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Effects of Vermicompost on Soil and Plant Health and Promoting Sustainable Agriculture 蚯蚓堆肥对土壤和植物健康的影响及促进可持续农业
Q2 SOIL SCIENCE Pub Date : 2023-11-10 DOI: 10.3390/soilsystems7040101
Ivan Oyege, Maruthi Sridhar Balaji Bhaskar
This review highlights the potential of vermicompost and its derived products as sustainable and eco-friendly solutions for enhancing production and pest management in grain crops. It assesses their impact comprehensively on crops such as maize, wheat, barley, rice, and pearl millet. Vermicompost improves soil quality, increases nutrient availability, boosts crop productivity, and enhances pest and disease tolerance. It acts as an organic fertilizer, enriching the soil with essential nutrients, humic acids, growth-regulating hormones, and enzymes, improving plant nutrition, photosynthesis, and overall crop quality. Furthermore, vermicompost shows promise in mitigating soil degradation and sequestering organic carbon while demonstrating the potential for pest management, including effectiveness against pests like fall armyworm (Spodoptera frugiperda). This review emphasizes the importance of integrated nutrient management and proper application strategies to maximize the benefits of vermicompost in grain crops. Factors such as the form and timing of application, efficacy against specific pests, and economic viability for different farming scales are discussed. Understanding these factors is crucial for successfully implementing and adopting vermicompost-based pest management strategies in grain crops. This review also explores the potential of vermicomposting as an eco-friendly and cost-effective solution to remediate organic contaminants, emerging contaminants, personal-care and pharmaceutical products, and microplastics. The review further identifies knowledge gaps and highlights the need for future studies to effectively utilize vermicompost and its derived products in cereal production for sustainable agriculture, contributing to global food security.
这篇综述强调了蚯蚓堆肥及其衍生产品作为可持续和生态友好的解决方案在提高粮食作物生产和病虫害管理方面的潜力。它全面评估了它们对玉米、小麦、大麦、水稻和珍珠粟等作物的影响。蚯蚓堆肥改善土壤质量,增加养分利用率,提高作物生产力,增强病虫害耐受性。它作为一种有机肥料,为土壤提供必需的营养物质,腐殖酸,生长调节激素和酶,改善植物营养,光合作用和整体作物质量。此外,蚯蚓堆肥在缓解土壤退化和固存有机碳方面显示出前景,同时也显示出害虫管理的潜力,包括对秋粘虫等害虫的防治效果。通过对蚯蚓堆肥进行综合养分管理和合理施用策略,使蚯蚓堆肥在粮食作物中的效益最大化。讨论了诸如施用形式和时间、对特定害虫的有效性以及不同养殖规模的经济可行性等因素。了解这些因素对于在粮食作物中成功实施和采用基于蚯蚓堆肥的病虫害管理策略至关重要。本综述还探讨了蚯蚓堆肥作为一种生态友好且具有成本效益的解决方案在修复有机污染物、新兴污染物、个人护理和医药产品以及微塑料方面的潜力。该综述进一步确定了知识差距,并强调需要开展未来研究,以便在谷物生产中有效利用蚯蚓堆肥及其衍生产品,促进可持续农业,促进全球粮食安全。
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引用次数: 0
Physico-Chemical Properties and Phosphorus Solubilization of Organomineral Fertilizers Derived from Sewage Sludge 污泥有机肥料的理化性质及磷的增溶作用
Q2 SOIL SCIENCE Pub Date : 2023-11-06 DOI: 10.3390/soilsystems7040100
Andre Luiz de Freitas Espinoza, Henrique Rasera Raniro, Camille Nunes Leite, Paulo Sergio Pavinato
Sewage sludge (SS) is an organic waste that may potentially be used as a slow-release source of phosphorus (P), despite the necessity for pre-treatment and its lower P content compared to soluble mineral fertilizers. For these reasons, composted sewage sludge was used to manufacture pelletized organomineral fertilizers, by mixing it with the inorganic sources monoammonium phosphate (MAP) and AshDec® (ASD) (thermochemically incinerated SS). The fertilizers were physiochemically characterized and evaluated for their P solubilization dynamics and lability in the soil. The sources tested were as follows: organic compost of sewage sludge powder (SSC) and its pelletized form (SCP), pelletized organomineral SSC + MAP (S + MAP) and SSC + ASD (S + ASD), ASD alone, compared conventional MAP and a control (nil-P). These fertilizers were applied to columns containing 50 g of soil at the dose of 100 mg P column−1 and were leached daily with 30 mL of water or 2% citric acid for 30 days. We analyzed the leachates for pH and P content. Pelletizing process resulted in denser products and promoted more gradual P release. The organomineral S + MAP was the most water-soluble recycled source, solubilizing about 70% of the total P, while the others presented much lower solubilization (<20%). In contrast, all fertilizers showed high solubility in 2% citric acid (except for S + ASD). After leaching, soil P fractionation disclosed that the P leftover in the soil remained mostly in the labile and moderately labile pools. Composting and the ASD process produced materials with slow P solubilization, being favored in acidic soils and in plant’s rhizosphere. In turn, S + MAP resulted in a promising product with intermediate P solubility, better synchronized with crop demand, potentially increasing P-use efficiency. Our results shed light in the physico-chemical properties and on the solubilization dynamics of novel organomineral products in tropical soil conditions.
