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A comprehensive review on natural convection in various shaped enclosures by FEM: Engineering applications 有限元法在不同形状外壳内自然对流的综合研究:工程应用
Q1 Social Sciences Pub Date : 2025-08-23 DOI: 10.1016/j.sajce.2025.08.009
Asif Hasan, Mohammad Mokaddes Ali, Shakhawat Hossain, Neamul Haque Siam, Asaduzzaman Rony, Al-Amin Shohan
Natural convection within enclosed cavities plays a critical role in heat and mass transfer across a wide range of engineering applications. Buoyancy flows are a fundamental aspect of many optimized systems currently deployed, including passive cooling of electronic devices, thermoregulation of solar collectors, and insulation of buildings to store energy used by aerospace systems. Recent advancements in nanofluids, magnetohydrodynamics (MHD), and smart materials have increased the functional applicability of natural-convection-based systems, and modern forms of the Finite Element Method (FEM) have become essential in the accurate modelling of heat and fluid flow in geometrically complex enclosures. The review explores the dynamic fields in detail but with particular focus on how they are applicable in heat exchangers in industry, microfluidic devices, biomedical incubators, and environmental ventilation systems. The review further explores localized heat sources, vortex formation due to embedded obstacles, porous media effects, and the synergistic influence of thermal and magnetic fields. This review investigates how integrating the Finite Element Method (FEM) with artificial intelligence, entropy-based optimization, and experimental validation can transform the design and advancement of next-generation thermal management systems. The findings underscore FEM’s utility as a multi-physics simulation tool for real-world thermal challenges, with particular relevance to South Africa’s growing demand for energy-efficient buildings, renewable energy solutions, and sustainable manufacturing technologies.
在广泛的工程应用中,封闭腔内的自然对流在传热传质中起着至关重要的作用。浮力流动是目前部署的许多优化系统的基本方面,包括电子设备的被动冷却,太阳能集热器的温度调节,以及用于航空航天系统的存储能量的建筑物的绝缘。纳米流体、磁流体力学(MHD)和智能材料的最新进展增加了基于自然对流系统的功能适用性,现代形式的有限元方法(FEM)在几何复杂外壳的热量和流体流动的精确建模中变得至关重要。该综述详细探讨了动态领域,但特别关注它们如何应用于工业热交换器、微流体装置、生物医学孵化器和环境通风系统。综述进一步探讨了局域热源、嵌入障碍物涡的形成、多孔介质效应以及热磁场的协同影响。本文探讨了如何将有限元法与人工智能、基于熵的优化和实验验证相结合,从而改变下一代热管理系统的设计和进步。研究结果强调了FEM作为现实世界热挑战的多物理场模拟工具的实用性,特别是与南非对节能建筑、可再生能源解决方案和可持续制造技术日益增长的需求相关。
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引用次数: 0
Water hyacinth derived activated carbon electrode materials for water defluoridation using capacitive deionization technology 水葫芦衍生的电容去离子水除氟活性炭电极材料
Q1 Social Sciences Pub Date : 2025-08-23 DOI: 10.1016/j.sajce.2025.08.013
Hassan Johnson Kalilo , Joyce Elisadiki , Maheswara Rao Vegi , Said Ali Hamad Vuai
Safe water is a vital component of human life that requires purification to reduce the concentration of ionic pollutants using appropriate water treatment techniques, such as capacitive deionization (CDI) water treatment technology. The porous activated carbon electrode materials have prepared via the carbonization of water hyacinth plants followed by chemical activation using KOH at different temperatures (400-700°C with an increment of 100°C) labeled as CWH-400, WHAC-500, WHAC-600 and WHAC-700 all being activated for 1 h where CWH represents carbonized water hyacinths and WHAC represents water hyacinths activated carbon. The activation temperature has a significant effect on the specific surface area of the porous carbon prepared, as it increases from 464.67 m²/g for CWH-400 to 1020.01 m²/g for WHAC-700. The defluoridation experiments were done using water samples with initial fluoride concentrations of 4.21, 4.61 and 3.51 mg/L for water samples from Arusha (A), Manyara (B) and Shinyanga (C) respectively when the 2 V was supplied to the cell with 10 mL/min flow rate at 3 hours charging time. The defluoridation results were 1.28, 1.37, and 1.15 mg/L for water samples A, B, and C, respectively. The WHAC-700 electrode was found to possess a capacitance of 501.89 F/g, exhibiting removal efficiencies of 69.60%, 70.28%, and 67.24% for water samples from Arusha (A), Manyara (B), and Shinyanga (C), respectively, at a potential of 2 V with a charging time of 3 hours. Therefore, the water hyacinth plants are suitable precursors for preparing porous activated carbon electrodes to be used in a CDI cell for the defluoridation of any water sample.
