Sedimentary Geology最新文献

The Oceanic Anoxic Event 1a (OAE1a), or the Selli Event, occurred in the early Aptian (~120 Ma) and represents an episode of global carbon-cycle perturbation caused by substantial greenhouse gas emissions, leading to profound environmental and climatic changes. However, our understanding of the impact of OAE1a in the eastern Tethys region, particularly regarding regional volcanic activities in southern Tibet and their influence on environmental changes, remains limited. Here we presented high-resolution inorganic and organic geochemical data from marine sediments of the lower Aptian Gucuo Formation in southern Tibet (eastern Tethys). This study aims to reveal the impact of volcanic activity and related regional to global environmental perturbations, such as continental weathering, detrital input, and bioproductivity. Our results suggested that the lower Aptian sediments in southern Tibet were influenced by regional volcanic activity linked to the disintegration of eastern Gondwana. Continental weathering showed a declining trend preceding the OAE1a, followed by a significant increase at the onset of OAE1a associated with regional volcanic activities in southern Tibet. Additionally, changes in weathering intensity at the Gucuo area coincided with contemporaneous weathering signals observed in the western Tethyan and Boreal realms, indicating a supra-regional intensification of continental weathering at this time. Increased fluvial detrital input revealed heightened continental runoff at the onset of OAE1a, driven by elevated continental weathering. The role of marine primary productivity during the early Aptian was governed by regional volcanism, global climate, and hydrological cycling. Prior to OAE1a, nutrient-rich inputs from regional volcanic sources and volcanism-induced climate variation controlled bioproductivity evolution. High biological paleoproductivity at the onset of OAE1a was associated with increased nutrient input under enhanced continental weathering and riverine runoff linked to warm and humid climates. This study contributes to our understanding of organic carbon distribution in the eastern Tethys region and its correlation with TOC patterns observed in the western Tethys realm.

In hydrogeology, a key challenge involves identifying patterns within ancient formations to forecast the distribution of fluid pathways and barriers to permeability, as well as comprehending the palaeohydrological system and its changes over time. This study addresses two main research inquiries concerning fluid flow: firstly, the influence of dolomitization induced by paleosols on flow characteristics, and secondly, the implications for fluid flow pattern distribution in continental sedimentary units. The objectives are pursued through: (1) meticulous, high-resolution measurements of porosity and permeability coupled with well-log data from an outcrop and two boreholes; (2) investigation of petrographic features of diagenetic minerals and their ages using the UPb geochronology system; and (3) an integration of these methodologies to grasp rock properties and fluid flow at a broader scale. Findings suggest that early dolomitization in continental sequences significantly affects fluid flow properties across the basin. The development of paleosols triggered early dolomitization, supported by UPb geochronology evidence. Subsequent groundwater migration along hydraulic gradients, influenced by fluctuations in the local aquifer's water table, facilitated the vertical distribution of dolomitization. Dolomitization occurred in residual pores resulting from initial mineral alteration, early lithifying the sediment and preventing mechanical compaction, thus preserving porosity. During migration events, fluids moved vertically along local faults and horizontally through the dolomitized layers of the formation, which likely remained porous at the time, leading to substantial silica mineralization.

Speleothems are among the most important archives for past climatic and environmental change. Calcite recrystallization can modify the authigenic structure and geochemical composition of the speleothems and affect the reliability of calcite stalagmites as repositories of authigenic geochemical proxies of past climates and environments. The criteria for distinguishing primary from secondary speleothem calcite, and the conditions (open or semi-closed) of speleothem calcite recrystallization remain poorly understood. Thus, in this study, we investigated the fabric, geochemical composition, and recrystallization dynamics of a partially recrystallized calcite stalagmite (DDH-Z-2) from Didonghe Cave in Shaanxi Province, China, through petrographic observations, fluorescence microscopy, and geochemical analyses (stable isotopes, trace elements, UTh isotopes). We found that: (1) in the DDH-Z-2 stalagmite, open elongated columnar calcite recrystallized into compact elongated columnar calcite. Particulate organic matter and fulvic and humic acids were removed during recrystallization, while aromatic compounds were preserved and became incorporated into the secondary calcite; (2) calcite recrystallization was affected by multiple factors, including external fluid chemistry, primary calcite microstructure, and organic matter; (3) calcite recrystallization occurred under open, fluid-buffered conditions for alteration of the stable isotopes (δ¹⁸O and δ¹³C) and trace elements (Mg, Sr, U). The effect of external fluid composition on trace element (Mg, Sr) composition of secondary calcite varied across the stages of calcite recrystallization. Caution should, therefore, be exercised when using geochemical proxies in stalagmites composed of inclusion-free elongated columnar calcite: such calcite is likely to be recrystallized, and thus record the composition of reactive fluids at the time of recrystallization. Regarding the geochemical system of speleothem diagenesis, the contribution of the parent material and the sources of reactive fluids are key factors to consider.