污水污泥(SS)是一种有机废物,尽管需要进行预处理,而且与可溶性矿物肥料相比,其P含量较低,但它可能被用作磷(P)的缓释源。由于这些原因,堆肥污泥被用于制造颗粒状有机肥料,通过将其与无机源磷酸一铵(MAP)和AshDec®(ASD)(热化学焚烧SS)混合。对这些肥料进行了理化表征,并评价了它们在土壤中的溶磷动态和稳定性。试验来源为:有机堆肥污泥粉末(SSC)及其颗粒状(SCP),颗粒状有机污泥SSC + MAP (S + MAP)和SSC + ASD (S + ASD), ASD单独,比较常规MAP和对照(ni - p)。这些肥料施用于含有50 g土壤的柱上,剂量为100 mg P柱- 1,每天用30 mL水或2%柠檬酸浸出30天。我们分析了渗滤液的pH和P含量。制粒过程使产物更加致密,促使P释放更加缓慢。有机无机S + MAP是水溶性最高的再生源,可增溶总磷的70%左右,而其他再生源的增溶率较低(约20%)。除S + ASD外,其余肥料在2%柠檬酸中溶解度均较高。淋溶后土壤磷分异表明,土壤中剩余磷主要停留在不稳定和中等不稳定库中。堆肥和ASD过程产生的材料P溶解缓慢,有利于酸性土壤和植物根际。反过来,S + MAP产生了具有中等磷溶解度的有希望的产品,与作物需求更好地同步,可能提高磷的利用效率。我们的研究结果揭示了热带土壤条件下新型有机产物的物理化学性质和增溶动力学。
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引用次数: 0
Managing Root Parasitic Weeds to Facilitate Legume Reintroduction into Mediterranean Rain-Fed Farming Systems 管理根部寄生杂草,促进豆科植物重新引入地中海雨养农业系统
Q2 SOIL SCIENCE Pub Date : 2023-11-01 DOI: 10.3390/soilsystems7040099
Diego Rubiales
Grain and forage legumes are important sources of food and feed, key for sustainable agriculture given the environmental services they provide. However, their cultivation is hampered in the Mediterranean Basin and Near East by the widespread occurrence of the root parasitic weed crenate broomrape (Orobanche crenata). Other broomrape species such as O. minor, O. foetida, and Phelipanche aegyptica are also of local importance. As for other parasitic weeds, a number of management strategies have been proposed, but considering that temperate legumes in the area are low-input crops, these strategies are largely uneconomical or hard to achieve, leaving the use of resistant cultivars as the most desirable option. Breeding for broomrape resistance is not an easy task, but significant progress has been achieved by classical breeding and selection and will profit from recent developments in phenomics and genomics. Here, achievements and prospects in broomrape management and resistance breeding are presented and critically discussed.
谷物和草料豆类是食物和饲料的重要来源,鉴于它们提供的环境服务,对可持续农业至关重要。然而,它们在地中海盆地和近东的种植受到广泛存在的根寄生杂草圆齿帚苔(orobche crenata)的阻碍。其他雀花种类,如O. minor, O. foetida和埃及菲利潘切也在当地具有重要意义。对于其他寄生杂草,已经提出了许多管理策略,但考虑到该地区温带豆科作物是低投入作物,这些策略在很大程度上是不经济或难以实现的,因此使用抗性品种是最理想的选择。抗性育种不是一件容易的事,但经典育种和选择已经取得了重大进展,并将受益于表型组学和基因组学的最新发展。本文介绍了在锦绣菜管理和抗性育种方面取得的成就和前景,并进行了批判性的讨论。
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引用次数: 0
Advancements in Soil and Sustainable Agriculture 土壤与可持续农业进展
Q2 SOIL SCIENCE Pub Date : 2023-10-31 DOI: 10.3390/soilsystems7040098
Mohamed Houssemeddine Sellami, Antonella Lavini
The growing interest in soil health and sustainable agriculture has emerged as a paramount element in addressing the multifaceted challenges facing modern agriculture [...]