安全水是人类生活的重要组成部分,需要使用适当的水处理技术进行净化,以降低离子污染物的浓度,例如电容性去离子(CDI)水处理技术。通过将水葫芦炭化,然后在不同温度(400-700℃,增加100℃)下用KOH进行化学活化制备多孔活性炭电极材料,标记为CWH-400, WHAC-500, WHAC-600和WHAC-700,其中CWH代表炭化水葫芦,WHAC代表水葫芦活性炭。活化温度对制备的多孔碳的比表面积有显著影响,从CWH-400的464.67 m²/g增加到WHAC-700的1020.01 m²/g。分别在Arusha (A)、Manyara (B)和Shinyanga (C)的水样中进行初始氟浓度为4.21、4.61和3.51 mg/L的除氟实验,以10 mL/min的流量向电池供电2 V,充电3小时。水样A、水样B、水样C的除氟结果分别为1.28、1.37、1.15 mg/L。WHAC-700电极的电容为501.89 F/g,对阿鲁沙(a)、Manyara (B)和Shinyanga (C)水样的去除率分别为69.60%、70.28%和67.24%,充电时间为3小时。因此,水葫芦植物是制备多孔活性炭电极的合适前体,用于CDI电池中用于任何水样的除氟。
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引用次数: 0
The potential of the Bland-Altman method in chemical engineering 布兰德-奥特曼方法在化学工程中的潜力
Q1 Social Sciences Pub Date : 2025-08-22 DOI: 10.1016/j.sajce.2025.08.012
Mrs.Cecilia M. Botha , Shawn C. Liebenberg , Frederik H. Conradie , Mr.Abraham F. van der Merwe
Statistical methods play a crucial role in the analysis and interpretation of complex data in chemical engineering research. However, parametric statistical approaches may not always suffice in addressing the intricacies of data analysis within design, process modelling and process development. This paper explores the application potential of less conventional statistical methods in the context of chemical engineering. The application potential of these methods will be demonstrated using recent findings from a study conducted on a low-flux flue gas desulphurisation circulating fluidised bed (FGD-CFB). We analysed the solids flux measurements in a novel, low-flux CFB system by using a less conventional statistical technique, the Bland-Altman method, and verifying the findings using the Kruskal-Wallis test. This statistical analysis validated a non-isokinetic solids sampling technique for low-flux dry and semi-dry FGD-CFBs. This case study demonstrates the applicability of this statistical method within chemical engineering, highlighting its potential beyond its traditional use in medical research. Importantly, the focus of this contribution lies not on the specific findings of the case study, but on the methodologies employed therein. This paper aims to be an educational piece to inform the chemical engineering researcher on how and why this less-used-within-engineering statistical method may be applied. It highlights the potential of utilising statistical approaches that are typically used outside the context of engineering in addressing practical engineering challenges. This paper emphasises the applicability of this statistical method in providing valuable insights into complex engineering systems. It is guided by a systematic inquiry aimed at assessing the statistical methods’ suitability for different types of data sets. By embracing this method, chemical engineers can potentially unlock new insights for research and development, facilitating innovation, sustainability, and advancement in the field.