The present investigation aims to analyze the depositional environment, sequence stratigraphy, and geochemistry of the Early–Middle Eocene succession in the Laki Range of the Southern Indus Basin, Pakistan. The sequence is subsequently correlated with other sections within the Southern Indus Basin, Central Indus Basin, Upper Indus Basin, and Hazara Basin in Pakistan. For this study, the Lakhra and Laki formations were sampled from four sections in the Laki Range. Based on detailed outcrop observations, eight lithofacies were identified including four clastic lithofacies (CLF-1 to 4) and four limestone lithofacies (LLF-1 to 4). Similarly, based on detailed petrographic examination, seven microfacies were identified in limestone units. Considering the biotic paleoecology, facies texture, and chemical composition, depositional environments were assigned to the microfacies and lithofacies. All the microfacies, and the shale and sandstone lithofacies (CLF-1 and CLF-4) represent shallow inner to deeper outer-shelf settings whereas the other two lithofacies (CLF-2 and CLF-3) represent deltaic and tidal flat settings, respectively. All the microfacies and lithofacies information was used to establish sequence stratigraphy for the studied strata. The top of the Lakhra Formation and the whole of the Laki Formation in the Bara Nala Section (BNS) represent two complete, and two partial, third-order sequences, further divided into fourth order and small-scale cycles. The sequence's development is primarily influenced by regional and local tectonics. The regional correlation of the Indus Basin and Hazara Basin indicates that the regional basin's bathymetry and resultant depositional sequence were significantly influenced by the Himalayan Orogeny. The regional depositional pattern indicates that subsequent to India–Asia collision, the closure of eastern Tethys took place in a temporal succession from northwestern to the southwestern parts of the Indus Basin. In the Central Indus Basin, marine environments persisted until the Priabonian Stage (SBZ20) compared to those of the Upper (SBZ11–12) and Southern (SBZ13–14) Indus basins. This study offers valuable insights into both the local and regional depositional frameworks and the influence of local and regional tectonics on a carbonate platform evolution.

The processes responsible for reddening of Continental Red Beds (CRBs) and the relationship between color variation and paleoenvironmental conditions are presented focusing on a comprehensive multi-proxy study of Permian sediments in the Bohemian Massif, Czechia. The investigation incorporates facies analysis, quantitative color assessment using diffuse Vis-spectral reflectance (DRS), optical and electron microprobe microscopy, bulk-rock (XRF and XRD), and in-situ geochemistry (laser-ablation ICP-MS). Results indicate a progressive drying trend from the Cisuralian to Guadalupian series in studied continental red sediments. Different facies indicate the change of the sedimentary environment from a deep lacustrine environment (lower part of Rudník Member, Cisuralian) to a fluvial floodplain and eolian environment (Trutnov Formation, Guadalupian). Examination of the three major categories (white, gray–green and red sediments) identified in the studied continental red beds indicates that diagenetic alteration of clay minerals and biotite was the main source of iron fueling the growth of hematite responsible for their red color. Early diagenetic processes and paleoenvironmental conditions, particularly the oxidizing or reducing conditions play a key role in the red sediment formation. It is suggested that later diagenetic stages are incapable of coloring non-red, iron-rich sediments formed in deep anoxic lacustrine environments. Microbial activities and reducing fluids have been identified as the main factors in the formation of gray–green sediments forming distinct reduction zones. The reduction spots formed during the early stages of diagenesis (eodiagenesis), and they were likely never red. In contrast, reduction strips, initially exhibiting a red hue, underwent a color change during more advanced stages of diagenesis (mesodiagenesis).

