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Sourcing and nuclear magnetic resonance: new applications for old materials 采购和核磁共振:旧材料的新应用
Pub Date : 2018-05-20 DOI: 10.1080/20548923.2019.1643549
I. Pianet, A. Gutiérrez Garcia-M., M. Savin, Pilar Lapuente Mercadal, Marta Sánchez de la Torre, François‐Xavier Le Bourdonnec
ABSTRACT Solid-state nuclear magnetic resonance, which enables the characterization of structures of a variety of materials whatever their crystallinity/amorphous state, is used in the present work to determine the provenance of two raw materials, namely marbles and cherts. Regarding marbles, the 13C NMR signal of the carbonate function contains information about both the Fe content in its area and the presence of calcium substitutions in the calcite crystal in its linewidth. Regarding cherts, discriminant information is provided by both 29Si and 27Al NMR: the 29Si area signal depends on the paramagnetic ion content of the material, and the 27Al spectra give information both on the aluminosilicate content and its distribution in tecto- and layer-lattice aluminosilicates. As an application, we use the differences observed from one source to another to determine the provenance of archaeological finds. GRAPHICAL ABSTRACT
固态核磁共振能够表征各种材料的结构,无论其结晶度或非晶态,在本工作中用于确定两种原材料的来源,即大理石和燧石。对于大理岩,碳酸盐函数的13C核磁共振信号包含其区域内的铁含量和方解石晶体线宽中钙取代的存在信息。对于燧石,29Si和27Al核磁共振都提供了判别信息:29Si区域信号取决于材料的顺磁离子含量,27Al光谱提供了硅铝酸盐含量及其在构造和层晶格硅铝酸盐中的分布信息。作为一种应用,我们使用从一个来源到另一个来源观察到的差异来确定考古发现的来源。图形抽象
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引用次数: 4
Time-averaging and the spatial scale of regional cultural differentiation in archaeological assemblages 考古组合中区域文化差异的时间平均和空间尺度
Pub Date : 2018-01-01 DOI: 10.1080/20548923.2018.1504490
Galen A. Miller-Atkins, L. Premo
ABSTRACT The degree to which societies differ in dress, diet, laws, and language appears to be such an integral part of today's human experience that some researchers think of it as a hallmark of so-called “modern human behavior.” Yet it remains unclear to what extent the current pattern of relatively low within-region cultural variation paired with relatively high between-region cultural variation can be assessed in time-averaged Paleolithic assemblages. Here, we use a spatially explicit agent-based model to begin to examine how time-averaging can affect the spatial scale of similarity among culturally transmitted variants in archaeological assemblages. Our results show that time-averaging, alone, can increase the scale of local spatial association among the relative frequency of the most prevalent cultural variant in an archaeological landscape. Our findings have important implications for archaeological interpretations of the spatial scale of regional cultural differentiation (or lack thereof) in the Paleolithic record and beyond.
社会在服饰、饮食、法律和语言上的差异程度似乎是当今人类经验的一个组成部分,一些研究人员认为这是所谓“现代人类行为”的一个标志。然而,目前尚不清楚的是,在时间平均的旧石器时代组合中,区域内相对较低的文化差异与区域间相对较高的文化差异相匹配的模式在多大程度上可以评估。在这里,我们使用一个空间显式的基于主体的模型来开始研究时间平均如何影响考古组合中文化传播变异的空间相似性尺度。我们的研究结果表明,单独的时间平均可以增加考古景观中最流行的文化变体相对频率之间的局部空间关联规模。我们的发现对旧石器时代及以后的区域文化差异(或缺乏差异)的空间尺度的考古解释具有重要意义。
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引用次数: 16
Identifying sources of fibre in Chinese handmade papers by phytoliths: A methodological exploration 植物岩鉴定中国手工纸纤维来源的方法学探索
Pub Date : 2018-01-01 DOI: 10.1080/20548923.2018.1475454
Tao Li
ABSTRACT This paper proposed phytoliths as promising for identifying and distinguishing sources of fibre in Chinese handmade papers. For an initial methodological exploration, two types of Raw Xuan (unprocessed Xuan paper) and the two plant materials used in making them—namely rice straw and bark from blue sandalwood (Pteroceltis tatarinowii Maxim.)—were collected. The dry ashing method was used to extract phytoliths from Raw Xuan and its plant materials. The results can be summarized as follows. First, phytoliths characteristic of rice (Oryza sativa) were abundant in both rice straw and Raw Xuan. By looking for rice phytoliths, it is possible to tell whether or not rice straw fibre is used in a particular paper. Second, hair cell phytoliths were observed in considerable quantities in blue sandalwood bark, but absent in the examined papers. Heat experiments showed that phytoliths in blue sandalwood were resistant to long-term heat and they would unlikely be eliminated when exposed to the heat in papermaking (with heat source barely above 200°C). It is hypothesised that they dissolved while cooked in an alkaline pH (limewater). Further studies are necessary to understand whether phytoliths in blue sandalwood—while cooked in limewater—undergo morphological changes and, if yes, how. GRAPHICAL ABSTRACT