统计方法在化学工程研究中对复杂数据的分析和解释中起着至关重要的作用。然而,参数统计方法在处理设计、过程建模和过程开发中的数据分析的复杂性时可能并不总是足够的。本文探讨了非常规统计方法在化工领域的应用潜力。这些方法的应用潜力将通过对低通量烟气脱硫循环流化床(FGD-CFB)进行的研究的最新发现来证明。我们分析了新型低通量CFB系统中的固体通量测量,使用了一种不太传统的统计技术,即Bland-Altman方法,并使用Kruskal-Wallis测试验证了结果。该统计分析验证了低通量干式和半干式FGD-CFBs的非等速固体取样技术。本案例研究证明了这种统计方法在化学工程中的适用性,突出了其在医学研究中的传统应用之外的潜力。重要的是,这篇文章的重点不在于个案研究的具体结果,而在于其中所采用的方法。本文旨在成为一篇教育文章,告知化学工程研究人员如何以及为什么可以应用这种较少使用的工程统计方法。它强调了利用统计方法的潜力,这些方法通常在工程背景之外用于解决实际的工程挑战。本文强调了这种统计方法在为复杂工程系统提供有价值的见解方面的适用性。它以系统的调查为指导,旨在评估统计方法对不同类型数据集的适用性。通过采用这种方法,化学工程师可以潜在地为研究和开发提供新的见解,促进该领域的创新,可持续性和进步。
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引用次数: 0
Life cycle assessment of facile applicable biodiesel production 简易适用生物柴油生产的生命周期评估
Q1 Social Sciences Pub Date : 2025-08-18 DOI: 10.1016/j.sajce.2025.08.011
Mohamed A. Hanafy , Rehab M. Ali , Abdallah S. Elgharbawy , Ahmed I. Osman , Mohamed A. Farrag , Abdulaziz H. Al-Anazi
Biodiesel is crucial for mitigating fossil fuel depletion and reducing environmental impacts. Herein, this approach represents a life cycle assessment (LCA) of biodiesel production from waste cooking oil (WCO) utilizing potassium carbonate (K2CO3) as a heterogeneous catalyst instead of potassium hydroxide (KOH), which is the most used catalyst in industry. However, KOH requires a 20% methanol and a 66% reaction time, higher than K2CO3. Besides, KOH is used once, and produces impure biodiesel and glycerol. While K2CO3 can be used, recovered and reused twice, which decreases the net required catalyst amount without a significant decrease in biodiesel production yield, decreases the environmental burdens, and produces purer products. When using WCO or high free fatty acid (FFA) oils, K2CO3 has the advantage of effective direct transesterification, while KOH requires post-treatment process (esterification), which means extra usage of methanol besides the acid catalyst, which is commonly H2SO4, to decrease the FFA content and avoid the saponification reaction. Therefore, this research aims to quantify the environmental burdens of biodiesel production and compare the performance of K2CO3 with that of conventional KOH. Using the ReCiPe method in SimaPro 9.5 software, the LCA adheres to ISO 14040 and 14044 standards. Key findings indicate significant impacts in climate change (0.274 kg CO2,eq), human non-carcinogenic toxicity (0.12 kg 14-DCBeq), terrestrial ecotoxicity (0.536 kg 14-DCBeq), and fossil resource scarcity (0.183 kg oileq). Methanol and K2CO3 are identified as major contributors to environmental burdens. In contrast, KOH demonstrates a less environmental impact compared to K2CO3. The economic study revealed that, for producing 250 thousand tons of biodiesel per year, the total CAPEX needed to build up the plant is around 12 M$ for both catalysts. The results proved that using K2CO3 leads to higher net profits. The study revealed that the biodiesel plant would achieve a remarkable net profit using any type of catalyst, with an advantageous economic indicator for K2CO3 over KOH, proving the high profitability of using K2CO3 as a catalyst.