The lithofacies architecture and depositional evolution of the Lower Mississippian (Tournaisian) Pekisko Formation in the subsurface of the Hawk Hills area in northwestern Alberta have been established by integrating detailed core work and well log data. The formation is composed of skeletal-peloidal limestones and argillaceous limestones that were deposited along the northern flank of the Peace River Embayment, a semi-restricted and tectonically active oceanic re-entrant located along the western margin of Laurasia at low paleolatitude. Lithofacies associations recognized in the study area include the outer ramp to slope (LA 1), outer ramp (LA 2) and mid ramp (LA 3), which are stacked into three decameter-scale, deepening-upward and aggradational cycles that are of regional extent and have meter-scale deepening and shallowing-upward trends. A previously unrecognized paleosol horizon at the top of decameter-scale cycle 2, indicating widespread subaerial exposure of the ramp, is interpreted as a sequence boundary that divides the Pekisko and Shunda formations in the study area (and possibly elsewhere in the Peace River Embayment) into two third-order sequences, each consisting of transgressive and highstand systems tracts. The Pekisko Formation in the study area is interpreted to represent a low-energy, temperature-stratified ramp that was mainly homoclinal, but with transient, distal steepening occurring in the southern part of the study area. Ramp deposition was strongly affected by basement-fault reactivation causing differential subsidence and uplift in the Peace River Embayment. The paleogeography and paleoceanographic conditions of the embayment favored upwelling currents and development of a temperature-stratified ramp, as well as the formation of heterozoan carbonate deposits and mid ramp facies of predominantly packstones and wackestones. This depositional scenario is atypical, as most other documented examples of the Pekisko Formation and other Lower Mississippian ramp successions in western North America and western Europe are characterized by moderate to high-energy, mid to inner ramp facies deposited in open-ocean conditions. The results of this study contribute to an improved understanding of the range of depositional settings along the western margin of Laurasia during the Early Mississippian and demonstrate the applicability of the thermocline-stratified ramp model, with some modification, to ramps in semi-restricted embayments and other low energy settings.

Epicontinental basins are extremely prone to major paleogeographic changes, and this will directly affect any organic matter (OM) preserved in the depositional record. In this study the Middle–Late Miocene successions in the northern Pannonian Basin System were investigated via sedimentological, petrographic, and geochemical analyses of cores from the Danube Basin to reveal the interplay of factors driving the character of the OM. In the late Middle Miocene (~12.3 Ma), the Central Paratethys Sea maintained normal marine salinity, with dysoxic bottom waters in a distal basin floor environment rich in aquatic OM. The last rifting phase followed during the Late Miocene and led to formation of the deep Lake Pannon. Like seawater, the brackish lake water still also contained sulfate. These open lacustrine deposits (~11.6–10.0 Ma) reveal OM sourced from submerged/floating macrophytes and algae, and humid conditions are indicated by the preponderance of deciduous trees and shrubs on shores. The study identifies hybrid event beds (HEBs) on Lake Pannon's floor (~10.0–9.3 Ma), with currents redepositing mud and OM, resulting in similarities between the Middle Miocene and Late Miocene successions. Turbidite deposition (~9.3–9.0 Ma) from the paleo-Danube induced a shift in OM, replacing algae with terrestrial input. Complete isolation from the main water masses of Lake Pannon (~9.0–8.9 Ma) altered its sources of OM, transitioning from algae to macrophytes, and caused a drop in salinity, likely associated with a humidity peak. The subsequent deltaic dominance (~8.9–8.6 Ma) features well-developed topset lakes, swamps, and floodplain forests, reflecting warm temperate to subtropical climates. The Middle–Upper Miocene deposits studied here are source rocks with fair to very good richness and poor to fair generative potential, and contain kerogen types III and IV, while type II is rare. The rapid paleoenvironmental changes observed over the order of ~100 kyr caused the complete switching of OM type and delivery, giving an indication of the complexity of epicontinental basins.

