Micrite envelopes are common early diagenetic features in marine carbonate grains. Most case studies of micrite envelopes focus on those with calcium-carbonate compositions. This paper documents a new type of lacustrine dolomicrite envelopes, coating both terrigenous grains and bioclasts, which developed in the upper Shahejia Formation of early Oligocene age in the middle of the Bohai Bay Basin. These dolomicrite envelopes on grains in a lacustrine mixed sedimentary environment are puzzling for their formation and linkage with the porosity preservation of porosity among grains. We investigate the microstructure and formation mechanism of these dolomicrite envelopes that coat grains through the study of the mineralogy, petrology and porosity characteristics. These studies show that there are two occurrences of the dolomicrite envelopes, i.e., coating on detrital grains and coating on carbonate grains, with a multi-layer microstructure. A potential two stage model to interpret the formation of dolomicrite envelopes incorporates an initial illite coating followed by dolomite encrustation. The illite coating played an important role in the precipitation of the dolomite. Post-envelope diagenetic processes include sparry cementation and destructive dissolution. The quantitative content of dolomicrite envelopes positively correlates with the preserved porosity, which suggests that their formation contributed to resisting compaction and protecting porosity among grains. Indeed, the dolomicrite envelopes appear to have aided in maintaining a kind of extremely high-quality reservoir for hydrocarbon exploration within the Shahejia Formation of the Bohai Bay Basin. In addition, the coating film seems to be conducive to the exchange of anions, thereby resulting in the dissolution of interior feldspar-, bioclast- or ooid-grains. In summary the Shahejia Formation of the Bohai Bay Basin provides a new type of dolomicrite envelope on grains in a lacustrine setting.
Siliciclastic grains, characterized by concentrated Al, Si, K and other elements, are typical components of ooids, but their distribution and contribution to ooid formation are uncertain. Coatings have played a significant role in small shelly fossil preservation in early Cambrian phosphate or phosphatic carbonates. However, the relationship between ooid construction and the preservation of small shelly fossils has not been fully elucidated. Herein, we report well-developed flaggy ooids containing siliciclastic grains from a middle Cambrian carbonate–siliciclastic depositional system in North China. We observe that ooids consist of multiple layers of dark and light laminae. The dark laminae with a high organic content and flexible appearance are interpreted as biofilms. The distribution of detrital grains is closely coupled with these dark laminae and the filamentous structures around fossil shells, which indicates that the detrital particles are bound by the biofilms or filamentous structures. The high occurrence and compacted nature of siliciclastic particles observed in these ooids reveal that detrital grains could be the main contributing factor in ooid formation in the middle Cambrian Longwanggou section. Those flaggy ooids composed of clay-size detrital grains finely mimic the shell morphology and microstructure, providing another important window for the preservation of small shelly fossils in the Cambrian.
Detrital single-mineral geochemistry and geochronology are strong tools in provenance studies and indicate great potentials in addressing issues in earth sciences. Various biases (both natural and artificial) exist objectively and may mislead provenance interpretations. Both the sedimentary sorting process and hand-picking in-laboratory processing may lead to analyzed grain textural (e.g., size and shape) variability and thus may introduce biases in single-mineral provenance analysis. Here, we take the Mesozoic–Cenozoic Qaidam basin, northeastern Tibet, as an example to investigate the relationship between single-mineral grain texture and detrital zircon geochronological and detrital tourmaline, rutile and garnet geochemical data and to explain how grain texture affects detrital single-mineral provenance interpretations. Results indicate that Precambrian zircons take less proportions in coarse (>125 μm), subrounded and high aspect ratio (>2) fractions than Phanerozoic zircons. Parent rock lithology discrimination results of detrital tourmaline and garnet in different grain size fractions show significant differences. Zr-temperature values of detrital rutile have an increasing trend with increasing grain size. The geochemistry of detrital tourmaline, rutile and garnet shows no dependence with grain aspect ratio and roundness. We suggest that inheritance of grain texture features from parent rocks is the major reason. Detrital zircons from recycled (meta)sedimentary rocks tend to be smaller and more rounded than those from igneous rocks. Detrital tourmaline, rutile and garnet grains from different parent rock types vary in size. Grain textural bias may cause the underestimated contributions of the Qilian Shan to the Cenozoic Qaidam basin if small detrital zircons were not involved in the analysis. Quantitative description of the source-to-sink system of the Cenozoic Qaidam is also influenced by grain textural bias. This study highlights the underestimated grain textural bias in single-mineral provenance studies. We suggest that a comprehensive understanding of potential sedimentary sources, depositional processes, sample petrographic features and laboratory analysis procedures is important to reliable provenance interpretations and to related implications in earth sciences.