生物柴油对于缓解化石燃料枯竭和减少环境影响至关重要。在此,该方法代表了从废食用油(WCO)生产生物柴油的生命周期评估(LCA),利用碳酸钾(K2CO3)作为非均相催化剂,而不是氢氧化钾(KOH),氢氧化钾是工业上最常用的催化剂。然而,KOH需要20%的甲醇和66%的反应时间,比K2CO3高。此外,KOH是一次性使用的,产生不纯的生物柴油和甘油。而K2CO3可以二次使用、回收和重复使用,在不显著降低生物柴油产量的情况下,减少了催化剂的净用量,减轻了环境负担,生产出更纯净的产品。当使用WCO或高游离脂肪酸(FFA)油时,K2CO3具有有效的直接酯交换的优势,而KOH则需要后处理(酯化),这意味着除了酸性催化剂(通常为H2SO4)外,还需要额外使用甲醇来降低FFA含量,避免皂化反应。因此,本研究旨在量化生物柴油生产的环境负担,并比较K2CO3与常规KOH的性能。使用SimaPro 9.5软件中的ReCiPe方法,LCA符合ISO 14040和14044标准。主要研究结果表明,气候变化(0.274 kg CO2,eq)、人类非致癌毒性(0.12 kg 14-DCBeq)、陆地生态毒性(0.536 kg 14-DCBeq)和化石资源稀缺(0.183 kg oileq)具有显著影响。甲醇和K2CO3被认为是造成环境负担的主要因素。相比之下,与K2CO3相比,KOH对环境的影响较小。经济研究显示,为了每年生产25万吨生物柴油,建立工厂所需的总资本支出约为1200万美元,用于两种催化剂。结果证明,使用K2CO3可以带来更高的净利润。研究表明,使用任何类型的催化剂,生物柴油装置都能获得显著的净利润,其中K2CO3的经济指标优于KOH,证明了使用K2CO3作为催化剂的高盈利能力。
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引用次数: 0
Green synthesis, characterization, antibacterial, and antifungal activity investigation of zinc oxide nanoparticles using Verbascum Sinaiticum leaf extract 马鞭草叶提取物氧化锌纳米颗粒的绿色合成、表征、抗菌及抗真菌活性研究
Q1 Social Sciences Pub Date : 2025-08-18 DOI: 10.1016/j.sajce.2025.08.007
Berie Kumie , Walelign Wubet , Tadesse Bizuayehu , Hailemichael Tegenu , Melesse Ababay , Aklilu Melese
In this study, zinc oxide nanoparticles (ZnO NPs) were eco-friendly synthesized using Verbascum sinaiticum leaf extract (VSPLE). The amount effects such as pH adjusted at (4, 6, 7, 8, 10 and 12), zinc acetate concentration (0.1, 0.2, 0.3, 0.05, and 0.025 M), reaction temperature (20, 40, 60, 80 and 100 °C), reaction time (20,40, 60, 80, 100, 120, and 140 min), and plant extract volume(1, 2, 3, 4, and 5 mL). The synthesized nanoparticles were characterized by using SEM, TGA/DTA, XRD, UV-Vis, and FT-IR spectroscopic techniques. The SEM analysis revealed that the synthesized ZnO NPs exhibited a rod-shaped morphology, and a total weight loss of 15.29 % observed at 24-544 °C in the TGA/DTA analysis, with no further weight loss above 544 °C, confirmed the high thermal stability of ZnO NPs. The XRD analysis confirmed the formation of small sized ZnO NPs with an average crystal size of 52.9 nm. The UV-Vis analysis revealed the absorption of ZnO NPs at 400 nm, and the characteristic band observed in FT-IR analysis at 635 cm⁻¹ for Zn-O stretching confirmed the formation of ZnO NPs. The biosynthesized ZnO NPs demonstrated a significant in vitro antimicrobial activity as evidenced by the inhibition zone sizes against one Gram-positive S. aureus (17.10 ± 0.17) and two Gram-negative bacteria K. pneumoniae (14.17 ± 0.29), and E. coli(12.83 ± 0.29) at 10 mg/mL using the disc diffusion method. It also showed good antifungal activity against Candida ethanolica (6.90 ± 0.10) and Saccharomyces cerevisiae (6.00 ± 0.10), support the potential of plant-mediated nanoparticle synthesis as a promising route for developing biocompatible antimicrobial agents.