对土壤健康和可持续农业日益增长的兴趣已成为解决现代农业面临的多方面挑战的首要因素[…]
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引用次数: 0
Sediment Mercury, Geomorphology and Land Use in the Middle Araguaia River Floodplain (Savanna Biome, Brazil) 中阿拉瓜亚河漫滩(巴西稀树草原生物群系)沉积物汞、地貌和土地利用
Q2 SOIL SCIENCE Pub Date : 2023-10-27 DOI: 10.3390/soilsystems7040097
Lilian Moraes, José Vicente Elias Bernardi, João Pedro Rodrigues de Souza, Joelma Ferreira Portela, Ludgero Cardoso Galli Vieira, Carlos José Sousa Passos, Jurandir Rodrigues de Souza, Wanderley Rodrigues Bastos, Lucas Cabrera Monteiro, Ygor Oliveira Sarmento Rodrigues, José Garrofe Dorea
In order to assess the influencing factors of the presence of mercury in a river within the Savanna biome (Cerrado), we surveyed total mercury (THg) in bottom sediment from 50 lakes along 750 km of the Middle Araguaia floodplain. The sampling sites included non-urban and urban surroundings over three distinct geomorphologies. We measured water physicochemical parameters at each site and tested statistically if land use nested within the geological formation influenced the THg concentration in bottom sediments and related water parameters. Multivariate results indicate that the interaction between geological groups and land use is statistically significant (p < 0.05). Nested ANOVA and Tukey HSD tests confirmed that the geological formation with its nested land use influences the THg, pH, DO, conductivity, and TDS (p < 0.05). THg was significantly lower in Quaternary terrains (p < 0.05) and differed significantly between non-urban and urban areas in Neoproterozoic terrains (p = 0.02). The spatial projections of the THg eigenvector on the main axes with the scoring factors of the Neoproterozoic/Paleoproterozoic terrains, and urban/non-urban, confirmed the spatial correlations. These results indicate that the association of land use and geology could be the main driver of THg in the bottom sediments of lakes from the Middle Araguaia floodplain.
为了评估热带稀树草原生物群系(Cerrado)内河流中汞存在的影响因素,我们调查了中阿拉瓜亚漫滩750公里50个湖泊底部沉积物中的总汞(THg)。采样地点包括三种不同地貌的非城市和城市环境。我们测量了每个站点的水物理化学参数,并统计测试了地质地层中嵌套的土地利用是否影响底部沉积物中的THg浓度和相关的水参数。多变量结果表明,地质类群与土地利用之间的相互作用具有统计学意义(p <0.05)。巢式方差分析和Tukey HSD检验证实,地质构造及其巢式土地利用影响THg、pH、DO、电导率和TDS (p <0.05)。第四纪地形THg显著较低(p <新元古代地形非城市地区与城市地区差异显著(p = 0.02)。THg特征向量在主轴上与新元古代/古元古代地形、城市/非城市地形评分因子的空间投影证实了这种空间相关性。这些结果表明,土地利用与地质的关联可能是阿拉瓜中河滩湖底沉积物中THg的主要驱动因素。
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引用次数: 1
Sustainable Restoration of Soil Functionality in PTE-Affected Environments: Biochar Impact on Soil Chemistry, Microbiology, Biochemistry, and Plant Growth pte影响环境中土壤功能的可持续恢复:生物炭对土壤化学、微生物学、生物化学和植物生长的影响
Q2 SOIL SCIENCE Pub Date : 2023-10-26 DOI: 10.3390/soilsystems7040096
Matteo Garau, Paola Castaldi, Maria Vittoria Pinna, Stefania Diquattro, Alberto Cesarani, Nicoletta P. Mangia, Sotirios Vasileiadis, Giovanni Garau
Biochar can be useful for the functional recovery of soils contaminated with potentially toxic elements (PTEs), even if its effectiveness is variable and sometimes limited, and conflicting results have been recently reported. To shed some light on this regard, softwood-derived biochar was added at 2.5 (2.5-Bio) and 5.0% w/w (5.0-Bio) rates to an acidic (pH 5.74) soil contaminated by Cd (28 mg kg−1), Pb (10,625 mg kg−1), and Zn (3407 mg kg−1). Biochar addition increased soil pH, available P and CEC, and reduced labile Cd, Pb, and Zn (e.g., by 27, 37, and 46% in 5.0-Bio vs. the unamended soil). The addition of biochar did not change the number of total heterotrophic bacteria, actinomycetes, and fungi, while it reduced the number of Pseudomonas spp. and soil microbial biomass. Dehydrogenase activity was reduced in amended soils (e.g., by ~60 and 75% in 2.5- and 5.0-Bio, respectively), while in the same soils, urease increased by 48 and 78%. Approximately 16S rRNA gene amplicon sequencing and the Biolog community-level physiological profile highlighted a significant biochar impact (especially at a 5% rate) on soil bacterial diversity. Tomato (but not triticale) yield increased in the amended soils, especially in 2.5-Bio. This biochar rate was also the most effective at reducing Cd and Pb concentrations in shoots. Overall, these results demonstrate that 2.5% (but not 5.0%) biochar can be useful to restore the soil chemical fertility of PTE-polluted soils with limited (or null) impact on soil microbial and biochemical parameters.