摘要:本文提出植物岩是鉴别中国手工纸纤维来源的重要材料。为了进行初步的方法论探索,我们收集了两种未经加工的宣纸和两种用于制作宣纸的植物材料——稻草和蓝檀香树皮。采用干法灰化法从生玄及其植物原料中提取植物岩。结果可以总结如下。首先,水稻(Oryza sativa)的植物岩特征在水稻秸秆和生玄中都很丰富。通过寻找水稻植物岩,可以判断特定纸张中是否使用了水稻秸秆纤维。其次,在蓝檀香树皮中观察到相当数量的毛细胞植物岩,但在被检查的论文中没有。热实验表明,蓝檀香中的植物岩耐长期高温,在造纸过程中(热源仅高于200°C),它们不太可能被消除。据推测,它们在碱性(石灰水)中煮熟时会溶解。进一步的研究是必要的,以了解在石灰水中煮熟的蓝檀香中的植物岩是否会发生形态变化,如果是,是如何发生的。图形抽象
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引用次数: 3
19th century ornamented metal trays from Greece and Turkey: metallurgy and provenance 来自希腊和土耳其的19世纪装饰金属托盘:冶金和来源
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2018.1436804
Despoina Kotzamani, V. Kantarelou, I. Karatasios, Marianna Zacharia
ABSTRACT Twelve ‘Japanned’ metal trays from Greece and Turkey, dated in the 19th century, were subjected to macroscopic and microscopic examination (stereoscopy, metallography, scanning electron microscopy) as well as to XRF and SEM-EDX analysis. The trays represent two stylistic types made of wrought iron either tin-plated or protected with a primer. Two were manufactured by forging while the rest were made by rolling prior to die forming with drop hammers or machine presses. Wrought iron was produced indirectly from cast iron with fossil fuels. Only in one case charcοal fuel was implied. Most pure iron was recognized for four trays dated at the end of the 19th century. Three of them also revealed the deliberate incorporation of metallic manganese while one of them was found to be alloyed. The other metals used such as copper, brass, silver and tin as also the methods applied, seem to follow the industrial evolution of the iron substrate but more analysis is required. As regards origin, the metallurgical results, even limited, combined with historical information, indicated that the metals/techniques used, were probably originally produced in west Europe although the supply of materials could have depended on different sources.
来自希腊和土耳其的12个19世纪的“日本”金属托盘进行了宏观和微观检查(立体、金相、扫描电子显微镜)以及XRF和SEM-EDX分析。托盘代表两种风格类型的锻铁要么镀锡或保护底漆。其中两种是通过锻造制造的,而其余的则是在用落锤或机器压力机模压成型之前通过轧制制造的。熟铁是用化石燃料间接从铸铁中生产出来的。只有在一个案例中使用了碳ο燃料。最纯的铁被认为是19世纪末的四个托盘。其中三颗还显示故意加入了金属锰,而其中一颗被发现是合金。所用的其他金属,如铜、黄铜、银和锡,以及所采用的方法,似乎遵循铁衬底的工业演变,但需要更多的分析。关于起源,冶金结果,即使是有限的,结合历史资料,表明所使用的金属/技术,最初可能是在西欧生产的,尽管材料的供应可能依赖于不同的来源。
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引用次数: 0
Roman cooking vessels (ollae): a preliminary study of the material from the Pontine region, Central Italy 罗马烹饪器皿(ollae):对意大利中部庞廷地区材料的初步研究
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2018.1445824
B. Borgers, G. Tol, T. de Haas
ABSTRACT This paper presents the petrographic analysis of cooking vessels (ollae) from the Pontine region, Central Italy, dated between the 4th and the 1st centuries BC. Cooking vessels of three surveys in different parts of the Pontine Plain and around Norba, in the Lepine foothills, are considered. The considered time-span covers the period in which the Pontine region became integrated in the Roman state until the end of the Republic, and cooking vessels have much to tell us about the region's integration in production and distribution systems, and whether changes occurred therein. The petrographic study shows that the cooking pots were produced and distributed at regional and supra-regional scales. The production and distribution systems that are tentatively inferred show aspects of continuity and change during the time-span considered. Roman cooking vessels that circulated in the Pontine region between the 4th and the 3rd centuries BC had a supra-regional and regional provenance. During the 2nd and the 1st centuries BC, the region continued to have access to these products, as well as to other ones that were produced within and outside the region. Furthermore, the distribution of supra-regional products increased, whereas the importance of existing regional centres decreased in favour of others.