本研究以马鞭草叶提取物(VSPLE)为原料,对氧化锌纳米粒子(ZnO NPs)进行了环保合成。pH值(4、6、7、8、10和12),醋酸锌浓度(0.1、0.2、0.3、0.05和0.025 M),反应温度(20、40、60、80和100℃),反应时间(20、40、60、80、100、120和140 min),植物提取物量(1、2、3、4和5 mL)。采用SEM、TGA/DTA、XRD、UV-Vis、FT-IR等光谱技术对合成的纳米颗粒进行了表征。SEM分析表明,合成的ZnO NPs呈棒状形貌,在24-544°C时,TGA/DTA分析的总失重率为15.29%,在544°C以上没有进一步失重,证实了ZnO NPs具有较高的热稳定性。XRD分析证实形成了平均晶粒尺寸为52.9 nm的小尺寸ZnO纳米粒子。UV-Vis分析显示ZnO NPs在400 nm处被吸收,FT-IR分析在635 cm(⁻¹)处观察到的ZnO - o拉伸特征波段证实了ZnO NPs的形成。采用圆盘扩散法对10 mg/mL的革兰氏阳性金黄色葡萄球菌1株(17.10±0.17)、革兰氏阴性肺炎克雷伯菌2株(14.17±0.29)和大肠杆菌2株(12.83±0.29)具有明显的抑菌作用。对乙醇假丝酵母(6.90±0.10)和酿酒酵母菌(6.00±0.10)具有良好的抑菌活性,表明植物介导的纳米颗粒合成是开发生物相容性抗菌药物的一条有前景的途径。
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引用次数: 0
Chemical characterization and antimicrobial potential of purified aceh patchouli oil (Pogostemon cablin Benth.) residue for floor cleaning product innovation 用于地板清洁产品创新的纯化亚齐广藿香油(Pogostemon cablin Benth.)残留物的化学特性和抗菌潜力
Q1 Social Sciences Pub Date : 2025-08-18 DOI: 10.1016/j.sajce.2025.08.010
Syaifullah Muhammad , Nadia Isnaini , Binawati Ginting , Hanifa Rifdah Aiman , Ernawati , Vicky Prajaputra , Elly Sufriadi
Patchouli oil residue, a by-product of vacuum distillation, remains underutilized despite its bioactive compound content. This study aimed to characterize the residue using Gas Chromatography–Mass Spectrometry (GC-MS), purify iron (Fe) contamination using activated carbon, evaluate its antimicrobial and antifungal activities, and formulate it into a floor-cleaning soap. GC-MS analysis identified patchouli alcohol (57.19%) as the dominant compound. Purification using 5 g of activated carbon for 3 hours reduced Fe content from 10.351 mg/L to 4.062 mg/L (60.7% reduction), improved residue clarity, and eliminated naphthalene, a potential contaminant. The purified residue exhibited strong antibacterial activity against Staphylococcus aureus (13.28 mm ± 1.38) and moderate activity against Escherichia coli (7.02 mm ± 0.23), as well as strong antifungal activity against Candida albicans (14.88 mm ± 2.88). The formulated floor-cleaning soap met Indonesian National Standard (SNI 1842:2019) for pH, viscosity, specific gravity, foam stability, and homogeneity. It retained bioactivity with inhibition zones of 15.89 mm (S. aureus), 6.00 mm (E. coli), and 10.89 mm (C. albicans), showing enhanced antibacterial activity against S. aureus compared to the purified residue, but slightly lower activity against E. coli and C. albicans. These findings confirm that the formulated product not only meets national standards but also offers antimicrobial functionality. This study contributes a sustainable and scientific approach to valorizing agro-industrial waste into a value-added floor-cleaning product with confirmed antimicrobial and antifungal efficacy, aligning with green chemistry and circular economy principles.
