。这项研究通过引入以泥浆为主的动态区域,拓宽了对河道口环境的认识,这些区域经历了泥沙绕流和微弱的侵蚀。所确定的边缘河道口 1 区和 2 区的河床类型和典型特征,可作为解释其他深水盆地以泥浆为主、有零星薄层和粗粒沉积的河道口环境边缘区域的参考。
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引用次数: 0
A new type of dolomicrite envelope formed in Oligocene lacustrine sediments and its significance for preserving porosity, Bohai Bay Basin, North China 华北渤海湾盆地渐新世湖相沉积物中形成的一种新型白云岩包体及其对保存孔隙度的意义
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.sedgeo.2024.106745
Caineng Mu , Xiaobo Huang , Liya Da , Anqing Chen , James G. Ogg , Huan Lu , Yuzhu Ge , Jian Luo , Siyu Xiong , Haiyang Cao , Mingcai Hou

Micrite envelopes are common early diagenetic features in marine carbonate grains. Most case studies of micrite envelopes focus on those with calcium-carbonate compositions. This paper documents a new type of lacustrine dolomicrite envelopes, coating both terrigenous grains and bioclasts, which developed in the upper Shahejia Formation of early Oligocene age in the middle of the Bohai Bay Basin. These dolomicrite envelopes on grains in a lacustrine mixed sedimentary environment are puzzling for their formation and linkage with the porosity preservation of porosity among grains. We investigate the microstructure and formation mechanism of these dolomicrite envelopes that coat grains through the study of the mineralogy, petrology and porosity characteristics. These studies show that there are two occurrences of the dolomicrite envelopes, i.e., coating on detrital grains and coating on carbonate grains, with a multi-layer microstructure. A potential two stage model to interpret the formation of dolomicrite envelopes incorporates an initial illite coating followed by dolomite encrustation. The illite coating played an important role in the precipitation of the dolomite. Post-envelope diagenetic processes include sparry cementation and destructive dissolution. The quantitative content of dolomicrite envelopes positively correlates with the preserved porosity, which suggests that their formation contributed to resisting compaction and protecting porosity among grains. Indeed, the dolomicrite envelopes appear to have aided in maintaining a kind of extremely high-quality reservoir for hydrocarbon exploration within the Shahejia Formation of the Bohai Bay Basin. In addition, the coating film seems to be conducive to the exchange of anions, thereby resulting in the dissolution of interior feldspar-, bioclast- or ooid-grains. In summary the Shahejia Formation of the Bohai Bay Basin provides a new type of dolomicrite envelope on grains in a lacustrine setting.

微晶包络是海洋碳酸盐颗粒中常见的早期成岩特征。大多数关于微晶岩包层的案例研究都集中在碳酸钙成分的微晶岩包层上。本文记录了在渤海湾盆地中部早更新世上部沙河家地层中发育的一种新型湖相白云母包体,它既包裹着陆生颗粒,也包裹着生物碎屑。在湖相混合沉积环境中,这些包覆在颗粒上的白云母包层的形成及其与颗粒间孔隙度保存的联系令人费解。我们通过对矿物学、岩石学和孔隙度特征的研究,调查了这些包裹在颗粒上的白云母包体的微观结构和形成机制。这些研究表明,白云母包体有两种情况,即包裹在脱落晶粒上和包裹在碳酸盐晶粒上,具有多层微观结构。解释白云母包层形成的潜在两阶段模型包括最初的伊利石包层和随后的白云石包层。伊利石包层在白云石的沉淀过程中发挥了重要作用。包壳后成岩过程包括疏松胶结和破坏性溶解。白云岩包体的数量含量与保存的孔隙度呈正相关,这表明包体的形成有助于抵抗压实和保护晶粒间的孔隙度。事实上,白云母包膜似乎有助于在渤海湾盆地沙河家地层中维持一种极优质的油气勘探储层。此外,包膜似乎有利于阴离子的交换,从而导致内部长石粒、生物碎屑岩粒或类卵石粒的溶解。总之,渤海湾盆地的沙河家地层提供了一种新类型的湖积环境中晶粒上的白云母包膜。
{"title":"A new type of dolomicrite envelope formed in Oligocene lacustrine sediments and its significance for preserving porosity, Bohai Bay Basin, North China","authors":"Caineng Mu ,&nbsp;Xiaobo Huang ,&nbsp;Liya Da ,&nbsp;Anqing Chen ,&nbsp;James G. Ogg ,&nbsp;Huan Lu ,&nbsp;Yuzhu Ge ,&nbsp;Jian Luo ,&nbsp;Siyu Xiong ,&nbsp;Haiyang Cao ,&nbsp;Mingcai Hou","doi":"10.1016/j.sedgeo.2024.106745","DOIUrl":"10.1016/j.sedgeo.2024.106745","url":null,"abstract":"<div><p>Micrite envelopes are common early diagenetic features in marine carbonate grains. Most case studies of micrite envelopes focus on those with calcium-carbonate compositions. This paper documents a new type of lacustrine dolomicrite envelopes, coating both terrigenous grains and bioclasts, which developed in the upper Shahejia Formation of early Oligocene age in the middle of the Bohai Bay Basin. These dolomicrite envelopes on grains in a lacustrine mixed sedimentary environment are puzzling for their formation and linkage with the porosity preservation of porosity among