生物炭对于被潜在有毒元素(pte)污染的土壤的功能恢复是有用的,即使它的有效性是可变的,有时是有限的,最近报道了相互矛盾的结果。为了阐明这一点,将软木衍生的生物炭以2.5 (2.5- bio)和5.0% w/w (5.0-Bio)的速率添加到受Cd (28 mg kg - 1)、Pb (10,625 mg kg - 1)和Zn (3407 mg kg - 1)污染的酸性(pH 5.74)土壤中。添加生物炭增加了土壤pH值、有效磷和CEC,降低了不稳定的Cd、Pb和Zn(例如,与未添加生物炭的土壤相比,5.0-Bio的土壤分别降低了27%、37%和46%)。添加生物炭对土壤中异养细菌、放线菌和真菌的总数量没有影响,但减少了假单胞菌的数量和土壤微生物生物量。在改良土壤中,脱氢酶活性降低了(例如,2.5- bio和5.0-Bio分别降低了60%和75%),而在相同的土壤中,脲酶活性增加了48%和78%。大约16S rRNA基因扩增子测序和生物群落水平生理剖面强调了生物炭对土壤细菌多样性的显著影响(特别是在5%的速率下)。改良土壤中番茄(小黑麦除外)产量增加,特别是在2.5-Bio土壤中。这种生物炭速率在降低地上部Cd和Pb浓度方面也是最有效的。总体而言,这些结果表明2.5%(而不是5.0%)的生物炭可用于恢复pte污染土壤的土壤化学肥力,而对土壤微生物和生化参数的影响有限(或零)。
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引用次数: 0
Sediments as Sentinels of Pollution Episodes in the Middle Estuary of the Tinto River (SW Spain) 西班牙西南丁托河中河口沉积物污染事件的哨兵特征
Q2 SOIL SCIENCE Pub Date : 2023-10-24 DOI: 10.3390/soilsystems7040095
Luis Miguel Cáceres, Francisco Ruiz, Javier Bermejo, Lucía Fernández, María Luz González-Regalado, Joaquín Rodríguez Vidal, Manuel Abad, Tatiana Izquierdo, Antonio Toscano, Paula Gómez, Verónica Romero
Estuaries are excellent environments for identifying pollution episodes that have affected river basins, as their sediments are the final destination of some of the pollutants. This paper studies the geochemical evolution of five elements (As, Co, Cu, Pb, Zn) in a core extracted from the middle estuary of the Tinto River (SW Spain). The results are based on facies interpretation, ICP atomic emission spectrometry analysis, the application of a regional background to obtain the geoaccumulation index and dating. The main objective of this communication is the detection of natural or anthropogenic pollution episodes in the middle estuary of the Tinto River (SW Spain). Four pollution episodes have been detected: (1) ~5.8 cal. kyr BP, probably caused by natural acid rock drainage processes derived from the oxidation of the Iberian Pyritic Belt deposits found in its drainage basin; (2) 4.7–4.5 kyr BP, coming from the first mining activities and characterized by a significant increase in the concentrations of the five elements analyzed; (3) 1850–1960 interval, coinciding with intensive mining and characterized by increasing values of As and, to a lesser extent, Pb (intensive mining); and (4) the second half of the 20th century, with high element concentrations from mining and industrial effluents. All episodes show an increase in their geochemical classes deduced from the geoaccumulation index. This communication can serve as an example for assessing the impact of different types of pollution in estuarine environments.