广藿香油渣是真空蒸馏的副产品,尽管其含有生物活性化合物,但仍未得到充分利用。本研究旨在利用气相色谱-质谱(GC-MS)对残渣进行表征,使用活性炭净化铁(Fe)污染,评估其抗菌和抗真菌活性,并将其配制成地板清洁皂。GC-MS分析鉴定广藿香醇(57.19%)为优势化合物。用5 g活性炭净化3小时,铁含量从10.351 mg/L降至4.062 mg/L(降低60.7%),提高了残渣的透明度,并消除了潜在的污染物萘。纯化后的菌渣对金黄色葡萄球菌(13.28 mm±1.38)具有较强的抑菌活性,对大肠杆菌(7.02 mm±0.23)具有中等抑菌活性,对白色念珠菌(14.88 mm±2.88)具有较强的抑菌活性。该配方的地板清洁皂符合印尼国家标准(SNI 1842:2019)的pH值、粘度、比重、泡沫稳定性和均匀性。其对金黄色葡萄球菌、大肠杆菌和白色念珠菌的抑制范围分别为15.89 mm、6.00 mm和10.89 mm,对金黄色葡萄球菌的抑菌活性明显增强,但对大肠杆菌和白色念珠菌的抑菌活性略低于纯化后的菌渣。这些研究结果证实,配方产品不仅符合国家标准,而且具有抗菌功能。本研究符合绿色化学和循环经济原则,为将农业工业废弃物转化为具有抗菌和抗真菌功效的增值地板清洁产品提供了可持续和科学的途径。
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引用次数: 0
Removal of sulfur compounds from sour gas using metal nano-absorbents: Process optimization 金属纳米吸收剂去除含硫气体中的含硫化合物:工艺优化
Q1 Social Sciences Pub Date : 2025-08-16 DOI: 10.1016/j.sajce.2025.08.008
Mehdi Sedaghat, Farshad Farahbod
Sour gas, a natural gas laden with significant quantities of the highly toxic and corrosive hydrogen sulfide (H2S), presents substantial environmental and economic challenges due to its sulfur content. This study explores the potential of nanotechnology to enhance hydrogen sulfide removal from sour gas. The corrosive nature of sulfur compounds necessitates substantial investments in equipment maintenance and protection, particularly within gas pipelines and storage facilities. The removal or reduction of sulfur compounds, including H2S, associated with oil and gas operations offers significant economic, environmental, and health benefits. A hybrid adsorption and magnetic field approach was employed to capture H2S from natural sour gas. The application of a magnetic field elevated the operating temperature, influencing the mobility of carbon nanotubes within the nanofluid and the nanofluid layer. Consequently, a current of 1.5 amperes resulted in a 4.8 % increase in mass transfer coefficient and a 3.6 % increase in mass flow rate. Based on the results of the analysis of variance (ANOVA), as well as the comparison of predicted and experimental data and residual plots, the degree of validity of the predicted model is considered satisfactory. This research demonstrates that the R² coefficient is 0.9972 and the Adjusted R² coefficient is 0.9948.