Marine red beds (MRBs) are often attributed to specific redox environments during syndepositional and early diagenetic phases. During the Middle Ordovician, a succession of reddish, deeper-water nodular argillaceous limestones (i.e., Zitai and Kuniutan formations) were deposited along the margin of Yangtze Platform in South China. However, the origin of their color remains enigmatic. In this study, we investigated the Middle Ordovician MRBs from a borehole core newly drilled in the Lower Yangtze area of South China whose stratigraphy frameworks are constrained by carbon isotope and biostratigraphy. This study investigates the pigmentation of these MRBs by integrating petrographic observations, elemental geochemistry, diffusive reflectance spectrometry (DRS), and scanning electron microscope (SEM) coupled with energy dispersive X-ray spectrometry (EDS). DRS results show that the red pigment is caused by hematite particles in submicron- to micron-level size. SEM demonstrates that the hematite grains are either detrital grains with traces of physical transport from terrestrial source, or flaky amorphous hematite aggregates situated within the calcite crystal interstices, implicating both syndepositional and early diagenetic origins, respectively. In terms of the geochemical result of the bulk rocks, the close positive correlation between Al₂O₃ and Fe₂O₃ indicates that the iron pigment materials may mainly originate from terrestrial Fe-bearing phyllosilicates. These observations are also consistent with the distribution patterns of rare earth elements (REEs) in carbonate leachates. The MRB limestones are characterized by MREE-bulged patterns and close to ~1 Ce anomalies, suggesting active reductive dissolution and subsequent reprecipitation of iron oxides during diagenesis in pore systems. This study proposes that the coloration of Middle Ordovician MRBs in Lower Yangtze Platform was linked to the enhanced input of terrestrial clay minerals rich in iron. The reductive dissolution released iron ions from terrestrial detrital and allowed subsequent reprecipitation of iron-oxides in pore water system during the fluid-buffered diagenesis. In this light, hematites formed during both the syndepositional and diagenetic processes thus could have involved the coloration of the Middle Ordovician carbonate red beds in this case.

Fine-grained rocks have historically been interpreted as a product of the settling of fine fractions in low-energy environments. However, recent studies have suggested that in these environments, more dynamic and complex processes operate. These processes involve a much more diverse set of sedimentary processes than those previously assumed. The lithological homogeneity of clayey successions, associated with the obliteration of their primary characteristics by diagenetic and/or weathering processes, makes it difficult to interpret depositional processes and understand the paleoenvironment. To contribute to a better comprehension of the mechanisms of transport and deposition of fine-grained rocks in a siliciclastic mud-dominated succession, as well as their depositional site, the present study aims at the detailed analysis of a continuous drill core. This core contains a thick Devonian succession consisting essentially of shale from the Ponta Grossa Formation (Paraná Basin, Brazil). Throughout the analyzed succession, a wide variety of sedimentary structures have been identified, such as parallel laminations, wave-ripple cross-stratification, hummocky cross-stratification, normal grading, and gutter casts. These structures show the constant performance of high-energy flows, which are configured as important deposition and/or rework agents. The integrated analysis of facies and trace fossils has proven to be more efficient for paleoenvironmental characterization than isolated approaches. This is because facies and ichnofacies (e.g., Cruziana, with its proximal, impoverished, archetypal, and distal expressions; Skolithos and Glossifungites) can be easily correlated, facilitating the identification of facies associations. This approach not only allows for the interpretation of a shallow marine platform with a gentle slope (ramp shelf) paleoenvironment of moderate to high energy, subject to storm wave action, but also enables the identification of the particular characteristics of deposits from different sub-environments (proximal to distal offshore, offshore transition, shoreface to offshore transition, and prodelta) and their deposition mechanisms. Furthermore, the facies associations are useful for highlighting the variations formed in response to oscillations of the relative sea level and changes in sedimentary input.