河口是识别影响流域的污染事件的绝佳环境,因为它们的沉积物是一些污染物的最终目的地。本文研究了西班牙托托河河口中部提取的岩心中As、Co、Cu、Pb、Zn五种元素的地球化学演化。研究结果是基于相解释、ICP原子发射光谱分析、应用区域背景获得地聚集指数和定年。本通讯的主要目的是检测蒂诺河(西班牙西南部)中部河口的自然或人为污染事件。发现了4次污染事件:(1)~5.8 cal. kyr BP,可能是由伊比利亚黄铁矿带沉积物氧化形成的天然酸性岩石排水过程引起的;(2) 4.7 ~ 4.5 kyr BP,来自第一次采矿活动,其特征是五种元素的浓度显著增加;(3) 1850 ~ 1960年段,与密集开采期重合,以As值增加为特征,Pb值增加幅度较小,为密集开采期;(4) 20世纪下半叶,矿区和工业废水中元素含量较高。根据地质聚集指数推断,各期的地球化学分类均有所增加。这种交流可以作为评估不同类型的污染对河口环境的影响的一个例子。
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引用次数: 0
Tracking Soil Health Changes in a Management-Intensive Grazing Agroecosystem 管理集约化放牧农业生态系统土壤健康变化的跟踪研究
Q2 SOIL SCIENCE Pub Date : 2023-10-23 DOI: 10.3390/soilsystems7040094
Tad Trimarco, Joe E. Brummer, Cassidy Buchanan, James A. Ippolito
Management-intensive Grazing (MiG) has been proposed to sustainably intensify agroecosystems through careful management of livestock rotations on pastureland. However, there is little research on the soil health impacts of transitioning from irrigated cropland to irrigated MiG pasture with continuous livestock rotation. We analyzed ten soil health indicators using the Soil Management Assessment Framework (SMAF) to identify changes in nutrient status and soil physical, biological, and chemical health five to six years after converting irrigated cropland to irrigated pastureland under MiG. Significant improvements in biological soil health indicators and significant degradation in bulk density, a physical soil health indicator, were observed. Removal of tillage and increased organic matter inputs may have led to increases in β-glucosidase, microbial biomass carbon, and potentially mineralizable nitrogen, all of which are biological indicators of soil health. Conversely, trampling by grazing cattle has led to increased bulk density and, thus, a reduction in soil physical health. Nutrient status was relatively stable, with combined manure and fertilizer inputs leading to stabilized plant-available phosphorous (P) and increased potassium (K) soil concentrations. Although mixed effects on soil health were present, overall soil health did increase, and the MiG system appeared to have greater overall soil health as compared to results generated four to five years earlier. When utilizing MiG in irrigated pastures, balancing the deleterious effects of soil compaction with grazing needs to be considered to maintain long-term soil health.
管理集约化放牧(MiG)已被提出,通过精心管理牧场上的牲畜轮作,可持续地加强农业生态系统。然而,目前对水田向水牧轮作过渡对土壤健康的影响研究较少。我们使用土壤管理评估框架(SMAF)分析了10个土壤健康指标,以确定在MiG下将灌溉农田转化为灌溉牧场后5至6年的养分状况和土壤物理、生物和化学健康的变化。土壤生物健康指标显著改善,土壤物理健康指标容重显著下降。免耕和增加有机质投入可能导致β-葡萄糖苷酶、微生物生物量碳和潜在矿化氮的增加,所有这些都是土壤健康的生物指标。相反,放牧牛的践踏导致体积密度增加,从而降低了土壤的物理健康。土壤养分状况相对稳定,粪肥配施使土壤速效磷(P)稳定,钾(K)含量增加。尽管存在对土壤健康的混合影响,但总体土壤健康确实有所增加,与四到五年前的结果相比,MiG系统似乎具有更大的总体土壤健康。在灌溉牧草中利用MiG时,需要考虑平衡土壤压实和放牧的有害影响,以保持土壤的长期健康。
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引用次数: 0
Soil Carbon Stock and Indices in Sandy Soil Affected by Eucalyptus Harvest Residue Management in the South of Brazil 巴西南部桉叶采伐对沙质土壤碳储量及指数的影响
Q2 SOIL SCIENCE Pub Date : 2023-10-21 DOI: 10.3390/soilsystems7040093
Jackson Freitas Brilhante de São José, Luciano Kayser Vargas, Bruno Britto Lisboa, Frederico Costa Beber Vieira, Josiléia Acordi Zanatta, Elias Frank Araujo, Cimelio Bayer
There has been limited research on the effect of eucalyptus harvest residue management on soil organic carbon (SOC) in subtropical environments. This research evaluated the effect on soil C indices of the following eucalyptus harvest residue managements: AR, with all forest remnants left on the soil; NB, where bark was removed; NBr, in which branches were removed; NR, which removed all residues; and NRs, which is same as NR but also used a shade net to prevent the litter from the new plantation from reaching the soil surface. C stocks within the soil depths of 0–20 cm and 0–100 cm increased linearly with the C input from eucalyptus harvest residues. In the layer of 0–20 cm, the lowest soil C retention rate was 0.23 Mg ha−1 year−1, in the NR treatment, while in the AR treatment, the retention rate was 0.68 Mg ha−1 year−1. In the 0–100 cm layer, the highest C retention rate was obtained in the AR (1.47 Mg ha−1 year−1). The residues showed a high humification coefficient (k1 = 0.23) and a high soil organic matter decomposition rate (k2 = 0.10). The carbon management index showed a close relationship with the C input and tree diameter at breast height.