含硫气体是一种含有大量高毒性和腐蚀性硫化氢(H2S)的天然气,由于其含硫量,给环境和经济带来了巨大挑战。本研究探讨了纳米技术在提高酸性气体硫化氢脱除方面的潜力。硫化合物的腐蚀性需要在设备维护和保护方面进行大量投资,特别是在天然气管道和储存设施中。去除或减少与油气作业相关的硫化物(包括H2S)具有显著的经济、环境和健康效益。采用吸附-磁场混合法从天然含硫气中捕集H2S。磁场的作用提高了工作温度,影响了碳纳米管在纳米流体和纳米流体层内的迁移率。因此,1.5安培的电流导致传质系数增加4.8%,质量流率增加3.6%。方差分析(ANOVA)的结果以及预测数据与实验数据和残差图的比较表明,预测模型的效度令人满意。本研究表明,R²系数为0.9972,调整后的R²系数为0.9948。
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引用次数: 0
Quantum mechanical investigation of polypyrrole-MXene nanocomposite as an electrode material for magnesium-ion batteries 聚吡咯- mxene纳米复合材料作为镁离子电池电极材料的量子力学研究
Q1 Social Sciences Pub Date : 2025-08-14 DOI: 10.1016/j.sajce.2025.08.006
Anthony Chidi Ezika , Williams Kehinde Kupolati , Emmanuel Rotimi Sadiku , Gbolahan Joseph Adekoya
The current challenge in energy storage technologies lies in identifying efficient electrode materials for Magnesium-ion (Mg-ion) batteries, motivating the exploration of the energy storage capabilities of Polypyrrole-MXene (Ti2CO2) nanocomposites as a potential solution to enhance battery performance. Hence, in this paper, quantum mechanical simulations were employed to examine the capability of energy storage of Polypyrrole-MXene (Ti2CO2) filled nanocomposite. The electronic structures, adsorption energies, and adsorption site of Mg@PPy/MXene (Ti2CO2) nanocomposite were investigated. The results reveal that Mg-ions on MXene/PPy nanocomposite have a very high adsorption energy of -0.84 eV. The distance of Mg-ion adsorption from the MXene’s surface at the bridge site is 2.75 Å. However, its distance from the PPy is considerably farther at 2.83 Å. The electron difference study, using the charge transfer analysis, revealed that physisorption is the dominating adsorption mechanism for the Mg-ion in the system. The electrode's propensity to transport electrons during the electrochemical reaction is shown by the projected density of state (PDOS), and its energy bandgap is 0.05. Consequently, the MXene (Ti2CO2) /PPy nanocomposite might be used as an Mg-ion electrode in battery applications.
当前储能技术的挑战在于确定镁离子(Mg-ion)电池的高效电极材料,促使人们探索聚吡咯- mxene (Ti2CO2)纳米复合材料的储能能力,作为提高电池性能的潜在解决方案。因此,本文采用量子力学模拟来检验聚吡咯- mxene (Ti2CO2)填充纳米复合材料的储能能力。研究了Mg@PPy/MXene (Ti2CO2)纳米复合材料的电子结构、吸附能和吸附部位。结果表明,MXene/PPy纳米复合材料对镁离子的吸附能高达-0.84 eV。MXene在桥位的吸附距离为2.75 Å。然而,它与PPy的距离远得多,为2.83 Å。利用电荷转移分析的电子差研究表明,物理吸附是镁离子在体系中的主要吸附机制。电极在电化学反应过程中输运电子的倾向由状态的投射密度(PDOS)表示,其能带隙为0.05。因此,MXene (Ti2CO2) /PPy纳米复合材料可作为镁离子电极应用于电池。
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引用次数: 0
A review of the co-pyrolysis of low-rank coals and microalgae biomass for fuel production 低阶煤与微藻生物质共热解制备燃料研究进展
Q1 Social Sciences Pub Date : 2025-08-11 DOI: 10.1016/j.sajce.2025.08.005
Hope Baloyi , Bilal Patel
This review comprehensively examines recent advancements in the co-pyrolysis of low-rank coal and microalgae biomass. The co-pyrolysis process aims to improve coal conversion efficiency and enhance the quality of pyrolysis products while integrating renewable biomass to facilitate cleaner fuel production. The article highlights significant research progress in coal-microalgae pyrolysis studies, concentrating on pyrolysis reactions and the underlying reaction mechanisms involving low-rank coals and various microalgae species. Key factors influencing product yield distribution, such as feedstock composition, pyrolysis temperature, heating rate, catalyst use, and reaction time, are analysed in detail. The findings indicate that optimising the blend ratio between coal and biomass substantially enhances bio-oil yield, while pyrolysis temperature significantly impacts product distribution. The heating rate is crucial for promoting pyrolysis reactions, and catalysts play a vital role in improving the efficiency of the co-pyrolysis process, particularly by increasing oil yield and improving its quality. Furthermore, the combined effect of pyrolysis temperature and blend ratio greatly influences char properties. The review concludes by emphasizing both the challenges and opportunities in implementing co-pyrolysis technology for low-rank coal and microalgae biomass, while also offering future perspectives on the practical application of this novel process.