grains. We investigate the microstructure and formation mechanism of these dolomicrite envelopes that coat grains through the study of the mineralogy, petrology and porosity characteristics. These studies show that there are two occurrences of the dolomicrite envelopes, i.e., coating on detrital grains and coating on carbonate grains, with a multi-layer microstructure. A potential two stage model to interpret the formation of dolomicrite envelopes incorporates an initial illite coating followed by dolomite encrustation. The illite coating played an important role in the precipitation of the dolomite. Post-envelope diagenetic processes include sparry cementation and destructive dissolution. The quantitative content of dolomicrite envelopes positively correlates with the preserved porosity, which suggests that their formation contributed to resisting compaction and protecting porosity among grains. Indeed, the dolomicrite envelopes appear to have aided in maintaining a kind of extremely high-quality reservoir for hydrocarbon exploration within the Shahejia Formation of the Bohai Bay Basin. In addition, the coating film seems to be conducive to the exchange of anions, thereby resulting in the dissolution of interior feldspar-, bioclast- or ooid-grains. In summary the Shahejia Formation of the Bohai Bay Basin provides a new type of dolomicrite envelope on grains in a lacustrine setting.</p></div>","PeriodicalId":21575,"journal":{"name":"Sedimentary Geology","volume":"472 ","pages":"Article 106745"},"PeriodicalIF":2.7,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142239517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon–sulfur–calcium isotopic variability of lower Cambrian shale-hosted carbonate concretions: Insights into growth mechanisms and calcium cycling 下寒武统页岩包裹碳酸盐岩的碳硫钙同位素变异:洞察生长机制和钙循环
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-09-10 DOI: 10.1016/j.sedgeo.2024.106746
Xiqiang Zhou , Xiyuan Chen , Tongxuan Du , Jian Sun , Dongjie Tang , Run Li , Kang-Jun Huang , Yi Ding , Daizhao Chen
Marine calcium cycling is closely linked with carbon cycling in the ocean, in which authigenic carbonates precipitated in sediments play a non-negligible role. However, calcium cycling during authigenic carbonate precipitation in organic-rich, shaly sediments in geological history remains underexplored. This study focuses on carbonate concretions (aggregates of authigenic carbonates) in the lower Cambrian Niutitang Formation, South China, to provide insights into calcium cycling during their growth. Sedimentological and mineralogical observations suggest that these concretions were formed through concentric growth by authigenic calcite and pyrite precipitation during the early diagenetic stage. Geochemical analyses reveal internal variations in “M-shaped” δ13Ccarb trends (from −11.9 ‰ to −4.4 ‰) and diverse δ34Spyr trends (from 4.7 ‰ to 14.0 ‰) along core-to-rim transects. These findings suggest formation through microbial sulfate reduction by organic matter in a shallow depth beneath the sediment–water interface. In contrast to the dynamic δ13Ccarb and δ34Spyr variations and multi-stage concentric growth, these carbonate concretions display nearly uniform δ44/40Cacarb values (from 0.80 ‰ to 1.03 ‰, average 0.96 ± 0.06 ‰, 1SD) and consistent internal trends, which are further attributed to strongly seawater-buffered porewater calcium geochemistry and small calcium isotope fractionation due to calcite precipitation at slow rates. This study confirms that early diagenetic carbonate concretions in the lower Cambrian Niutitang Formation are characterized by much heavier δ44/40Ca values compared to coeval shallow platform carbonates. In light of abundant authigenic carbonates observed in the lower Cambrian successions, their roles in calcium isotope mass balance in the early Cambrian ocean warrant further investigation in the future. Therefore, early diagenetic carbonate concretions in black shales could provide valuable insights into porewater and seawater calcium isotope signals, as well as early diagenetic and marine calcium cycling in geological history.