目前对亚热带桉树采伐剩余物管理对土壤有机碳(SOC)影响的研究较少。本研究评价了桉树采伐剩余物管理对土壤C指数的影响:AR,所有森林剩余物都留在土壤中;注意,树皮被去除;NBr,其中的分支被移除;NR,去除所有残留物;NRs与NR相同,但也使用遮荫网来防止新人工林的凋落物到达土壤表面。0 ~ 20 cm和0 ~ 100 cm土壤深度的碳储量随着桉树采伐剩余物的碳输入呈线性增加。在0 ~ 20 cm土层,NR处理的土壤碳保持率最低,为0.23 Mg ha−1年−1,AR处理的土壤碳保持率最低,为0.68 Mg ha−1年−1。在0 ~ 100 cm层,AR的碳滞留率最高(1.47 Mg ha−1 year−1)。腐殖化系数高(k1 = 0.23),有机质分解率高(k2 = 0.10)。碳管理指数与碳输入和胸高树径密切相关。
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引用次数: 0
Comparison between Chemical and Biological Degradation Processes for Perfluorooctanoic Acid 全氟辛酸化学与生物降解过程的比较
Q2 SOIL SCIENCE Pub Date : 2023-10-20 DOI: 10.3390/soilsystems7040091
Xuhan Shu, Rama Pulicharla, Pratik Kumar, Satinder Kaur Brar
Perfluorooctanoic acid (PFOA) is a perfluoro compound that contains an eight-carbon perfluoroalkyl chain followed by a carboxylic acid function group. The C-F bound possesses a strong bond energy of approximately 485 kJ/mol, rendering PFOA thermally and chemically stable. It has found applications in water-resistant coating and is produced either by degrading other long-chain perfluorinated carboxylic acids or fluorotelomer alcohol. PFOA is challenging to further degrade during water treatment processes, leading to its accumulation in natural systems and causing contamination. Research has been conducted to develop several methods for its removal from the water system, but only a few of these methods effectively degrade PFOA. This review compares the most common chemical degradation methods such as photochemical, electrochemical, and sonochemical methods, to the cutting-edge biodegradation method. The chemical degradation and biodegradation methods both involve the stepwise degradation of PFOA, with the latter capable of occurring both aerobically and anaerobically. However, the degradation efficiency of the biological process is lower when compared to the chemical process, and further research is needed to explore the biological degradation aspect.
全氟辛酸(PFOA)是一种含八碳全氟烷基链和羧酸官能团的全氟化合物。C-F键具有约485 kJ/mol的强键能,使PFOA具有热稳定性和化学稳定性。它已在防水涂料中得到应用,并可通过降解其他长链全氟羧酸或氟聚体醇来生产。在水处理过程中,PFOA很难进一步降解,导致其在自然系统中积累并造成污染。研究开发了几种从水系统中去除PFOA的方法,但这些方法中只有少数几种有效地降解PFOA。本文对光化学、电化学、声化学等常用的化学降解方法与生物降解方法进行了比较。化学降解和生物降解方法都涉及到PFOA的逐步降解,后者既可以发生好氧降解,也可以发生厌氧降解。然而,与化学工艺相比,生物工艺的降解效率较低,生物降解方面的研究有待进一步深入。
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引用次数: 0
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Soil Systems
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