本文介绍了公元前4世纪至公元前1世纪意大利中部Pontine地区的烹饪容器(ollae)的岩石学分析。在蓬廷平原的不同地区和勒平山麓的诺尔巴周围的三个调查的烹饪容器被考虑在内。所考虑的时间跨度涵盖了Pontine地区融入罗马国家的时期,直到共和国结束,烹饪容器告诉我们很多关于该地区生产和分配系统的整合,以及其中是否发生了变化。岩石学研究表明,该炊具是在区域和超区域尺度上生产和分布的。试探性推断的生产和分配系统在考虑的时间跨度内显示出连续性和变化的方面。公元前4世纪至3世纪在本庭地区流通的罗马烹饪器皿具有超区域和区域起源。在公元前2世纪和1世纪,该地区继续可以获得这些产品,以及该地区内外生产的其他产品。此外,超区域产品的分配增加了,而现有区域中心的重要性则下降,有利于其他区域中心。
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引用次数: 3
Technological implications of neo-formed hematite crystals in ceramic lead glazes 陶瓷铅釉中新形成赤铁矿晶体的技术意义
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2017.1419675
Roberta Di Febo, J. Molera, T. Pradell, O. Vallcorba, C. Capelli
ABSTRACT Hexagonal neo-formed crystallites have been observed in thin section of different medieval and post-medieval lead-glazed ceramics. Although they are clearly visible in thin section using plane polarized light, their plate shape makes them barely seen on the polished cross sections. Basal sections have never been found on the polished sections and only few transversal very thin sections could be seen. In this case, the morphology resembles acicular and it is not possible to analyze them properly by SEM–EDX because the crystals are very thin and the glaze surrounding is analyzed as well. Micro-Raman microscopy was carried out directly on the polished thin sections. This technique allows specific areas as small as 1 μm in diameter to be analyzed and it is able to characterize inclusions that are not found on the glaze surface. However, the wavenumber features observed cannot be assigned to a specific compound. The thickness of the crystallites (a few hundred nanometers) seems to be responsible for the low sensitivity of the Raman instrumentation. 15 × 15 μm2 micro-X-ray diffraction patterns using synchrotron radiation (SR-μXRD) in transmission geometry were obtained from the crystals using the same thin section preparation. SR-μXRD was able to localize the crystallites and avoid the overlapping signals corresponding to other mineral phases. In this way, the hexagonal crystallites present in the glaze have been unambiguously identified as hematite crystallites. Finally, some replications were made under laboratory-controlled conditions to determine the firing conditions in the formation of those crystallites. The presence of hematite coexisting with melanotekite indicates a firing temperature <925°C, while the presence of only hematite suggests a firing temperature >925°C
在不同的中世纪和后中世纪铅釉陶瓷薄片中观察到六方新形成的晶体。虽然使用平面偏振光在薄片上可以清楚地看到它们,但它们的板状形状使它们在抛光截面上几乎看不见。在抛光剖面上从未发现基底剖面,只有少数横向非常薄的剖面可以看到。在这种情况下,形态类似针状,不可能通过SEM-EDX正确地分析它们,因为晶体非常薄,并且也分析了釉面周围。微拉曼显微镜直接在抛光薄片上进行。该技术允许对直径小至1 μm的特定区域进行分析,并且能够表征在釉面上没有发现的夹杂物。然而,所观察到的波数特征不能分配给特定的化合物。晶体的厚度(几百纳米)似乎是拉曼仪器灵敏度低的原因。利用同步辐射(SR-μXRD)在透射几何上获得了15 × 15 μm2的微x射线衍射图。SR-μXRD能够对晶体进行定位,避免了与其他矿相相对应的重叠信号。通过这种方法,釉中存在的六方晶已被明确地确定为赤铁矿晶。最后,在实验室控制的条件下进行了一些重复实验,以确定这些晶体形成的烧成条件。赤铁矿与黑曜石共存,表明烧成温度为925℃
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引用次数: 11
Characterisation and Analysis of Metallic Artefacts from the Pylos Archaeological Museum 皮洛斯考古博物馆金属文物的特征和分析
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2018.1456742
M. Kylafi, A. Katakos, S. Boyatzis, E. Palamara, N. Zacharias