海洋钙循环与海洋碳循环密切相关,其中沉积物中沉淀的自生碳酸盐发挥着不可忽视的作用。然而,在地质历史上,富含有机质的有页岩沉积物中自生碳酸盐沉淀过程中的钙循环仍未得到充分探索。本研究以华南下寒武统牛蹄塘地层中的碳酸盐凝块(自生碳酸盐的聚集体)为研究对象,探讨其生长过程中的钙循环。沉积学和矿物学观察表明,这些凝块是在早期成岩阶段通过自生方解石和黄铁矿沉淀同心生长形成的。地球化学分析表明,沿着岩心到岩缘的横断面,"M 型 "δ13Ccarb 趋势(从 -11.9 ‰ 到 -4.4‰)和δ34Spyr 趋势(从 4.7 ‰ 到 14.0‰)存在内部变化。这些发现表明,硫酸盐是在沉积物-水界面下的浅层通过有机物的微生物还原作用形成的。与δ13Ccarb和δ34Spyr的动态变化和多阶段同心生长不同,这些碳酸盐圆锥体显示出近乎一致的δ44/40Cacarb值(从0.80‰到1.03‰,平均0.96±0.06‰,1SD)和一致的内部趋势,这进一步归因于强海水缓冲孔隙水钙地球化学和方解石缓慢沉淀导致的微小钙同位素分馏。该研究证实,与同时期的浅地台碳酸盐岩相比,下寒武统牛蹄塘组早期成岩碳酸盐岩凝块的δ44/40Ca值要重得多。考虑到在下寒武统地层中观察到丰富的自生碳酸盐岩,它们在早寒武统海洋钙同位素质量平衡中的作用值得进一步研究。因此,黑色页岩中的早期成岩碳酸盐凝块可为了解孔隙水和海水钙同位素信号以及地质历史上早期成岩和海洋钙循环提供宝贵的信息。
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引用次数: 0
Organic matter binding detrital grains contributing to ooid formation and small shelly fossil preservation, a case from the middle Cambrian, southern North China 华北南部中寒武世的一个案例:有机质结合碎屑颗粒有助于类卵石的形成和小型搁架化石的保存
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-09-06 DOI: 10.1016/j.sedgeo.2024.106740
Yazhou Hu , Timothy P. Topper , Junming Zhou , Zhao Wang , Bing Pan , Yue Liang , Fan Liu , Zhifei Zhang

Siliciclastic grains, characterized by concentrated Al, Si, K and other elements, are typical components of ooids, but their distribution and contribution to ooid formation are uncertain. Coatings have played a significant role in small shelly fossil preservation in early Cambrian phosphate or phosphatic carbonates. However, the relationship between ooid construction and the preservation of small shelly fossils has not been fully elucidated. Herein, we report well-developed flaggy ooids containing siliciclastic grains from a middle Cambrian carbonate–siliciclastic depositional system in North China. We observe that ooids consist of multiple layers of dark and light laminae. The dark laminae with a high organic content and flexible appearance are interpreted as biofilms. The distribution of detrital grains is closely coupled with these dark laminae and the filamentous structures around fossil shells, which indicates that the detrital particles are bound by the biofilms or filamentous structures. The high occurrence and compacted nature of siliciclastic particles observed in these ooids reveal that detrital grains could be the main contributing factor in ooid formation in the middle Cambrian Longwanggou section. Those flaggy ooids composed of clay-size detrital grains finely mimic the shell morphology and microstructure, providing another important window for the preservation of small shelly fossils in the Cambrian.