本文综述了近年来低阶煤与微藻生物质共热解的研究进展。共热解工艺旨在提高煤的转化效率,提高热解产物质量,同时整合可再生生物质,促进清洁燃料的生产。本文重点介绍了煤-微藻热解研究的重要进展,重点介绍了低阶煤与多种微藻的热解反应及其反应机理。详细分析了影响产物收率分布的关键因素,如原料组成、热解温度、升温速率、催化剂使用和反应时间。研究结果表明,优化煤与生物质的混合比例可显著提高生物油收率,而热解温度对产物分布有显著影响。升温速率对促进热解反应至关重要,催化剂在提高共热解过程效率,特别是提高油收率和质量方面起着至关重要的作用。热解温度和掺混比的共同作用对炭的性质影响较大。综述最后强调了低阶煤和微藻生物质共热解技术的挑战和机遇,同时对该新工艺的实际应用前景进行了展望。
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引用次数: 0
Freeze- and oven-drying of red ginger juice (Zingiber officinale var. Rubrum): A comparative study on physicochemical properties, bioactive retention, and microstructural characteristics 冷冻干燥和烘箱干燥红姜汁:理化性质、生物活性保持和微观结构特征的比较研究
Q1 Social Sciences Pub Date : 2025-08-10 DOI: 10.1016/j.sajce.2025.08.004
Maisaroh , Lusiana Kresnawati Hartono , Olivia Bunga Pongtuluran , Priyo Atmaji , Sri Yuliani , Wahyu Bahari Setianto , Elvi Restiawaty , Yazid Bindar
This study evaluates the influence of drying methods and oven drying temperatures on the physicochemical properties, bioactive compounds, and microstructure of red ginger (Zingiber officinale var. Rubrum) juice powder. Two drying techniques were applied, freeze-drying (FD) and oven-drying (OD) at 40 °C to 80 °C. FD preserved the highest levels of bioactive compounds, particularly 6-gingerol, but required prolonged drying (63.0-72.0 hours) and yielded lower product mass. In contrast, OD at 50 °C provided the best compromise between processing efficiency (9.3-10.0 hours) and quality retention, maintaining high levels of total phenolic content (TPC), 6-gingerol, and antioxidant activity. Drying at ≥ 60 °C caused 6-gingerol degradation into 6-shogaol, reducing antioxidant capacity and altering color due to Maillard reactions. Scanning electron microscopy (SEM) revealed that FD retained intact microstructures, whereas OD at higher temperatures induced porosity and fragmentation. Overall, OD at 50 °C is recommended as a practical and effective method for producing high-quality red ginger juice powder on an industrial scale.
本研究考察了干燥方式和烘箱干燥温度对红姜汁粉理化性质、生物活性成分和微观结构的影响。采用冷冻干燥(FD)和烘箱干燥(OD)两种干燥技术,温度为40 ~ 80℃。FD保存了最高水平的生物活性化合物,特别是6-姜辣素,但需要长时间干燥(63.0-72.0小时),产品质量较低。相比之下,50°C的OD在加工效率(9.3-10.0小时)和质量保持之间提供了最佳折衷,保持了高水平的总酚含量(TPC), 6-姜辣素和抗氧化活性。≥60℃干燥导致6-姜辣素降解为6-姜辣素,抗氧化能力降低,因美拉德反应而变色。扫描电镜(SEM)显示,FD保留了完整的微观结构,而高温下的OD则导致孔隙和碎裂。综上所述,推荐50℃OD法作为工业生产高品质红姜汁粉的实用有效方法。
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引用次数: 0
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South African Journal of Chemical Engineering
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