ABSTRACT The present study focuses on the analysis of four unique artefacts, originally recovered from a tomb complex of the Hellenistic period and now displayed at the New Pylos Archaeological Museum, Niokastro fortress of Pylos, Greece (since 2016). The items are rod-shaped, with a length between 5.5 and 14.6 cm and intricate decorative patterns. The rods were analysed following a multi-technique, non-invasive approach, using optical microscopy, XRF, SEM/EDS and FTIR. The analysis suggests that the three brown rods are made of wrought iron; successive areas of calcite crystal formations are associated with environmental depositions and corrosion defects. The white rod shows distinctly different chemical characteristics: it is composed of a thick core identified as bone and covered by a thin layer of lead. The combined microscopic, chemical and spectroscopic analysis resulted in the chemical characterisation of the artefacts and thus in a better understanding of their properties. In turn, the analysis has lead to hypotheses for the likely function of these unique artefacts (i.e. three writing implements and one decorative hinge).
本研究的重点是分析四件独特的文物,这些文物最初是在希腊化时期的一个古墓群中发现的,现在在希腊皮洛斯的新皮洛斯考古博物馆展出(自2016年以来)。这些物品呈棒状,长度在5.5到14.6厘米之间,有复杂的装饰图案。采用光学显微镜、XRF、SEM/EDS和FTIR等多技术、非侵入性方法对杆状细胞进行分析。分析表明,这三根棕色棒是由熟铁制成的;方解石晶体形成的连续区域与环境沉积和腐蚀缺陷有关。白色的棒子显示出明显不同的化学特征:它是由一个被称为骨头的厚芯组成的,上面覆盖着一层薄薄的铅。显微、化学和光谱分析相结合,得出了这些文物的化学特征,从而更好地了解了它们的性质。反过来,分析导致了这些独特的人工制品(即三个书写工具和一个装饰铰链)的可能功能的假设。
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引用次数: 0
A Landmark in the History of Chinese Ceramics: The Invention of Blue-and-white Porcelain in the Tang Dynasty (618–907 A.D.) 中国陶瓷史上的一个里程碑:唐朝(公元618-907年)青花瓷的发明
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2016.1272310
Weidong Li, Xiaoke Lu, Hongjie Luo, Xinmin Sun, Lanhua Liu, Zhiwen Zhao, M. Guo
Abstract This study investigates the origin and development of Tang blue-and-white porcelain. Test samples consist of excavated shards of blue-and-white porcelain, white porcelain, Tang tricolor pottery, and blue-on-white pottery from the Tang strata of the Baihe and the Huangye kiln sites. The chemical compositions, firing temperatures, and physical properties were studied scientifically, and multivariate statistical analysis was applied to analyze the compositional data. The results show that Tang blue-and-white porcelain developed from a mature manufacturing technology of white porcelain in the late Tang. Moreover, the type of cobalt pigment used is similar to that used for blue-on-white pottery. This study contributes to our understanding of the invention of Tang blue-and-white porcelain. Statement of significance In recent years, several shards of blue-and-white porcelain have been found in the late Tang strata of the Huangye and the Baihe kiln sites in Gongyi district of Henan Province (Henan Provincial Institute of Cultural Relics and Archaeology 2005,17; 2007; 2009,22). Notably, these are the only pieces of blue-and-white wares of the Tang dynasty that have been excavated at a kiln site. For the very first time, with data analysis of the chemical compositions and comparisons among pottery and porcelain throughout distinct time periods of the Tang Dynasty, this study explicates the invention of Tang blue-and-white porcelain from a scientific standpoint. Derived from Tang tricolor pottery, blue-on-white pottery and, especially, white porcelain production, raw materials and firing techniques lay the groundwork for the emergence of blue-and-white wares. The invention of Tang blue-and-white porcelain marks a crucial milestone in the developmental history of ancient Chinese ceramics.