硅质岩粒的特征是富含 Al、Si、K 和其他元素,是类鸟粪岩的典型成分,但它们的分布和对类鸟粪岩形成的贡献还不确定。在寒武纪早期的磷酸盐或磷酸盐碳酸盐中,涂层在小型搁架化石的保存中发挥了重要作用。然而,类鸟粪状结构与小型类鸟粪状化石保存之间的关系尚未完全阐明。在此,我们报告了华北中寒武统碳酸盐-硅质岩沉积系统中发育良好、含有硅质岩颗粒的旗状卵石。我们观察到卵岩由多层深色和浅色层理组成。深色层理有机质含量高,外观柔韧,被解释为生物膜。碎屑颗粒的分布与这些深色层状结构和化石贝壳周围的丝状结构密切相关,这表明碎屑颗粒是被生物膜或丝状结构结合在一起的。在这些卵岩中观察到的硅质颗粒的高出现率和致密性表明,碎屑颗粒可能是中寒武统龙王沟段卵岩形成的主要因素。这些由粘土大小的碎屑颗粒组成的旗状卵石精细地模拟了贝壳的形态和微观结构,为寒武纪小型壳状化石的保存提供了另一个重要的窗口。
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引用次数: 0
Grain textural bias in detrital single-mineral provenance studies 碎屑岩单矿物出处研究中的晶粒纹理偏差
IF 2.7 2区 地球科学 Q1 GEOLOGY Pub Date : 2024-09-01 DOI: 10.1016/j.sedgeo.2024.106731
Xiaotian Shen , Xing Jian , Wei Zhang , Ping Guan

Detrital single-mineral geochemistry and geochronology are strong tools in provenance studies and indicate great potentials in addressing issues in earth sciences. Various biases (both natural and artificial) exist objectively and may mislead provenance interpretations. Both the sedimentary sorting process and hand-picking in-laboratory processing may lead to analyzed grain textural (e.g., size and shape) variability and thus may introduce biases in single-mineral provenance analysis. Here, we take the Mesozoic–Cenozoic Qaidam basin, northeastern Tibet, as an example to investigate the relationship between single-mineral grain texture and detrital zircon geochronological and detrital tourmaline, rutile and garnet geochemical data and to explain how grain texture affects detrital single-mineral provenance interpretations. Results indicate that Precambrian zircons take less proportions in coarse (>125 μm), subrounded and high aspect ratio (>2) fractions than Phanerozoic zircons. Parent rock lithology discrimination results of detrital tourmaline and garnet in different grain size fractions show significant differences. Zr-temperature values of detrital rutile have an increasing trend with increasing grain size. The geochemistry of detrital tourmaline, rutile and garnet shows no dependence with grain aspect ratio and roundness. We suggest that inheritance of grain texture features from parent rocks is the major reason. Detrital zircons from recycled (meta)sedimentary rocks tend to be smaller and more rounded than those from igneous rocks. Detrital tourmaline, rutile and garnet grains from different parent rock types vary in size. Grain textural bias may cause the underestimated contributions of the Qilian Shan to the Cenozoic Qaidam basin if small detrital zircons were not involved in the analysis. Quantitative description of the source-to-sink system of the Cenozoic Qaidam is also influenced by grain textural bias. This study highlights the underestimated grain textural bias in single-mineral provenance studies. We suggest that a comprehensive understanding of potential sedimentary sources, depositional processes, sample petrographic features and laboratory analysis procedures is important to reliable provenance interpretations and to related implications in earth sciences.

碎屑单一矿物地球化学和地质年代学是来源研究的有力工具,在解决地球科学问题方面具有巨大潜力。各种偏差(自然的和人为的)客观存在,可能会误导出处解释。沉积分选过程和实验室处理过程中的手工挑选都可能导致分析颗粒纹理(如大小和形状)的变化,从而可能在单矿物出处分析中引入偏差。在此,我们以西藏东北部中生代-新生代柴达木盆地为例,研究单矿物晶粒质地与锆英石和电气石、金红石、石榴石地球化学数据之间的关系,并解释晶粒质地如何影响单矿物产地解释。结果表明,与新生代锆石相比,前寒武纪锆石中粗粒(125微米)、近圆形和高纵横比(2)组分所占比例较少。不同粒度分部的碎屑电气石和石榴石的母岩岩性判别结果显示出显著差异。随着晶粒尺寸的增大,金红石的Zr-温度值呈上升趋势。非晶质电气石、金红石和石榴石的地球化学与晶粒长宽比和圆度无关。我们认为,从母岩继承晶粒纹理特征是主要原因。与来自火成岩的锆石相比,来自再循环(元)沉积岩的锆石往往更小、更圆。来自不同母岩类型的碎屑电气石、金红石和石榴石晶粒大小不一。如果在分析中不涉及小的锆英石,那么晶粒质地的偏差可能会导致低估祁连山对新生代柴达木盆地的贡献。对新生代柴达木源-汇系统的定量描述也会受到颗粒纹理偏差的影响。本研究强调了单矿物出处研究中被低估的颗粒纹理偏差。我们认为,全面了解潜在的沉积来源、沉积过程、样品岩相特征和实验室分析程序对于可靠的出处解释和地球科学的相关影响非常重要。
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Sedimentary Geology
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