摘要本研究考察了唐代青花瓷的起源和发展。测试样品包括从白河和黄野窑遗址的唐代地层中出土的青花瓷、白瓷、唐代三色陶和青花陶碎片。对其化学成分、烧成温度和物理性质进行了科学研究,并采用多元统计分析方法对成分数据进行了分析。结果表明,唐代青花瓷是由晚唐成熟的白瓷制造技术发展而来的。此外,所使用的钴颜料类型与用于青花瓷的颜料相似。这有助于我们了解唐代青花瓷的发明。近年来,在河南省巩义区黄野窑和白河窑遗址的晚唐地层中发现了几块青花瓷碎片(河南省文物考古研究所2005,17;2007;2009年,22)。值得注意的是,这些是唯一在窑址出土的唐代青花瓷。本研究首次通过对唐代不同时期陶器和瓷器的化学成分的数据分析和比较,从科学的角度阐述了唐代青花瓷的发明。青花瓷,特别是白瓷的生产、原料和烧制技术为青花瓷的出现奠定了基础。唐代青花瓷的发明是中国古代陶瓷发展史上一个重要的里程碑。
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引用次数: 4
The sanctuary of Hercules in Sesklo Region, Volos, Greece: an archaeometric approach of the archaic bronze objects 希腊Volos的Sesklo地区的赫拉克勒斯神庙:古代青铜器的考古方法
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2018.1424301
Evaggelia Stamelou, Argyroula Doulgeri-Intzesiloglou, Eleni Asderaki-Tzoumerkioti, M. Vaxevanopoulos
ABSTRACT The study of the bronze offerings obtained from the Sanctuary of Hercules in the area of Sesklo, Municipality of Volos, Thessaly, Greece is presented in this paper. The objects were examined initially with non-destructive followed with invasive methods in order to better understand their manufacture technology. The provenance of copper is also briefly discussed.
本文介绍了从希腊色萨利沃罗斯市塞斯克洛地区的赫拉克勒斯神庙获得的青铜祭品的研究。为了更好地了解它们的制造技术,首先用非破坏性方法对这些物体进行了检查,然后用侵入性方法进行了检查。并对铜的来源作了简要讨论。
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引用次数: 4
Kastro Palaia settlement, Volos, Greece: a diachronical technological approach to bronze metalwork 希腊Volos的castro Palaia定居点:青铜金属制品的历时技术方法
Pub Date : 2017-12-15 DOI: 10.1080/20548923.2018.1427182
E. Asderaki-Tzoumerkioti, T. Rehren, E. Skafida, M. Vaxevanopoulos, P. Connolly
ABSTRACT The paper examines diachronically the technological knowledge and the level of copper metallurgy at Kastro Palaia, Volos, in Magnesia, examining various objects with dates from the Early Bronze Age through to the Early Christian era. Of the 70 objects that have been examined so far using pXRF, a small sample was selected for further metallographic and chemical analyses. In this way, the manufacturing processes for the production of each object were identified, as well as the alloy used. Combining the results of these two methods with the typology of the objects provided safe conclusions concerning the technological knowledge and the specialisation of metal production at Kastro Palaia from the Bronze Age to the Early Christian era. In the end, the potential provenance of the copper was also examined.
本文考察了镁州Volos的castro Palaia的技术知识和铜冶金水平,研究了从早期青铜器时代到早期基督教时代的各种物品。在迄今为止使用pXRF检测的70个物体中,选择了一个小样本进行进一步的金相和化学分析。通过这种方式,确定了生产每个物体的制造过程,以及所使用的合金。将这两种方法的结果与物品的类型学相结合,可以得出关于卡斯特罗帕拉亚从青铜器时代到早期基督教时代的技术知识和金属生产专业化的可靠结论。最后,对铜的潜在来源进行了分析。
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引用次数: 6
期刊
STAR: Science & Technology of Archaeological Research
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